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During the last decade many hypotheses were suggested to explain the phenomenon of induced electrical polarization in ionic conductive media. The most reliable of these is Fredricksberg's. Fredricksberg (1962) supposed that the pore spaces of a rock is composed of successively narrow (active zones) and wide (inactive zones). He simulated these pore spaces by a synthetic material that has an extremely high resistance. The pore spaces were generally in tube forms which exhibited some constrictions. He saturated these tubes with an electrolyte of a given concentration. An electric current was passed through this model. He observed an induced polarization voltage after current interruption. He attributed the formation of this voltage to a concentration gradient which took place due to the presence of excess charges in the active zones. Fredricksberg introduced a parameter (9) which described the relation among the lengths and cross sectional areas of the wide zones, the number of ions within each zone after current interruption with the recorded polarizability. The aim of this work is to correlate Fredricksberg's parameter with a parameter determined for natural rocks and to show experimentally the validity of this hypothesis when applying for some varieties of sandstones and volcanic rocks. The new parameter will help to evaluate a relationship between the polarizability and the water-collecting properties of rocks. Herein, we used the tortuosity T of sandstone samples instead of the parameter φ which was used by Fredricksberg to represent the pore geometry within his model (tortuosity of the passes within the model). It was shown that both φ and T have the same relationship with the polarizability ν of the rock samples and if φ or T have very low or very high values the polarizability ν tends to its minimum value, i.e. the curve representing the relation between ν and T has a maximum point corresponding to an intermediate value of T. This result supports Fredricksberg's hypothesis and confirm his results on synthetic models. For volcanic rocks the formation factor F was used since it was difficult to determine the porosity of the samples and consequently to calculate the tortuosity T as for sandstone samples. Experimental results confirm those obtained from sandstone. The grain constituents of sandstone samples were represented on equilateral triangle and the magnitude of induced polarization ν of each sample was deduced and represented on this triangle. Equipolarizability values ν drawn on this triangle showed that TJ will increase as the silty fractions of the rock increase, where the center of this triangle (represents minimum porosity) has polarizability less than 0.25%. An attempt was made to determine the coefficient of anisotropy of volcanic rock samples using the induced polarization method. For this reason the polarizability was deduced by measuring the induced polarization voltage for two perpendicular directions in a fractured cubes of andesitic basalt samples the coefficient of anisotropy was found to be equal 1.18.