1. Thermoelectric studies on hydrogenated cobalt and iron
- Author
-
A. N. Nigam and R. Rani
- Subjects
inorganic chemicals ,Electrolysis ,Materials science ,Hydrogen ,Diffusion ,General Engineering ,Analytical chemistry ,chemistry.chemical_element ,law.invention ,Cathodic protection ,Nickel ,chemistry ,law ,Thermoelectric effect ,Gaseous diffusion ,Cobalt - Abstract
The thermoelectric behaviour of cobalt and iron wires subjected to cathodic hydrogen diffusion by electrolysis has been studied. Hydrogenated wire samples lose hydrogen when left to themselves. If one follows the time variation of thermo emf, conclusions regarding the unfilled part of the minority spin-d band can be drawn. Cobalt shows certain new structures not predicted by the theory. The behaviour of cobalt and iron differs from that of nickel. The extent of filling up of the band above E f,min. has been estimated, but roughly. It is found that the sequence of the amount of hydrogen diffusion by cathodic process is Ni>Co>Fe in contrast to the gaseous diffusion where we have Ni>Fe>Co. The reason for less hydrogen absorption by cobalt and iron when compared with nickel has been discussed.
- Published
- 1975
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