1. Single crystal growth of IVa-diborides from metal solutions
- Author
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H. Hayashi, Toru Imura, and K. Nakano
- Subjects
Materials science ,Single crystal growth ,Diboride ,chemistry.chemical_element ,Condensed Matter Physics ,Mole fraction ,Inorganic Chemistry ,Metal ,Solvent ,Crystallography ,Nickel ,chemistry ,visual_art ,Materials Chemistry ,visual_art.visual_art_medium ,Internal stress ,Cobalt - Abstract
The conditions of growth of TiB 2 single crystals from iron, cobalt and nickel solutions and those of ZrB 2 and HfB 2 from iron solution have been investigated and the quality of the crystals grown by this method have been characterized. The diboride crystals were formed only when the mole percent of the metal diboride and solvent metal were higher than a critical value in each case. TiB 2 crystals grown from iron contained less than 0.2 wt% Fe, those from cobalt contained about 1 wt% Co and those from nickel contained more than 1.5 wt% Ni. ZrB 2 and HfB 2 crystals from iron solution included less than 0.5 wt% Fe. Etch-pit densities of the (0001) plane of TiB 2 single crystals grown from iron were lower than those from cobalt or nickel. It was possible to obtain single crystals of low etch-pit density in the case of ZrB 2 and HfB 2 . Lang X-ray topographs of TiB 2 , ZrB 2 and HfB 2 crystals grown from iron showed images representing low internal stresses. In contrast, the topographs of TiB 2 crystals grown from cobalt and nickel showed high internal stress images.
- Published
- 1974
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