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Thiophene sulfide is difficult to be removed by hydrodesulfurization. In this study, ZnCl2-waste paper fiber activated carbon was used as adsorbent to remove thiophene sulfide from simulated oil by hydrothermal modification. Under the optimum condition of ammonia modification, the adsorption capacity of modified adsorbent to BT is 14.8 mg S/g, 2.98 times that of unmodified. BET, FTIR and Boehm analysis showed that the mesopore volume of ammonia modified adsorbent increased by 96.62% and the mesopore ratio increased from 12.58% to 43.40%, which was conducive to improving the adsorption rate. After modification, the basic groups on the surface of the adsorbent increased by 44.3 times, and –NH3+, –OH and –NH2 enhanced the electron attraction and hydrogen bonding force between the adsorbent and BT molecule. Adsorption isotherms, adsorption kinetics and adsorption thermodynamics show that the adsorption process is spontaneous, entropic and exothermic. The pseudo-second-order kinetic rate constant increases with the increase of adsorption temperature, indicating that the increase of temperature is beneficial to accelerate the adsorption rate. The adsorption desulfurization process follows the mechanism of single and multilayer adsorption mixing. The results of this study can help to reveal more clearly that biobased activated carbon can be modified to adsorb thiophene sulfide. Ammonia modified adsorbents enhance the adsorption capacity for benzothiophene [ABSTRACT FROM AUTHOR]

Objectives: This study aims to: (i) evaluate the outcome of patients with Harrington class III lesions who were treated according to Harrington classification; (ii) propose a modified surgical classification for Harrington class III lesions; and (iii) assess the efficiency of the proposed modified classification. Methods: This study composes two phases. During phase 1 (2006 to 2011), the clinical data of 16 patients with Harrington class III lesions who were treated by intralesional excision followed by reconstruction of antegrade/retrograde Steinmann pins/screws with cemented total hip arthroplasty (Harrington/modified Harrington procedure) were retrospectively reviewed and further analyzed synthetically to design a modified surgical classification system. In phase 2 (2013 to 2019), 62 patients with Harrington class III lesions were classified and surgically treated according to our modified classification. Functional outcome was assessed using the Musculoskeletal Tumor Society (MSTS) 93 scoring system. The outcome of local control was described using 2‐year recurrence‐free survival (RFS). Owing to the limited sample size, we considered P < 0.1 as significant. Results: In phase 1, the mean surgical time was 273.1 (180 to 390) min and the mean intraoperative hemorrhage was 2425.0 (400.0 to 8000.0) mL, respectively. The mean follow‐up time was 18.5 (2 to 54) months. Recurrence was found in 4 patients and the 2‐year RFS rate was 62.4% (95% confidence interval [CI] 31.6% to 93.2%). The mean postoperative MSTS93 score was 56.5% (20% to 90%). Based on the periacetabular bone destruction, we categorized the lesions into two subgroups: with the bone destruction distal to or around the inferior border of the sacroiliac joint (IIIa) and the bone destruction extended proximal to inferior border of the sacroiliac joint (IIIb). Six patients with IIIb lesions had significant prolonged surgical time (313.3 vs 249.0 min, P = 0.022), massive intraoperative hemorrhage (3533.3 vs 1760.0 mL, P = 0.093), poor functional outcome (46.7% vs 62.3%, P = 0.093), and unfavorable local control (31.3% vs 80.0%, P = 0.037) compared to the 10 patients with IIIa lesions. We then modified the surgical strategy for two subgroup of class III lesions: Harrington/modified Harrington procedure for IIIa lesions and en bloc resection followed by modular hemipelvic endoprosthesis replacement for IIIb lesions. Using the proposed modified surgical classification, 62 patients in the phase 2 study demonstrated improved surgical time (245.3 min, P = 0.086), intraoperative hemorrhage (1466.0 mL, P = 0.092), postoperative MSTS 93 scores (65.3%, P = 0.067), and 2‐year RFS rate (91.3%, P = 0.002) during a mean follow‐up time of 19.9 (1 to 60) months compared to those in the phase 1 study. Conclusion: The Harrington surgical classification is insufficient for class III lesions. We proposed modification of the classification for Harrington class III lesions by adding two subgroups and corresponding surgical strategies according to the involvement of bone destruction. Our proposed modified classification showed significant improvement in functional outcome and local control, along with acceptable surgical complexity in surgical management for Harrington class III lesions. [ABSTRACT FROM AUTHOR]