9 results on '"Nitin G. Valsange"'
Search Results
2. Synthesis and melt-spinning of partly bio-based thermoplastic poly(cycloacetal-urethane)s toward sustainable textiles
- Author
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Patric Jannasch, Nitin G. Valsange, Nicola Rehnberg, Zengwei Guo, Baozhong Zhang, Stefan Lundmark, Erik Nilsson, Niklas Warlin, and Smita V. Mankar
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chemistry.chemical_classification ,Thermogravimetric analysis ,Materials science ,Thermoplastic ,Polymers and Plastics ,Organic Chemistry ,Diol ,Bioengineering ,Solution polymerization ,Polymer ,Biochemistry ,chemistry.chemical_compound ,Monomer ,chemistry ,Chemical engineering ,Polytetrahydrofuran ,Glass transition - Abstract
A rigid diol with a cyclic acetal structure was synthesized by facile acetalation of fructose-based 5-hydroxymethyl furfural (HMF) and partly bio-based di-trimethylolpropane (di-TMP). This diol (Monomer T) was copolymerized with potentially bio-based flexible polytetrahydrofuran and diisocyanates to prepare thermoplastic poly(cycloacetal-urethane)s. A modified one-step solution polymerization protocol resulted in relatively high molecular weights (Mn ∼ 41.5–98.9 kDa). All the obtained poly(cycloacetal-urethane)s were amorphous with tuneable glass transition temperatures up to 104 °C. Thermogravimetric analysis indicated that these polymers were thermally stable up to 253 °C and had a relatively high pyrolysis char residue, which may indicate potential inherent flame resistance. Melt rheology measurements were performed to determine a suitable processing window between 165–186 °C, after which the polymer was successfully melt-spun into ∼150 meters of homogeneous fibres at 185 °C. The resulting fibres could be readily hydrolysed under acidic conditions, resulting in partial recovery of the original chemical building blocks.
- Published
- 2021
3. Biobased aliphatic polyesters from a spirocyclic dicarboxylate monomer derived from levulinic acid
- Author
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Nitin G. Valsange, Maria Nelly Garcia Gonzalez, Niklas Warlin, Smita V. Mankar, Nicola Rehnberg, Stefan Lundmark, Baozhong Zhang, and Patric Jannasch
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Adipic acid ,Condensation polymer ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Pollution ,Neopentyl glycol ,Pentaerythritol ,0104 chemical sciences ,Polyester ,chemistry.chemical_compound ,Monomer ,chemistry ,Succinic acid ,Levulinic acid ,Environmental Chemistry ,Organic chemistry ,0210 nano-technology - Abstract
Levulinic acid derived from lignocellulose is an important biobased building block. Here, we report on the synthesis and polymerization of a rigid spirocyclic diester monomer to produce polyesters and copolyesters. The monomer was prepared via a one-step acid catalyzed ketalization involving ethyl levulinate and pentaerythritol by employing a straightforward, solvent-free, and readily scalable method which required no chromatographic purification. Still, careful removal of traces of water from the spiro-diester prior to polycondensations proved crucial to avoid side reactions. A preliminary life cycle assessment (LCA) in terms of greenhouse gas (GHG) emissions indicated that the corresponding spiro-diacid tended to be environmentally favourable, producing less CO2 emission than e.g., biobased succinic acid and adipic acid. A series of aliphatic polyesters with reasonably high molecular weights was subsequently prepared in melt and modified melt polycondensations of the spiro-diester with 1,4-butanediol, 1,6-hexanediol, neopentyl glycol and 1,4-cyclohexanedimethanol, respectively. The resulting fully amorphous polyesters showed glass transition temperatures in the range 12–49 °C and thermal stability up to 300 °C. Hot-pressed films of the polyesters based on neopentyl glycol and 1,4-cyclohexanedimethanol were transparent and mechanically strong, and dynamic melt rheology showed stable shear moduli over time to indicate good processability. In addition, the spiro-diester monomer was employed in copolycondensations with diethyl adipate and 1,4-butanediol and demonstrated good reactivity and stability. Hence, the results of the present study indicate that the spiro-diester based on levulinic acid is an effective monomer for the preparation of aliphatic polyesters and other condensation polymers.
- Published
- 2021
4. Synthesis, Life Cycle Assessment, and Polymerization of a Vanillin-Based Spirocyclic Diol toward Polyesters with Increased Glass-Transition Temperature
- Author
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Stefan Lundmark, Nicola Rehnberg, Smita V. Mankar, Baozhong Zhang, Nelly Garcia Gonzalez, Niklas Warlin, Patric Jannasch, and Nitin G. Valsange
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Dimethyl terephthalate ,Materials science ,Renewable Energy, Sustainability and the Environment ,General Chemical Engineering ,Diol ,02 engineering and technology ,General Chemistry ,Dynamic mechanical analysis ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Pentaerythritol ,0104 chemical sciences ,Polyester ,chemistry.chemical_compound ,chemistry ,Polymerization ,Environmental Chemistry ,Organic chemistry ,Thermal stability ,0210 nano-technology ,Glass transition - Abstract
Bio-based rigid diols are key building blocks in the development and preparation of high performance bioplastics with improved thermal and dimensional stability. Here, we report on the straightforward two-step synthesis of a diol with a spirocyclic acetal structure, starting from bio-based vanillin and pentaerythritol. According to a preliminary life cycle assessment (LCA), the greenhouse gas emissions of this bio-based diol are significantly lower than that of bio-based 1,3-propanediol. Copolymerization of the rigid spiro-diol with 1,6-hexanediol and dimethyl terephthalate by melt polymerization yielded a series of copolyesters, which showed improved glass transition temperature and thermal stability upon the incorporation of the spiro-acetal units. The crystallinity and melting point of copolyesters decreased with increasing content of the spirocyclic backbone structures. The copolyesters containing 10% of the new diol was semicrystalline while those with 20 and 30% spiro-diol incorporated were completely amorphous. Moreover, dynamic mechanical analysis indicated that the copolyesters showed comparable storage moduli as AkestraTM, a commercial fossil-based high-performance polyester.
- Published
- 2019
5. A rigid spirocyclic diol from fructose-based 5-hydroxymethylfurfural: synthesis, life-cycle assessment, and polymerization for renewable polyesters and poly(urethane-urea)s
- Author
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Patric Jannasch, Smita V. Mankar, Sang-Hyun Pyo, Nicola Rehnberg, Stefan Lundmark, Baozhong Zhang, Maria Nelly Garcia Gonzalez, Mahmoud A. Sayed, Niklas Warlin, Nitin G. Valsange, and Rajni Hatti-Kaul
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Solid-state chemistry ,010405 organic chemistry ,Diol ,Context (language use) ,010402 general chemistry ,01 natural sciences ,Pollution ,Pentaerythritol ,0104 chemical sciences ,Polyester ,chemistry.chemical_compound ,chemistry ,Polymerization ,Environmental Chemistry ,Organic chemistry ,Glass transition ,Polyurethane - Abstract
There is currently an intensive development of sugar-based building blocks toward the production of renewable high-performance plastics. In this context, we report on the synthesis of a rigid diol with a spirocyclic structure via a one-step acid-catalyzed acetalation of fructose-sourced 5-hydroxymethylfurfural and pentaerythritol. Preliminary life cycle assessment (LCA) indicated that the spiro-diol produced 46% less CO2 emission than bio-based 1,3-propanediol. Polymerizations of the spiro-diol together with another sugar-based flexible 1,6-hexanediol for the production of polyesters and poly(urethane-urea)s were investigated, and reasonably high molecular weights were achieved when up to 20 and 60 mol% spiro-diol was used for polyesters and poly(urethane-urea)s, respectively. The glass transition temperatures (Tgs) of the polyesters and poly(urethane-urea)s significantly increased upon the incorporation of the rigid spirocyclic structure. On the other hand, it was observed that the spiro-diol was heat-sensitive, which could cause coloration and partial crosslinking when >10% (with respect to dicarboxylate) was used for the polyester synthesis at high temperatures. The results indicated that the polymerization conditions have to be carefully controlled under these conditions. However, when the spiro-diol was used for the synthesis of polyurethanes at lower temperature, the side reactions were insignificant. This suggests that the new spiro-diol can be potentially suitable toward the production of sustainable rigid polyurethane materials like coatings or foams, as well as renewable polyesters after further optimization of the polymerization conditions.
- Published
- 2019
6. A new pyrene cored small organic molecule with a flexible alkyl spacer: a potential solution processable blue emitter with bright photoluminescence
- Author
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Samuel Chang, Sergei Manzhos, Vellaisamy A. L. Roy, Fu-Lung Wong, Prakash P. Wadgaonkar, Ryuzi Katoh, Durgaprasad Shinde, Chun-Sing Lee, Nitin G. Valsange, Prashant Sonar, and Krishna Feron
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chemistry.chemical_classification ,Photoluminescence ,Carbazole ,Quantum yield ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Photochemistry ,01 natural sciences ,Catalysis ,0104 chemical sciences ,chemistry.chemical_compound ,chemistry ,Materials Chemistry ,OLED ,Moiety ,Pyrene ,Thermal stability ,0210 nano-technology ,Alkyl - Abstract
A new pyrene cored small organic molecule viz. 1,3,6,8-tetrakis(4-((5-(9H-carbazol-9-yl)pentyl)oxy)phenyl)pyrene (PY-II) was designed and synthesized. The carbazole moiety with an alkyl spacer was introduced at 1, 3, 6 and 8 positions of the pyrene core to improve the charge transport properties and solution processability. PY-II exhibited excellent solubility in common organic solvents and high thermal stability up to 345 °C. The photoluminescence quantum yield (PLQY) of PY-II in solution was found to be 0.9 with bright blue emission near 450 nm which is just appropriate for the human eye. The solution processed non-doped OLED device fabricated using PY-II as an emissive layer afforded a pure blue emission with CIE coordinates of 0.16 and 0.16, a power efficiency of 0.17 lm W−1, a maximum current efficiency of 0.41 cd A−1 and a maximum brightness of 202 cd m−2.
- Published
- 2017
7. Synthesis and characterization of polyhydrazides and poly(1,3,4-oxadiazole)s containing multiple arylene ether linkages and pendent pentadecyl chains
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Nitin G. Valsange, Prakash P. Wadgaonkar, and Bhausaheb V. Tawade
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Terephthalic acid ,Materials science ,Polymers and Plastics ,Organic Chemistry ,Arylene ,Oxadiazole ,Ether ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Chloride ,0104 chemical sciences ,Isophthalic acid ,chemistry.chemical_compound ,Monomer ,chemistry ,Pyridine ,Polymer chemistry ,Materials Chemistry ,medicine ,0210 nano-technology ,medicine.drug - Abstract
A new diacylhydrazide monomer, namely, 4-(4-(4-(4-(hydrazinocarbonyl)phenoxy)-2-pentadecylphenoxy)phenoxy) benzohydrazide (HPPDPB), was synthesized starting from 4-(4-hydroxyphenoxy)-3-pentadecylphenol. HPPDPB was polycondensed with terephthalic acid chloride (TPC), isophthalic acid chloride (IPC) and a mixture of TPC and IPC (50:50 mol%) to obtain polyhydrazides containing multiple arylene ether linkages in the backbone and pendent pentadecyl chains. Polyhydrazides were subsequently cyclized in the presence of phosphorus oxychloride to obtain the corresponding poly(1,3,4-oxadiazole)s. Polyhydrazides and poly(1,3,4-oxadiazole)s exhibited inherent viscosities in the range 0.65–0.72 dL g−1 and 0.54–0.62 dL g−1, respectively, which indicated the formation of reasonably high-molecular weight polymers. Polyhydrazides were soluble in polar aprotic solvents such as N,N-dimethylformamide, N,N-dimethylacetamide (DMAc), 1-methyl-2-pyrrolidinone and pyridine whereas poly(1,3,4-oxadiazole)s exhibited excellent solubility even in common organic solvents such as chloroform, dichloromethane and tetrahydrofuran. Tough, transparent and flexible films of polyhydrazides and poly(1,3,4-oxadiazole)s could be cast from DMAc and chloroform solutions, respectively. X-Ray diffraction studies revealed amorphous nature of polyhydrazides and poly(1,3,4-oxadiazole)s and the formation of layered structure was observed due to ordered packing of pentadecyl chains. The 10% decomposition temperature ( T10) values for poly(1,3,4-oxadiazole)s were in the range 425–440°C indicating their good thermal stability. Glass transition temperature ( Tg) values of polyhydrazides and poly(1,3,4-oxadiazole)s were in the range 175–192°C and 92–103°C, respectively. The excellent solubility characteristics and the large gap between Tg (92–103°C) and T10 (425–440°C) values give poly(1,3,4-oxadiazole)-containing pendent pentadecyl chains better opportunities for processability.
- Published
- 2016
8. Synthesis and properties of poly(arylene ether)s based on 3-pentadecyl 4,4'-biphenol
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Ulhas K. Kharul, Bhausaheb V. Tawade, Sayali V. Shaligram, Prakash P. Wadgaonkar, and Nitin G. Valsange
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Polymers and Plastics ,Organic Chemistry ,Arylene ,Ether ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,chemistry.chemical_compound ,chemistry ,Polymer chemistry ,Materials Chemistry ,Organic chemistry ,Thermal stability ,4,4'-Biphenol ,0210 nano-technology - Published
- 2016
9. Aromatic polyesters containing pendent 4-(phenylsulfonyl)phenyl groups: synthesis and characterization
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Nayaku Chavan, Prakash P. Wadgaonkar, Bhausaheb V. Tawade, Sushilkumar A. Jadhav, Nitin G. Valsange, Snehalata P. Bapat, and Pandurang N. Honkhambe
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Terephthalic acid ,Condensation polymer ,Chloroform ,Materials science ,Polymers and Plastics ,Organic Chemistry ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Interfacial polymerization ,0104 chemical sciences ,Isophthalic acid ,Polyester ,chemistry.chemical_compound ,chemistry ,Polymer chemistry ,Materials Chemistry ,Organic chemistry ,0210 nano-technology ,Tetrahydrofuran ,Dichloromethane - Abstract
A new bisphenol, 1,1-bis-[(4-hydroxyphenyl)-1-(4-phenylsulfonyl)phenyl)]ethane (DPSBP) was synthesized starting from diphenylsulfide and was characterized by spectroscopic methods. DPSBP was polycondensed with isophthalic acid chloride (IPC), terephthalic acid chloride (TPC) and a mixture of IPC and TPC (50:50 mol%) by phase-transfer catalysed interfacial polymerization method to obtain aromatic polyesters containing pendent 4-(phenylsulfonyl)phenyl groups. A series of copolyesters was also obtained by polycondensation of varying molar proportions of DPSBP and bisphenol-A (BPA) with TPC. (Co)polyesters exhibited inherent viscosities in the range 0.56–1.57 dLg−1 and number average molecular weights (Mn) were in the range 28,650–80,230 g/mol. Polyesters dissolved readily in common organic solvents such as dichloromethane, chloroform, tetrahydrofuran and aprotic polar solvents such as N-methylpyrrolidone, and N,N-dimethylacetamide. Tough, transparent and flexible films of polyesters could be cast from their chloroform solutions. X-Ray diffraction studies indicated amorphous nature of aromatic polyesters. Polyesters showed Tg values in the range 223–257 °C while T10 values were in the range of 469–484 °C indicating their excellent thermal stability.
- Published
- 2017
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