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In data from the New Horizons encounter with Pluto in 2015, attention was called to a crater named Kiladze and its surroundings because of the water ice spectral properties, which contrast with the primarily methane ice regional surface composition. The water ice carries the spectral signature of an ammoniated compound, similar to that seen at two other sites on Pluto where cryovolcanism has been identified. The faulted structure of Kiladze, including shaping by numerous collapse pits and the distorted shape of the crater, are compatible with the surroundings in Hayabusa Terra, east of Spunik Planitia. They are further compatible with an interpretation as a resurgent caldera formed during a past era of active cryovolcanic period that appears to be significantly more recent than the overall age of the planet's surface, possibly in the last several million years. In view of the size of the caldera and the large scale of the surrounding distribution of water ice, we propose that Kiladze is a "supervolcano" in which one or more explosive events has scattered more than ~1000 km$^{3}$ of icy cryomagma erupted from the interior onto the surface., Comment: 22 pages, 6 figures, submitted to Icarus

We report on a study of the mounds that dominate the appearance of Kuiper Belt Object (KBO) (486958) Arrokoth's larger lobe, named Wenu. We compare the geological context of these mounds, measure and intercompare their shapes, sizes/orientations, reflectance, and colors. We find the mounds are broadly self-similar in many respects and interpret them as the original building blocks of Arrokoth. It remains unclear why these building blocks are so similar in size, and this represents a new constrain and challenge for solar system formation models. We then discuss the interpretation of this interpretation., Comment: 24 pages, 8 figures

We present new, ice species-specific New Horizons/Alice upper gas coma production limits from the 01 Jan 2019 MU69/Arrokoth flyby of Gladstone et al. (2021) and use them to make predictions about the rarity of majority hypervolatile (CO, N$_2$, CH$_4$) ices in KBOs and Oort Cloud comets. These predictions have a number of important implications for the study of the Oort Cloud, including: determination of hypervolatile rich comets as the first objects emplaced into the Oort Cloud; measurement of CO/N$_2$/CH$_4$ abundance ratios in the proto-planetary disk from hypervolatile rich comets; and population statistical constraints on early (< 20 Myr) planetary aggregation driven versus later (> 50 Myr) planetary migration driven emplacement of objects into the Oort Cloud. They imply that the phenomenon of ultra-distant active comets like C/2017K2 (Jewitt et al. 2017, Hui et al. 2018) should be rare, and thus not a general characteristic of all comets. They also suggest that interstellar object 2I/Borisov did not originate in a planetary system that was inordinately CO rich (Bodewits et al. 2020), but rather could have been ejected onto an interstellar trajectory very early in its natal system's history., Comment: 16 Pages, 2 Figures, 1 Table; accepted for Publication in PSJ 14-Mar-2022

We discuss in a thermodynamic, geologically empirical way the long-term nature of the stable majority ices that could be present in Kuiper Belt Object 2014 MU69 after its 4.6 Gyr residence in the EKB as a cold classical object. Considering the stability versus sublimation into vacuum for the suite of ices commonly found on comets, Centaurs, and KBOs at the average ~40K sunlit surface temperature of MU69 over Myr to Gyr, we find only 3 common ices that are truly refractory: HCN, CH3OH, and H2O (in order of increasing stability). NH3 and H2CO ices are marginally stable and may be removed by any positive temperature excursions in the EKB, as produced every 1e8 - 1e9 yrs by nearby supernovae and passing O/B stars. To date the NH team has reported the presence of abundant CH3OH and evidence for H2O on MU69s surface (Lisse et al. 2017, Grundy et al. 2020). NH3 has been searched for, but not found. We predict that future absorption feature detections will be due to an HCN or poly-H2CO based species. Consideration of the conditions present in the EKB region during the formation era of MU69 lead us to infer that it formed "in the dark", in an optically thick mid-plane, unable to see the nascent, variable, highly luminous Young Stellar Object-TTauri Sun, and that KBOs contain HCN and CH3OH ice phases in addition to the H2O ice phases found in their Short Period comet descendants. Finally, when we apply our ice thermal stability analysis to bodies/populations related to MU69, we find that methanol ice may be ubiquitous in the outer solar system; that if Pluto is not a fully differentiated body, then it must have gained its hypervolatile ices from proto-planetary disk sources in the first few Myr of the solar systems existence; and that hypervolatile rich, highly primordial comet C/2016 R2 was placed onto an Oort Cloud orbit on a similar timescale., Comment: 34 Pages, 5 Figures, 2 SOM Tables

The Kuiper Belt is a distant region of the Solar System. On 1 January 2019, the New Horizons spacecraft flew close to (486958) 2014 MU69, a Cold Classical Kuiper Belt Object, a class of objects that have never been heated by the Sun and are therefore well preserved since their formation. Here we describe initial results from these encounter observations. MU69 is a bi-lobed contact binary with a flattened shape, discrete geological units, and noticeable albedo heterogeneity. However, there is little surface color and compositional heterogeneity. No evidence for satellites, ring or dust structures, gas coma, or solar wind interactions was detected. By origin MU69 appears consistent with pebble cloud collapse followed by a low velocity merger of its two lobes., Comment: 43 pages, 8 figure

The Cold Classical Kuiper Belt, a class of small bodies in undisturbed orbits beyond Neptune, are primitive objects preserving information about Solar System formation. The New Horizons spacecraft flew past one of these objects, the 36 km long contact binary (486958) Arrokoth (2014 MU69), in January 2019. Images from the flyby show that Arrokoth has no detectable rings, and no satellites (larger than 180 meters diameter) within a radius of 8000 km, and has a lightly-cratered smooth surface with complex geological features, unlike those on previously visited Solar System bodies. The density of impact craters indicates the surface dates from the formation of the Solar System. The two lobes of the contact binary have closely aligned poles and equators, constraining their accretion mechanism.

The New Horizons spacecraft's encounter with the cold classical Kuiper belt object (486958) Arrokoth (formerly 2014 MU69) revealed a contact-binary planetesimal. We investigate how it formed, finding it is the product of a gentle, low-speed merger in the early Solar System. Its two lenticular lobes suggest low-velocity accumulation of numerous smaller planetesimals within a gravitationally collapsing, solid particle cloud. The geometric alignment of the lobes indicates the lobes were a co-orbiting binary that experienced angular momentum loss and subsequent merger, possibly due to dynamical friction and collisions within the cloud or later gas drag. Arrokoth's contact-binary shape was preserved by the benign dynamical and collisional environment of the cold classical Kuiper belt, and so informs the accretion processes that operated in the early Solar System., Comment: Published in Science 28 Feb 2020 (First release 13 Feb 2020)

The outer Solar System object (486958) Arrokoth (provisional designation 2014 MU$_{69}$) has been largely undisturbed since its formation. We study its surface composition using data collected by the New Horizons spacecraft. Methanol ice is present along with organic material, which may have formed through radiation of simple molecules. Water ice was not detected. This composition indicates hydrogenation of carbon monoxide-rich ice and/ or energetic processing of methane condensed on water ice grains in the cold, outer edge of the early Solar System. There are only small regional variations in color and spectra across the surface, suggesting Arrokoth formed from a homogeneous or well-mixed reservoir of solids. Microwave thermal emission from the winter night side is consistent with a mean brightness temperature of 29$\pm$5 K., Comment: 31 pages, 8 figures

The New Horizons spacecraft provided near global observations of Pluto that far exceed the resolution of Earth-based data sets. Most Pluto New Horizons analysis hitherto has focused on the encounter hemisphere of Pluto (i.e., the antiCharon hemisphere containing Sputnik Planitia). In this work, we summarize and interpret data on the far side (i.e., the non-encounter hemisphere), providing the first integrated New Horizons overview of the far side terrains. We find strong evidence for widespread bladed deposits, evidence for an impact crater about as large as any on the near side hemisphere, evidence for complex lineations approximately antipodal to Sputnik Planitia that may be causally related, and evidence that the far side maculae are smaller and more structured than the encounter hemisphere maculae., Comment: 45 pages 12 figures

The deep nitrogen-covered Sputnik Planitia (SP; informal name) basin on Pluto is located very close to the longitude of Pluto's tidal axis[1] and may be an impact feature [2], by analogy with other large basins in the solar system[3,4]. Reorientation[5-7] due to tidal and rotational torques can explain SP's location, but requires it to be a positive gravity anomaly[7], despite its negative topography. Here we argue that if SP formed via impact and if Pluto possesses a subsurface ocean, a positive gravity anomaly would naturally result because of shell thinning and ocean uplift, followed by later modest N2 deposition. Without a subsurface ocean a positive gravity anomaly requires an implausibly thick N2 layer (greater than 40 km). A rigid, conductive ice shell is required to prolong such an ocean's lifetime to the present day[8] and maintain ocean uplift. Because N2 deposition is latitude-dependent[9], nitrogen loading and reorientation may have exhibited complex feedbacks[7].

The vast, deep, volatile-ice-filled basin informally named Sputnik Planum is central to Pluto's geological activity[1,2]. Composed of molecular nitrogen, methane, and carbon monoxide ices[3], but dominated by N2-ice, this ice layer is organized into cells or polygons, typically ~10-40 km across, that resemble the surface manifestation of solid state convection[1,2]. Here we report, based on available rheological measurements[4], that solid layers of N2 ice approximately greater than 1 km thick should convect for estimated present-day heat flow conditions on Pluto. More importantly, we show numerically that convective overturn in a several-km-thick layer of solid nitrogen can explain the great lateral width of the cells. The temperature dependence of N2-ice viscosity implies that the SP ice layer convects in the so-called sluggish lid regime[5], a unique convective mode heretofore not definitively observed in the Solar System. Average surface horizontal velocities of a few cm/yr imply surface transport or renewal times of ~500,000 years, well under the 10 Myr upper limit crater retention age for Sputnik Planum[2]. Similar convective surface renewal may also occur on other dwarf planets in the Kuiper belt, which may help explain the high albedos of some of them.

A unique feature of Pluto's large satellite Charon is its dark red northern polar cap. Similar colours on Pluto's surface have been attributed to organic macromolecules produced by energetic radiation processing of hydrocarbons. The polar location of this material on Charon implicates the temperature extremes that result from Charon's high obliquity and long seasons. The escape of Pluto's atmosphere provides a potential feed stock for production of complex chemistry. Gas from Pluto that is transiently cold-trapped and processed at Charon's winter pole was proposed as an explanation on the basis of an image of Charon's northern hemisphere, but not modelled quantitatively. Here we report images of the southern hemisphere illuminated by Pluto-shine and also images taken during the approach phase showing the northern polar cap over a range of longitudes. We model the surface thermal environment on Charon, the supply and temporary cold-trapping of material escaping from Pluto, and, while cold-trapped, its photolytic processing into more complex and less volatile molecules. The model results are consistent with the proposed mechanism producing the observed colour pattern on Charon.

New Horizons observations suggest that CH4 on Pluto has a complex history, involving reservoirs of different composition, thickness and stability controlled by volatile processes occurring on different timescales. In order to interpret these observations, we use a Pluto volatile transport model able to simulate the cycles of N2 and CH4 ices over millions of years. By assuming fixed solid mixing ratios, we explore how changes in surface albedos, emissivities and thermal inertias impact volatile transport. This work is therefore a direct and natural continuation of the work by Bertrand et al. (2018), which only explored the N2 cycles. Results show that bright CH4 deposits can create cold traps for N2 ice outside Sputnik Planitia, leading to a strong coupling between the N2 and CH4 cycles. Depending on the assumed albedo for CH4 ice, the model predicts CH4 ice accumulation (1) at the same equatorial latitudes where the Bladed Terrain Deposits are observed, supporting the idea that these CH4-rich deposits are massive and perennial, or (2) at mid-latitudes (25{\deg}N-70{\deg}N), forming a thick mantle which is consistent with New Horizons observations. In our simulations, both CH4 ice reservoirs are not in an equilibrium state and either one can dominate the other over long timescales, depending on the assumptions made for the CH4 albedo. This suggests that long-term volatile transport exists between the observed reservoirs. The model also reproduces the formation of N2 deposits at mid-latitudes and in the equatorial depressions surrounding the Bladed Terrain, as observed by New Horizons. At the poles, only seasonal CH4 and N2 deposits are obtained in Pluto's current orbital configuration. Finally, we show that Pluto's atmosphere always contained, over the last astronomical cycles, enough gaseous CH4 to absorb most of the incoming Lyman-flux., Comment: Accepted in Icarus

The flyby of Pluto and Charon by the New Horizons spacecraft provided high-resolution images of cratered surfaces embedded in the Kuiper belt, an extensive region of bodies orbiting beyond Neptune. Impact craters on Pluto and Charon were formed by collisions with other Kuiper belt objects (KBOs) with diameters from ~40 kilometers to ~300 meters, smaller than most KBOs observed directly by telescopes. We find a relative paucity of small craters less than approximately 13 kilometers in diameter, which cannot be explained solely by geological resurfacing. This implies a deficit of small KBOs (less than 1 to 2 kilometers in diameter). Some surfaces on Pluto and Charon are likely greater than 4 billion years old, thus their crater records provide information on the size-frequency distribution of KBOs in the early Solar System.

The centerpiece objective of the NASA New Horizons first Kuiper Extended Mission (KEM-1) was the close flyby of the Kuiper Belt Object KBO) 2014 MU69, nicknamed Ultima Thule. On 1 Jan 2019 this flyby culminated, making the first close observations of a small KBO. Initial post flyby trajectory reconstruction indicated the spacecraft approached to within ~3500 km of MU69 at 5:33:19 UT. Here we summarize the earliest results obtained from that successful flyby. At the time of this submission, only 4 days of data down-link from the flyby were available; well over an order of magnitude more data will be down-linked by the time of this Lunar and Planetary Science Conference presentation in 2019 March. Therefore many additional results not available at the time of this abstract submission will be presented in this review talk., Comment: 2 pages, 2 figures

Observations of Pluto's surface made by the New Horizons spacecraft indicates present-day nitrogen ice glaciation in and around the basin known as Sputnik Planum. Motivated by these observations, we have developed an evolutionary glacial flow model of solid nitrogen ice taking into account its published thermophysical and rheologies properties. This model assumes that glacial ice layers flow laminarly and have low aspect ratios which permits a vertically integrated mathematical formulation. We assess the conditions for the validity of laminar nitrogen ice motion by revisiting the problem of the onset of solid-state buoyant convection of nitrogen ice for a variety of bottom thermal boundary conditions. Subject to uncertainties in nitrogen ice rheology, nitrogen ice layers are estimated to flow laminarly for thicknesses less than 400-1000 meters. The resulting mass-flux formulation for when the nitrogen ice flows as a laminar dry glacier is characterized by an Arrhenius-Glen functional form. The flow model developed is used here to qualitatively answer some questions motivated by observed glacial flow features found on Sputnik Planum. We find that the wavy transverse dark features found along the northern shoreline of Sputnik Planum may be a transitory imprint of shallow topography just beneath the ice surface suggesting the possibility that a major shoreward flow event happened relatively recently within the last few hundred years. Model results also support the interpretation that the prominent darkened features resembling flow lobes observed along the eastern shoreline of the Sputnik Planum basin may be a result of wet nitrogen glacial ice flowing into the basin from the pitted highlands of eastern Tombaugh Regio., Comment: This definitive version has several typos corrected including equation expressions in Appendix C.2 and C.3. Updated version with associated errata in process at Icarus (July 26, 2018). All previous results appearing in journal version --especially those pertaining to glacial flow and their related timescales (Sections 4 & 5) -- are unchanged

The New Horizons mission has provided resolved measurements of Pluto's moons Styx, Nix, Kerberos, and Hydra. All four are small, with equivalent spherical diameters of $\approx$40 km for Nix and Hydra and ~10 km for Styx and Kerberos. They are also highly elongated, with maximum to minimum axis ratios of $\approx$2. All four moons have high albedos ( $\approx$50-90 %) suggestive of a water-ice surface composition. Crater densities on Nix and Hydra imply surface ages $\gtrsim$ 4 Ga. The small moons rotate much faster than synchronous, with rotational poles clustered nearly orthogonal to the common pole directions of Pluto and Charon. These results reinforce the hypothesis that the small moons formed in the aftermath of a collision that produced the Pluto-Charon binary., Comment: in Science 351, aae0030 (2016)

The Pluto system was recently explored by NASA's New Horizons spacecraft, making closest approach on 14 July 2015. Pluto's surface displays diverse landforms, terrain ages, albedos, colors, and composition gradients. Evidence is found for a water-ice crust, geologically young surface units, surface ice convection, wind streaks, volatile transport, and glacial flow. Pluto's atmosphere is highly extended, with trace hydrocarbons, a global haze layer, and a surface pressure near 10 microbars. Pluto's diverse surface geology and long-term activity raise fundamental questions about how small planets remain active many billions of years after formation. Pluto's large moon Charon displays tectonics and evidence for a heterogeneous crustal composition, its north pole displays puzzling dark terrain. Small satellites Hydra and Nix have higher albedos than expected., Comment: 8 pages - Initial Science paper from NASA's New Horizons Pluto Encounter

We report a reversible and hysteretic change in the topography measured with a scanning tunneling microscope near a single Fe dopant in a GaAs surface when a small positive bias voltage is applied. First-principles calculations of the formation energy of a single Fe atom embedded in GaAs as a function of displacement from the substitutional site support the interpretation of a reversible lattice displacement of the Fe dopant. Our calculations indicate a second stable configuration for the Fe dopant within the lattice, characterized by a displacement along the [111] axis, accompanied by a change in atomic configuration symmetry about the Fe from four-fold to six-fold symmetry. The resulting atomic configurations are then used within a tight-binding calculation to determine the effect of a Fe position shift on the topography. These results expand the range of demonstrated local configurational changes induced electronically for dopants, and thus may be of use for sensitive control of dopant properties and dopant-dopant interactions., Comment: 6 pages, 6 figures

NASA's New Horizons mission acquired a large set of images and other data making possible thorough geological analysis of landscapes in the Pluto System. Pluto and Charon exhibit strikingly different surface appearances, despite their similar densities and presumed bulk compositions. Systematic investigation, modelling and mapping revealed that much of Pluto's surface is attributed to surface-atmosphere interactions and the mobilization of volatile ices by insolation. Many mapped valley systems appear to be the consequence of glaciation involving nitrogen ice. Other geological activity requires or required long periods of internal heating, such as Pluto's extensive tectonic fabric. The convection and advection of volatile ices in Sputnik Planitia are thought to be powered by present-day radiogenic heat loss. The prominent mountains at the western margin of Sputnik Planitia, and the strange, multi-km-high mound features to the south, probably composed of H2O, are young geologically as inferred by light cratering and superposition relationships. These multi-km-high mound features might be cryo-volcanoes. Their origin, and what drove their formation so late in Solar System history, is under investigation. East of Sputnik Planitia are large fields of aligned ranks of sharp-crested ridges found only at high altitude that are apparently composed of massive deposits of CH4 ice, referred to as Bladed Terrain. New Horizons found evidence that Bladed Terrain may cover much of Pluto's low latitudes and may have originally formed there as a consequence of Pluto's very high obliquity. Currently Bladed Terrain is undergoing net erosion. This observation, along with evidence for formally more extensive nitrogen glaciation implies that Pluto undergoes significant climate evolution. The dynamic remolding of landscapes by volatile transport seen on Pluto is not unambiguously evident in the mapping of Charon. Charon does, however, display a large resurfaced plain and globally engirdling extensional tectonic network attesting to its early endogenic vigor.

We conclude that Bladed Terrain on Pluto is a deposit of massive CH4, which preferentially precipitates at high elevations, and has since its initial formation, undergone episodes of sublimation erosion that has given this deposit its characteristic texture.

Pluto's large moon Charon [radius 606 km; density = 1.70 g cm(exp. -3)] exhibits a striking variety of landscapes. Charon can be divided into two broad provinces separated by a roughly aligned assemblage of ridges and canyons, which span from east to west. North of this tectonic belt is rugged, cratered terrain (Oz Terra); south of it are smoother but geologically complex plains (Vulcan Planum). (All place names here are informal.) Relief exceeding 20 km is seen in limb profiles and stereo topography.

Impact crater morphology can be a very useful tool for probing planetary interiors, but nowhere in the solar system is a greater variety of crater morphologies observed (Fig. 1) than on the large icy Galilean satellites Ganymede and Callisto [e.g., 1- 3]. As on the rocky terrestrial planets, impact crater morphology becomes more complex with increasing size on these satellites. With increasing size, however, these same craters become less like their counterparts on the rocky planets. Several impact landforms and structures (multiring furrows, palimpsests, and central domes, for example), have no obvious analogs on any other planets. Further, several studies [e.g., 4-6] have drawn attention to impact landforms on Europa which are unusual, even by Galilean satellite standards. These radical differences in morphology suggest that impact into icy lithospheres that are mechanically distinct from silicate lithospheres may be responsible. As such, large impact structures may be important probes of the interiors of these bodies over time [e.g., 7]. The first goal of this work is to integrate and correlate the detailed morphologic and morphometric measurements and observations of craters on icy Galilean satellites [e.g., 4, 8-12] with new detailed mapping of these structures from Galileo high-resolution images. As a result, we put forward a revised crater taxonomy for Ganymede and Callisto in order to simplify the nonuniform impact crater nomenclature cluttering the literature. We develop and present an integrated model for the development of these unusual crater morphologies and their implications for the thermal evolution of these bodies.

A unique feature of Plutos large satellite Charon is its dark red northern polar cap. Similar colours on Plutos surface have been attributed to tholin-like organic macromolecules produced by energetic radiation processing of hydrocarbons. The polar location on Charon implicates the temperature extremes that result from Charons high obliquity and long seasons in the production of this material. The escape of Pluto's atmosphere provides a potential feedstock for a complex chemistry. Gas from Pluto that is transiently cold-trapped and processed at Charon's winter pole was proposed as an explanation for the dark coloration on the basis of an image of Charon's northern hemisphere, but not modelled quantitatively. Here we report images of the southern hemisphere illuminated by Pluto-shine and also images taken during the approach phase that show the northern polar cap over a range of longitudes. We model the surface thermal environment on Charon and the supply and temporary cold-trapping of material escaping from Pluto, as well as the photolytic processing of this material into more complex and less volatile molecules while cold-trapped. The model results are consistent with the proposed mechanism for producing the observed colour pattern on Charon.

Several icy-world surfaces in the solar system exhibit sublimation-driven landform modification erosion, condensation, and mass wasting [1]. In addition to the obvious role of gravity, mass wasting can work in conjunction with internal disaggregation of a landform's relief-supporting material through the loss (or deteriorating alteration) of its cohesive matrix. To give a conspicuous example, Callisto's landscape exhibits widespread erosion from sublimation erosion of slopes, which results in smooth, undulating, low albedo plains composed of lag deposits, with isolated high albedo pinnacles perched on remnants of crater rims due to the re-precipitation of ice on local cold traps [2, 3, 4]. Sublimation-driven mass wasting was anticipated on Pluto prior to the encounter (see refs in [5]). Here we report on several landscapes on Pluto we interpret to be formed, or at least heavily modified, by sublimation erosion.

NASA's New Horizons spacecraft has revealed the complex geology of Pluto and Charon. Pluto shows ongoing surface geological activity centered on a vast basin containing a thick layer of volatile ices that is involved in convection and advection, with a crater retention age no greater than 10 Ma. Surrounding terrains show active glacial flow, apparent transport and rotation of large buoyant water-ice crustal blocks, and pitting by sublimation erosion and/or collapse. More enigmatic features include tall mounds with central depressions that are conceivably cryovolcanic, and ridges with complex bladed textures. Pluto also has ancient cratered terrains up to 4 Ga old that are extensionally fractured and extensively mantled and eroded by glacial or other processes. Charon is not currently active, but experienced major extensional tectonism and resurfacing (probably cryovolcanic) nearly 4 billion years ago. Impact crater populations on Pluto and Charon are not consistent with the steepest proposed impactor size-frequency distributions.

The July encounter with Pluto by the New Horizons spacecraft permitted imaging of its cratered terrains with scales as high as approximately 100 m/pixel, and in stereo. In the initial download of images, acquired at 2.2 km/pixel, widely distributed impact craters up to 260 km diameter are seen in the near-encounter hemisphere. Many of the craters appear to be significantly degraded or infilled. Some craters appear partially destroyed, perhaps by erosion such as associated with the retreat of scarps. Bright ice-rich deposits highlight some crater rims and/or floors. While the cratered terrains identified in the initial downloaded images are generally seen on high-to-intermediate albedo surfaces, the dark equatorial terrain informally known as Cthulhu Regio is also densely cratered. We will explore the range of possible processes that might have operated (or still be operating) to modify the landscape from that of an ancient pristinely cratered state to the present terrains revealed in New Horizons images. The sequence, intensity, and type of processes that have modified ancient landscapes are, among other things, the record of climate and volatile evolution throughout much of the Pluto's existence. The deciphering of this record will be discussed. This work was supported by NASA's New Horizons project.