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Developing efficient electrocatalyst in sulfides for hydrogen evolution reaction (HER) still poses challenges due to the lack of understanding the role of sulfide heterointerface. Here, we report a sulfide heterostructure RuSx/NbS2, which is composed of 3R‐type NbS2 loaded by amorphous RuSx nanoparticles with S−S bonds formed at the interface. As HER electrocatalyst, the RuSx/NbS2 shows remarkable low overpotential of 38 mV to drive a current density of 10 mA cm−2 in acid, and also low Tafel slope of 51.05 mV dec−1. The intrinsic activity of RuSx/NbS2 is much higher than that of Ru/NbS2 reference as well as the commercial Pt/C. Both experiments and theoretical calculations unveil a reversed charge transfer at the interface from NbS2 to RuSx that driven by the formation of S−S bonds, resulting in electron‐rich Ru configuration for strong hydrogen adsorption. Meanwhile, electronic redistribution induced by the sulfide heterostructure facilitates hydrogen spillover (HSo) effect in this system, leading to accelerated hydrogen desorption at the basal plane of NbS2. This study provides an effective S−S bond strategy in sulfide heterostructure to synergistically modulate the charge transfer and adsorption thermodynamics, which is very valuable for the development of efficient electrocatalysts in practical applications. [ABSTRACT FROM AUTHOR]

Organic–inorganic metal halides (OIMHs) have drawn considerable attention due to their remarkable optoelectronic properties and substantial promise for nonlinear optical applications. In this research, phenazine has been selected as the organic cation because of its π-conjugated feature. Three compounds, (C12H9N2)PbCl3, (C12H9N2)SbCl4, and (C12H9N2)2InBr4·Br, were synthesized. Initial space group assignments were centrosymmetric for (C12H9N2)PbCl3 and (C12H9N2)SbCl4. However, under 1550 nm laser excitation, (C12H9N2)PbCl3 and (C12H9N2)SbCl4 exhibited second harmonic generation intensities ∼1.7 times greater than that of the benchmark KH2PO4. Structural reevaluation ultimately confirmed non-centrosymmetric P1 and P21 space groups for (C12H9N2)PbCl3 and (C12H9N2)SbCl4, respectively. Upon excitation at 335 nm and 470 nm, (C12H9N2)PbCl3, (C12H9N2)SbCl4, and (C12H9N2)2InBr4·Br emit fluorescence at room temperature. (C12H9N2)2InBr4·Br exhibits reversible phase transitions, showing potential for phase change energy storage. Our research underscores the critical role of comprehensive experimental validation in determining the precise crystallographic space groups and reveals the extensive potential of OIMHs as versatile candidates for advanced optoelectronic applications. [ABSTRACT FROM AUTHOR]

Electric energy routers (EERs) can effectively deal with the energy management issues caused by the access of multi-sources and multi-loads. Different from the energy transmission form in the existing series architecture EER (SA-EER) for low-voltage distribution networks, a new series-parallel architecture EER (SPA-EER) has the advantages of high-power transmission capability and reactive power flexible operation. However, if controller parameters change beyond their critical stability boundaries, SPA-EER will produce slow- and fast-scale bifurcation behaviors, which are manifested as low- and high-frequency oscillations of port voltages or port currents in varying degrees. To avoid the system instability caused by controller parameter changes, how to discriminate the stability regions of controller parameters for SPA-EER is a key research content in this paper. To this end, the stroboscopic mapping discrete model of SPA-EER system is first established, and system bifurcation behaviors are analyzed based on bifurcation theory. Furthermore, the critical stability boundaries of controller parameters are discriminated by using Jacobian matrix, root locus and bifurcation diagram. After that, a time delay feedback control (TDFC) is employed to suppress system bifurcation behaviors. Finally, the correctness of bifurcation analysis and the effectiveness of TDFC are verified by a hardware-in-the-loop (HIL) experimental platform. [ABSTRACT FROM AUTHOR]