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We examined the effect of localized brain lesions on processing of the basic speech acts (BSAs) of question, assertion, request, and command. Both left and right cerebral damage produced significant deficits relative to normal controls, and left brain damaged patients performed worse than patients with right-sided lesions. This finding argues against the common conjecture that the right hemisphere of most right-handers plays a dominant role in natural language pragmatics. In right-hemisphere damaged patients, there was no correlation between location and extent of lesion in perisylvian cortex and performance on BSAs. By contrast, processing of the different BSAs by left hemisphere-damaged patients was strongly affected by perisylvian lesion location, with each BSA showing a distinct pattern of localization. This finding raises the possibility that the classical left perisylvian localization of language functions, as measured by clinical aphasia batteries, partly reflects the localization of the BSAs required to perform these functions.

Elucidating physicochemical processes in the degradation of pollutants may optimize their removal from water sources. Although the photodegradation of carbamazepine (CBZ) in Advanced Oxidation Processes (AOPs) has been widely studied, there is no detailed report on the elementary steps of the kinetics. This study proposes a set of elementary steps for the AOP of CBZ, combining short-wave ultraviolet radiation (UVC), a homogeneous reagent (H2O2), and a heterogeneous catalyst (TiO2), which includes the excitation of both reagents/catalysts by UVC photons, the adsorption of CBZ by the excited TiO2, or its oxidation by hydroxyl radicals. Assuming the steady-state approximation on the intermediate products (excited TiO2, CBZ-excited TiO2 complex, and hydroxyl radicals) leads to rate laws for the degradation of CBZ, in which UVC radiation, TiO2, and H2O2 are pseudo-first-order at all concentrations or intensities and have no direct influence on CBZ pseudo-order, whereas CBZ shifts from pseudo-first-order at low concentrations to pseudo-zero-order at high concentrations. Several experiments to test the mechanism were conducted by varying CBZ, H2O2, and TiO2 concentrations and UVC radiation intensities. The measured results indeed fit the suggested mechanism for the first three, but the irradiation intensity appears to shift the CBZ influence from pseudo-second- to pseudo-first-order with increased intensities. Part of the elementary steps were changed to fit the results.

Eddy correlation measures gas exchange between canopy and the overlying atmosphere by evaluating the correlation between fluctuations in the gas-of-interest’s mixing ratio and the vertical wind velocity and considered the most accurate approach for measuring gas fluxes, mostly carbon dioxide and water vapor under ideal homogeneous conditions. It has been used in micrometeorology for decades to quantify mass and energy transfer between urban, natural and agricultural ecosystems and the atmosphere. We assessed its application under various—homogeneous and non-homogeneous—conditions. Our study indicates that fluxes of CO2 and H2O correlate well with plants activity only when turbulent conditions are present, in open fields. At such conditions, direct measurements of concentration of those gases are not an accurate indicator for plants activity. On the other hand, in closed systems (e.g. greenhouses)- fluxes as measured by an eddy correlation system can't accurately be related to the state of the vegetation, but the fluctuations in the concentrations of CO2 and H2O directly correlate to the actual plants activity. Adapting conditions in greenhouses to limiting factors as temperature, increases CO2 sequestration by plants, and may increase productivity

Poly-DADMAC (PD) is a commonly used organic polymer in water treatment, known for its effectiveness as a coagulant. However, its presence as a residue in water raises concerns related to membrane fouling and the potential formation of carcinogenic compounds. Therefore, fast and simple quantification is necessary to efficiently control and monitor the optimal dose of poly-DADMAC with minimal negative effects. This study introduces a new colorimetric quantification method for poly-DADMAC, based on complexation with a cationic dye (fast green-FG). The method was examined through varying conditions, which included different analytical and commercial poly-DADMAC formulations and concentrations. These experiments confirm its effectiveness in quantifying poly-DADMAC with a detection limit of 3.22 µg L−1 (0.02 µM based on monomers’ molecular weight), which is one order of magnitude lower than regulatory requirements (50 µg L−1). To validate the method, the effect of pH was examined, and implementation demonstrations were conducted on cyanobacteria and cowshed-polluted water samples. This research introduces a fast, cost-effective innovative method to accurately quantify poly-DADMAC, enhancing water treatment strategies for high-quality purification and water reuse

Carbamazepine (CBZ) is one of the most common emerging contaminants released to the aquatic environment through domestic and pharmaceutical wastewater. Due to its high persistence through conventional degradation treatments, CBZ is considered a typical indicator for anthropogenic activities. This study tested the removal of CBZ through two different clay-based purification techniques: adsorption of relatively large concentrations (20–500 μmol L−1) and photocatalysis of lower concentrations (−1). The sorption mechanism was examined by FTIR measurements, exchangeable cations released, and colloidal charge of the adsorbing clay materials. Photocatalysis was performed in batch experiments under various conditions. Despite the neutral charge of carbamazepine, the highest adsorption was observed on negatively charged montmorillonite-based clays. Desorption tests indicate that adsorbed CBZ is not released by washing. The adsorption/desorption processes were confirmed by ATR-FTIR analysis of the clay-CBZ particles. A combination of synthetic montmorillonite or hectorite with low H2O2 concentrations under UVC irradiation exhibits efficient homo-heterogeneous photodegradation at μM CBZ levels. The two techniques presented in this study suggest solutions for both industrial and municipal wastewater, possibly enabling water reuse.

Few would disagee with the need for training in order to become a skilled psychotherapist. However, much of the training that novice therapists receive is in the form of supervision provided by psychotherapists with little or no training in the craft of supervision. It is now recognized that psychotherapy skills are not identical to the skills needed for psychotherapy supervision. Nevertheless, there are few programs that provide training in how to supervise. The authors describe a doctoral level supervision trainee- ship program aimed at meeting this need. [ABSTRACT FROM PUBLISHER]

Quantification of adsorbed amounts requires in most cases several assumptions. Adsorption of organic compounds, for example, is usually measured indirectly, by mass balance calculations based on the evaluation of the remaining chemical in solution. Such procedure might yield overestimates when precipitation or degradation of the adsorbate occurs and underestimates when separation of the sorbent material (e.g., clay particles) with the adsorbed chemical is not effective. This study presents a simple quantification procedure based on the ratio between IR absorption bands of the sorbate and the adsorbate. The advantages of the procedure are (a) direct evaluation of the adsorbed amount and (b) accurate measurement of chemicals that are hard to quantify, as those that do not absorb light in the UV-Visible range, or require expensive chromatography procedures.

Some agricultural effluents are unsuitable for discharge into standard sewage-treatment plants: their pretreatment is necessary to avoid clogging of the filtering devices by colloidal matter. The colloidal stability of the effluents is mainly due to mutual repulsive forces that keep charged particles in suspension. Pretreatment processes are based on two separate stages: (a) neutralization of the charges (“coagulation”) and (b) bridging between several small particles to form larger aggregates that sink, leaving clarified effluent (“flocculation”). The consequent destabilization of the colloidal suspension lowers total suspended solids (TSSs), turbidity, and other environmental quality parameters, making the treatments that follow more efficient. Clay-based materials have been widely used for effluent pretreatment and pollutant removal. This study presents the use of nanocomposites, comprised of an anchoring particle and a polymer, as “coagoflocculants” for the efficient and rapid reduction of TSS and turbidity in wastewater with a high organic load. The use of such particles combines the advantages of coagulant and flocculant by neutralizing the charge of the suspended particles while bridging between them and anchoring them to a denser particle (the clay mineral), enhancing their precipitation. Very rapid and efficient pretreatment is achieved in one single treatment step.

Katz and Ferretti's, ( Discourse Processes, 2003, 36, 19) pioneering paper was the first to address and systematically examine the role of marking ( literally speaking, in a manner of speaking, proverbially speaking ) during online processing of proverbs (see also Schwint et al., 28th Annual Conference of the Cognitive Science Society Proceedings, 2006, 768). For Katz and colleagues, such markers function as introductory formulae, signaling to the addressee the intended interpretation of an incoming proverb. Inspired by their work, this paper explores the effects of marking, showing that some markers ( literally, in the full sense of the word, double entendre, really ) rather than disambiguating an ambiguous utterance, can allow for ambiguation (e.g., S/he is radiant, in the full sense of the word uttered in reference to a smiling person wearing sparkling clothes). Two offline questionnaire studies and one online reading task experiment, all conducted in Hebrew, test the Low-Salience Marking Hypothesis (Givoni, Low-salience marking , 2011; Givoni, Marking multiple meanings, 2020; Givoni, Journal of Pragmatics , 2013, 48, 29). Accordingly, such marking boosts low-salience meanings ("glittery", here the literal meaning) which are less-frequent, less-familiar, less-prototypical, and less-conventionalized (The Graded Salience Hypothesis, see Giora, Cognitive Linguistics, 1997, 8, 183; Giora, On our mind: Salience, context and figurative language , Oxford University Press, 2003; Givoni & Giora, Handbuch Pragmatik, J.B. Metzler, 2018). Marked utterances were embedded in contexts, strongly supportive of the salient meaning of the ambiguities ("happy", here the figurative meaning). Results support the Low-Salience Marking Hypothesis. They show preference for low-salience meanings as well as faster reading times of such meanings following low-salience marking relative to control conditions. (PsycInfo Database Record (c) 2021 APA, all rights reserved).

We used event-related fMRI (ER-fMRI) to test the hypothesis that metaphors bias cognitive processing of semantic relatedness towards a search for a wider range of associations. Twelve right-handed male volunteers read a mixture of metaphoric and literal sentences, each sentence being followed by a single word, which could be semantically related or not to the preceding sentence context. We found that judging unrelated words as contextually irrelevant was associated with increased blood oxygenation level-dependent (BOLD) signal in the right ventrolateral prefrontal cortex in the metaphoric but not in the literal condition. The same region was also activated when subjects endorsed a semantic relation between words and metaphoric sentence primes but not between words and literal sentence primes. We argue that these results are consistent with the notion of semantic open-endedness, whereby figurative statements bias cognitive processing towards a search for a wider range of semantic relationships compared to literal statements, and thus lend further support to the view that coarse semantic coding occurs preferentially in the right hemisphere.