Forest Resources and Environmental Conservation, Virginia Water Resources Research Center, Bailey, Scott W., McGuire, Kevin J., Ross, Donald S., Green, Mark B., Fraser, Olivia L., Forest Resources and Environmental Conservation, Virginia Water Resources Research Center, Bailey, Scott W., McGuire, Kevin J., Ross, Donald S., Green, Mark B., and Fraser, Olivia L.
Headwater streams in the White Mountains, NH, United States have been shown to have downstream gradients of increasing pH and concentrations of base cations coupled with decreasing concentrations of aluminum. A two-stage acid neutralization model involving shallow soil exchange processes in headwaters coupled with deeper mineral weathering downstream had been proposed to explain these gradients. We conducted synoptic sampling of three headwater catchments in this region that showed variations in this longitudinal pattern, ranging from streams that remain acidic throughout their length to streams with circumneutral pH beginning at their source. To explain these differences, we mapped soils using a hydropedologic approach that emphasizes the influence of groundwater saturation frequency and water table regime on soil formation processes. Stream segments with lower pH and base cation concentrations, coupled with higher concentrations of dissolved organic carbon (DOC), aluminum, and in one case iron, were in subcatchments mapped with shallow to bedrock soils where eluvial soil forming processes dominated. In contrast, stream segments with higher pH and base cation concentrations coupled with low concentrations of DOC and aluminum were associated with subcatchments with deeper soils where illuvial processes were more dominant. Concentrations of sodium and silicon were relatively uniform across these gradients. Coupled with the higher concentrations of dissolved aluminum and small pools of exchangeable aluminum in the areas of bedrock outcrops and shallow soils, these data suggest that primary mineral dissolution is an important process influencing upper stream reaches, not just along longer, deeper flowpaths in downslope areas. In contrast, some stream reaches with obvious groundwater springs show a more abrupt transition in pH and base cation concentrations higher along the stream, suggesting that neutralization along deeper flowpaths may play a role in upslope areas as