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Stabilizing the surrounding rock provides an important environmental safeguard for tunnel blasting. To investigate the damage characteristics and rupture mechanism of the surrounding rock in long-distance tunnels under cyclic explosive loading, it takes the in-situ surrounding rock and rock samples of diversion tunnel underneath the highway as the study object. The impact splitting test was carried out with the SHPB test system. It revealed the mechanical behaviors and energy evolution characteristics of the rock body. It is also introduced the 4D ultra-high-definition imaging technology of the mine roadway to further analyze the in-situ fissure expansion mechanism of the tunnel peripheral rock under the cyclic explosive loading. The results show that: ① The splitting stress-strain curves of granite and tuff under impact splitting are different from the “stress yield” characteristic of impact compression. But they have the “residual stress” characteristics. The peak stress and dynamic growth factor DIF show a positive linear growth trend; The strain time curve does not exhibit the characteristic of “later reduction” deformation during impact compression. It exhibits the characteristic of “later stability” deformation as an elastic brittle material. ② The rock mass impacting energy - time curve undergoes an evolutionary stage of “initial slow growth - fast linear growth - later stable”. The energy conversion ratio of the rock mass under the same impact energy level satisfies the following conditions: reflected energy ratio > dissipated energy ratio > transmitted energy ratio; The overall damage and failure of the rock mass exhibits a state characteristic of “central splitting + loading end crushing → central splitting + loading end crushing + semi circular fracture → overall crushing”. ③ A peephole imaging test combining “less domains and more tests” and “more domains and less tests” is proposed. The crack propagation characteristics of the in-situ surrounding rock hole wall are mainly manifested in following evolutionary stage: “microcrack development → crack propagation → slow propagation → stop extension”. There is no significant phenomenon of fragmentation detachment and further inward extension. ④ The observation results of the D1 hole of the top pipe tunnel at the foot of the mountain and the D2 hole of the Shancha maintenance tunnel have verified the good boundary control blasting effect; The impact splitting results of rock samples taken from the original site of the tunnel provide an effective theoretical basis and reference for the design of pre blasting drilling and blasting schemes.

An in-depth understanding of the mechanical properties and damage and fracture mechanism of selected rocks in a diversion tunnel plays an important role in promoting the efficient construction and safety of rock blasting excavation in a diversion tunnel. To study the mechanical properties and damage evolution characteristics of selected rocks in diversion tunnels under uniaxial loading, the uniaxial compression and uniaxial splitting tests of granite and tuff were carried out. In terms of mechanical properties, the evolution characteristics of complete stress-strain curves, instantaneous modulus-strain curves, and input energy density-strain curves were analyzed. In the aspect of damage characteristics, the macroscopic and mesoscopic failure modes were analyzed and the damage fracture mechanism was revealed. Compression-shear failure mainly occurred in granite and tuff under uniaxial compression, showing the characteristics of elastic-brittle fracture failure. Both granite and tuff showed a failure mode of coexistence of “compression-shear failure zone at the loading ends” and “tension-shear failure zone in the middle” under uniaxial splitting. The compression-shear fracture of granite was relatively smooth, and the matrix and mineral particles produced fine particles due to friction in the process of shear slip. The compression-shear fracture of tuff was relatively rough and the characteristics of shear slip were not prominent enough. The fracture failure of granite and tuff was mainly caused by the common fracture of rock matrix and mineral particles. Based on the Lemaitre equivalent strain principle, the pre-peak-post-peak two-stage damage constitutive model established by Weibull statistical distribution theory can accurately describe the static stress-strain relationships of granite and tuff under uniaxial compression.

This paper describes the two-dimensional (2D) crystallization of side-chain giant molecules (SCGMs) having the fixed number ratio of two types of functionalized building blocks with 1:1. SCGMs are regarded to a certain degree as size-amplified versions of universal synthetic polymers that are prepared by precisely connecting molecular nanoparticles (MNPs) to polymer chains. Our previous experimental results have shown that individually changing the number ratio of one of the building blocks would significantly affect the structural parameters of molecular crystals, mainly the longitudinal thickness. Herein, we systematically discussed the 2D crystallization of two categories of POSS-based SCGMs with constant building blocks ratio. Solution self-assembly of such SCGMs resulted in well-defined 2D nanosheets with similar structural configurations, showing great tolerance in the number of building blocks. Subsequently, we proposed a “sandwiched-type” mode to illustrate the bilayer 2D supramolecular framework, in which crystalline blocks pack in head-to-head manner. In addition, sequence isomers provide an ideal platform to further verify that the thickness of 2D nanocrystal is linked with the tethering density determined by the number ratio of building blocks. We believe that this study could be a better complement to our previous work and then make us to be more in-depth understand the crystallization mechanism of SCGMs.

Inorganic-organic hybridization is a widely used method to develop new functional materials involving polyoxometalates (POMs), affording them with unique synergistic physical and chemical properties. As one of the core topics in hybrid materials, the study of their assembly structures is critical for the optimization of their performances.In the present work, dynamic co-assembly behaviors of several giant surfactants XPOSS-PS (X, POSS and PS denote different polar groups, polyhedral oligomeric silsesquioxane and polystyrene, respectively) and Keggin-type silicotungstic acid H4SiW12O40 (H4SiW for short) were investigated. We designed and synthesized three series of giant surfactants that possess heads bearing cationic (NPOSS-PS, N for ammonium group), neutral (DPOSS-PS, D for dihydroxyl group) and anionic charges (APOSS-PS, A for carboxylic acid group), respectively. The different charge types of POSS heads lead to different electrostatic interactions with the anionic POM clusters, resulting in different co-assembly structures in dual mixed solvents. Moreover, we found the POM's loading content and PS chain length are another two important factors that can determine the morphology of co-assembly structures. This work expands the scope of co-assembled structures of POM-based hybrid materials, and provides a platform for the study of the basic physical principles of their co-assembly behaviors.

An in-depth understanding of the pre-peak mechanical damage and energy-evolution characteristics of typical hard-rock in a diversion tunnel under cyclic load is of great significance to promote the safe and efficient construction of the diversion tunnel and the stability of surrounding rock. To study the pre-peak mechanical characteristics and the competition mechanism between energy storage and energy dissipation of typical hard-rock in a diversion tunnel under cyclic loading-unloading, combined with the internal drilling and blasting excavation of the actual engineering rock mass and the external vehicle cyclic load environment of the diversion tunnel, the cyclic loadingunloading tests of typical granite and tuff in diversion tunnel were carried out. Based on the analysis principle of mechanics and energy, the strain variables, modulus variables, energy variables and damage variables of granite and tuff under cyclic loading-unloading test were defined. The cyclic mechanical properties and energyevolution characteristics of granite and tuff under pre-peak load were analyzed. The competition mechanism between pre-peak energy storage and pre-peak energy dissipation of granite and tuff and the evolution law of strain damage variable and energy damage variable were revealed. The selection principle of rock sample size and the limitation of the test scheme were further discussed. The study of the damage evolution of rocks close to failure (pre-peak stage) under cyclic load is helpful to better understand the damage and failure mechanism of rocks in practical engineering problems. [ABSTRACT FROM AUTHOR]