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Your search keyword '"Eck, E.R.H. van"' showing total 241 results
Start Over Author "Eck, E.R.H. van" Publication Year Range Last 50 years
241 results on '"Eck, E.R.H. van"'

1. Re-investigating the structure-property relationship of the solid electrolytes Li 3-xIn1-xZrxCl6 and the impact of In-Zr(iv) substitution

Author

Maas, Eveline van der, Famprikis, Theodosios, Pieters, Saskia, Dijkstra, Jonas P., Li, Zhaolong, Parnell, Steven R., Eck, E.R.H. van, Ganapathy, S., Wagemaker, M., Maas, Eveline van der, Famprikis, Theodosios, Pieters, Saskia, Dijkstra, Jonas P., Li, Zhaolong, Parnell, Steven R., Eck, E.R.H. van, Ganapathy, S., and Wagemaker, M.

Abstract

Item does not contain fulltext

Published
2023

3. Self-organized hetero-nanodomains actuating super Li+ conduction in glass ceramics

Author

Wang, Yantao, Qu, Hongtao, Liu, Bowen, Li, Xiaoju, Ju, Jiangwei, Li, Jiedong, Eck, E.R.H. van, Kentgens, Arno P.M., Cui, Guanglei, Chen, Liquan, Wang, Yantao, Qu, Hongtao, Liu, Bowen, Li, Xiaoju, Ju, Jiangwei, Li, Jiedong, Eck, E.R.H. van, Kentgens, Arno P.M., Cui, Guanglei, and Chen, Liquan

Abstract

Item does not contain fulltext

Published
2023

4. A Water-Free In Situ HF Treatment for Ultrabright InP Quantum Dots

Author

Ubbink, R.F., Almeida, G., Iziyi, H., Fosse, R. du, Verkleij, R., Ganapathy, S., Eck, E.R.H. van, Houtepen, A.J., Ubbink, R.F., Almeida, G., Iziyi, H., Fosse, R. du, Verkleij, R., Ganapathy, S., Eck, E.R.H. van, and Houtepen, A.J.

Abstract

Contains fulltext : 284727.pdf (Publisher’s version ) (Open Access)

Published
2022

6. Improving Li-ion interfacial transport in hybrid solid electrolytes

Author

Liu, Ming, Zhang, Shengnan, Eck, E.R.H. van, Wang, Chao, Ganapathy, S., Wagemaker, M., Liu, Ming, Zhang, Shengnan, Eck, E.R.H. van, Wang, Chao, Ganapathy, S., and Wagemaker, M.

Abstract

18 augustus 2022, Contains fulltext : 253724.pdf (Publisher’s version ) (Closed access)

Published
2022

7. Phase Behavior and Ion Dynamics of Nanoconfined LiBH4 in Silica

Author

Lambregts, S.F.H., Eck, E.R.H. van, Suwarno, ?, Ngene, P., Jongh, P.E. de, Kentgens, Arno P.M., Lambregts, S.F.H., Eck, E.R.H. van, Suwarno, ?, Ngene, P., Jongh, P.E. de, and Kentgens, Arno P.M.

Abstract

Contains fulltext : 209542.pdf (publisher's version ) (Open Access)

Published
2019

8. Manipulating the Optical Properties of Carbon Dots by Fine-Tuning their Structural Features

Author

Luo, Hui, Papaioannou, Nikolaos, Salvadori, Enrico, Roessler, Maxie M., Ploenes, Gereon, Eck, E.R.H. van, Dimitrov, Stoichko D., Titirici, Maria-Magdalena, Luo, Hui, Papaioannou, Nikolaos, Salvadori, Enrico, Roessler, Maxie M., Ploenes, Gereon, Eck, E.R.H. van, Dimitrov, Stoichko D., and Titirici, Maria-Magdalena

Abstract

Contains fulltext : 207736.pdf (publisher's version ) (Closed access)

Published
2019

9. Preactive Site in Ziegler-Natta Catalysts

Author

Blaakmeer, E.S., Wensink, Frank J., Eck, E.R.H. van, Wijs, Gilles A. de, Kentgens, Arno P.M., Blaakmeer, E.S., Wensink, Frank J., Eck, E.R.H. van, Wijs, Gilles A. de, and Kentgens, Arno P.M.

Abstract

Contains fulltext : 205049.pdf (publisher's version ) (Open Access)

Published
2019

11. Investigation of Li-ion transport in Li7P3S11 and solid-state lithium batteries

Author

Yu, C., Ganapathy, S., Eck, E.R.H. van, Eijck, Lambert van, Klerk, Niek de, Kelder, E.M., Wagemaker, M., Yu, C., Ganapathy, S., Eck, E.R.H. van, Eijck, Lambert van, Klerk, Niek de, Kelder, E.M., and Wagemaker, M.

Abstract

Contains fulltext : 206087.pdf (publisher's version ) (Closed access)

Published
2019

13. Exploring the mechanism of solid-state phase transitions in molecular crystals

Author

Cuppen, H.M., Vlieg, E., Meekes, H.L.M., Eck, E.R.H. van, Smets, M.M.H., Cuppen, H.M., Vlieg, E., Meekes, H.L.M., Eck, E.R.H. van, and Smets, M.M.H.

Abstract

Radboud University, 28 september 2018, Promotores : Cuppen, H.M., Vlieg, E. Co-promotores : Meekes, H.L.M., Eck, E.R.H. van, Contains fulltext : 195017.pdf (publisher's version ) (Open Access)

Published
2018

14. MgCl2-Supported Ziegler-Natta Catalysts; An NMR Perspective

Author

Kentgens, A.P.M., Eck, E.R.H. van, Blaakmeer, E.S., Kentgens, A.P.M., Eck, E.R.H. van, and Blaakmeer, E.S.

Abstract

Radboud University, 8 november 2018, Promotor : Kentgens, A.P.M. Co-promotor : Eck, E.R.H. van, Contains fulltext : 196533.pdf (publisher's version ) (Open Access), Ziegler-Natta catalysts (ZNCs) for the production of isotactic polypropylene are one of the most important industrial catalysts, yet they are still not properly understood at the molecular level. This work presents studies of these catalysts using solid state NMR. Different parts of Ziegler-Natta catalyst model systems have been studied in detail, including the donors, the cocatalyst and the TiCl4 adsorption site. The MgCl2-support is readily observed using 25Mg and 35Cl NMR. The surface sites of these nanoparticles are more difficult to observe. A new method, employing 2D nutation NMR of the satellite transitions, to differentiate between central and satellite transitions is introduced. Distinctive patterns originate from the nutation of the satellites that can be clearly set apart from the nutation behaviour of extensively broadened central transitions. 1H NMR showed, for the first time, the presence of Al-methyl groups in MgCl2/Al-alkyl adducts, which also helped to assign the 27Al spectra. The Al-alkyls were found to be very reactive and a variety of resonances was detected, indicating a multitude of coordination modes. This might be one of the reasons why only a fraction of the titanium in the catalyst system is converted into active Ti3+ species. Titanium chlorides are studied as reference compounds using 35Cl and 47,49Ti NMR. Ti signal could also be obtained for varying ZNC samples. Interestingly, the resulting line shapes appear very similar, suggesting that the titanium coordination is not influenced by donors or cocatalyst. Using correlation experiments, interactions between different components are probed. The use of 1H and 13C NMR, in a tandem approach with DFT calculations, proved to be a fruitful method to investigate the preferential adsorption sites of different donors on the MgCl2 surface.

Published
2018

17. Tail gas catalyzed N2O decomposition over Fe-beta zeolite. On the promoting role of framework connected AlO6 sites in the vicinity of Fe by controlled dealumination during exchange

Author

Melian-Cabrera, I., Eck, E.R.H. van, Espinosa, S., Siles-Quesada, S., Falco, L., Kentgens, A.P.M., Kapteijn, F., Moulijn, J.A., Melian-Cabrera, I., Eck, E.R.H. van, Espinosa, S., Siles-Quesada, S., Falco, L., Kentgens, A.P.M., Kapteijn, F., and Moulijn, J.A.

Abstract

Contains fulltext : 169088.pdf (publisher's version ) (Closed access)

Published
2017

18. Understanding the single-crystal-to-single-crystal solid-state phase transition of DL-methionine

Author

Smets, M.M.H., Brugman, S.J.T., Eck, E.R.H. van, Tinnemans, P.T., Meekes, H.L.M., Cuppen, H.M., Smets, M.M.H., Brugman, S.J.T., Eck, E.R.H. van, Tinnemans, P.T., Meekes, H.L.M., and Cuppen, H.M.

Abstract

Contains fulltext : 166274.pdf (publisher's version ) (Closed access), The solid-state phase transition between the low temperature β and the high temperature α forms of DL-methionine was characterised in detail using DSC, SCXRD, thermal stage polarisation microscopy and solid-state NMR. The thermodynamic transition point of the α ↔ β transition of DL-methionine was determined to fall between 306 and 317 K. The transition is kinetically hindered, as is indicated by a large hysteresis. Moreover, the transition rate during cooling is significantly lower than during heating and there is a large temperature region of coexistence. The kinetic barriers involved are lower for single crystals than for powders. DL-Methionine crystals consist of 2D hydrogen-bonded bilayers interconnected by weak Van der Waals interactions. The crystals transform layer-wise, without complete delamination or deterioration, and with a transition front that propagates perpendicular to the layers and a relatively fast transition within one layer. The fast kinetics within the plane of the layers, combined with the faster kinetics in single crystals, indicate that cooperative motion could play a role in this single-crystal-to-single-crystal phase transition.

Published
2016

21. Solid-State NMR Investigations of MgCl2 Catalyst Support

Author

Blaakmeer, E.S., Antinucci, G., Busico, V., Eck, E.R.H. van, Kentgens, A.P.M., Blaakmeer, E.S., Antinucci, G., Busico, V., Eck, E.R.H. van, and Kentgens, A.P.M.

Abstract

Contains fulltext : 158680.pdf (publisher's version ) (Closed access)

Published
2016

28. Desilication and silylation of mo/hzsm-5 for methane dehydroaromatization

Author

Tempelman, C.H.L., Rodrigues, V.O. de, Eck, E.R.H. van, Magusin, P.C.M.M., Hensen, E.J.M., Tempelman, C.H.L., Rodrigues, V.O. de, Eck, E.R.H. van, Magusin, P.C.M.M., and Hensen, E.J.M.

Abstract

Contains fulltext : 140158.pdf (publisher's version ) (Closed access)

Published
2015

29. A fast and activatable cross-linking strategy for hydrogel formation

Author

Jonker, A.M., Borrmann, A., Eck, E.R.H. van, Delft, F.L. van, Lowik, D.W.P.M., Hest, J.C.M. van, Jonker, A.M., Borrmann, A., Eck, E.R.H. van, Delft, F.L. van, Lowik, D.W.P.M., and Hest, J.C.M. van

Abstract

Contains fulltext : 140104.pdf (publisher's version ) (Closed access)

Published
2015

30. Accelerated testing of thermal control coatings using synchrotron radiation and evaluation of materials performance

Author

Fischer, H.R., Butenko, Y.V., Mooney, C., Semprimoschnig, C., Verkuijlen, M.H.W., Eck, E.R.H. van, Gerber, T., Kleiman, J., Tagawa, M., Kimoto, Y., Kleiman, J., Tagawa, M., and Kimoto, Y.

Subjects
Materials science, business.industry, Electrical engineering, Synchrotron radiation, chemistry.chemical_element, Crystal structure, Radiation, Solid State NMR, Thermal control, Oxygen, Synchrotron, law.invention, Metal, chemistry, law, visual_art, visual_art.visual_art_medium, Irradiation, Composite material, business
Abstract

Accelerated testing of white thermal control coatings was performed using the high intensity UV radiation generated by a synchrotron and resulting in a substantial shortening of test times. The origin of coloration of metal oxides upon UV irradiation has been identified to be most likely a generation of oxygen vacancies connected with the appearance of colour centers in the crystal lattice.

Published
2013
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33. Colloidal silica rods: Material properties and fluorescent labeling

Author

Kuijk, A., Imhof, A., Verkuijlen, M.H.W., Besseling, T.H., Eck, E.R.H. van, Blaaderen, A. van, Kuijk, A., Imhof, A., Verkuijlen, M.H.W., Besseling, T.H., Eck, E.R.H. van, and Blaaderen, A. van

Abstract

Contains fulltext : 131472.pdf (publisher's version ) (Closed access)

Published
2014

40. Zeolites and Solid State NMR

Author

Eck, E.R.H. van

Subjects
Solid State NMR
Abstract

Item does not contain fulltext NSRIM Symposium, 07 mei 2004

Published
2004

45. MicroMAS NMR : a study of nano liter volume solid samples

Author

Kentgens, A.P.M., Eck, E.R.H. van, Vasa, S.K., Kentgens, A.P.M., Eck, E.R.H. van, and Vasa, S.K.

Abstract

Radboud Universiteit Nijmegen, 30 mei 2013, Promotor : Kentgens, A.P.M. Co-promotor : Eck, E.R.H. van, Contains fulltext : 107676.pdf (publisher's version ) (Open Access)

Published
2013

49. Direct backbone structure determination of polyisocyanodipeptide using solid-state nuclear magnetic resonance

Author

Gowda, C.M., Eck, E.R.H. van, Buul, A.M. van, Schwartz, E., Pruissen, G.W.P. van, Cornelissen, J.J.L.M., Rowan, A.E., Nolte, R.J.M., Kentgens, A.P.M., Gowda, C.M., Eck, E.R.H. van, Buul, A.M. van, Schwartz, E., Pruissen, G.W.P. van, Cornelissen, J.J.L.M., Rowan, A.E., Nolte, R.J.M., and Kentgens, A.P.M.

Abstract

Contains fulltext : 93812.pdf (publisher's version ) (Closed access)

Published
2012

50. Nanoconfined libh4 and enhanced mobility of li+ and bh4- studied by solid-state nmr

Author

Verkuijlen, M.H.W., Ngene, P., Kort, D.W. de, Barre, C., Nale, A., Eck, E.R.H. van, Bentum, P.J.M. van, Jongh, P.E. de, Kentgens, A.P.M., Verkuijlen, M.H.W., Ngene, P., Kort, D.W. de, Barre, C., Nale, A., Eck, E.R.H. van, Bentum, P.J.M. van, Jongh, P.E. de, and Kentgens, A.P.M.

Abstract

Contains fulltext : 103552.pdf (publisher's version ) (Closed access)

Published
2012

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