Author: "CSNSM PCI" / Publication Year Range: Last 50 years - Searchworks@Jio Institute Digital Library Search Results

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134 results on '"CSNSM PCI"'

1. An analysis of binary microlensing event OGLE-2015-BLG-0060

Author: Tsapras, Y., Cassan, A., Ranc, C., Bachelet, E., Street, R., Udalski, A., Hundertmark, M., Bozza, V., Beaulieu, J. P., Marquette, J. B., Euteneuer, E., Figuera Jaimes, R., Calchi Novati, S., Bramich, D. M., Dominik, M., Jaimes, R. Figuera, Horne, K., Mao, S., Menzies, J., Schmidt, R., Snodgrass, C., Steele, I. A., Wambsganss, J., Mróz, P., Szymański, M. K., Soszyński, I., Skowron, J., Pietrukowicz, P., Kozłowski, S., Poleski, R., Ulaczyk, K., PAWLAK, M., Jørgensen, U. G., Skottfelt, J., Popovas, A., Ciceri, S., Korhonen, H., Kuffmeier, M., Evans, D. F., Peixinho, N., Hinse, T. C., Burgdorf, M. J., Southworth, J., Tronsgaard, R., Kerins, E., Andersen, M. I., Rahvar, S., Wang, Y., Wertz, O., Rabus, M., Novati, S. Calchi, D'Ago, G., Scarpetta, G., Mancini, L., Abe, F., Asakura, Y., Bennett, D. P., Bhattacharya, A., Donachie, M., Evans, P., Fukui, A., Hirao, Y., Itow, Y., Kawasaki, K., Koshimoto, N., Li, M. C. A., Ling, C. H., Masuda, K., Matsubara, Y., Muraki, Y., Miyazaki, S., Nagakane, M., Ohnishi, K., Rattenbury, N., Saito, T. O., Sharan, A., Shibai, H., Sullivan, D. J., Sumi, T., Suzuki, D., Tristram, P. J., Yamada, T., Yonehara, A., Figuera Jaimes, R, Calchi Novati, S, D’Ago, G, Jaimes, R Figuera, Novati, S Calchi, Astronomische Rechen-Institut [Heidelberg] (ARI), Zentrum für Astronomie der Universität Heidelberg (ZAH), Universität Heidelberg [Heidelberg]-Universität Heidelberg [Heidelberg], M2A 2019, Laboratoire d'Astrophysique de Bordeaux [Pessac] (LAB), Université de Bordeaux (UB)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Bordeaux (UB)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Senckenberg Institute, Geophysical Laboratory [Carnegie Institution], Carnegie Institution for Science [Washington], NSF Center for EUV Science and Technology, NSF, Ifremer (COP), Institut Français de Recherche pour l'Exploitation de la Mer (IFREMER), CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), School of Chemical and Physical Sciences [Keele], Keele University [Keele], Okayama Astrophysical Observatory, National Astronomical Observatory of Japan (NAOJ), Department of Materials Science [Tokyo], Tokyo Institute of Technology [Tokyo] (TITECH), Laboratory for Intelligent Systems and Informatics, Department of Mechano-Informatics Graduate School of Information Science and Technology, University of Tokyo, Tokyo, Japan (ISI laboratory), University of Tokyo (UTokyo), Atmosphere and Ocean Research Institute [Kashiwa-shi] (AORI), Institut d'Astrophysique de Paris (IAP), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC), NASA Goddard Space Flight Center (GSFC), Astronomical Observatory [Warsaw], Faculty of Physics [Warsaw] (FUW), University of Warsaw (UW)-University of Warsaw (UW), Space Science Department of ESA, European Space Research and Technology Centre (ESTEC), European Space Agency (ESA)-European Space Agency (ESA), Max-Planck-Institut für Sonnensystemforschung (MPS), Max-Planck-Gesellschaft, Max-Planck-Institut für Astronomie (MPIA), Ohio State University [Columbus] (OSU), Niels Bohr Institute [Copenhagen] (NBI), Faculty of Science [Copenhagen], University of Copenhagen = Københavns Universitet (KU)-University of Copenhagen = Københavns Universitet (KU), Kuopio Unit [FMI], Finnish Meteorological Institute (FMI), Laboratoire d'études spatiales et d'instrumentation en astrophysique (LESIA), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université Paris Diderot - Paris 7 (UPD7)-Centre National de la Recherche Scientifique (CNRS), University of Copenhagen = Københavns Universitet (KU), Argelander Institute for Astronomy (AlfA), Rheinische Friedrich-Wilhelms-Universität Bonn, Instituto de Astrofisica de Canarias (IAC), Nagoya University, Department of Physics [Notre Dame], University of Notre Dame [Indiana] (UND), University of Auckland [Auckland], Osaka University [Osaka], Tokyo University of Science [Tokyo], Department of Chemistry, Université de Tsukuba = University of Tsukuba, Laboratoire d'Astrophysique de Marseille (LAM), Aix Marseille Université (AMU)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS), Department of Earth and Space Science [Toyonaka-shi], Osaka University, Tokyo University Sci. Dept. Sci. & Technol., The University of Tokyo (UTokyo), Science & Technology Facilities Council, University of St Andrews. St Andrews Centre for Exoplanet Science, University of St Andrews. School of Physics and Astronomy, Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Agence Spatiale Européenne = European Space Agency (ESA)-Agence Spatiale Européenne = European Space Agency (ESA), Max-Planck-Institut für Sonnensystemforschung = Max Planck Institute for Solar System Research (MPS), University of Copenhagen = Københavns Universitet (UCPH)-University of Copenhagen = Københavns Universitet (UCPH), University of Copenhagen = Københavns Universitet (UCPH), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: GRAVITATIONAL LENS, T-EFF, Event (relativity), observational [methods], Binary number, Galaxy: Bulge, gravitational lensing: Micro, methods: Observational, techniques: Photometric, Astrophysics, gravitational lensing: micro, GALACTIC BULGE, 01 natural sciences, Galaxy: bulge, photometric [techniques], techniques: photometric, Bulge, Observatory, QB Astronomy, NETWORK, 010303 astronomy & astrophysics, QC, ComputingMilieux_MISCELLANEOUS, QB, Physics, Earth and Planetary Astrophysics (astro-ph.EP), MILKY-WAY, Astrophysics::Earth and Planetary Astrophysics, methods: observational, Astrophysics - Instrumentation and Methods for Astrophysics, [PHYS.ASTR.EP]Physics [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP], bulge [Galaxy], FOS: Physical sciences, Astrophysics::Cosmology and Extragalactic Astrophysics, Gravitational microlensing, Settore FIS/05 - Astronomia e Astrofisica, SYSTEMS, SEARCH, 0103 physical sciences, ALGORITHM, Instrumentation and Methods for Astrophysics (astro-ph.IM), Astrophysics::Galaxy Astrophysics, 010308 nuclear & particles physics, Order (ring theory), DAS, Astronomy and Astrophysics, Light curve, [SDU.ASTR.IM]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Instrumentation and Methods for Astrophysic [astro-ph.IM], QC Physics, Space and Planetary Science, [SDU]Sciences of the Universe [physics], DISCOVERY, astro-ph.EP, micro [gravitational lensing], Parallax, astro-ph.IM, Astrophysics - Earth and Planetary Astrophysics, PLANETS, QB799
Abstract: We present the analysis of stellar binary microlensing event OGLE-2015-BLG-0060 based on observations obtained from 13 different telescopes. Intensive coverage of the anomalous parts of the light curve was achieved by automated follow-up observations from the robotic telescopes of the Las Cumbres Observatory. We show that, for the first time, all main features of an anomalous microlensing event are well covered by follow-up data, allowing us to estimate the physical parameters of the lens. The strong detection of second-order effects in the event light curve necessitates the inclusion of longer-baseline survey data in order to constrain the parallax vector. We find that the event was most likely caused by a stellar binary-lens with masses $M_{\star1} = 0.87 \pm 0.12 M_{\odot}$ and $M_{\star2} = 0.77 \pm 0.11 M_{\odot}$. The distance to the lensing system is 6.41 $\pm 0.14$ kpc and the projected separation between the two components is 13.85 $\pm 0.16$ AU. Alternative interpretations are also considered., Comment: 13 pages, 5 figures, Published in MNRAS
Published: 2019
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2. Damage accumulation in MgO irradiated with MeV Au ions at elevated temperatures

Author: Lionel Thomé, Diana Bachiller-Perea, Moni Behar, Aurélien Debelle, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM PCI), and Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Saclay-Univ. Paris-Sud
Subjects: Diffraction, Nuclear and High Energy Physics, Materials science, MIGRATION, Annealing (metallurgy), Analytical chemistry, Oxide, MgO, 02 engineering and technology, 01 natural sciences, Fluence, Ion, chemistry.chemical_compound, 0103 physical sciences, General Materials Science, Cubic zirconia, Irradiation, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], 010306 general physics, [PHYS]Physics [physics], ZIRCONIA, Irradiation damage, Radiochemistry, OXIDE, 021001 nanoscience & nanotechnology, Reciprocal lattice, Nuclear Energy and Engineering, chemistry, Ion irradiation, 0210 nano-technology, RBS/C
Abstract: International audience; The damage accumulation process in MgO single crystals under medium-energy heavy ion irradiation (1.2 MeV Au) at fluences up to 4 x 1014 cm(-2) has been studied at three different temperatures: 573, 773, and 1073 K. Disorder depth profiles have been determined through the use of the Rutherford back-scattering spectrometry in channeling configuration (RBS/C). The analysis of the RBS/C data reveals two steps in the MgO damage process, irrespective of the temperature. However, we find that for increasing irradiation temperature, the damage level decreases and the fluence at which the second step takes place increases. A shift of the damage peak at increasing fluence is observed for the three temperatures, although the position of the peak depends on the temperature. These results can be explained by an enhanced defect mobility which facilitates defect migration and may favor defect annealing. X-ray diffraction reciprocal space maps confirm the results obtained with the RBS/C technique. (C) 2016 Elsevier B.V. All rights reserved.
Published: 2016
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3. How relative defect migration energies drive contrasting temperature-dependent microstructural evolution in irradiated ceramics

Author: Alexandre Boulle, Enrique Martínez, Jean-Paul Crocombette, Frédérico Garrido, Lionel Thomé, Blas P. Uberuaga, Moni Behar, Yara Haddad, Aurélien Debelle, Diana Bachiller-Perea, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Service de recherches de métallurgie physique (SRMP), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, IRCER - Axe 3 : organisation structurale multiéchelle des matériaux (IRCER-AXE3), Institut de Recherche sur les CERamiques (IRCER), Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM PCI), Université Paris-Saclay-Univ. Paris-Sud-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3), Universidad Federal de Río Grande del Sur, Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), and Los Alamos National Laboratory (LANL)
Subjects: Diffraction, Materials science, Physics and Astronomy (miscellaneous), Condensed matter physics, 02 engineering and technology, Rate equation, [CHIM.MATE]Chemical Sciences/Material chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, Ion, [SPI.MAT]Engineering Sciences [physics]/Materials, visual_art, Vacancy defect, 0103 physical sciences, visual_art.visual_art_medium, General Materials Science, Cubic zirconia, Ceramic, Irradiation, 010306 general physics, 0210 nano-technology, Energy (signal processing), ComputingMilieux_MISCELLANEOUS
Abstract: Ceramic materials have become widely used in various fields of material science, and ceramic oxides such as cubic zirconia (c-${\mathrm{ZrO}}_{2})$ and magnesia (MgO) are candidate materials for nuclear energy applications. For the corresponding in-service conditions of these materials, there is a crucial need in studies at moderate or high temperatures of the physical phenomena underlying the damage buildup under irradiation. In the present work, we show, using x-ray diffraction, that these two materials exhibit a similar damage accumulation process under ion irradiation at fixed temperature. However, they display an unexpected opposite damaging rate to changes in the irradiation temperature. In fact, as the temperature is increased, the final damage state is reached earlier in c-${\mathrm{ZrO}}_{2}$ while it is delayed in MgO. Rate equation cluster dynamics simulations show that defect clustering is favored over defect recombination in c-${\mathrm{ZrO}}_{2}$, but the situation is reversed for MgO, explaining the observed opposite response to temperature of the two materials. This contrasting behavior can be rationalized in terms of nonequivalent interstitial versus vacancy defect migration energies in MgO. We finally demonstrate that these results allow for a qualitative prediction of the evolution of the experimental irradiation-induced disorder with temperature, henceforth potentially reducing the cost in selecting and developing ad hoc materials.
Published: 2018
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4. Multi-scale simulation of the experimental response of ion-irradiated zirconium carbide: Role of interstitial clustering

Author: Aurélien Debelle, Lionel Thomé, S. Pellegrino, Patrick Trocellier, Thomas Jourdan, Jean-Paul Crocombette, Service de recherches de métallurgie physique (SRMP), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Materials science, Polymers and Plastics, Ion beam, 02 engineering and technology, 01 natural sciences, Molecular physics, Fluence, Ion, Zirconium carbide, Interstitial clusters, chemistry.chemical_compound, 0103 physical sciences, Irradiation, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], Diffusion (business), [PHYS]Physics [physics], 010302 applied physics, Metals and Alloys, Rate equation, 021001 nanoscience & nanotechnology, Rate equation cluster dynamics, Electronic, Optical and Magnetic Materials, Crystallography, chemistry, Ion irradiation, Transmission electron microscopy, Ceramics and Composites, 0210 nano-technology
Abstract: International audience; The response of zirconium carbide to heavy-ion irradiation at room temperature has been studied by X-ray diffraction, ion channeling and transmission electron microscopy. Below 5 × 1014 cm−2, we observe a build-up of elastic strain with increasing fluences. At this threshold fluence the strain is released and important dechanneling appears as well as visible TEM damage. With increasing fluence, this damage is found to spread in the material deeper than the depth of direct damaging by the ion beam. These experimental observations are reproduced and explained by Density Functional Theory informed Rate Equation Cluster Dynamics simulations. Simulations show that the response of ZrC upon ion-irradiation is driven by the diffusion and clustering of interstitials. The two-step evolution seen in experiments stems from the growth of interstitial clusters with a concomitant starvation of the smallest clusters induced by the continuous accumulation of vacancies. The damaging of the material beyond the range of primary damage is driven by diffusion of interstitials.
Published: 2016
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5. Damage processes in MgO irradiated with medium-energy heavy ions

Author: Aurélien Debelle, Sandra Moll, William J. Weber, Jacek Jagielski, Lionel Thomé, Yanwen Zhang, Jean-Paul Crocombette, Z. Zihua, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Department of Mechanical and Aerospace Engineering [Princeton] (MAE), Princeton University, CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Institute of Electronic Materials Technology (IEMT), Institute of Electronic Materials Technology, Pacific Northwest National Laboratory (PNNL), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: Materials science, [PHYS.NUCL]Physics [physics]/Nuclear Theory [nucl-th], Polymers and Plastics, Metals and Alloys, Analytical chemistry, [PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex], Rutherford backscattering spectrometry, Electronic, Optical and Magnetic Materials, Ion, Secondary ion mass spectrometry, Transmission electron microscopy, Nuclear reaction analysis, Ceramics and Composites, Cubic zirconia, Irradiation, Atomic physics, medium-energy, Yttria-stabilized zirconia
Abstract: International audience; The micro-structural modifications produced in MgO single crystals exposed to medium-energy heavy ions (1.2-MeV Au) were investigated using Rutherford backscattering spectrometry in channeling geometry coupled to Monte-Carlo analyses, secondary ion mass spectrometry, X-ray diffraction and transmission electron microscopy. The damage accumulation and the elastic strain variation were interpreted in the framework of the multi-step damage accumulation (MSDA) model. Both build-ups follow a multi-step process similar to that recently observed for ion-irradiated yttria-stabilized zirconia (YSZ) single crystals. However, in MgO, an unexpectedly high disorder level occurs far beyond the theoretical damage distribution. These results strongly suggest that the migration of defects created in the near-surface layer is most likely at the origin of the broadening of the damage depth distribution in MgO.
Published: 2015
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6. Lattice strain in irradiated materials unveils a prevalent defect evolution mechanism

Author: Alain Chartier, Diana Bachiller-Perea, Frédérico Garrido, Thomas Jourdan, Alexandre Boulle, S. Pellegrino, Jean-Paul Crocombette, Jayanth Channagiri, Tien-Hien Nguyen, Aurélien Debelle, Denise Carpentier, Lionel Thomé, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Service de recherches de métallurgie physique (SRMP), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, IRCER - Axe 3 : organisation structurale multiéchelle des matériaux (IRCER-AXE3), Institut de Recherche sur les CERamiques (IRCER), Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Service de la Corrosion et du Comportement des Matériaux dans leur Environnement (SCCME), Département de Physico-Chimie (DPC), Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Science des Procédés Céramiques et de Traitements de Surface (SPCTS), Université de Limoges (UNILIM)-Ecole Nationale Supérieure de Céramique Industrielle (ENSCI)-Institut des Procédés Appliqués aux Matériaux (IPAM), Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM PCI), and Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Saclay-Univ. Paris-Sud
Subjects: Diffraction, computation, Materials science, Physics and Astronomy (miscellaneous), 02 engineering and technology, 01 natural sciences, Atomic units, Ion, [SPI.MAT]Engineering Sciences [physics]/Materials, Molecular dynamics, strain, 0103 physical sciences, General Materials Science, 010306 general physics, ComputingMilieux_MISCELLANEOUS, defects, atomic scale, Strain (chemistry), irradiation, Relaxation (NMR), [CHIM.MATE]Chemical Sciences/Material chemistry, 021001 nanoscience & nanotechnology, Microstructure, X-ray diffraction, Chemical physics, Dislocation, 0210 nano-technology
Abstract: International audience; Modification of materials using ion beams has become a widespread route to improve or design materials for advanced applications, from ion doping for microelectronic devices to emulation of nuclear reactor environments. Yet, despite decades of studies, major issues regarding ion/solidinteractions are not solved, one of them being the lattice-strain development process in irradiated crystals. In this work, we address this question using a consistent approach that combines X-ray diffraction (XRD) measurements with both molecular dynamics (MD) and rate equation clusterdynamics (RECD) simulations. We investigate four distinct materials that differ notably in terms of crystalline structure and nature of the atomic bonding. We demonstrate that these materials exhibit a common behaviour with respect to the strain development process. In fact, a strain build-upfollowed by a strain relaxation is observed in the four investigated cases. The strain variation is unambiguously ascribed to a change in the defect configuration, as revealed by MD simulations. Strain development is due to the clustering of interstitial defects into dislocation loops, while the strain release is associated with the disappearance of these loops through their integration into a network of dislocation lines. RECD calculations of strain depth profiles, which are in agreement with experimental data, indicate that the driving force for the change in the defect nature is the defect clustering process. This study paves the way for quantitative predictions of the microstructure changes in irradiated materials.
Published: 2018
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7. The First Planetary Microlensing Event with Two Microlensed Source Stars

Author: Martin Donachie, Denis J. Sullivan, Michael D. Albrow, Andrew Williams, D. Dominis Prester, Kailash C. Sahu, K. R. Pollard, Joachim Wambsganss, Andrzej Udalski, Michał K. Szymański, Takahiro Sumi, Richard W. Pogge, Yutaka Matsubara, Masayuki Nagakane, S. R. Kane, M. Zub, J.-B. Marquette, Yuki Hirao, M. M. Rosenthal, M. Hundertmark, J.-P. Beaulieu, Krzysztof Ulaczyk, Man Cheung Alex Li, Darren L. DePoy, Ian A. Bond, Paul J. Tristram, Andrew A. Cole, C. H. Ling, Radosław Poleski, Andrew Gould, Clément Ranc, Yuichiro Asakura, Aparna Bhattacharya, Naoki Koshimoto, V. Batista, A. Sharan, Yasushi Muraki, Igor Soszyński, Atsunori Yonehara, R. Bowens-Rubin, S. Brillant, Keith Horne, P. Fouqué, Ch. Coutures, John A. R. Caldwell, S. Dieters, Phil Evans, Kimiaki Masuda, Chang S. Han, J. W. Menzies, N. Kains, Daisuke Suzuki, J. Donatowicz, Kouji Ohnishi, B. S. Gaudi, Nicholas J. Rattenbury, Jan Skowron, Fumio Abe, David P. Bennett, Yoshitaka Itow, Łukasz Wyrzykowski, Richard Barry, To. Saito, H. Oyokawa, Akihiko Fukui, Jennifer C. Yee, Etienne Bachelet, Institut d'Astrophysique de Paris (IAP), Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Okayama Astrophysical Observatory, National Astronomical Observatory of Japan (NAOJ), Laboratoire d'Etude et de Recherche sur le Matériau Bois (LERMAB), Université de Lorraine (UL), Institute of Geology and Geoinformation, Department of Materials Science [Tokyo], Tokyo Institute of Technology [Tokyo] (TITECH), Department of Earth and Space Science [Toyonaka-shi], Osaka University, Institut de Physique Nucléaire d'Orsay (IPNO), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Max-Planck-Institut für Astronomie (MPIA), Max-Planck-Gesellschaft, Department of Astronomy (Ohio State University), Ohio State University [Columbus] (OSU), Cyclotron Réunion Océan Indien (CYROI), Université de La Réunion (UR)-Centre Hospitalier Universitaire de La Réunion (CHU La Réunion), School of Mathematics and Physics, University of Tasmania [Hobart, Australia] (UTAS), Laboratoire Astrophysique de Toulouse-Tarbes (LATT), Centre National de la Recherche Scientifique (CNRS)-Observatoire Midi-Pyrénées (OMP), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées, M2A 2018, Laboratoire d'Astrophysique de Bordeaux [Pessac] (LAB), Université de Bordeaux (UB)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Bordeaux (UB)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Department of Physics and Astronomy [Leicester], University of Leicester, Astronomische Rechen-Institut [Heidelberg] (ARI), Zentrum für Astronomie der Universität Heidelberg (ZAH), Universität Heidelberg [Heidelberg]-Universität Heidelberg [Heidelberg], Cranfield University, University of St Andrews. School of Physics and Astronomy, and University of St Andrews. St Andrews Centre for Exoplanet Science
Subjects: NDAS, FOS: Physical sciences, gravitational lensing: micro, Astrophysics, Astrophysics::Cosmology and Extragalactic Astrophysics, Gravitational microlensing, 01 natural sciences, micro [Gravitational lensing], Planet, 0103 physical sciences, Binary star, QB Astronomy, Astrophysics::Solar and Stellar Astrophysics, planetary systems, 010303 astronomy & astrophysics, QC, ComputingMilieux_MISCELLANEOUS, Astrophysics::Galaxy Astrophysics, QB, Earth and Planetary Astrophysics (astro-ph.EP), Physics, 010308 nuclear & particles physics, Astronomy and Astrophysics, Planetary system, Light curve, Exoplanet, [SDU.ASTR.IM]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Instrumentation and Methods for Astrophysic [astro-ph.IM], Planetary systems, Stars, QC Physics, Gravitational lens, Space and Planetary Science, Astrophysics::Earth and Planetary Astrophysics, Astrophysics - Earth and Planetary Astrophysics
Abstract: 著者人数: 68名(所属. 宇宙航空研究開発機構宇宙科学研究所(JAXA)(ISAS): 鈴木, 大介), Accepted: 2018-02-06, 資料番号: SA1170273000
Published: 2017
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8. Annealing Effect on the Structural and Magnetic Properties of Mn-Implanted 6H-SiC

Author: Alain Declémy, Khalid Bouziane, Maya Al Azri, Lionel Thomé, M. E. Elzain, Michel Viret, Salim M. Chérif, CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Service de physique de l'état condensé (SPEC - UMR3680), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: [PHYS]Physics [physics], 010302 applied physics, silicon carbide (SiC), Electron probe microanalysis, Materials science, Annealing (metallurgy), Analytical chemistry, diluted magnetic semiconductors (DMSs), 02 engineering and technology, 021001 nanoscience & nanotechnology, 01 natural sciences, Fluence, Spectral line, Electronic, Optical and Magnetic Materials, Dilution, Magnetization, 0103 physical sciences, Annealing effect, implantation, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], Electrical and Electronic Engineering, 0210 nano-technology, Spectroscopy
Abstract: International audience; n-type 6H-SiC(0001) substrates were implanted with a fluence of Mn+ 5x 10(16) (maximum Mn content of 7%), with implantation energy of 80 keV and substrate temperature of 365 degrees C to promote recrystallization. The samples were characterized using Rutherford backscattering and channeling (RBS/C) spectroscopy and electron probe microanalysis in the energy dispersive X-ray (EPMA-EDX) technique; while the magnetization was studied using a superconducting quantum interference device techniques. In the as-implanted sample, three well-defined specific defect zones were identified as deduced from the analysis of RBS/C spectra. It is shown that the two main vacancy-related and interstitial-related defects undergo limited changes when annealing at 800 degrees C, while a major recovery is obtained after annealing at 1100 degrees C. Strain relaxation was also observed upon annealing as determined from HRXRD. Magnetization was strongly reduced with increasing annealing temperature from 800 degrees C to 1600 degrees C. This effect seems to be related to the dilution effect (reduction of Mn content) due to the local diffusion of Mn as suggested from the results obtained using both RBS/C and EPMA-EDX techniques.
Published: 2014
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9. Effects of thermal annealing on the evolution of He bubbles in zirconia

Author: Sha Yan, Tengfei Yang, Chenxu Wang, Gihan Velisa, A. Debelle, Yugang Wang, Shuyan Kong, Lionel Thomé, Jianming Xue, CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Nuclear and High Energy Physics, Materials science, Irradiation stability, Thermal annealing, Annealing (metallurgy), Economies of agglomeration, Bubble, He bubbles, Fluence, Ion, Crystal, Crystallography, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Defects, Cubic zirconia, Liquid bubble, Composite material, Instrumentation
Abstract: Single crystals of yttria-stabilized zirconia were implanted with 100 keV He ions at two fluences of 9 × 1016 and 3 × 1017 cm−2 (5 and 17 He at.%). In order to investigate the effect of thermal annealing on the evolution of both zirconia lattice and implanted He, the samples were annealed at several temperatures ranging from 500 °C to 1400 °C. Three complementary analysis techniques, RBS/C, AFM and TEM were used to study structural damage and surface morphology of the crystal before and after implantation. Results show different He evolution phenomena under the two implantation fluences. It is inferred that, at the lower fluence, the migration and agglomeration of He ions lead to bubble formation after annealing. These bubbles jack up sample surface causing the deformation of surface region and the damage level of surface region increase accordingly. As the temperature continues to increase, He gradually releases and the damage recovers. However, at the higher fluence, the He concentration is sufficient to induce bubble precipitation without annealing. He release and damage recovering is less efficient upon annealing. 2014 Elsevier B.V. All rights reserved
Published: 2014
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10. Experimental approach and atomistic simulations to investigate the radiation tolerance of complex oxides: Application to the amorphization of pyrochlores

Author: Clara Grygiel, C. Legros, Gaël Sattonnay, Lionel Thomé, Isabelle Monnet, R. Tetot, N. Sellami, Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), Normandie Université (NU), Université Paris-Sud - Paris 11 (UP11)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), and Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Nuclear and High Energy Physics, Materials science, Scattering, Coordination number, Pyrochlore, engineering.material, Charged particle, Ion, Crystallography, Ion irradiation Pyrochlores X-ray diffraction Atomistic simulation, Chemical physics, X-ray crystallography, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], engineering, Irradiation, Instrumentation, Radiation resistance
Abstract: Both experimental approach and atomistic simulations are performed in order to investigate the influence of the composition of pyrochlores on their radiation tolerance. Therefore, Gd2Ti2O7 and Gd2Zr2O7 were irradiated with 4 MeV Au and 92 MeV Xe ions in order to study the structural changes induced by low and high-energy irradiations. XRD results show that, for both irradiations, the structural modifications are strongly dependent on the sample composition: Gd2Ti2O7 is readily amorphized, whereas Gd2Zr2O7 is transformed into a radiation-resistant anion-deficient fluorite structure. Using atomistic simulations with new interatomic potentials derived from the SMTB-Q model, the lattice properties and the defect formation energies were calculated in Gd2Ti2O7 and Gd2Zr2O7. Calculations show that titanates have a more covalent character than zirconates. Moreover, in Gd2Ti2O7 the formation of cation antisite defects leads to strong local distortions around Ti-defects and to a decrease of the Ti coordination number, which are not observed in Gd2Zr2O7. Thus, the radiation resistance is related to the defect stability: the accumulation of structural distortions around Ti-defects could drive the Gd2Ti2O7 amorphization induced by irradiation. 2014 Elsevier B.V. All rights reserved
Published: 2014
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11. Structural stability of Nd2Zr2O7 pyrochlore ion-irradiated in a broad energy range

Author: Clara Grygiel, Lionel Thomé, N. Sellami, Jacek Jagielski, I. Jozwik-Biala, Gaël Sattonnay, Isabelle Monnet, C. Legros, Patrick Simon, Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), Université Paris-Sud - Paris 11 (UP11)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS), The Andrzej Soltan Institute for Nuclear Studies, Institute of Electronic Materials Technology (IEMT), Institute of Electronic Materials Technology, Conditions Extrêmes et Matériaux : Haute Température et Irradiation (CEMHTI), Université d'Orléans (UO)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), Normandie Université (NU), and Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université d'Orléans (UO)
Subjects: Materials science, Polymers and Plastics, Annealing (metallurgy), Pyrochlore, 02 engineering and technology, engineering.material, 01 natural sciences, Pyrochlores, Ion, symbols.namesake, High-resolution transmission electron microscopy, 0103 physical sciences, 010302 applied physics, Ion track, Metals and Alloys, Recrystallization (metallurgy), 021001 nanoscience & nanotechnology, X-ray diffraction, Electronic, Optical and Magnetic Materials, Crystallography, Ion irradiation, Raman spectroscopy, X-ray crystallography, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Ceramics and Composites, symbols, engineering, 0210 nano-technology
Abstract: The phase transformations induced by electronic excitation ( S e ) and ballistic processes ( S n ) in Nd 2 Zr 2 O 7 pyrochlores irradiated with heavy ions in three domains of energy (∼1 GeV, ∼100 MeV and a few MeV) were investigated by X-ray diffraction, Raman spectroscopy and transmission electron microscopy. In the S e regime at high energy, results show that: (i) ion tracks are formed above a S e threshold of 12.5 keV nm −1 ; (ii) both pyrochlore → anion-deficient fluorite phase transition and amorphization occur; (iii) total amorphization is always observed at the highest fluences; (iv) the internal structure (amount of amorphous phase vs. its anion-deficient fluorite counterpart) and the diameter of tracks depend on many parameters such as S e , the deposited energy density and the recrystallization rate. For irradiations performed with low-energy ions in the S n regime, only the anion-deficient fluorite phase is formed up to a dose of 40 dpa. Thus Nd 2 Zr 2 O 7 exhibits an unusual behaviour since this compound is amorphizable by S e and non-amorphizable by S n . Annealing of totally amorphized Nd 2 Zr 2 O 7 samples reveals strong differences in the recovery processes with other pyrochlore materials that are related to their different chemical compositions.
Published: 2013
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12. Ion irradiation studies of silver/amorphous carbon nanocomposite thin film

Author: J.C. Pivin, D.K. Avasthi, Rahul Singhal, Ramesh Chandra, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: Materials science, Physics::Instrumentation and Detectors, Physics::Medical Physics, Analytical chemistry, Physics::Optics, 02 engineering and technology, 7. Clean energy, 01 natural sciences, Ion, Condensed Matter::Materials Science, symbols.namesake, Swift heavy ion, Surface plasmon resonance, 0103 physical sciences, Materials Chemistry, Irradiation, Graphite, Nuclear Experiment, 010302 applied physics, Nanocomposite, Surfaces and Interfaces, General Chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, Surfaces, Coatings and Films, Amorphous carbon, Ion irradiation, Transmission electron microscopy, Raman spectroscopy, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], symbols, Nanoparticles, 0210 nano-technology
Abstract: We study the optical and microstructural properties of silver/amorphous carbon (Ag/a-C) nanocomposite thin film and its modification induced by swift heavy ion irradiation. Ag nanoparticles (NPs) embedded in a-C matrix were synthesized by co-sputtering of Ag and graphite by 1.5 keV neutral Ar atom beam. These Ag NPs were irradiated by 120 MeV Ag ions at different fluences ranging from 1 × 10 12 to 3 × 10 13 ions/cm 2 . Optical absorption studies revealed that surface plasmon resonance of Ag NPs in pristine film occurs at a wavelength of ~ 430 nm and it shows a blue shift (~ 26 nm) with increasing ion fluence up to 3 × 10 13 ions/cm 2 . Transmission electron microscopy and Rutherford backscattering spectroscopy were used to quantify particle size and metal atomic fraction, respectively, in the nanocomposite films. The growth of Ag NPs with bi-model distribution at a fluence of 3 × 10 13 ions/cm 2 was observed with ion irradiation. Raman spectroscopy was used to investigate the effect of heavy ion irradiation on carbon matrix. The blue shift in plasmonic wavelength is explained in terms of increase in sp 2 content in carbon matrix by heavy ion irradiation due to thermal energy deposition which leads to a decrease in dielectric properties of the matrix.
Published: 2013
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13. Proton beam modification of lead white pigments

Author: F. Miserque, P.C. Gutiérrez, Lionel Thomé, Lucile Beck, Service de recherches de métallurgie physique (SRMP), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, Centre de recherche et de restauration des musées de France (C2RMF), Centre National de la Recherche Scientifique (CNRS)-Ministère de la Culture et de la Communication (MCC), Laboratoire d'Etude de la Corrosion Aqueuse (LECA), Service de la Corrosion et du Comportement des Matériaux dans leur Environnement (SCCME), Département de Physico-Chimie (DPC), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Département de Physico-Chimie (DPC), CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Ministère de la Culture et de la Communication (MCC)-Centre National de la Recherche Scientifique (CNRS), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Pigments, Nuclear and High Energy Physics, Materials science, Inorganic chemistry, Analytical chemistry, UV treatments, chemistry.chemical_element, Zinc, Thermal treatment, 01 natural sciences, Annealing, Painting, symbols.namesake, Pigment, chemistry.chemical_compound, X-ray photoelectron spectroscopy, Ion beam modification, 0103 physical sciences, Irradiation, Instrumentation, 010302 applied physics, Calcite, 010401 analytical chemistry, 0104 chemical sciences, Titanium oxide, chemistry, Ion irradiation, visual_art, Raman spectroscopy, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], symbols, visual_art.visual_art_medium, sense organs
Abstract: Pigments and paint materials are known to be sensitive to particle irradiation. Occasionally, the analysis of paintings by PIXE can induce a slight or dark stain depending on the experimental conditions (beam current, dose, particle energy). In order to understand this discoloration, we have irradiated various types of art white pigments – lead white (hydrocerussite and basic lead sulfate), gypsum, calcite, zinc oxide and titanium oxide – with an external 3 MeV proton micro-beam commonly used for PIXE experiments. We have observed various sensitivities depending on the pigment. No visible change occurs for calcite and titanium oxide, whereas lead white pigments are very sensitive. For the majority of the studied compounds, the discoloration is proportional to the beam current and charge. The damage induced by proton beam irradiation in lead white pigments was studied by micro-Raman and XPS spectroscopies. Structural modifications and dehydration were detected. Damage recovery was investigated by thermal treatment and UV-light irradiation. The discoloration disappeared after one week of UV illumination, showing that PIXE experiments could be safely undertaken for pigments and paintings.
Published: 2013
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14. Effect of combined local variations in elastic and inelastic energy losses on the morphology of tracks in ion-irradiated materials

Author: Aurélien Debelle, Stamatis Mylonas, Lionel Thomé, Bruce W. Arey, Gaël Sattonnay, Isabelle Monnet, I. Jozwik-Biala, Libor Kovarik, Jacek Jagielski, Institute of Electronic Materials Technology (IEMT), Institute of Electronic Materials Technology, Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), Normandie Université (NU), Université Paris-Sud - Paris 11 (UP11)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), and Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Materials science, Polymers and Plastics, SOLIDS, Mineralogy, High resolution transmission electron microscopy, 02 engineering and technology, PRESSURE, 01 natural sciences, Molecular physics, Focused ion beam, Ion, Crystal, Tracks, 0103 physical sciences, Atom, SWIFT HEAVY-IONS, 010306 general physics, Envelope (waves), DAMAGE, Ion track, Metals and Alloys, Elastic energy, INORGANIC INSULATORS, 021001 nanoscience & nanotechnology, Electronic, Optical and Magnetic Materials, MODEL, Core (optical fiber), Ion irradiation, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Ceramics and Composites, Defects, 0210 nano-technology, PYROCHLORE
Abstract: Detailed analysis of the morphology of latent tracks created by swift heavy ions from the surface entry point on a pyrochlore crystal to the end of the ion trajectory reveals continuous changes in the track diameter as a function of ion deceleration, loss of track parallelism beyond a certain depth and the evolution from continuous to discontinuous tracks. The tracks exhibit a layered structure composed of a non-crystalline core surrounded by a strained crystalline envelope. Furthermore, surprising local increases in the diameter of the latent tracks are readily observed. This feature can be interpreted using a model based on the concept of effective local energy deposition, defined as the sum of the inelastic energy deposited by the swift track-forming ion and the elastic energy deposited by a primary knock-on atom inside the ion track. (C) 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
Published: 2013
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15. Comparison between bulk and thin foil ion irradiation of ultra high purity Fe

Author: B. Décamps, Robin Schäublin, A. Prokhodtseva, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: 010302 applied physics, Nuclear and High Energy Physics, Materials science, Single beam, Analytical chemistry, 02 engineering and technology, 021001 nanoscience & nanotechnology, 01 natural sciences, Ion, Ultra high purity, Nuclear Energy and Engineering, Transmission electron microscopy, 0103 physical sciences, Radiation damage, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], General Materials Science, Irradiation, Dislocation, 0210 nano-technology, FOIL method
Abstract: Accumulation of radiation damage in ultra high purity iron under self ion irradiation without and with simultaneous He implantation was investigated in bulk and thin foil form to assess, on the one hand, the effect of free surfaces and, on the other hand, the influence of He. Specimens were irradiated at room temperature to a dose of 0.8 dpa and similar to 900 appm He content. We found in thin foils after irradiation with single beam a majority of a(0) < 100 > type loops, while in the presence of He it is the 1/2 a(0) < 111 > type loops that prevail. In single beam irradiated bulk samples most of the loops are of 1/2 a(0) < 111 > type. In both bulk and thin foils density of defects visible in transmission electron microscope is considerably higher when He is implanted with prevailing 1/2 a(0) < 111 > dislocation loops, indicating that He stabilizes them. (C) 2013 Elsevier B.V. All rights reserved.
Published: 2013
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16. Impact of He and Cr on defect accumulation in ion-irradiated ultrahigh-purity Fe(Cr) alloys

Author: Amuthan Ramar, A. Prokhodtseva, B. Décamps, Robin Schäublin, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Microscope, Materials science, Polymers and Plastics, Ion beam, Population, Analytical chemistry, 02 engineering and technology, 01 natural sciences, 010305 fluids & plasmas, law.invention, Ion, Radiation damage, law, 0103 physical sciences, Irradiation, education, education.field_of_study, Number density, Metals and Alloys, 021001 nanoscience & nanotechnology, In situ transmission electron microscopy irradiation, Electronic, Optical and Magnetic Materials, Crystallography, Transmission electron microscopy, Fe(Cr) alloys, Ceramics and Composites, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], 0210 nano-technology
Abstract: The effect of He on the primary damage induced by irradiation in ultrahigh-purity (UHP) Fe and Fe(Cr) alloys was investigated by transmission electron microscopy (TEM). Materials were irradiated at room temperature in situ by TEM in a microscope coupled to two ion accelerators, simultaneously providing 500 keV Fe+ and 10 keV He+ ions. Single Fe ion and dual Fe and He ion beam experiments were performed up to a dose of 1 dpa and to a He content of up to 1000 appm. Defects appear in the form of nanometric black dots with sizes between 1 and 5 nm. Defocused images reveal a dense population of sub-nanometric cavities after both single-beam and dual-beam irradiation. In Fe(Cr) alloys, the number densities of visible black dot defects still resolved in TEM are significantly higher after single than after dual-beam irradiation. In UHP Fe, conversely, the presence of He strongly increases the defect number density. The presence of He changes a a(0)< 1 0 0 > dominated defect population to a 1/2a(0)< 1 1 1 > dominated one in all materials, and the more so in UHP Fe. It appears that Cr increases the number of visible defects relative to UHP Fe. The dependence with increasing Cr content is weak, however, showing only a slight decrease in the number densities. The decrease in the density of visible a(0)< 1 0 0 > loops and increase in the visible 1/2a(0)< 1 1 1 > loops in all materials when He is present supports the idea that visible a(0)< 1 0 0 > loops are formed by the interaction between mobile 1/2a(0)(1 1 1) loops, as the latter would be immobilized by He already at sub-microscopic sizes. It is concluded that the primary loop population is dominated by 1/2a(0)< 1 1 1 > loops. (C) 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
Published: 2013
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17. In situ Raman spectroscopy a technique to investigate the nuclear material modifications under ion beam irradiation

Author: Gutierrez, G., Miro, S., Bordas, E., Lepretre, F., Serruys, Y., Onofri, Claire, Thome, L., Garrido, F., Debelle, A., Sattonnay, G., Gosset, D., CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), CSNSM PCI, Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), and amplexor, amplexor
Subjects: [PHYS.NUCL] Physics [physics]/Nuclear Theory [nucl-th], [PHYS.NUCL]Physics [physics]/Nuclear Theory [nucl-th], [PHYS.NEXP] Physics [physics]/Nuclear Experiment [nucl-ex], Raman in-situ, [PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex], Irradiation mono et double faisceau
Abstract: International audience; Raman spectroscopy is an efficient technique to study the irradiation damage in nuclear materials [1]. Indeed it is possible to investigate the microstructural modifications and to monitor the damage build-up. In order to observe the dynamic evolution of materials under irradiation, in situ Raman setup has been developed on the triple beam chamber of the JANNUS-Saclay irradiation facility. The sample evolution can thus be followed by Raman spectroscopy during single, dual or triple ion beams irradiation. Irradiation damages of several nuclear materials under single ion beam have already been investigated by in situ Raman at JANNUS facility UO2 as nuclear fuel [1-2], SiC [1,3] and Zircaloy as cladding materials [1] and B4C as neutron absorber [4]. It appears that Raman spectroscopy is a good technique to study on-line crystalline phase changes or amorphization of irradiated iono-covalent solids. Moreover, the use of dual ion beam irradiation coupled with in situ Raman has highlighted combined effects of nuclear (Sn) and electronic (Se) energy losses, which can induce additive damage production (as in ZrO2) or competitive recovery processes (as in SiC), in good agreement with Rutherford backscattering channelling (RBS/C) measurements [3].This paper will give a review of these results and present the new in situ Raman results for single and double ion beam irradiations. A particular emphasis will be given to the synergetic Se/Sn effects.[1] S. Miro et al., J. Raman Spectrosc., 45, 481 (2015).[2] C. Onofri et al., NIM B, 371, 51 (2016).[3] L. Thome et al., JAP, 117, 105901 (2015).[4] D. Gosset et al. JNM, 476, 198 (2016).
Published: 2016

18. Kinetics of alpha ' precipitation in an electron-irradiated Fe15Cr alloy

Author: C. Pareige, Jean Henry, B. Décamps, O. Tissot, E. Meslin, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM PCI), Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Saclay-Univ. Paris-Sud, Groupe de physique des matériaux (GPM), Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Université de Caen Normandie (UNICAEN), Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), and Commissariat à l'énergie atomique et aux énergies alternatives (CEA)
Subjects: Materials science, Alloy, 02 engineering and technology, Atom probe, Precipitation, engineering.material, 01 natural sciences, law.invention, Ion, law, FE-CR ALLOYS, 0103 physical sciences, Electron beam processing, Radiation damage, General Materials Science, Neutron, Irradiation, STRUCTURAL-MATERIALS, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], 010302 applied physics, [PHYS]Physics [physics], Fe-Cr, CHALLENGES, STABILITY, Precipitation (chemistry), Mechanical Engineering, Radiochemistry, Metals and Alloys, Electron irradiation, 021001 nanoscience & nanotechnology, Condensed Matter Physics, RADIATION-DAMAGE, Mechanics of Materials, NEUTRON-IRRADIATION, engineering, 0210 nano-technology, Atom probe tomography (APT), PHASE-SEPARATION
Abstract: International audience; A high purity Fe15Cr alloy has been irradiated with 1 MeV electrons at 573 K to doses up to 0.7 dpa. Alpha' precipitates have been revealed by Atom Probe Tomography (APT). They were not associated with the irradiation induced defects confirming a radiation-enhanced mechanism. Comparison with literature shows that alpha' precipitation occurred after similar doses after neutron and electron irradiations but not under ion irradiation. Electron irradiation is more efficient to enhance alpha' precipitation. The same a Cr solubility limit as under neutron irradiation were found. alpha' Cr equilibrium composition at 573 K has been measured for the first time with APT.
Published: 2016
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19. X-ray diffraction study of the Y2Ti2O7 pyrochlore disordering sequence under irradiation

Author: Gaël Sattonnay, Neila Sellami, Jean-Paul Crocombette, Isabelle Monnet, Alain Chartier, Jean-Luc Béchade, Denis Menut, Aurélien Soulié, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM PCI), and Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Saclay-Univ. Paris-Sud
Subjects: Nuclear and High Energy Physics, Materials science, Pyrochlore, Mineralogy, 02 engineering and technology, engineering.material, 01 natural sciences, Molecular physics, Fluence, Condensed Matter::Disordered Systems and Neural Networks, Ion, Condensed Matter::Materials Science, Swift heavy ion, 0103 physical sciences, General Materials Science, Irradiation, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], High-resolution transmission electron microscopy, 010302 applied physics, [PHYS]Physics [physics], 021001 nanoscience & nanotechnology, Nuclear Energy and Engineering, X-ray crystallography, engineering, Frenkel defect, 0210 nano-technology
Abstract: International audience; The disordering sequence of Y2Ti2O7 pyrochlore, a nano-oxide phase that strengthens ODS steels under irradiation is studied in the experimental and modeling framework. XRD analysis has been performed considering both swift heavy ion and low energy/low mass ion irradiations. The simulation within molecular dynamics of Frenkel pair accumulation proves able to reproduce the variation of the amorphization fluence with temperature. XRD patterns calculated from the simulations reproduce well the patterns observed experimentally in the literature. Both experiments and calculations point to a first transition from pyrochlore to fluorite before an eventual amorphization. For swift heavy ion irradiations with 93 MeV Xe ions, tracks of direct impact amorphization are visible by HRTEM. Advanced refinement shows that one third of the pyrochlore impacted by an ion transforms into fluorite, while two third are directly amorphized.
Published: 2016
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20. Intrinsic defects and structural phase of ZnS nanocrystalline thin films: effects of substrate temperature

Author: Shiv P. Patel, Lokendra Kumar, J.C. Pivin, Ramesh Chandra, D. Kanjilal, CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: SOLAR-CELLS, Materials science, Photoluminescence, Band gap, Nanotechnology, 02 engineering and technology, Substrate (electronics), 01 natural sciences, Pulsed laser deposition, Phase (matter), SYNTHESIZED ZNS, 0103 physical sciences, NANOPARTICLES, Electrical and Electronic Engineering, Thin film, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], Wurtzite crystal structure, 010302 applied physics, [PHYS]Physics [physics], PULSED-LASER DEPOSITION, OPTICAL-PROPERTIES, 021001 nanoscience & nanotechnology, Condensed Matter Physics, Atomic and Molecular Physics, and Optics, Grain size, TRANSFORMATION, Electronic, Optical and Magnetic Materials, IRRADIATION, Chemical engineering, GROWTH, PHOTOLUMINESCENCE, 0210 nano-technology, TRANSITION
Abstract: International audience; Fabrications of ZnS nanocrystalline thin films at different substrate temperatures (T-S) of 200, 300 and 400 degrees C by means of pulsed laser deposition are presented. Thin film deposited at TS of 200 degrees C is in cubic zinc-blende (ZB) structure while those deposited at TS of 300 and 400 degrees C are in hexagonal wurtzite (W) phase. The grain size, surface roughness and bandgap of the films increases with increasing TS. The zinc vacancies and interstitials in the films increases while sulfur vacancies decreases with increasing TS. The variation of zinc and sulfur vacancies in ZnS films with TS is responsible for structural phase transition from ZB to W which causes the change in energy bandgap.
Published: 2016
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21. Monitoring of the microstructure of ion-irradiated nuclear ceramics by in situ Raman spectroscopy

Author: Miro, S., Bordas, E., Thome, L., Costantini J., -M., Lepretre, F., Trocellier, P., Serruys, Y., Beck, L., Gosset, D., Verlet, R., Huguet-Garcia, J., Tupin, M., Belleil, M., Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM PCI), and Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Saclay-Univ. Paris-Sud
Subjects: DAMAGE, [PHYS]Physics [physics], ZIRCONIA, ALLOYS, RECRYSTALLIZATION, PHASE-TRANSITION, SCATTERING, BEAM, IMPLANTED SILICON-CARBIDE, BORON-CARBIDE, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], AMORPHIZATION
Abstract: International audience; Raman spectroscopy is an efficient technique for studying the evolution of microstructure of materials under irradiation. For that purpose, a Raman spectrometer has been recently installed at the JANNUS-Saclay platform. In this paper, we describe the new setup for in situ experiments. These in situ experiments allowed following the microstructural evolution of different materials (SiC, ZrO2 and B4C) as a function of ion fluence on a single sample (either single crystal or polycrystalline ceramics) under the same irradiation conditions. Our results show that Raman spectroscopy is a versatile non-contact technique for studying on-line crystalline phase changes or amorphization of irradiated iono-covalent solids. A detailed analysis of Raman spectra is provided for the three materials (SiC, ZrO2 and B4C) investigated in this study, revealing quite different behaviors upon irradiation. Basically, Raman spectroscopy gives insight on these evolutions at the level of bonds given by specific phonon modes, in good agreement with Rutherford backscattering channeling (RBS/C), X-ray diffraction (XRD) or transmission electron microscopy (TEM) data, which provide information at a long-range scale. Copyright (c) 2015 John Wiley & Sons, Ltd.
Published: 2016
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22. Study of the initial stages of defect generation in ion-irradiated MgO at elevated temperatures using high-resolution X-ray diffraction

Author: Diana Bachiller-Perea, Jean-Paul Crocombette, Aurélien Debelle, Lionel Thomé, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM PCI), Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Saclay-Univ. Paris-Sud, Service de recherches de métallurgie physique (SRMP), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), and Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay
Subjects: Diffraction, Materials science, STRESS, Annealing (metallurgy), ENERGIES, Analytical chemistry, 02 engineering and technology, 01 natural sciences, Ion, 0103 physical sciences, Radiation damage, General Materials Science, Irradiation, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], MAGNESIUM-OXIDE, DISPLACEMENT, 010302 applied physics, [PHYS]Physics [physics], Mechanical Engineering, 021001 nanoscience & nanotechnology, Crystallographic defect, Crystallography, RADIATION-DAMAGE, Mechanics of Materials, CERAMICS, X-ray crystallography, Frenkel defect, POINT-DEFECTS, GROWTH, SINGLE-CRYSTALS, IMPLANTATION, 0210 nano-technology
Abstract: International audience; The initial stages of defect generation in magnesia (MgO) single crystals irradiated with 1.2 MeV Au+ ions at 573, 773, and 1073 K and at different fluences have been studied. High-resolution X-ray diffraction was used to measure the irradiation-induced elastic strain. Point-defect relaxation volumes were computed using density functional theory calculations. The defect concentration was then calculated. It was found to increase with ion fluence at all temperatures, with maximum values being similar to 0.46 % at 573 K, similar to 0.24 % at 773 K, and similar to 0.13 % at 1073 K. The decrease in the maximum strain with increasing temperature indicates a dynamic annealing. The defect generation efficiencies were found to be very low and the values obtained were in the range of similar to 2.4, 1.2, and 0.6 % at 573, 773, and 1073 K, respectively. An annealing effect due to electronic energy deposition is suspected to explain these low values.
Published: 2016
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23. Effect of temperature on the behavior of ion-irradiated cubic zirconia

Author: Lionel Thomé, Frédérico Garrido, Sandra Moll, A. Debelle, Gaël Sattonnay, Jacek Jagielski, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), Institute of Electronic Materials Technology (IEMT), Institute of Electronic Materials Technology, and The Andrzej Soltan Institute for Nuclear Studies
Subjects: Ceramics, Nuclear and High Energy Physics, Materials science, Analytical chemistry, 02 engineering and technology, 01 natural sciences, Ion, 0103 physical sciences, Cubic zirconia, Irradiation, Ceramic, Instrumentation, RBS, Yttria-stabilized zirconia, Channeling, 010302 applied physics, Range (particle radiation), 021001 nanoscience & nanotechnology, Rutherford backscattering spectrometry, Ion fluence, Crystallography, visual_art, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], visual_art.visual_art_medium, Zirconia, 0210 nano-technology
Abstract: Yttria-stabilized zirconia (YSZ) single crystals were irradiated with 4-MeV Au ions at several temperatures from RT up to 800 degrees C. For each temperature, the amount of damage created by irradiation was measured as a function of the ion fluence by Rutherford backscattering spectrometry in channeling geometry (RBS/C). In all cases the damage exhibits a peak around the ion projected range (similar to 500 nm) and it accumulates via a multi-step process. Furthermore, the damage build-up strongly depends on the irradiation temperature: the occurrence of the second stage of damage accumulation, which presents a high increase of the damage fraction, is shifted towards lower fluences as the temperature is increased. This effect may be explained by enhanced defect-clustering at high temperature. (C) 2011 Elsevier B.V. All rights reserved.
Published: 2012
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24. A comprehensive study of structural and magnetic properties of sputter deposited nickel–silica thin films

Author: Ramesh Chandra, R. Jayaganthan, Amit Kumar Chawla, Yogendra K. Gautam, Rajan Walia, J.C. Pivin, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: Magnetic measurement, Materials science, Analytical chemistry, chemistry.chemical_element, Nanoparticle, 02 engineering and technology, 01 natural sciences, Nanocomposites, Sputtering, 0103 physical sciences, General Materials Science, Thin film, RBS, 010302 applied physics, Nanocomposite, Mechanical Engineering, Superparamagnetism, Sputter deposition, 021001 nanoscience & nanotechnology, Condensed Matter Physics, Nickel, chemistry, Mechanics of Materials, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Particle size, 0210 nano-technology, Magnetron sputtering
Abstract: The present work reports the formation of Ni nanoparticles inside the SiO2 matrix and deals with the influence of Ni concentration on structural and magnetic properties of Ni–SiO2 nanocomposite thin films. The films with varying Ni concentration (20–55 at% measured by Rutherford back scattering spectroscopy) were deposited using DC/RF magnetron co-sputtering. TEM and XRD analysis reveal the formation of FCC Ni nanoparticles in all the samples. The particle size varies from 3 to 10 nm as a function of Ni concentration. The surface roughness of the films is also found to increase with increase in nickel concentration. Magnetic measurements show that the Ni nanoparticles behave as superparamagnets when their size is ≤6 nm, in spite of their large volume fractions. The results show that the magnetic properties of the nanoparticles can be controlled by their size and Ni concentration in the samples.
Published: 2012
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25. Structural irradiation damage and recovery in nanometric silicon carbide

Author: A. Audren, Nathalie Herlin-Boime, Yann Leconte, Lionel Thomé, D. Gosset, I. Monnet, Laboratoire d'Analyse Microstructurale des Matériaux (LA2M), Service des Recherches Métallurgiques Appliquées (SRMA), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Département des Matériaux pour le Nucléaire (DMN), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, Laboratoire Francis PERRIN (LFP - URA 2453), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), and Normandie Université (NU)
Subjects: SiC, Nanostructure, Materials science, Annealing (metallurgy), Nucleation, Energy Engineering and Power Technology, 02 engineering and technology, 01 natural sciences, Nanoceramic, Nuclear materials, [SPI.MAT]Engineering Sciences [physics]/Materials, chemistry.chemical_compound, 0103 physical sciences, Silicon carbide, Ceramic, Irradiation, Composite material, Safety, Risk, Reliability and Quality, Waste Management and Disposal, 010302 applied physics, 021001 nanoscience & nanotechnology, Grain size, Amorphisation, Nuclear Energy and Engineering, chemistry, Ion irradiation, 13. Climate action, visual_art, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], visual_art.visual_art_medium, Crystallite, 0210 nano-technology
Abstract: Silicon carbide is one of the candidate materials for core components of some nuclear reactor projects (Gen-IV). In order to improve their thermo-mechanical properties, materials with nanometric grain size are considered. For such materials, nearly no data concerning their behaviour under irradiation are available. In this paper, we study the damage and subsequent recovery of a nanostructured 3C–SiC ceramic. Samples were irradiated at room temperature with 4 MeV Au ions and subsequently annealed. Their structural modifications are analysed with a grazing incidence X-ray diffraction method. Results show that these nanoceramic materials present the same damage kinetics during irradiation as conventional micrometric grained SiC, with total amorphisation at the highest fluence. However, while the recrystallisation of a conventional ceramic is expected to occur through an epitaxial recrystallisation from the non-damaged parts of the large grains, the nanometric material is healed only after annealing at 1000 °C through mechanisms that can be attributed to a heterogeneous nucleation and growth of β crystallites in the totally amorphised grains.
Published: 2012
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26. Effect of composition on the behavior of pyrochlores irradiated with swift heavy ions

Author: Lionel Thomé, Gaël Sattonnay, M. Herbst-Ghysel, Isabelle Monnet, A. Calvo, Sandra Moll, C. Legros, C. Decorse, Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), Normandie Université (NU), Université Paris-Sud - Paris 11 (UP11)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), and Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Nuclear and High Energy Physics, Materials science, Pyrochlore, Analytical chemistry, Mineralogy, 02 engineering and technology, engineering.material, 01 natural sciences, Pyrochlores, [SPI.MAT]Engineering Sciences [physics]/Materials, Ion, 0103 physical sciences, [SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering, Irradiation, Instrumentation, Chemical composition, 010302 applied physics, Ion track, 021001 nanoscience & nanotechnology, Titanate, X-ray diffraction, Amorphous solid, Ion irradiation, X-ray crystallography, engineering, 0210 nano-technology
Abstract: A 2 B 2 O 7 pyrochlores (zirconates with A = Gd, Nd, Sm or Eu, and a titanate Gd 2 Ti 2 O 7 ) were irradiated with swift heavy ions in order to investigate the effects of the chemical composition on the structural changes induced by high electronic excitation. XRD results show that the structural modifications induced by irradiation with 119 MeV U ions are strongly dependent on the sample composition: Gd 2 Ti 2 O 7 is readily amorphized, whereas Gd 2 Zr 2 O 7 is transformed into a radiation-resistant anion-deficient fluorite structure. For Sm 2 Zr 2 O 7 , Eu 2 Zr 2 O 7 and Nd 2 Zr 2 O 7 , a more complex behavior is observed since both a pyrochlore–fluorite phase transformation and amorphization occur. The results suggest that an ion track is composed of an amorphous track core surrounded by an anion-deficient fluorite shell. The diameters of different track regions were estimated by using a direct impact mechanism coupled with a single overlap process to fit the transformation build-ups. These diameters depend on the sample composition, the susceptibility to amorphization by high electronic excitation increasing with the cation radius ratio r A / r B .
Published: 2012
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27. Influence of ion energy on damage induced by Au-ion implantation in silicon carbide single crystals

Author: Patrick Simon, F. Linez, Lionel Thomé, Marie-France Barthe, Aurélie Gentils, Aurélien Canizares, CSNSM PS2, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Conditions Extrêmes et Matériaux : Haute Température et Irradiation (CEMHTI), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université d'Orléans (UO), CSNSM PCI, and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: FLUX, RAMAN-SCATTERING, Materials science, Analytical chemistry, 02 engineering and technology, Channelling, 01 natural sciences, Fluence, Ion, Positron annihilation spectroscopy, symbols.namesake, POSITRON, 0103 physical sciences, General Materials Science, TEMPERATURE, ACCUMULATION, 010302 applied physics, SPECTROSCOPY, Mechanical Engineering, Radiochemistry, DEFECTS, 021001 nanoscience & nanotechnology, Rutherford backscattering spectrometry, Crystallographic defect, Ion implantation, Mechanics of Materials, CERAMICS, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], symbols, 0210 nano-technology, Raman spectroscopy
Abstract: This article reports on the influence of the ion energy on the damage induced by Au-ion implantation in silicon carbide single crystals. 6H-SiC samples were implanted with Au ions at room temperature at two different energies: 4 and 20 MeV. Both Rutherford Back-scattering spectrometry in channelling geometry (RBS/C) and Raman spectroscopy were used to probe the ion implantation-induced damage. Results show that the accumulated damage increases with the fluence up to the amorphization state. RBS/C data indicate that 4-MeV implantation induces more damage than 20-MeV implantation at a given fluence. This effect is attributed to nuclear collisions since the amount of damage is identical at 4 or 20 MeV when the fluence is rescaled in dpa. Surprisingly, Raman data detect more damage for 20-MeV implantation than for 4-MeV implantation at low fluence (below 10(13) cm(-2)) where point defects are likely formed.
Published: 2011
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28. Synthesis and characterization of nc-Ge embedded in SiO2/Si matrix

Author: K.G.M. Nair, D.K. Avasthi, J.C. Pivin, Sumaira Khan, B. K. Panigrahi, S. Dhamodaran, N. Srinivasa Rao, D. Kabiraj, B. Sundaravel, Anand P. Pathak, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: Nuclear and High Energy Physics, Materials science, AMORPHOUS-SILICON OXIDE, Silicon, ION-IMPLANTATION, Analytical chemistry, chemistry.chemical_element, Germanium, 02 engineering and technology, Substrate (electronics), 01 natural sciences, Fluence, GERMANIUM, symbols.namesake, Swift heavy ion, implantation, General Materials Science, SI, Irradiation, RBS, VISIBLE PHOTOLUMINESCENCE, Radiation, irradiation, 010401 analytical chemistry, OPTICAL-PROPERTIES, 021001 nanoscience & nanotechnology, Condensed Matter Physics, SIO2-FILMS, X-ray diffraction, 0104 chemical sciences, Crystallography, NANOCRYSTALS, chemistry, Raman spectroscopy, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], symbols, Crystallite, sputtering, 0210 nano-technology
Abstract: International audience; We have prepared germanium nanoparticles embedded in SiO2 matrix by atom beam co-sputtering (ABS) of Ge+SiO2 on Si substrate. The as-deposited films were annealed at various temperatures in Ar+H2 atmosphere and irradiated with various energies with fixed fluence. The pristine and irradiated samples were characterized by Raman, X-ray diffraction and atomic force microscopy (AFM). Rutherford back scattering (RBS) was used to quantify the concentration of Ge in the SiO2 matrix and the film thickness. Raman studies of the films indicate the formation of Ge crystallites as a result of swift heavy ion (SHI) irradiation. Moreover, the crystalline nature of Ge improves with an increase in energy. Glancing angle X-ray diffraction and Raman results also confirm the presence of Ge crystallites in the irradiated samples. Similarly, 400keV Ge+ ions implanted into silicon substrate at higher fluence at 573K have been irradiated with 100MeV Au8+ions at RT. These irradiated implanted samples were subsequently characterized by XRD and Raman to understand the crystallization behavior. We also studied the surface morphology of a high-energy irradiated sample by AFM. The irradiation results were compared with those obtained by thermal annealing in ABS. The basic mechanism for crystallization induced by SHI in these films has been investigated.
Published: 2009
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29. Effects of electronic and nuclear interactions in SiC

Author: Isabelle Monnet, Abdenacer Benyagoub, Y. Leconte, Xavier Portier, Lionel Thomé, F. Garrido, Cécile Reynaud, A. Audren, Nathalie Herlin-Boime, D. Gosset, M. Levalois, Service des Photons, Atomes et Molécules (SPAM), Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), Normandie Université (NU), Laboratoire d'Analyse Microstructurale des Matériaux (LA2M), Service des Recherches Métallurgiques Appliquées (SRMA), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Département des Matériaux pour le Nucléaire (DMN), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Laboratoire Francis PERRIN (LFP - URA 2453), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), CSNSM PCI, and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: PACS: 61.82.Rx, SiC, Diffraction, Nuclear and High Energy Physics, Grazing incidence X-ray diffraction, Materials science, Nanostructure, nanostructure, 02 engineering and technology, 01 natural sciences, Ion, Condensed Matter::Materials Science, 0103 physical sciences, Atom, Irradiation, grazing incidence X ray diffraction, Instrumentation, [PHYS]Physics [physics], 010302 applied physics, Radiation material science, irradiation, Rutherford Backscattering Spectrometry, single crystalline, 021001 nanoscience & nanotechnology, Rutherford backscattering spectrometry, Ion implantation, Chemical physics, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Atomic physics, 0210 nano-technology
Abstract: International audience; In this study, we performed irradiation experiments on nanostructured 3C–SiC samples, with 95 MeV Xe ions at room temperature. This energy permits the observation of the combined electronic and nuclear interactions with matter. The grazing incidence X-ray diffraction results do not reveal a complete amorphization, despite value of displacement per atom overcoming the total amorphization threshold. This may be attributed to competing effects between nuclear and electronic energy loss in this material since a total amorphization induced by nuclear interactions was found after low energy ion irradiation (4 MeV Au). Moreover, electronic interactions created by high energy ion irradiations induce no disorder in single crystalline 6H–SiC. But in samples previously disordered by low energy ion implantation (700 keV I), the electronic interactions generate a strong defects recovery.
Published: 2009
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30. Synthesis and characterization of Ni-doped ZnO: A transparent magnetic semiconductor

Author: D.K. Avasthi, J.C. Pivin, Babita Pandey, D. Kabiraj, Santanu Ghosh, P. C. Srivastava, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: FERROMAGNETIC SEMICONDUCTORS, Materials science, Grazing angle X-ray diffraction, Analytical chemistry, Magnetic property, 02 engineering and technology, 01 natural sciences, Magnetization, THIN-FILMS, DESIGN, Electrical resistivity and conductivity, High-resolution transmission electron microscopy, 0103 physical sciences, NANOPARTICLES, OXIDES, Thin film, 010302 applied physics, Condensed matter physics, Doping, Transparent magnetic semiconductor, Magnetic semiconductor, Sputter deposition, Coercivity, 021001 nanoscience & nanotechnology, Condensed Matter Physics, Electronic, Optical and Magnetic Materials, CO, ROOM-TEMPERATURE, Ferromagnetism, SPINTRONICS, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], 0210 nano-technology
Abstract: We report synthesis of a transparent magnetic semiconductor by incorporating Ni in zinc oxide (ZnO) matrix. ZnO and nickel-doped zinc oxide (ZnO: Ni) thin films (similar to 60 nm) are prepared by fast atom beam (FAB) sputtering. Both undoped and doped films show the presence of ZnO phase only. The Ni concentration ( in at%) as determined by energy dispersive X-ray (EDX) technique is similar to 12 +/- 2%. Magnetisation measurement using a SQUID magnetometer shows that the Ni-doped films are ferromagnetic, having coercivity (H(c)) values 192, 310 and 100 Oe and saturation magnetization (M(s)) values of 6.22, 5.32 and 4.73 emu/g at 5, 15 and 300 K, respectively. The Ni-doped film is transparent (> 80%) across visible wavelength range. Resistivity of the ZnO: Ni film is similar to 2.5 x 10(-3) Omega cm, which is almost two orders of magnitude lower than the resistivity (similar to 4.5 x 10(-1) Omega cm) of its undoped counterpart. Impurity d-band splitting is considered to be the cause of increase in conductivity. Interaction between free charges generated by doping and localized d spins of Ni is discussed as the reason for ferromagnetism in the ZnO: Ni film. (C) 2008 Elsevier B.V. All rights reserved.
Published: 2008
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31. Structure and magnetic properties of ZnO films doped with Co, Ni or Mn synthesized by pulsed laser deposition under low and high oxygen partial pressures

Author: J.C. Pivin, L. Vincent, Fouran Singh, Gabriel Socol, P. Berthet, Ion N. Mihailescu, Maulik K. Patel, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: Analytical chemistry, Pulsed laser deposition, Magnetic films, 02 engineering and technology, FERROMAGNETIC-RESONANCE, SEMICONDUCTORS, 01 natural sciences, law.invention, Condensed Matter::Materials Science, Paramagnetism, THIN-FILMS, Transition metal, law, 0103 physical sciences, Materials Chemistry, Texture (crystalline), Thin film, Electron paramagnetic resonance, 010302 applied physics, Chemistry, Metals and Alloys, OXIDE, BACKSCATTERING, Surfaces and Interfaces, Magnetic semiconductor, 021001 nanoscience & nanotechnology, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Ferromagnetism, ZnO, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Dilute magnetic semiconductors, 0210 nano-technology
Abstract: Zn(1-x)M(x)O (M=Co, Ni, Mn) films with different concentrations of transition metal (10-30%)were synthesized by pulsed laser deposition. The substrates were heated at 400 degrees C and the depositions were performed either under secondary vacuum or under an oxygen pressure of 30 Pa. The occurrence of ion channeling in the films during Rutherford Backscattering Analysis, together with X-ray diffraction, optical absorption and transmission electron microscopy, clearly show that the M atoms are in solid solution on Zn sites. Magnetic properties were investigated by means of magnetometry at 5 and 300 K and Electron Spin Resonance. The Zn(1-x)Co(x)O and Zn(1-x)Ni(x)O films deposited under low 02 pressure exhibit both a ferromagnetic and a paramagnetic response up to 300 K, while films deposited under high 02 pressure and Zn(1-x)Mn(x)O films are paramagnetic. Broad spin resonance peaks are recorded at room temperature, from ferromagnetic films only. The nearly isotropic magnetic response of these films, which is observed in ESR when varying the field orientation with respect to the surface, seems to indicate that the crystalline anisotropy oppose the shape anisotropy, because of the strong [001] texture of the films. (C) 2008 Elsevier B.V. All rights reserved.
Published: 2008
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32. Structural modifications in pyrochlores caused by ions in the electronic stopping regime

Author: J.C. Pivin, Adish Tyagi, S. Kailas, V. Vijayakumar, Maulik K. Patel, D.K. Avasthi, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: Diffraction, Nuclear and High Energy Physics, Fission, Coordination number, Analytical chemistry, 02 engineering and technology, TRANSMUTATION, AMORPHIZATION, 01 natural sciences, Fluorite, Ion, symbols.namesake, RAMAN-SPECTROSCOPY, 0103 physical sciences, General Materials Science, Irradiation, OXIDES, TEMPERATURE, 010302 applied physics, RADIATION TOLERANCE, Chemistry, 021001 nanoscience & nanotechnology, IRRADIATION, Nuclear Energy and Engineering, X-ray crystallography, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], symbols, FLUORITE, Atomic physics, 0210 nano-technology, Raman spectroscopy, RESISTANCE
Abstract: Damage caused by swift heavy ions with three different electronic stopping powers (120 MeV Au9+ (22 keV/nm), 90 MeV I7+ (17 keV/nm) and 70 MeV Ni5+ (11 keV/nm)) in three pyrochlores (Gd2Zr2O7, Nd2Zr2O7 and Gd2Ti2O7) with progressively increasing radius ratios (r(A)/r(B) of A(2)B(2)O(7)) of cations is reported. Since I+7 is one of the ions used, these measurements also simulate fission fragment damage in pyrochlores and identify a potential host lattice for inert matrix fuel. X-ray diffraction on the irradiated materials indicate amorphization in Gd2Ti2O7 at the lowest S-e used, and a transition to anion-deficient fluorite (Fm (3) over barm) structure with about 1% decrease in volume in Nd2Zr2O7 and Gd2Zr2O7 at higher S-e. In Nd2Zr2O7 this is followed by amorphization and Gd2Zr2O7 does not amorphize even at the highest S-e employed. Raman analysis of Gd2Zr2O7 and Nd2Zr2O7, indicate an increase of Zr coordination number after irradiation and the bands become broader due to disordering. Analysis of the results shows that the radiation susceptibility of these pyrochlores in the electronic stopping regime strongly depends on the radius ratio of A to B cations and hence on the energy required for formation of cation antisites and anion Frenkel pairs, similar to their susceptibility in the nuclear stopping regime. Published by Elsevier B.V.
Published: 2008
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33. Sensitivity of ZnO films doped with Er, Ta and Co to NH3at room temperature

Author: Orlin Angelov, V. Georgieva, Valdek Mikli, D. Dimova-Malinovska, H. Nichev, J.C. Pivin, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: Analytical chemistry, 02 engineering and technology, 01 natural sciences, GAS-SENSOR, THIN-FILMS, Adsorption, 0103 physical sciences, Materials Chemistry, ZINC-OXIDE, Electrical and Electronic Engineering, Thin film, 010302 applied physics, Aqueous solution, Chemistry, Doping, AL2O3, Sorption, ELECTRICAL-PROPERTIES, OPTICAL-PROPERTIES, Surfaces and Interfaces, Quartz crystal microbalance, Sputter deposition, 021001 nanoscience & nanotechnology, Condensed Matter Physics, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, AL, ZN1-XCOXO, Cavity magnetron, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], 0210 nano-technology
Abstract: International audience; The sensitivity of ZnO films, undoped and doped with Er, Ta and Co, to exposure to NH3 has been studied. The films were deposited by magnetron co-sputtering of a sintered ZnO target with chips of the different doping elements on its surface. The sensitivities of the ZnO films to exposure to NH3 were measured by the quartz crystal microbalance method using the resonance frequency shift. The adsorption process was investigated over an aqueous solution of ammonia with 100 ppm concentration. The speed and the mass of sorption were calculated on the basis of the time-frequency characteristic. (c) 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Published: 2008
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34. Ion beam irradiation of Sn films deposited on YSZ(100)

Author: Nihed Chaâbane, Patrick Trocellier, S. Poissonnet, Lionel Thomé, Service de recherches de métallurgie physique (SRMP), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: 010302 applied physics, Nuclear and High Energy Physics, Materials science, Ultra-high vacuum, Analytical chemistry, 02 engineering and technology, 021001 nanoscience & nanotechnology, Rutherford backscattering spectrometry, Microstructure, 01 natural sciences, Evaporation (deposition), Crystallography, Transmission electron microscopy, 0103 physical sciences, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Irradiation, Thin film, 0210 nano-technology, Instrumentation, Yttria-stabilized zirconia
Abstract: International audience; This paper reports the formation processes of crystalline Sn nanostructured films grown under ultra high vacuum conditions on monocrystalline yttria-stabilized zirconia (YSZ) substrates with (10 0) orientation. The microstructure of the films was analyzed using SEM and X-ray diffraction. Evaporation of Sit films yields crystallographically well-defined metallic islands of different shapes depending on the substrate temperature. The overall growth mechanism appears to follow the Stranski-Krastanov type. Irradiation of deposited films was performed at room temperature with 4 MeV Au2+ ions at a fluence of 10(15) cm(-2) to induce material decomposition and aggregation of host atoms. X-ray diffraction and Rutherford backscattering spectrometry (RBS) experiments conducted on Sn films deposited on YSZ(l 00) prior to and after irradiation demonstrate that ion irradiation drives a structural phase transformation for Sri and Zr-rich compositions. The microstructural evolution upon ion irradiation was also examined by cross-sectional transmission electron microscopy (TEM). (C) 2008 Published by Elsevier B.V.
Published: 2008
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35. Radiation stability of fluorite-type nuclear oxides

Author: Gaël Sattonnay, Lionel Thomé, Laetitia Vincent, Lech Nowicki, F. Garrido, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), The Andrzej Soltan Institute for Nuclear Studies, Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), and Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)
Subjects: 010302 applied physics, Inert, Nuclear and High Energy Physics, Nuclear transmutation, Chemistry, Doping, Noble gas, 02 engineering and technology, Actinide, 021001 nanoscience & nanotechnology, Channelling, 7. Clean energy, 01 natural sciences, Ion, 13. Climate action, Chemical physics, 0103 physical sciences, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Radiation damage, Atomic physics, 0210 nano-technology, Instrumentation
Abstract: International audience; Oxides with the fluorite-type structure are radiation tolerant materials. They are widely used or envisaged in hostile nuclear environments, such as nuclear fuels or inert transmutation matrices for actinide burning. Study of the radiation stability of this class of solids in various radiative fields is of major importance. Two issues which may affect the stability of materials are considered in this work: the production of radiation damage (ballistic contribution); the modification of the matrix composition by doping (chemical contribution). Both contributions may drastically affect the solid stability. Urania and zirconia single crystals were chosen as fluorite-type canonical systems. They were implanted with low-energy inert gases (He or Xe). The damage in-growth, due to both ballistic and chemical contributions, was investigated by in situ RBS/C experiments in the channelling mode and TEM. Two main steps in the disordering kinetics were observed for both inert gases. Relevant key parameters were found to be: the number of displaced lattice atoms created by the slowing-down of energetic ions during the implantation process,, the concentration of noble gas atoms in the solid which cause the formation of large stress fields surrounding gas aggregates. (C) 2008 Elsevier B.V. All rights reserved.
Published: 2008
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36. Metal-oxide nanoclusters in Fe–10%Cr alloy by ion implantation

Author: Frédérico Garrido, Vladimir A. Borodin, J. Ribis, A. Gentils, O. Kaïtasov, Ce Zheng, CSNSM PS2, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), CSNSM SEMI, Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Service des Recherches Métallurgiques Appliquées (SRMA), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), and Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay
Subjects: Nuclear and High Energy Physics, Materials science, Precipitation (chemistry), Analytical chemistry, Nucleation, Oxide, FeCr alloys, Thermal treatment, Crystal structure, Precipitation, Nanoclusters, Crystallography, chemistry.chemical_compound, Ion implantation, chemistry, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Aluminium oxide, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], High-resolution transmission electron microscopy, Instrumentation, Transmission electron microscopy
Abstract: International audience; High contents of Al+ and O+ ions were implanted sequentially into high purity Fe–10%Cr alloy thin foils at room temperature. The as-implanted foils were then studied by transmission electron microscopy (TEM) using the conventional TEM, energy dispersive X-ray (EDX), energy-filtered TEM (EFTEM) and high-resolution TEM (HRTEM) methods. In contrast to the conventional precipitate ensemble synthesis by implantation/annealing, the synthesis of clusters took place already at the implantation stage without requiring any subsequent thermal annealing in our case. The observed precipitates with diameters in the range of 3–25 nm were enriched in Al and O. The crystal lattice of precipitates corresponded to a cubic crystallographic structure of aluminium-rich oxide. The precipitate lattice alignment with the matrix was revealed for at least a part of precipitates. The early stage of nucleation outside thermal treatment is discussed in terms of point defect enhanced diffusion ensuring sufficient atomic transport to allow solute atom precipitation.
Published: 2015
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37. Lattice location and annealing behaviour of helium atoms implanted in uranium dioxide single crystals

Author: Philippe Garcia, G. Carlot, P. Desgardin, T. Belhabib, Marie-France Barthe, F. Garrido, T. Sauvage, L. Nowicki, H. Erramli, Conditions Extrêmes et Matériaux : Haute Température et Irradiation (CEMHTI), Université d'Orléans (UO)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Nuclear and High Energy Physics, Lattice location, Uranium dioxide, chemistry.chemical_element, 02 engineering and technology, Monte-Carlo simulation, Channelling, 01 natural sciences, 7. Clean energy, Helium, Rutherford backscattering spectrometry, Crystal, chemistry.chemical_compound, Interstitial defect, Nuclear reaction analysis, 0103 physical sciences, Interstitial octahedral site, General Materials Science, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], 010306 general physics, [PHYS]Physics [physics], Uranium, 021001 nanoscience & nanotechnology, Nuclear Energy and Engineering, chemistry, Atomic physics, 0210 nano-technology
Abstract: International audience; Helium behaviour in irradiated uranium dioxide may play an important role in the mechanical stability of nuclear fuels during and after its use in nuclear power plants. Helium migration mechanisms in bulk UO2 have already been the subject of theoretical studies but there is a lack of experimental data relating to the most stable location in the crystal. To this end, we have studied uranium dioxide samples implanted with helium ions at low fluence before and after thermal annealing in the range 600 and 800 °C. UO2 single crystals were implanted with 50 keV−3He ions at the fluence of 1 × 1015 at cm−2 and the location in the lattice of helium atoms was investigated using NRA (Nuclear Reaction Analysis) based on the reaction of 3He with deuterons (3He (d,p) 4He) in a channelling mode, recording angular scans across axes and planes. Furthermore, the uranium sub-lattice was analysed by the classical RBS method. After implantation, the experimental angular scans recorded across the main crystallographic axes and along major planes show that the helium atoms in their large majority occupy octahedral interstitial sites. No modification of the occupied crystallographic site was found after annealing at 600 °C. Conversely, no crystallographic relationship between matrix and helium signals was revealed following annealing at 800 °C. The latter feature is likely related to the clustering of implanted helium atoms into gas-filled bubbles. These experimental results have been quantified and interpreted using Monte Carlo simulations with the McChasy code.
Published: 2015
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38. Mn fraction substitutional site and defects induced magnetism in Mn-implanted

Author: Bouziane, K., Al Azri, M., M., Elzain, Chérif, S.M., Mamor, M., Declémy, A., Thomé, L., CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Dilute magnetic semiconductor, [PHYS]Physics [physics], Ab initio, Magnetism, Defects, Mn-implanted 6H-SiC, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat]
Abstract: International audience; n-type 6H-SiC(0001) single crystal substrates were implanted with three fluences of manganese (Mn+) ions: 5×1015, 1×1016and 5×1016 cm–2 with implantation energy of 80 keV at 365°C to stimulate dynamic annealing. The samples were characterized using Rutherford backscattering channeling spectroscopy (RBS/C), high-resolution X-ray diffraction technique (HRXRD), and Superconducting Quantum Interference Device (SQUID) techniques. Two main defect regions have been identified using RBS/C spectra fitted with the McChasy code combined to SRIM simulations. Intermediate defects depth region is associated with vacancies (DV) and deeper defect (DN) essentially related to the Si and C interstitial defects. The defect concentration and the maximum perpendicular strain exhibit similar increasing trend with the Mn+ fluence. Furthermore, the amount of Mn atoms at Si substitutional sites and the corresponding magnetic moment per Mn atom were found to increase with increasing Mn fluence from 0.7μB to 1.7μB and then collapsing to 0.2μB. Moreover, a strong correlation has been found between the magnetic moment and the combination of both large DV/DN ratio and high Mn at Si sites. These results are corroborated by our ab initio calculations considering the most stable configurations showing that besides the amount of Mn substituting Si sites, local vacancy-rich environment is playing a crucial role in enhancing the magnetism.
Published: 2015
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39. Experimental location of helium atoms in 6H-SiC crystal lattice after implantation and after annealing at 400 degrees C

Author: Pierre Desgardin, Thierry Sauvage, Blandine Courtois, H. Erramli, M.F. Barthe, Frédérico Garrido, F. Linez, Conditions Extrêmes et Matériaux : Haute Température et Irradiation (CEMHTI), Université d'Orléans (UO)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: Nuclear and High Energy Physics, cristal lattice, Materials science, Annealing (metallurgy), chemistry.chemical_element, Crystal structure, Atomic units, Molecular physics, Fluence, Ion, chemistry.chemical_compound, Nuclear reaction analysis, Silicon carbide, SILICON-CARBIDE, General Materials Science, cristallographic planes, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], ANNIHILATION, TEMPERATURE, Helium, [PHYS]Physics [physics], ta114, MECHANICAL-PROPERTIES, NUCLEAR-REACTION ANALYSIS, DIFFUSION, IRRADIATION, POSITRON LIFETIME SPECTROSCOPY, Crystallography, Nuclear Energy and Engineering, chemistry, MICROSTRUCTURAL EVOLUTION, Helium atoms, BEHAVIOR
Abstract: International audience; The question of the helium behavior in silicon carbide has been studied at the atomic scale by numerical simulations, but no experiment has been carried out to assess the results hitherto. This paper describes the first experiments allowing this comparison. 6H-SiC single crystals were implanted with 50-keV He ions at a fluence of 10(15) He/cm(2) at room temperature. The as-received and as-implanted samples were analyzed by RBS and NRA in channeling mode along the main crystallographic planes and across three main axes. The measurements have shown that a portion of the He is located in the interstitial tetrahedral sites as predicted by the numerical simulations. The same measurements were performed on an implanted sample subsequently annealed at 400 degrees C under Ar atmosphere. They have shown that the quantity of He detected in interstitial tetrahedral sites T-Si and T-C has not significantly changed whereas that of He detected in the main crystallographic plane and in the main axis has increased. This increase is likely caused by He atoms migration at 400 degrees C toward interstitial positions located inside vacancies such as V-Si and VSiVC. In parallel a partial recovery of the Si and C sublattices has been observed. (C) 2015 Elsevier B.V. All rights reserved.
Published: 2015
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40. Mechanical response of UO2 single crystals submitted to low-energy ion irradiation

Author: Alexandre Boulle, Lionel Thomé, Frédérico Garrido, Valérie Demange, Tien-Hien Nguyen, Aurélien Debelle, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM PCI), Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Saclay-Univ. Paris-Sud, Axe 3 : organisation structurale multiéchelle des matériaux (SPCTS-AXE3), Science des Procédés Céramiques et de Traitements de Surface (SPCTS), Université de Limoges (UNILIM)-Ecole Nationale Supérieure de Céramique Industrielle (ENSCI)-Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université de Limoges (UNILIM)-Ecole Nationale Supérieure de Céramique Industrielle (ENSCI)-Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), We are grateful to the Semiramis staff for their help during irradiations. One of us (T.H. Nguyen) acknowledges the Ecole Doctorale MIPEGE at the Université Paris-Sud for financial support during his PhD thesis., Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Ecole Nationale Supérieure de Céramique Industrielle (ENSCI)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université de Limoges (UNILIM)-Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Ecole Nationale Supérieure de Céramique Industrielle (ENSCI)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université de Limoges (UNILIM), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)
Subjects: Diffraction, Nuclear and High Energy Physics, Materials science, XRD, elastic strain, 61.80.Jh, 62.20.D, 02 engineering and technology, UO2, 01 natural sciences, Fluence, Ion, Lattice constant, 0103 physical sciences, [CHIM]Chemical Sciences, General Materials Science, Irradiation, Composite material, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], 010306 general physics, PACS, [PHYS]Physics [physics], Range (particle radiation), Strain (chemistry), Relaxation (NMR), 021001 nanoscience & nanotechnology, Crystallography, 61.05.cp, Nuclear Energy and Engineering, 61.72.J, 61.72.Dd, radiation effects, Defects, 0210 nano-technology
Abstract: International audience; {111}- and {100}-oriented UO2 single crystals were irradiated with 500-keV Ce3+ ions in the 1014 - 9x1014 cm-2 fluence range. The irradiation-induced strain was monitored using high-resolution X-ray diffraction. A mechanical modelling dedicated to thin irradiated layers was applied to account for the reaction of the unirradiated part of the crystals. The elastic strain, which is confined along the surface normal of the samples, increases with ion fluence until it is dramatically relieved. This behaviour is observed for both orientations. While the measured elastic strain depends on the crystallographic direction, the strain due to irradiation defects only is found to be equal for both directions, with a maximum value of ∼0.5%. Strain relaxation takes place at the damage peak, but the in-plane lattice parameter of the irradiated layer remains unchanged and equal to that of the pristine material. Meanwhile, the strain at the damaged/pristine interface continues to increase.
Published: 2015
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41. Ferromagnetism in Ni doped ZnS thin films: Effects of Ni concentration and swift heavy ion irradiation

Author: Lokendra Kumar, Shiv P. Patel, Ramesh Chandra, J.C. Pivin, D. Kanjilal, Laboratoire Francis PERRIN (LFP - URA 2453), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Materials science, Analytical chemistry, SEMICONDUCTORS, Pulsed laser deposition, Magnetization, Condensed Matter::Materials Science, Swift heavy ion, Impurities in semiconductors, Condensed Matter::Superconductivity, NANOPARTICLES, Irradiation, Thin film, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], Instrumentation, Wurtzite crystal structure, [PHYS]Physics [physics], Exchange interaction, Condensed matter physics, Ion track, equipment and supplies, Condensed Matter Physics, TRANSFORMATION, Surfaces, Coatings and Films, CO, ROOM-TEMPERATURE FERROMAGNETISM, Ferromagnetism, Ion irradiation, GROWTH, human activities
Abstract: International audience; The magnetic properties of Ni doped ZnS thin films fabricated at substrate temperature of 400 degrees C by means of pulsed laser deposition are presented. The films show crystalline wurtzite structure. Optical absorption and transmission electron microscopic studies indicate that Ni has been appropriately substituted on Zn tetrahedral site. The films show ferromagnetism up to room temperature. The magnetization in the films decreases with increase of Ni concentration. Swift heavy ion (SHI) irradiations have been carried out using 120 MeV Ag ions for the modification of structural and magnetic properties of the films. SHI irradiation suggests the formation columnar ion track inside the films causing decrease in magnetization. (C) 2014 Elsevier Ltd. All rights reserved.
Published: 2015
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42. Recrystallization of hexagonal silicon carbide after gold ion irradiation and thermal annealing

Author: Lionel Thomé, Sandrine Miro, Jean-Marc Costantini, Juan Huguet-Garcia, Service de recherches de métallurgie physique (SRMP), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, Service des Recherches Métallurgiques Appliquées (SRMA), CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: AMORPHOUS SIC FILMS, Materials science, RAMAN-SCATTERING, Annealing (metallurgy), Analytical chemistry, BEAM, RELAXATION, 02 engineering and technology, AMORPHIZATION, 01 natural sciences, Ion, CRYSTAL GRAIN NUCLEATION, symbols.namesake, chemistry.chemical_compound, 0103 physical sciences, Silicon carbide, Irradiation, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], Spectroscopy, 010302 applied physics, [PHYS]Physics [physics], DAMAGE ACCUMULATION, Recrystallization (metallurgy), 021001 nanoscience & nanotechnology, Condensed Matter Physics, Amorphous solid, Crystallography, chemistry, MOLECULAR-DYNAMICS, symbols, IMPLANTATION, CRYSTALLIZATION, 0210 nano-technology, Raman spectroscopy
Abstract: International audience; Silicon carbide (SiC) single crystals with the 6H polytype structure were irradiated with 4.0-MeV Au ions at room temperature (RT) for increasing fluences ranging from 1 x 10(12) to 2 x 10(15)cm(-2), corresponding to irradiation doses from ~0.03 to 5.3 displacements per atom (dpa). The damage build-up was studied by micro-Raman spectroscopy that shows a progressive amorphization by the decrease and broadening of 6H-SiC lattice phonon peaks and the related growth of bands assigned to Si-Si and C-C homonuclear bonds. A saturation of the lattice damage fraction deduced from Raman spectra is found for ~0.8 dpa (i.e. ion fluence of 3 x 10(14)cm(-2)). This process is accompanied by an increase and saturation of the out-of-plane expansion (also for ~0.8 dpa), deduced from the step height at the sample surface, as measured by phase-shift interferometry. Isochronal thermal annealing experiments were then performed on partially amorphous (from 30 to 90%) and fully amorphous samples for temperatures from 200 degrees C up to 1500 degrees C under vacuum. Damage recovery and densification take place at the same annealing stage with an onset temperature of ~200 degrees C. Almost complete 6H polytype regrowth is found for partially amorphous samples (for doses lower than 0.8 dpa) at 1000 degrees C, whereas a residual damage and swelling remain for larger doses. In the latter case, these unrelaxed internal stresses give rise to an exfoliation process for higher annealing temperatures.
Published: 2014
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43. Oxide dispersion strengthened ferritic steels: a basic research joint program in France

Author: C. Barouh, A.L. Rouffié, N. Sallez, Arunodaya Bhattacharya, Constantinos Hatzoglou, L. Barguet, H. Salmon-Legagneur, V. Badjeck, J.-L. Boutard, Y. Colignon, M. Loyer-Prost, T. Schuler, Laboratoire de Physique des Solides (LPS), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS), CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11), Institut des Matériaux, de Microélectronique et des Nanosciences de Provence (IM2NP), Université de Toulon (UTLN)-Centre National de la Recherche Scientifique (CNRS)-Aix Marseille Université (AMU), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), and Aix Marseille Université (AMU)-Université de Toulon (UTLN)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Cladding (metalworking), Nuclear and High Energy Physics, Materials science, ALLOYS, Oxide, Nucleation, 02 engineering and technology, 7. Clean energy, 01 natural sciences, MECHANISMS, chemistry.chemical_compound, Basic research, 0103 physical sciences, PARTICLES, General Materials Science, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], Joint (geology), 010302 applied physics, [PHYS]Physics [physics], STABILITY, Metallurgy, MICROSCOPY, 021001 nanoscience & nanotechnology, ODS STEELS, IRRADIATION, Nuclear Energy and Engineering, Creep, chemistry, TEMPERATURE-DEPENDENCE, Dynamic loading, MARTENSITIC STEELS, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], RADIATION, 0210 nano-technology, Dispersion (chemistry)
Abstract: International audience; AREVA, CEA, CNRS, EDF and Mecachrome are funding a joint program of basic research on Oxide Dispersion Strengthened Steels (ODISSEE), in support to the development of oxide dispersion strengthened 9-14% Cr ferritic-martensitic steels for the fuel element cladding of future Sodium-cooled fast neutron reactors. The selected objectives and the results obtained so far will be presented concerning (i) physical-chemical characterisation of the nano-clusters as a function of ball-milling process, metallurgical conditions and irradiation, (ii) meso-scale understanding of failure mechanisms under dynamic loading and creep, and, (iii) kinetic modelling of nano-clusters nucleation and alpha/alpha' unmixing. (C) 2014 Elsevier B.V. All rights reserved.
Published: 2014
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44. Meso and macroscopic considerations about damage accumulation processes

Author: S. Moll, Jacek Jagielski, Lionel Thomé, Magdalena Romaniec, Institute of Electronic Materials Technology (IEMT), Institute of Electronic Materials Technology, The Andrzej Soltan Institute for Nuclear Studies, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), and Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)
Subjects: 010302 applied physics, Nuclear and High Energy Physics, CRYSTALLINE SILICON, Chemistry, Damage accumulation, COMPOSITE MODEL, 02 engineering and technology, AMORPHIZATION, 021001 nanoscience & nanotechnology, 01 natural sciences, AMORPHOUS TRANSFORMATION, IRRADIATION, MECHANISMS, Crystallography, Ion irradiation, CERAMICS, 0103 physical sciences, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Biophysics, Radiation damage, 0210 nano-technology, Instrumentation
Abstract: International audience; Meso (effect of grain size) and macroscopic ( effect of sample dimension) considerations about damage accumulation processes are discussed. Although both factors may significantly influence damage accumulation kinetics, they are not taken into account in most of currently used models. The role of meso and macroscopic factors may be explained in the framework of a recently developed model of damage accumulation (Multi-Step Damage Accumulation - MSDA), which assumes that the damage build-up can be regarded as a sequence of structural transformations triggered by the destabilization of the current structure of a crystal induced by radiation damage. (C) 2009 Elsevier B. V. All rights reserved.
Published: 2009
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45. Filiform corrosion of aluminium alloys after a phosphate treatment

Author: Thomé, T., Martinez, S., Czechowski, C., Thomé, L., P. Debovea, J., Benchabanea, S., PSA Peugeot Citroën, PSA Peugeot Citroën (PSA), CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: filiform corrosion, aluminium alloy, XPS, TEM, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], RBS, phosphate
Abstract: The role on filiform corrosion (FFC), after an automotive painting process with a phosphate treatment, of the near surface deformed layer (NSDL) formed during mechanical processing on AA8006 aluminium alloys is investigated. Samples subjected to specific surface pretreatments are examined before and after different steps of the phosphating process in order to identify the characteristics of the NSDL that are responsible for the susceptibility to FFC. The thickness, the structure and the composition of this NSDL are determined by SEM, RBS, XPS and transmission electron microscopy. The presence of a 200-nm thick NSDL which is not completely eliminated during the degreasing step of the phosphating process increases dramatically the FFC susceptibility of AA8006 aluminium alloys compared with beforehand etched samples. The influence of Pb and Mg segregation on top of the surface is found to be negligible whereas the specific microstructure of the NSDL characterised by nanograins with boundaries decorated by nano-sized oxide intermetallic particles seems to play a major role on FFC. Copyright © 2014 John Wiley & Sons, Ltd.
Published: 2014
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46. Swift heavy ion induced recrystallization in cubic silicon carbide: New insights from designed experiments and MD simulations

Author: Lionel Thomé, F. Garrido, Olli H. Pakarinen, William J. Weber, Isabelle Monnet, F. Paumier, Flyura Djurabekova, Kai Nordlund, Marie Backman, Aurélien Debelle, CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), Normandie Université (NU), Institut Pprime (PPRIME), Université de Poitiers-ENSMA-Centre National de la Recherche Scientifique (CNRS), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), and Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)
Subjects: SiC, Nuclear and High Energy Physics, Materials science, Kinetics, Analytical chemistry, Recrystallization (metallurgy), Recrystallization, 7. Clean energy, Fluence, Ion, Amorphous solid, Swift heavy ion, chemistry.chemical_compound, Crystallography, chemistry, Silicon carbide, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Irradiation, Instrumentation
Abstract: 3C-SiC single crystals have been initially irradiated in the nuclear energy loss regime with 100 keV Fe ions to fluences ranging from 4 × 1013 to 4 × 1014 cm−2 (i.e. 0.07-0.7 dpa). RBS/C measurements indicate that SiC rapidly becomes amorphous (at ∼0.4 dpa). Two damaged SiC crystals exhibiting a different defective structure have been subsequently irradiated in the electronic energy loss regime with 870 MeV swift heavy (Pb) ions (SHIs) up to a fluence of 4 × 1013 cm−2. Initially fully amorphous SiC layers showed a decrease in size after SHI irradiation with a recrystallization occurring at the amorphous-crystalline interface. On the contrary, partially amorphous crystals for which onset of amorphization just initiated at the damage peak recovered over the entire damage thickness. Variation of amorphous thickness or disorder level has been monitored as a function of Pb ion fluence, which allowed deriving recrystallization kinetics. Data have been fitted with the direct-impact model and recrystallization cross-sections and threshold values for recovery have been determined for both types of initially defective structures. Differences are qualitatively discussed in terms of nature and density of irradiation defects. All experimental trends have been successfully reproduced by molecular dynamics simulations that mimicked thermal spikes induced by SHIs.
Published: 2013
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47. Radiation effects in carbides: TiC and ZrC versus SiC

Author: Lionel Thomé, P. Trocellier, S. Pellegrino, Sandrine Miro, Aurélien Debelle, Service de recherches de métallurgie physique (SRMP), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, CSNSM PCI, Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
Subjects: SiC, RBS-C, Nuclear and High Energy Physics, TiC, Materials science, Nuclear fuel, XRD, Metallurgy, ZrC, Crystal structure, Radiation, 7. Clean energy, Fluence, Carbide, Ion, symbols.namesake, Chemical engineering, Raman spectroscopy, symbols, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Irradiation, Instrumentation
Abstract: The aim of this paper is to provide, in the framework of the use of carbides for nuclear fuel applications, a comparison of the effects of irradiation observed in TiC and ZrC with those already widely investigated in SiC. To achieve this goal, the three carbides (SiC, TiC, ZrC) were simultaneously irradiated at room temperature with 1.2 MeV Au ions at several fluences. The damage created by irradiation was evaluated by RBS-C, XRD and Raman experiments. The results indicate a drastic difference between TiC and ZrC versus SiC. Whereas amorphization is readily achieved for SiC at low Au fluence (between 5 × 1013 and 1.7 × 1014 cm−2), TiC and ZrC maintain their crystalline structure at the highest Au fluence used (7 × 1015 cm−2). Ionicity character of bondings as well as topological criteria in TiC and ZrC, as compared to SiC, could play a major role for preventing amorphization in the former two carbides.
Published: 2013
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48. Fe/He ion irradiated ultra high purity Fe(Cr) alloys

Author: Schaeublin, R., Prokhodtseva, A., Décamps, B., Kaïtasov, O., Ramar, A., Trocellier, P., Serruys, Y., CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), CSNSM SEMI, Service de recherches de métallurgie physique (SRMP), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), and Hadrossek, Christine
Subjects: [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], [PHYS.COND.CM-MS] Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]
Published: 2013

49. Understanding of the microstructural evolution of austenitic model alloy and 316 steel under ion irradiation by coupling of TEM and APT investigations- Part II: APT results

Author: Volgin, A., Radiguet, B., Pareige, Philippe, Décamps, B., Gentils, A., Fortuna, F., Pokor, C., Groupe de physique des matériaux (GPM), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU), CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), CSNSM PS2, Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), EDF (EDF), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Université de Caen Normandie (UNICAEN), Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM)
Subjects: [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]
Published: 2013

50. Radiation effects in nuclear materials: Role of nuclear and electronic energy losses and their synergy

Author: Gihan Velisa, B. Décamps, Marie Backman, C. Bachelet, Gaël Sattonnay, Lionel Thomé, Sandra Moll, Moni Behar, Flyura Djurabekova, Jacek Jagielski, Kai Nordlund, Lech Nowicki, Sandrine Miro, Iwona Jozwik-Biala, Isabelle Monnet, F. Garrido, Marcel Toulemonde, S. Pellegrino, Patrick Simon, Stamatis Mylonas, Aurélien Debelle, Yanwen Zhang, P. Trocellier, William J. Weber, Clara Grygiel, Yves Serruys, CSNSM PCI, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), Service de recherches de métallurgie physique (SRMP), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, Centre de recherche sur les Ions, les MAtériaux et la Photonique (CIMAP - UMR 6252), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Caen Normandie (UNICAEN), Normandie Université (NU), Conditions Extrêmes et Matériaux : Haute Température et Irradiation (CEMHTI), Université d'Orléans (UO)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), The Andrzej Soltan Institute for Nuclear Studies, Institute of Electronic Materials Technology (IEMT), Institute of Electronic Materials Technology, Universidade Federal do Rio Grande do Sul [Porto Alegre] (UFRGS), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Université Paris-Sud - Paris 11 (UP11)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), and Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)
Subjects: Nuclear and High Energy Physics, Nuclear transmutation, WASTE, chemistry.chemical_element, PLUTONIUM, 02 engineering and technology, Radiation, 01 natural sciences, 7. Clean energy, Nuclear materials, Nuclear physics, 0103 physical sciences, Ceramic, Irradiation, Instrumentation, 010302 applied physics, Range (particle radiation), Chemistry, Fusion power, Damage production, 021001 nanoscience & nanotechnology, Rutherford backscattering spectrometry, Engineering physics, Amorphization, Plutonium, IMMOBILIZATION, Ion irradiation, visual_art, CERAMICS, visual_art.visual_art_medium, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], 0210 nano-technology
Abstract: Ceramic oxides and carbides are promising matrices for the immobilization and/or transmutation of nuclear wastes, cladding materials for gas-cooled fission reactors and structural components for fusion reactors. For these applications there is a need of fundamental data concerning the behavior of nuclear ceramics upon irradiation. This article is focused on the presentation of a few remarkable examples regarding ion-beam modifications of nuclear ceramics with an emphasis on the mechanisms leading to damage creation and phase transformations. Results obtained by combining advanced techniques (Rutherford backscattering spectrometry and channeling, X-ray diffraction, transmission electron microscopy, Raman spectroscopy) concern irradiations in a broad energy range (from key to GeV) with the aim of exploring both nuclear collision (S-n) and electronic excitation (S-e) regimes. Finally, the daunting challenge of the demonstration of the existence of synergistic effects between S-n and S-e is tackled by discussing the healing due to intense electronic energy deposition (SHIBIEC) and by reporting results recently obtained in dual-beam irradiation (DBI) experiments. (C) 2013 Elsevier B.V. All rights reserved.
Published: 2013
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