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Hafnium (Hf) isotopes in zircon are important tracers of granite petrogenesis and continental crust evolution. However, zircon in granites generally shows large Hf isotope variations, and the reasons for this are debated. We applied U-Pb geochronology, traceelement, and Hf isotope analyses of zircon from the Miocene Himalayan granites to address this issue. Autocrystic zircon had εHf values (at 20 Ma) of -12.0 to -4.3 (median = -9). Inherited zircon yielded εHf values (at 20 Ma) of -34.8 to +0.3 (median = -13); the majority of εHf values were lower than those of autocrystic zircon. The εHf values of inherited zircon with high U concentrations resembled those of autocrystic zircon. Geochemical data indicates that the granites were generated during relatively low-temperature (<800 °C) partial melting of metasedimentary rocks, which, coupled with kinetic hindrance, may have led to the preferential dissolution of high-U zircon that could dissolve more efficiently into anatectic melt due to higher amounts of radiation damage. Consequently, Hf values of autocrystic zircon can be biased toward the values of U-rich zircon in the source. By contrast, literature data indicate that granites generated at high temperatures (>820-850 °C) generally contain autocrystic and inherited zircons with comparable Hf isotope values. During highertemperature melting, indiscriminate dissolution of source zircon until saturation is reached will result in near-complete inheritance of Hf isotope ratios from the source. Our results impose an extra layer of complexity to interpretation of the zircon Hf isotope archive that is not currently considered. [ABSTRACT FROM AUTHOR]

As one of the widest terranes exposed in icy Antarctica, the Larsemann Hills in the Prydz Bay belt preserves diverse rock types with a complex metamorphic history and thus is critical to the tectono-metamorphic evolution of East Antarctica. Garnet-sillimanite-spinel-cordierite–bearing and garnet-orthopyroxene–bearing granulites are typical rocks in the region. Phase equilibrium modelling and mineral thermometry based on detailed petrological and mineralogical analyses indicate that the granulites underwent extreme metamorphism with peak conditions to ultrahigh temperatures (UHTs). The high-UHT metamorphism is characterised by extremely high dT/dP values (>1000°C/GPa) along a clockwise path with evident decompression at high temperatures and subsequent near isobaric cooling. Textural relationships, in situ NanoSIMS zircon U–Pb analysis, and LA-ICP-MS zircon and monazite dating and trace element analysis indicate protracted tectono-thermal evolution from the latest Neoproterozoic to early Palaeozoic (c. 570–500 Ma), with a prograde stage likely from c. 570 to c. 550 Ma, a peak stage from c. 550 to c. 540 Ma, and a retrograde stage from c. 540 to c. 500 Ma. During the retrograde stage, major decompression should have occurred before c. 530 Ma, as indicated by the age of zircon included in spinel, and then near isobaric cooling followed and persisted from c. 530 to c. 500 Ma. The geochronological data contribute to the establishment of the thermal–temporal framework of the late Neoproterozoic to early Palaeozoic Prydz tectonic event. The results also indicate that the assemblage of the investigated granulites basically resulted from the late Neoproterozoic to the early Palaeozoic tectono-thermal event, and the high-UHT conditions revealed by the granulites in the Larsemann Hills imply a much wider distribution of high heat flow and potential UHT metamorphism in the Prydz Bay region. Both the Larsemann Hills and the Rauer Group may have been in a similar and interrelated tectono-thermal setting from the late Neoproterozoic to the early Palaeozoic during the assembly of the Gondwana supercontinent. [ABSTRACT FROM AUTHOR]

The response of garnet and zircon to prograde amphibolite-facies metamorphism in late Proterozoic mica schists from the Scottish Highlands has been investigated. Spatial analysis of zircon populations using scanning electron microscopy was undertaken in Dalradian Schists that have undergone a sequence of prograde garnet growth and localised breakdown reactions involving coupled dissolution–reprecipitation. Fluid availability and matrix permeability strongly control this metamorphic response and different generations of garnet contain radically different populations of metamorphic micro-zircon and associated changes in the detrital zircon population. Micro-zircon abundance increases during garnet growth, whereas that of detrital zircon decreases. The mineralogy of the matrix influences zircon abundance in porphyroblast phases, where garnet overgrows a micaceous matrix zircon-rich garnet forms and where it overgrows a quartzofeldspathic matrix the result is zircon-poor garnet. Following garnet growth, micro-zircon abundance decreases at each stage of the prograde reaction history, with sillimanite-zone schists containing the lowest abundance, suggesting micro-zircons are texturally less stable at staurolite- and sillimanite-grade metamorphism. Micro-zircons are distributed evenly across host minerals in the matrix, with the exception of retrograde chlorite where micro-zircons are absent due to fluids removing Zr before new zircon can precipitate. There is an overall decrease in the mode of zircon at each stage of the reaction history, indicating that zircon is a highly reactive phase during amphibolite-facies metamorphism and is very sensitive to individual prograde and retrograde reactions. [ABSTRACT FROM AUTHOR]

The Lohit Plutonic Complex (LPC) represents Trans‐Himalayan magmatic rocks in the easternmost sector of the Himalayan Orogen. It is divided into leucogranite‐granodiorite‐diorite dominant suite in the NE and the gabbro‐diorite‐granodiorite‐granite–trondhjemite suite in the SE by the Walong Thrust. U–Pb geochronological analyses of euhedral zircon grains from different magmatic phases of LPC reveal episodic magmatism. Zircon U–Pb age of 153.4 ± 1.4 Ma of a garnetiferous granite gneiss suggest that the crustal sourced magmatism was active in Arunachal Trans‐Himalaya during the late Jurassic. U–Pb ages of subduction induced magmatic rocks of LPC range between 117 ± 0.6 Ma and 49.5 ± 0.3 Ma. A significant contribution in crustal recycling during the Oligocene–Miocene is evident from crustally derived leucogranites having U–Pb ages ranging from 35.6 ± 0.3 Ma to 30 ± 0.3 Ma. A comparison of the crystallization ages of the Western Trans‐Himalayan units with those of eastern Trans‐Himalayan units reveals an earlier onset of Tethyan arc magmatism in the eastern sector. The most prominent phase in the eastern sector is during the Late Cretaceous while western and central sector show major activity during the Palaeocene–Eocene. [ABSTRACT FROM AUTHOR]

In most geologic applications, if barite is present, it must be separated from zircon to enable analysis of the zircon. Current methods of barite removal include mechanical comminution in a ball mill or conversion to barium carbonate by boiling in an aqueous solution of sodium carbonate. Both procedures have potentially serious drawbacks. We optimized an alternative technique for barite removal to avoid these shortcomings. In repeated experiments, boiling in an aqueous solution of 0.1 M diethylenetriaminepentaacetic acid (DTPA) and 6 wt% potassium carbonate for one hour dissolved about 90% of sand-size barite grains. Examination of barite after boiling in DTPA solution revealed evidence for attacks on crystal surfaces in the form of microscopic scallops and pits. In contrast, zircon crystal surfaces were not detectably altered at the microscopic scale by a boiling solution of DTPA and potassium carbonate. The DTPA and potassium carbonate solution procedure may be superior to the other two barite removal methods in two ways. First, it might not introduce bias into the sample, in contrast to both of the other two methods. Second, it requires less time than the sodium carbonate solution technique. If future research shows that the DTPA and potassium carbonate solution technique does not affect isotopic systems in zircon, this method appears to be a favorable alternative to both milling and boiling in sodium carbonate solution. [ABSTRACT FROM AUTHOR]

The Ellsworth belt is one of several fault-bounded blocks exposed along the southeastern coast of Maine that formed within Ganderia. New ID-TIMS U–Pb geochronological data integrated with field relationships provide additional insights into the timing of magmatism and deformation in the Ellsworth belt. The deformed Lamoine Granite was selected for U–Pb zircon analysis to: (i) establish the protolith age; (ii) provide direct temporal constraints on regional low-grade metamorphism and deformation; and (iii) elucidate relationships between the Ellsworth belt and coeval rocks elsewhere in the Appalachian orogen. The Lamoine Granite was emplaced within the Ellsworth Schist at 492 ± 1.7 Ma; this is the first unequivocal evidence for a Furongian magmatic event in the Ellsworth belt. The schistosity in the Lamoine Granite is parallel to the main fabric of the host Ellsworth Schist and provides a maximum estimate for timing of the regional metamorphic overprint. Widespread deformation in the Ellsworth belt where kinematic indicators indicate a top-to-northwest sense of shear is attributed to thrusting during which progressive horizontal shortening, caused crustal thickening and peak greenschist facies metamorphism. The Cambrian U–Pb age permits correlation of the Lamoine Granite with the Cameron Road Granite in the Annidale belt of New Brunswick where subduction-related magmas intruded the Penobscot arc–back-arc and were subsequently deformed during the Penobscot Orogeny. [ABSTRACT FROM AUTHOR]

The essential sources and processes required for the formation of Cu–(Au)-porphyry deposits have been part of a long-standing debate. In this study we investigate one of the youngest and best-preserved world-class Cu–(Au)-porphyry systems in order to learn more about melt sources and what geochemical tracers in zircon and apatite might be useful to identify ore-forming intrusions within porphyry systems. Combined, in-situ Hf, O, and Nd isotope analyses in zircon and apatite imply that the Tampakan magmas were derived from depleted mantle sources. Hence, we suggest that older crustal components or metasomatized mantle are not required for the production of metallogenically fertile magmas in island arc settings. Based on the compositions of apatite and zircon, we confirm that previously established fertility-indicator signatures of these minerals are useful to identify fertile porphyry systems. Our data show that intrusions directly associated with mineralization events contain apatite with elevated Cl and S concentrations compared to pre- and post- mineralization igneous events. [ABSTRACT FROM AUTHOR]

The mechanism and timing of crustal growth and differentiation on early Earth are debated. Evidence of crustal differentiation is detectable as deviations from Earth's assumed chondritic uniform reservoir (CHUR) as crust is extracted from the mantle leading to a melt-depleted reservoir. For the long-lived zircon Lu-Hf system, no incontrovertible evidence of significant mantle depletion >3.8 Ga exists. We conduct combined U-Pb and Lu-Hf isotopic analyses for the detrital zircon from the Caozhuang supracrustal sequence in North China. The zircon Hf isotopic compositions are broadly scattered along the CHUR evolution line. However, given the possibility of potential systematic biases in zircon petrogenesis and the unique tectonic setting of early Earth, we posit that magmatism controlled by the nascent forms of plate tectonics during the Eoarchean could have likely hidden the degree of ancient crust-mantle differentiation. The non-depleted zircon Hf isotopes observed in North China and globally during early Earth may in verity imply the existence of ubiquitous depleted mantle domains at that time. [ABSTRACT FROM AUTHOR]

The Gentio metagranitoid presents equigranular and porphyritic facies, modal composition ranging from tonalite to monzogranite with calculated TZr<800 °C for most samples. Its mineralogy is dominated by quartz and feldspar (77% to 95%), biotite is the only mafic mineral present (2% to 18%) and, titanite, zircon, apatite, allanite are important accessory phases. These rocks range from metaluminous to weakly peraluminous, and have large variation in major and trace elements, and high alkali contents (>6 wt.%). Zircon analyses by LA-ICP-MS and SHRIMP yielded a concordia age of 2 119±10 Ma for the porphyritic facies and an upper intercept age of 2 111±15 Ma for the equigranular facies. The whole-rock Sm-Nd TDM ages vary from 2.4 to 2.8 Ga with εNd(2.1) values between −0.7 and −5.3, indicating crustal derivation from distinct and/or heterogeneous protoliths. Field observations indicate that the Gentio metagranitoid was formed through different pulses of magma. Individual batches were subject to little or even no fractionation process after its emplacement. Although the Gentio metagranitoid crosscuts metamafic and metaultramafic rocks akin to an oceanic arc setting, this pluton is likely originated by partial melting of a more evolved quartz-feldspathic crustal igneous rock in a post-collisional environment, after the accretion of the arcs from the Mineiro belt and rocks of the Mantiqueira Complex. [ABSTRACT FROM AUTHOR]

Zircon separates from the contact aureole of the syn-tectonic Dawros–Currywongaun–Doughruagh Complex, western Ireland, are studied to constrain the nature and timing of magmatism associated with the early stages of the Grampian Orogeny. The samples analysed come from the uppermost part of the Dalradian Supergroup in northern Connemara (the Ben Levy Grit Formation), where a laterally extensive (>10 km) package of metamorphosed siliciclastic sedimentary rocks containing heavy mineral seams crops out. The seams mainly comprise magnetite, but zircon is also present in greater than accessory quantities. The seams have been locally reworked at granulite-facies metamorphic conditions during intrusion of the Dawros–Currywongaun–Doughruagh Complex magmas. Here we combine in situ mineral chemical and U–Pb geochronological analyses of zircons from samples of these heavy mineral seams collected at different locations in the Dawros–Currywongaun–Doughruagh Complex thermal aureole. An important finding is that the zircons studied have magmatic trace-element compositions, interpreted here as a function of their growth during contact metamorphic-induced partial melting. The zircons yield a range of U–Pb spot ages whose uncertainties suggest a maximum duration of zircon growth of ˜11 Ma, between 477.1 and 466.1 Ma, though it is likely that zircon growth occurred much more quickly than this. The age constraints revealed here match well with the range of 475 to 463 Ma previously proposed for the Grampian Orogeny overall in Connemara and lend useful support to models that argue for high-intensity, relatively short-lived Grampian orogenesis in the Connemara Caledonides. [ABSTRACT FROM AUTHOR]

The Capricorn Orogen, Western Australia, is a complex orogenic zone that records the convergence and collision of the Archaean Yilgarn and Pilbara cratons in forming the West Australian Craton (WAC), then over one billion years of subsequent intracontinental reworking. Granites associated with these tectonothermal events (the Dalgaringa, Bertibubba, Moorarie, Durlacher and Thirty Three supersuites) are exposed in the western part of the Capricorn Orogen. This study integrates radiogenic (U–Pb and Hf) and stable isotope (O) analysis of zircon grains from granitic rocks in the Capricorn Orogen to determine their ages and magmatic sources, including the relative contributions of mantle versus crustal material. Granites from the margin of the Yilgarn Craton record periods of crustal growth and reworking during the Archaean that influenced later Proterozoic magmatic events. Components of the Capricorn Orogen, collectively termed the Glenburgh Terrane, have previously been considered to be exotic to the adjacent Pilbara and Yilgarn cratons. However, new U–Pb zircon geochronology and Lu–Hf isotope compositions of basement rocks in the Glenburgh Terrane (the Halfway Gneiss) have similarities to some terranes of the Yilgarn Craton, and are interpreted to represent a reworked portion of the craton that was re-accreted during the Glenburgh Orogeny. Arc magmatism during the Ma Glenburgh Orogeny resulted in a period of crustal growth, with magmas representing a mixture of 50–90 % mantle-derived magmas and 50–10 % magmas derived from an evolved crustal component with an isotopic composition equivalent to that of the Halfway Gneiss. Following assembly of the WAC, granite magmatism in the Capricorn Orogen records a significant change from one dominated by mantle-derived magmatism to one dominated by crustal melting and an increased contribution from metasedimentary material. This transition reflects a geodynamic evolution from subduction–accretion to collision and intracratonic reworking. The isotopic characteristics of granites from the Moorarie Supersuite indicate three distinct sources: (1) a metasedimentary component; (2) an evolved crustal component, comparable with the Glenburgh Terrane; (3) a mafic juvenile component. Following this, the Hf–O compositions of the Durlacher Supersuite indicate that they were derived from reworking of the Moorarie Supersuite granites, and require no juvenile contribution or any additional sedimentary source. The isotopic compositions of the Thirty Three Supersuite pegmatites indicate that they were largely derived from reworking of the Moorarie and Durlacher supersuites. [ABSTRACT FROM AUTHOR]

Middle to Upper Jurassic strata in the Paradox Basin and Central Colorado trough (CCT; southwestern United States) record a pronounced change in sediment dispersal from dominantly aeolian deposition with an Appalachian source (Entrada Sandstone) to dominantly fluvial deposition with a source in the Mogollon and/or Sevier orogenic highlands (Salt Wash Member of the Morrison Formation). An enigmatic abundance of Cambrian (ca. 527-519 Ma) grains at this provenance transition in the CCT at Escalante Canyon, Colorado, was recently suggested to reflect a local sediment source from the Ancestral Front Range, despite previous interpretations that local basement uplifts were largely buried by Middle to Late Jurassic time. This study aims to delineate spatial and temporal patterns in provenance of these Jurassic sandstones containing Cambrian grains within the Paradox Basin and CCT using sandstone petrography, detrital zircon U-Pb geochronology, and detrital zircon trace elemental and rare-earth elemental (REE) geochemistry. We report 7887 new U-Pb detrital zircon analyses from 31 sandstone samples collected within seven transects in western Colorado and eastern Utah. Three clusters of zircon ages are consistently present (1.53-1.3 Ga, 1.3-0.9 Ga, and 500-300 Ma) that are interpreted to reflect sources associated with the Appalachian orogen in southeastern Laurentia (mid-continent, Grenville, Appalachian, and peri-Gondwanan terranes). Ca. 540-500 Ma zircon grains are anomalously abundant locally in the uppermost Entrada Sandstone and Wanakah Formation but are either lacking or present in small fractions in the overlying Salt Wash and Tidwell Members of the Morrison Formation. A comparison of zircon REE geochemistry between Cambrian detrital zircon and igneous zircon from potential sources shows that these 540-500 Ma detrital zircon are primarily magmatic. Although variability in both detrital and igneous REE concentrations precludes definitive identification of provenance, several considerations suggest that distal sources from the Cambrian granitic and rhyolitic provinces of the Southern Oklahoma aulacogen is also likely, in addition to a proximal source identified in the McClure Mountain syenite of the Wet Mountains, Colorado. The abundance of Cambrian grains in samples from the central CCT, particularly in the Entrada Sandstone and Wanakah Formation, suggests northwesterly sediment transport within the CCT, with sediment sourced from Ancestral Rocky Mountains uplifts of the southern Wet Mountains and/or Amarillo-Wichita Mountains in southwestern Oklahoma. The lack of Cambrian grains within the Paradox Basin suggests that the Uncompahgre uplift (southwestern Colorado) acted as a barrier to sediment transport from the CCT. [ABSTRACT FROM AUTHOR]

To better constrain the petrogenesis and tectonic setting of the granitic plutons in the Guaizihu region, NW China, this study presents a new analysis of zircon U–Pb ages, whole-rock geochemistry and Hf isotopes of syenogranites. The syenogranites are medium- to coarse-grained, with moderate to high SiO2 (72.55–74.27 wt%) and Al2O3 (13.02–13.75 wt%) contents and moderate total alkalis (Na2O + K2O, 7.58–7.98 wt%), which indicate that the syenogranites exhibit calc-alkaline and peraluminous characteristics. The low Ce, 10 000 Ga/Al, and A/CNK values and the negative correlation of SiO2 and P2O5 confirm that the syenogranites are of I-type origin. The whole-rock geochemistry demonstrates that the magma was generated by partial melting and experienced fractional crystallisation. Specifically, the correlations of Rb with Ba and Sr and the weak negative Eu anomalies indicate that the plagioclase has undergone fractional crystallisation. In addition, Eu anomalies and La/Sm–La relations show that both fractional crystallisation and partial melting contributed to the magmatic process. The positive εHf(t) values (0.11–9.78); enrichments in Rb, Th and other LILEs; depletions in Nb, Sr and other HFSEs; and the ratios of geochemical elements indicate that the syenogranites were generated from the partial melting of juvenile crust. The granites are inferred to have formed in a post-collisional extensional environment. Additionally, the U–Pb zircon ages (284.6 ± 0.84 Ma and 269.4 ± 1.2 Ma) of syenogranites suggest that final closure of the Paleo-Asian Ocean occurred before 285 Ma. Granites in the Guaizihu region are dated at 284.6 ± 0.84 Ma and 269.4 ± 1.2 Ma, and the Paleo-Asian Ocean, where the Engger Us Ophiolite Belt is located, closed before 285 Ma. Granites are medium- to coarse-grained and highly fractionated I-type syenogranites. Granites have been derived from magma generated by the partial melting of juvenile crust followed by fractional crystallisation. Granites were formed in an intraplate extensional environment related to a post-collisional event. [ABSTRACT FROM AUTHOR]

Oceanic arc subduction systems are the loci of substantial recycling of oceanic crust and production of juvenile arc crust that differentiates to more evolved felsic crust. Inevitably, some juvenile sediments are subducted with the oceanic crust. However, distinguishing the incorporation of juvenile sediments in oceanic arcs is not always straightforward, because they may not measurably shift many geochemical signatures, such as Sr and Nd isotopes, of oceanic arcs. Nevertheless, combined zircon U-Pb, Hf, and O isotope data can provide a powerful tool to decipher sedimentary flux into oceanic arc magmas, and here we report a case study for the late Paleozoic A-type granites from the West Junggar oceanic arc in the southern Central Asian Orogenic Belt. These plutons contain hastingsite and iron biotite diagnostic minerals and have high alkali, FeOT/MgO, Zr, and Ga/Al, but possess low CaO contents, and strongly negative Eu, Sr, and Ba anomalies, demonstrating their close affinity with A-type granites. Zircon U-Pb analyses indicate that these A-type granites emplaced in the Late Carboniferous to Early Permian (ca. 307-298 Ma). Their high zircon εHf(t) values (+12.4 to +15.5), suggest that the magmas were derived from a mantle or juvenile crustal source. However, their δ18Ozrn (+7.2‰ to +11.9‰) values are significantly higher than that of the mantle, and modeling using Hf-O isotope and rare earth element data indicate the assimilation of sedimentary materials at a proportion of ~50%. Our data suggest that juvenile sediments (e.g., greywacke) played an important role in the formation of the studied A-type granites. The re-melting of sedimentary material induced by the late Carboniferous ridge subduction can promote the transition from an intra-oceanic arc to continental crust. Our results show that the subduction and re-melting of juvenile sediments in oceanic arc systems could be an important mechanism for the maturation of oceanic arc crust. [ABSTRACT FROM AUTHOR]

Nineteen ichnotaxa, together with algal and invertebrate remains, and various pseudo-traces and sedimentary structures are described from the Torneträsk Formation exposed near Lake Torneträsk, Lapland, Sweden, representing a marked increase in the diversity of biotic traces recorded from this unit. The "lower siltstone" interval of the Torneträsk Formation contains mostly simple pascichnia, fodinichnia and domichnia burrows and trails of low-energy shoreface to intertidal settings. The assemblage has very few forms characteristic of high-energy, soft-sediment, foreshore or upper shoreface environments (representative of the Skolithos ichnofacies). Uranium-lead (U-Pb) LA-ICPMS analysis of zircon from a thin claystone layer within the "lower siltstone" interval yielded a maximum depositional age of 584 ± 13 Ma, mid-Ediacaran. Most of the zircon is represented by rounded detrital grains that yield dates between 3.3 and 1.0 Ga. Although the age of the basal sandstone-dominated interval of the Torneträsk Formation remains elusive owing to the absence of fossils, the ichnofossil suite from the overlying "lower siltstone" interval lacks deep arthropod trackways, such as Rusophycus and Cruziana, and is suggestive of a very early (Terreneuvian, possibly Fortunian) Cambrian age. The ichnofauna is otherwise similar to early Cambrian trace fossil assemblages from other parts of Baltica, regions further south in modern Europe, and from Greenland. [ABSTRACT FROM AUTHOR]

It is unclear whether the South China blocks have an affinity with continental Gondwana due to a lack of direct Pan‐African magmatic and metamorphic features. In this study, we conducted U‐Pb geochronological and Lu‐Hf isotopic analyses for detrital zircons from a sandstone of the Chang'an Formation of the Nanhua Group in the Longsheng region of northern Guangxi, with the aim of constraining the timing of sedimentation and information as to its source, as well as seeking evidence for Pan‐African events in the South China blocks. The results show that the ages of detrital zircons peaked at 654.7 ± 6.2 Ma, 773.2 ± 4.1 Ma and 821.9 ± 6.5 Ma, with some at 920–870 Ma; the youngest age indicates the existence of the Pan‐African thermal event. The ∊Hf(t) and TDM2 values demonstrate that the study area has experienced three stages of crustal growth at 3.0–2.4 Ga, 2.1–1.5 Ga and 1.3–0.9 Ga. With intensively distributed Neoproterozoic mafic‐ultramafic and granitic plutons emplaced at 830–810 Ma along the southwestern section of the Jiangnan Orogenic Belt and positive ∊Hf(t) values from a large group of zircon grains, it is proposed that the sediments of the Chang'an Formation (of Nanhua Group) were largely sourced from the southeastern margin of the Yangtze block. Comparison with the zircon age spectra of the Cathaysian block shows that about 79% of the Pan‐African aged detrital zircon grains that have TDM2 = 1352–1031 Ma and ∊Hf(t) = 3.68–8.79, were sourced from the recycled Grenvillian crust of the Cathaysian block, suggesting that the Cathaysian block had a close connection with Gondwana. [ABSTRACT FROM AUTHOR]

The Yangtze Block in South China constitutes an important Precambrian landmass in the present East Asian continent. The Neoproterozoic sedimentary successions of the Hengdan Group in the NW Yangtze Block record essential information for deciphering the Neoproterozoic tectonics along the NW margin. However, its depositional age, provenance and tectonic properties remain uncertain. Here, a combined analysis of detrital zircon U–Pb dating and geochemistry is performed on representative samples from the Hengdan Group. Concordant dating results of samples from the bottom and upper parts constrain the maximum depositional age at c. 720 Ma. Detrital zircon age patterns of samples reveal a uniformly pronounced age peak at c. 915–720 Ma, which is consistent with the magmatic pulses in domains at the NW end of the Yangtze Block. In addition, these samples display left-sloping post-Archaean Australian shale (PAAS)-normalized rare-earth element patterns and variable trace element patterns, resembling sediments accumulated in a basin related to an active continental margin geodynamic setting. Provenance analysis reveals that the main sources featured intermediate to felsic components, which experienced rapid erosion and sedimentation. These integrated new investigations, along with previous compilations, indicate that the Hengdan Group might have been deposited in a fore-arc basin controlled by subduction beneath the Bikou Terrane. Thus, such interpretation further supports proposals for subduction-related tectonics along the western margin of the Yangtze Block during the early Neoproterozoic. [ABSTRACT FROM AUTHOR]

A study of heavy mineral assemblages, rutile compositions, and detrital zircon age populations in Namurian to Westphalian sandstones in North Wales, deposited in the southwestern part of the Pennine Basin of the United Kingdom, has revealed considerable complexity in their provenance history. The Pendleian to Marsdenian Cefn‐y‐fedw Sandstone Formation, which is known to have been derived from the Wales–Brabant Massif (WBM) to the south on the basis of palaeocurrent and petrographic information, has a heavy mineral assemblage characteristic of this southerly provenance, and includes Late Neoproterozoic zircons apparently of local WBM origin. However, the formation is dominated by zircons that were most probably recycled from sandstones of northern origin from the Caledonian Belt that had been previously deposited over the massif during Late Devonian times, and, as such, has a comparable history to the sedimentologically‐equivalent Morridge Formation of the English Midlands. Heavy mineral analysis shows that sandstones in the Brigantian Minera Formation and Yeadonian part of the Bowland Shale Formation are of similar southern provenance. The Yeadonian Gwespyr Sandstone, previously interpreted as having a northern origin, similar to the time‐equivalent Rough Rock, has variations in heavy mineral analysis and zircon spectrum that suggest a complex provenance history and includes sand bodies with northern, western, and southern origins. [ABSTRACT FROM AUTHOR]

Multiple parting bands within Permo–Carboniferous coal that are generally enriched in critical metals in the northern North China have been confirmed to be altered from volcanic ash (tonsteins). The tonsteins and adjacent coal in some areas contain boehmite with varying contents. Whether or not the boehmite has a relationship with the volcanic-ash-altered kaolinite remains poorly understood. Herein, petrographical, mineralogical, whole-rock geochemical, and in-situ elemental analyses, combined with U–Pb–Hf isotopic analysis of zircon, were performed for the boehmite-bearing/rich partings and coal collected from the eastern edge of the Datong and Jungar coalfields. Except for the boehmite, well-ordered kaolinite is predominant in the parting samples, where the columnar/tabular and vermicular kaolinite are commonly present. Additionally, the zircons separated from the representative parting and coal samples are mostly igneous origin with only one age population of ca. 300 Ma, almost same with the depositional age of the coal, suggesting that the kaolinite in the inorganic constitutes of the investigated coal seams were mainly altered from volcanic ash. Numerous fine-grained boehmite exhibit textural features of replacement for columnar/tabular and vermicular kaolinite along the cleavage cracks in the parting samples, suggesting that such boehmite were formed from desilication of volcanic-ash-altered kaolinite. The tonsteins and coal along the eastern edge of the coalfields were uplifted and influenced by fault activities due to Indosinian and Yanshan orogeny, which were probably experienced intensive leaching by silica-undersaturated percolating water and groundwater, resulting in desilication of volcanic-ash-altered kaolinite and precipitation of residual Al as boehmite. The Ga, preserved in the alumina octahedral sheets of volcanic-ash-altered kaolinite, were retained by boehmite due to its very similar geochemical behavior with Al. The formation of boehmite and its retention for Ga made a contribution to the genesis of high–Al–Ga coal in the northern North China. • Boehmite was formed from desilication of volcanic-ash-altered kaolinite. • Formation of boehmite and its retention for Ga contributed to genesis of high–Al–Ga coal. • Volcanic ash play a role in enrichment of critical metals in Permo–Carboniferous coal of North China. [ABSTRACT FROM AUTHOR]

[Display omitted] Evolution of internal or external oceanic domains can bring decisive indications into the mode of formation of supercontinents, which is key to understand the supercontinent cycle. Defining the type of ocean evolving in the Central Asian Orogenic belt (CAOB) is thus critical to better understand the Earth's supercontinental evolution. In this contribution, we provide systematic and combined U-Pb, trace-element in zircon and hafnium-in-zircon analyses of four turbidites of the Altai accretionary wedge. These turbiditic rocks provide constraints into the early Paleozoic subduction-accretionary stages of the Mongolian Accretionary Collage (MAC) and show a major detrital age peak in the Cambro-Ordovician (∼490–500 Ma), with minor Neo- and Paleo-Proterozoic to Archean peaks. The zircon trace-elemental patterns are consistent with derivation mostly from magmatic arc (with granitoids affinity), interpreted as detritus sourced from the Ikh-Mongol continental arc system further north-east (present coordinates). The main detrital zircon peak together with the zircon magmatic arc origin suggest that the subduction-accretionary stage was active from 550 to 430 Ma showing mixed ε Hf (t) values (-20 to + 15). A summary of the detrital zircon ε Hf (t) values from 550 to 430 Ma suggests a continuous increase of ε Hf (t) mean values from + 0.2 to + 6.1 towards younger ages. The younging juvenile trend can be compared to the evolution of external orogeny, therefore consistent with a Pacific-type accretionary system facing an external ocean. At last, the results combined with two paleo-geographic reconstructions from the literature imply that the MAC may have been part of the Peri-Siberian accretionary orogeny in the early Paleozoic. [ABSTRACT FROM AUTHOR]

An increasing number of detrital zircon U–Pb geochronological data have been reported to trace sediment provenance for the Cenozoic Qaidam basin, which is crucial to understanding crustal deformation, paleoclimate change and basin development in northern Tibetan Plateau and to assessing geodynamic models of plateau growth. However, the existing provenance interpretations are highly diverse and how the northern Tibet has evolved remains controversial. This contribution presents new detrital zircon dating results from Cenozoic outcrop and borehole samples and compiles published data from the whole Qaidam basin, adjacent small Cenozoic basins and the surrounding mountains. Our new synthesis indicates that, Paleoproterozoic signals (1800–2000 Ma and 2350–2500 Ma), rather than the Permian–Triassic ages, can be applied effectively to distinguish the Qilian, Altun and Eastern Kunlun-sourced detrital zircons. The Cenozoic Qaidam basin exhibits spatiotemporally variable detrital zircon age populations. Most sandstones from the western and southern basin are characterized by Phanerozoic bimodal age spectra (i.e., 400–480 Ma and 220–280 Ma) with minor Precambrian signals, indicating major contributions from the neighboring Altun and Eastern Kunlun ranges. By contrast, almost all the northern and eastern basin sandstones display prominent early Paleozoic detrital zircon ages; but Paleoproterozoic, Neoproterozoic (750–950 Ma) and Permian–Triassic signals only appear as dominant age clusters in some samples. Different temporal variation trends are observed from the investigated sections in this region, revealing variable zircon supply from different micro-terranes in the Qilian Mountains. This implies that using detrital zircon provenance data from a single section or from a local area of the Qaidam basin to address regional tectonic and climatic issues of the northern Tibetan Plateau unlikely provide useful results. We propose that the Cenozoic Qaidam basin deposits were derived from localized, adjacent source regions, rather than cross-basinal, distant mountains. Our conclusions support models with synchronous deformation throughout most of northern Tibet in the Cenozoic. The observed spatiotemporal variations in detrital zircon populations are not only attributed to tectonic deformation-induced source changes, but can also be due to heterogeneity of the source terranes (e.g., durability and zircon fertility) and variable factors (e.g., hydrodynamic sorting, recycling and sedimentary microenvironment) in transport-deposition processes. This study also highlights the importance of involving detrital zircon textural and sedimentological parameters to zircon provenance interpretations. An integrated provenance analysis combining other detritus components is helpful to comprehensively characterize source-to-sink systems for sedimentary basins. • Spatiotemporal variations in Qaidam basin detrital zircon ages are evident. • Paleoproterozoic zircon ages are unique signatures for the Qilian Mountains. • Cenozoic deposits were from nearby sources, rather than cross-basinal mountains. • Varied source-to-sink systems contribute to detrital zircon provenance variations. • Detrital zircon analysis on a local area cannot address regional tectonic issues. [ABSTRACT FROM AUTHOR]

The Wulian complex is located on the northern margin of the Sulu orogenic belt, and was formed by collision between the North China Craton (NCC) to the north and South China Craton (SCC) to the south. It consists of the metasedimentary Wulian Group, gneissic granite and meta-diorite. The U–Pb analyses for the detrital zircons from the Wulian Group exhibit one predominant age population of 2600–2400 Ma with a peak at c. 2.5 Ga and several secondary age populations of > 3000, 3000–2800, 2800–2600, 2200–2000, 1900–1800, 1500–1300 and 1250–950 Ma; some metamorphic zircons have metamorphic ages of c. 2.7, 2.55–2.45, 2.1–2.0 and 1.95–1.80 Ga, which are consistent with magmatic-metamorphic events in the SCC. Additionally, the Wulian Group was intruded by the gneissic granite and meta-diorite at c. 0.76 Ga, attributed to Neoproterozoic syn-rifting bimodal magmatic activity in the SCC and derived from partial melting of Archaean continental crust and depleted mantle, respectively. The Wulian Group therefore has tectonic affinity to the SCC and was mainly sourced from the SCC. The detrital zircons have positive and negative ϵHf(t) values, indicating that their source rocks were derived from reworking of both ancient and juvenile crustal rocks. The major early Precambrian crustal growth took place during c. 3.4–2.5 Ga with a dominant peak at 2.96 Ga and several secondary peaks at 3.27, 2.74 and 2.52 Ga. The two oldest zircons with ages of 3307 and 3347 Ma record the recycling of ancient continental crust (> 3.35 Ga) and crustal growth prior to c. 3.95 Ga in the SCC. [ABSTRACT FROM AUTHOR]

The South Altyn Block (SAB), located along the southern margin of the Altyn Tagh in Qaidam Basin, has a significant relationship with the tectonics of the Qaidam Basin basement. This study presents the petrological features, geochemical compositions, and zircon U–Pb and Hf isotope data of four granitic plutons from the eastern segment of the SAB to constrain the petrogenesis and tectonic setting of this region during the Palaeozoic. Basing on previous U–Pb dating results, the zircon U–Pb analysis in this study suggests that Palaeozoic magmatic events can be subdivided into four episodes: Late Cambrian (approximately 502 Ma), Late Ordovician (approximately 444 Ma), Early Devonian, and Middle Permian (approximately 271 Ma). The Palaeozoic granitoids were derived mainly from Neoproterozoic juvenile crustal components, with minor palaeoproterozoic ancient materials. The S‐ and I‐type granitoids in Late Cambrian indicate a compressional tectonic environment with respect to subduction, and A‐type granitoids suggest post‐collision regime. The Late Ordovician granodiorites of A‐type imply typical magmatism within a post‐collision extensional setting. Ascribing to the subduction of Palaeo‐Tethys Ocean during the Devonian, S‐type granites were emplaced in the Early Devonian accompanied with the crust thickening. The Middle Permian magmatic events include a series of S‐type granitoids, demonstrating the setting of oceanic subduction along with the closure of the Palaeo‐Tethys Ocean. [ABSTRACT FROM AUTHOR]

The South China Block (SCB) has been regarded by many as an integral part of Gondwana, but proposed timing and processes for its accretion to Gondwana vary and remain contentious, largely owing to the lack of reliable Pan‐African age paleomagnetic data and tectono‐magmatic records from the SCB. Integrated in situ U‐Pb ages and Hf‐O isotope analyses of detrital zircons from geochronologically well‐calibrated Ediacaran‐Cambrian sedimentary rocks of western SCB reveal age populations of 2.51, 1.85, 1.20, 0.80, and 0.52 Ga. Detrital zircon age spectra indicate a major tectonic transition for the SCB during 0.56–0.54 Ga, interpreted to reflect the beginning of the collision between SCB‐Indochina and NW India blocks. The collisional event lasted until early Ordovician, leading to the suturing of the SCB‐Indochina to the northern margin of East Gondwana. Plain Language Summary: The South China Block is thought to be a part of the Gondwana superterrane, which was composed of more than half of all continents 650–400 million years ago (Ma). However, questions of when and how the South China Block collided with Gondwana are yet to be answered. In this study, we conducted provenance analyses of sedimentary rocks whose depositional ages were known via radioisotopic dating and chemo‐biostratigraphy in the western South China Block. The results reveal a change in tectonic setting of the South China Block at 560–540 Ma, interpreted as the onset of the collision between the South China Block and India along the northern margin of East Gondwana. Key Points: 1.2‐Ga detrital zircon population is present in age‐calibrated Ediacaran‐Cambrian strata of western South China BlockA major change in tectonic setting of the South China Block occurred in 0.56–0.54 GaThe connection between the South China Block and NW India Block started in the late Ediacaran [ABSTRACT FROM AUTHOR]

To detect the exhumation history of the southwestern South China Block (SCB), we performed fission track (FT) analysis on zircon and apatite grains in granitoid and sedimentary samples. From east to west, the study area includes the Yunkai Massif, Lingshan granitic belt, Shiwandashan Basin, and eastern margin of the Youjiang Basin. The granite sample of the Yunkai Massif has two peaks of 75 and 92 Ma for zircon FT dating. The Lingshan granitic belt samples yield zircon FT central ages from 135 to 132 Ma. The Permian bauxite samples of the Youjiang Basin yield zircon FT central ages from 109 to 93 Ma and display age peaks at ~97–93 Ma. The Yunkai Massif granite sample has two peaks at 74 and 104 Ma for apatite FT dating, while the Lingshan granitic belt sample has two peaks at 81 and 111 Ma. The cooling paths of the Yunkai Massif sample started with an Early Cretaceous (~120–100 Ma) cooling event that brought the granitoids into the apatite partial annealing zone (PAZ). Through comparative studies, we suggest that the southwestern SCB underwent three periods of crustal uplift during ~135–132, ~111–92, and ~ 81–74 Ma, respectively, which is consistent with the regional stratigraphic unconformity and crustal extension. Only the Yunkai Massif and Lingshan granitic belt were uplifted during ~135–132 Ma. During ~111–92 Ma, the southwestern SCB experienced crustal uplift, and the basal conglomerate began to deposit in the Shiwandashan Basin. Late Cretaceous uplifted occurred during ~81–74 Ma, and the Yunkai Massif was uplifted throughout the Cretaceous. From 97 to 92 Ma, the Permian bauxite deposits in the Youjiang Basin were uplifted, which provided the basis of the later transformation to Quaternary bauxite. [ABSTRACT FROM AUTHOR]

The retrieval of accurate thermal histories recorded by the (U-Th)/He system relies on empirical estimates of diffusion kinetics from natural minerals, although the difficulty in obtaining samples with homogeneous gas concentrations (required for accurate diffusivities) has limited the collection of such datasets. Whole-grain analyses are relatively time- and cost-effective, but natural 4He concentration heterogeneities caused by α-ejection, diffusional rounding, and/or parent nuclide zonation present an unquantified source of error. We employ a 1D spherical finite difference diffusion model to simulate effects of natural sources of He concentration heterogeneities, with a focus on the zircon (U-Th)/He (ZHe) system. Using He concentration profiles affected by various natural heterogeneities, models consistently predict that diffusion kinetics are strongly underestimated using such methods, especially at low gas release fractions. These underestimations are driven by He depletion near the grain boundary caused by α-ejection, and exacerbated by U and Th depletion. Conversely, models with parent nuclide (and therefore He) enrichment near the grain boundary compensate for ejection-based loss, yielding more accurate diffusion kinetics overall. A comparison of these results to real step-heating data yields few similarities, however, with He releases from real zircons either being linear in Arrhenius space, or having anomalously high diffusivities at low fractional releases. Radiation damage and its annealing are also significant factors affecting He diffusional mechanics. Using diffusivities and annealing as predicted by the current ZHe forward model, cycled step-heating of high-dose zircons (>1 × 1018 α/g) predict that diffusion decreases consistently with increased heating temperatures, similar to observations. The forward model predicts that annealing beyond this threshold dose should increase diffusivity, which is not observed, however. These results suggest that whole-grain step-heating data may provide a reasonable proxy for empirically measuring damage annealing kinetics in zircon. Major discrepancies between model results and real data reveal the need for more cycled-step heating data to understand the full complexities of He diffusion dynamics. [ABSTRACT FROM AUTHOR]

Previously dated zircon crystals from the Amalia-Kraaipan granite-greenstone belts and Makoppa Dome were analysed for their Lu-Hf isotopic characteristics to refine the geological evolution of these areas. Samples from the Makoppa Dome, belonging to the Pietersburg Block, largely fall within the epsilon Hf-age range for granitoids from the eastern part of the block. However, the oldest 3.01 to 3.03 Ga trondhjemitic gneisses show that reworking of juvenile mafic crust started earlier in the western than the eastern part of the block, suggesting a diachronous tectonic evolution. The three granitoids from the Amalia-Kraaipan area fall within the field for Pietersburg and Kimberley block granitoids. Contribution from older crustal material is seen in a 3.08 Ga schist, likely derived from a volcanic protolith, from the Madibe Belt, in the far east of the Kimberley Block, with a mantle extraction age of 3.25 to 3.45 Ga. The data suggest that the Kimberley Block, like the Pietersburg Block, also contains (minor) ancient crustal components, derived from a depleted mantle source prior to 3.1 Ga. The new data suggest that the Kimberley and Pietersburg blocks underwent a very similar Paleo- to Mesoarchean crustal evolution, with a major crust formation event at 3.1 to 3.0 Ga followed by successive crust reworking until 2.77 Ga. Lavas of the Ventersdorp Supergroup, for which zircon grains from a ca. 2.75 lapilli tuff give Hfi of +2, are the first evidence of a juvenile source, after 300 Myr of crustal reworking. [ABSTRACT FROM AUTHOR]

In the supercontinent of Rodinia, Baltica occurred next to Amazonia, then the two drifted away when Rodinia broke up. By the end of the Neoproterozoic, Baltica became an independent continent. At that time, Timanide orogen developed at its modern northeastern margin. In most paleogeographical reconstructions, the opposite (SW, Tornquist) edge faced the Tornquist Ocean and remained just a passive margin till the arrival of the Gondwana-born East Avalonia in the late Ordovician. However, preliminary isotopic studies of detrital zircons from the Tornquist passive margin succession hinted that rock components of Gondwana derivation reached Baltica already in the early Cambrian. In this paper, we examine 18 drill-cores of Ediacaran-Cambrian and Ordovician siliciclastic rocks from the tectonostratigraphic units along the SW–NE transect from Upper Silesia (USB) via Małopolska (MB) and the Holy Cross Mts (HCM) to the East European Platform (EEP), SE Poland, in terms of the provenance data gained from the LA-ICP-MS and SHRIMP analyses of 32 zircon samples. Rocks from all the units revealed abundant Cadomian 0.7–0.55 Ga detrital zircons (15–50% of the total analyzed grains) and other grains that yielded peaks at 0.9–1.2, 1.4–1.6, 1.8–2.2, 2.7–3.0 Ga assignable to Baltica rather than Amazonia. Such age spectra in the USB, HCM and EEP prove the proximity of peripheral (peri-Gondwanan) fragments of the Cadomian orogen to Baltica. These fragments formed the Teissyere-Tornquist Terrane Assemblage (TTA) that obliquely docked and overrode the thinned southwestern edge of Baltica which earlier accumulated Neoproterozoic rift and passive margin deposits. Our data show that in the late Ediacaran-early Cambrian, parts of the Cadomian orogenic belt became accreted to Baltica. [ABSTRACT FROM AUTHOR]

The gold mineralization in the Central Aldan ore district is genetically related to potassic calc-alkaline and alkaline magmatism dated at 115–150 Ma. The objective of this study is to establish the age of hydrothermal processes that accompanied the formation of Au-Te mineralization at the Samolazovsky Deposit. Based on the isotope-geochemical study of zircons from quartz-feldspar metasomatic rocks of the deposit, the granitoids and charnokites of the Nimnyr Complex (1 900–1 960 Ma) at the contact with the Yukhta monzonite-syenite massif (∼127 Ma) were studied. Zircon U-Pb dating was performed on a SHRIMP-II ion microprobe, and rare-earth and trace elements analyses of zircon were carried out in the same craters by secondary-ion mass spectrometry on a Cameca IMS-4f ion microprobe. It is revealed that the studied zircons have heterogeneous structures: dark core and lighter rim, which differ greatly in isotope-geochemical parameters. Zircon rims are cut by a network of fractures, extending into the central part of zircon grains. The rims yield a subconcordant age of 1 937±24 Ma, with an average total REE content of 550 ppm, which corresponds to the formation age of the Nimnyr Complex. All zircon cores yield a discordant age of 83±11 Ma and are characterized by a higher total REE content (∼1 812 ppm), as well as higher contents of U and non-formula elements (Ca, Sr, and Y) with respect to rims, due to the effect of fluid on zircons. Despite the limited number of zircon grains, the additional geochronological study of zircons from syenites of the ore-bearing Ryabinovy Massif has revealed the presence of two distinct age clusters: ∼125–138 and 76–83 Ma. The older ages of zircons from syenites are typical for the Central Aldan ore district. Until now, there is still no explanation for an age range (76–83 Ma) of single zircon grains from ore-bearing syenites of the Ryabinovy Massif. The obtained data suggest that the processes of activation (the effect of fluid) within the Central Aldan ore district continued until Late Mesozoic. With regards to the equivocal geotectonic position of the Mesozoic potassic magmatism in the study area and its high metallogenic potential, there exists an absolute necessity to determine the geochronological age of the rock formations. Therefore this study presents the Late Cretaceous geochronological data for the first time which can constrain the time-frame for the formation of gold-bearing magmatic and metasomatic rocks of the Aldan ore district. [ABSTRACT FROM AUTHOR]

Zirconium (Zr) plays a key role in the development of phases like zircon (ZrSiO4) and baddeleyite (ZrO2) in magmatic systems. These minerals are crucial for the study of geologic time and crustal evolution, and their high resistivity to weathering and erosion results in their preservation on timescales of billions of years. Although zircon and baddeleyite may also preserve a robust record of Zr isotope behavior in high-temperature terrestrial environments, little is known about the factors that control Zr isotope partitioning in magmatic systems, the petrogenetic significance of fractionated compositions, or how these variations are recorded in Zr-rich accessory phases. Here, we describe a new analytical protocol for accurately determining the Zr stable isotope composition of zircon by multicollector-inductively coupled plasma-mass spectrometry (MC-ICP-MS), using the double-spike method to correct for procedural and instrumental mass bias. We apply this technique to test whether zircon crystallization in carbonatite magmatic systems is a driver of Zr isotope fractionation by interrogating the internal zonation of a zircon megacryst from the Mud Tank carbonatite (MTUR1). We find the MTUR1 megacryst to lack internal zoning within analytical uncertainties with a mean μ94/90ZrNIST = −55 ± 28 ppm (2 SD, n = 151), which suggests that zircon crystallization is not a driver of Zr isotope fractionation in carbonatite magmas. This observation is in stark contrast with those made in silicate magmatic systems, raising the possibility that the bonding environment of Zr4+ ions may be fundamentally different in carbonatite vs. silicate melts. Because of its remarkable homogeneity, the MTUR1 megacryst is an ideal natural reference material for Zr isotopic analysis of zircon using both solution and spatially resolved methods. The reproducibility of a pure Zr solution and our chemically purified zircon fractions indicate that the external reproducibility of our method is on the order of ±28 ppm for μ94/90Zr, or ±7 ppm per amu, at 95% confidence. [ABSTRACT FROM AUTHOR]

In situ U-Pb geochronology has been conducted using laser ablation inductively coupled mass spectrometry (LA-ICP-MS) on shocked and thermally metamorphosed apatite, titanite, and zircon grains from the Steen River impact structure, Canada. The dated relict mineral phases occur within impact melt-bearing breccias that underwent post-deposition sintering at 450 °C > T < 800 °C. Apatite yields a refined lower intercept age of 141 ± 4 Ma, which we interpret as the best estimate age for the Steen River impact event. Titanite was only partially reset; yielding a lower intercept age of 113 ± 41 Ma. Zircon yields a lower intercept impact age of 120 ± 14 Ma, which is considered a minimum best-estimate impact age. The most reset zircon analyses that control this lower intercept are complicated by combinations of common-Pb incorporation and recent Pb loss associated with granularized and radiation-damaged (metamict) domains. All three phases preserve Paleoproterozoic crystalline basement ages, with a single concordant 206Pb/238U age of 1914 ± 39 Ma from apatite, an upper intercept age of 1882 ± 11 Ma from zircon, and an upper intercept age of 1842 ± 9 Ma from titanite. For apatite, the degree of isotopic resetting is largely thermally controlled, with the extent of reset closely associated with textural setting (degree of grain armouring, melt proximity and sample temperature) and, to a lesser extent, by shock/thermally generated microstructures (i.e., planar fractures, micro-vesicles, and recrystallized domains). While titanite records an impact age that falls within error of apatite and zircon, the majority of grains experienced only partial isotopic resetting, which we attribute to incomplete Pb loss associated with rapid cooling and post-depositional sintering of the breccia matrix below the titanite closure temperature (∼800 °C). In zircon, ancient (impact) Pb loss was facilitated along defect-related, fast-diffusion pathways within pre-impact metamict domains, shock defects, and via recrystallization. These same domains were also subject to recent (post-impact) Pb loss and common Pb contamination, significantly compromising the reliability of zircon ages. The distribution of U-Pb ratios in apatite and titanite is unlike those obtained in crystalline targets, a feature we interpret to be characteristic of impact structures developed in mixed (sedimentary – crystalline) targets, such as Steen River. In this case, disaggregated melt systems create thermal regimes distinct from those derived from predominantly igneous/metamorphic targets. With an age of 141 ± 4 Ma, Steen River joins the Dellen (Sweden), Gosses Bluff (Australia), Mjølnir (Barents Sea), and Morokweng (South Africa) impact structures in being formed at, or close to, the Jurassic-Cretaceous boundary. [ABSTRACT FROM AUTHOR]

Analysis of the distribution of detrital zircon grains is one of the few parameters by which Precambrian palaeogeography may be interpreted. However, the break-up of Pangea and the subsequent dispersal of some of its fragments around the Indian Ocean demonstrate that zircon analysis alone may be misleading, since zircons indicate their original derivation and not their subsequent plate-tectonic pathways. Based on analysis of Precambrian–Ordovician zircon distributions, the presence of microcontinents and separating oceans in the north Gondwanan realm has been rejected in favour of an undivided pre-Variscan continental northwards extension of Africa to include Iberia, Armorica and neighbouring southern European terranes, based on analysis of Precambrian–Ordovician zircon distribution. However, contrasting views, indicating the presence of three peri-Gondwanan oceans with complete Wilson cycles, are reinforced here by a critical reappraisal of the significance of that Variscan area detrital zircon record together with a comparison of the evolution of the present-day Indian Ocean, indicating that Iberia, Armorica and other terranes were each separate from the main Gondwanan craton during the early Palaeozoic Era. [ABSTRACT FROM AUTHOR]

Analysing the provenance changes of synorogenic sediments in the Turpan‐Hami basin by detrital zircon geochronology is an efficient tool to examine the uplift and erosion history of the easternmost Tian Shan. We present detrital zircon U‐Pb analysis from nine samples that were collected within marginal lacustrine Middle‐Late Jurassic and aeolian‐fluvial Early Cretaceous strata in the basin. Middle‐Early Jurassic (159–172 Ma) zircons deriving from the southern Junggar dominated the Middle Jurassic sample from the western Turpan‐Hami basin, whereas Permian‐Carboniferous (270–330 Ma) zircons from the Bogda mountains were dominant in the Late Jurassic to Early Cretaceous samples. Devonian‐Silurian (400–420 Ma) and Triassic (235–259 Ma) zircons from the Jueluotage and Harlik mountains constituted the subordinate age groups in the Late Jurassic and Early Cretaceous samples from the eastern basin respectively. These provenance transitions provide evidence for uplift of the Bogda mountains in the Late Jurassic and the Harlik mountains since the Early Cretaceous. [ABSTRACT FROM AUTHOR]

The temporal duration of lunar‐evolved magmatism is still poorly constrained. In lunar meteorite Northwest Africa (NWA) 10049, a melt inclusion‐bearing zircon fragment provides a new tool to understand the composition and age of the melts from which zircon directly crystallized. The studied zircon‐hosted melt inclusions are silica rich and iron poor (e.g., ~80–90 wt% SiO2; <0.5 wt% FeO), compositionally similar with immiscible silica‐rich melts found in Apollo rocks. Nano‐SIMS U–Pb analyses of the zircon yielded a minimum crystallization age of 4,382 ± 40 Ma, older than the ages for Apollo highly evolved alkali suite lithologies (~3.8–4.33 Ga). Our study shows that the melt inclusion‐bearing zircon in NWA 10049 is the oldest microscale evidence for documenting immiscible silica‐rich melts in lunar samples, suggesting that lunar‐evolved silica‐rich melts were prevalent as early as ~4.38 Ga. This work implies that there would be a prolonged silicic magmatism occurred on the Moon. Plain Language Summary: Lunar‐evolved silica‐rich melt is thought to be related to the formation of highly silicic lithologies (e.g., granitic lithologies). These rock types have been observed in Apollo returned samples as lithic clasts and also have been detected by remote‐sensing data as silicic domes. The Apollo‐evolved lithologies give a wide range of crystallization ages from ~3.8–4.33 Ga. However, there is still unclear about the temporal duration of lunar‐evolved magmatism and volcanism. In lunar meteorite breccia NWA 10049, a melt inclusions‐bearing zircon fragment provides a new tool to understand the composition and age of the melts from which zircon directly crystallized. The studied zircon‐hosted melt inclusions are compositionally similar with immiscible silica‐rich melts found in Apollo rocks. Nano‐SIMS U–Pb analyses of the zircon yielded a minimum crystallization age of ~4.38 Ga. This age is older than the ages for Apollo‐returned granites (up to 4.33 Ga) and ancient basaltic volcanism (i.e., up to ~4.37 Ga), making the studied zircon is the oldest microscale evidence for documenting lunar silicate liquid immiscibility. Key Points: A ~200‐μm‐sized melt inclusion‐bearing zircon fragment was found in lunar feldspathic breccia meteorite NWA 10049Melt inclusions in this zircon are compositionally consistent with lunar immiscible silica‐rich meltsThe zircon is 4.38 Ga and provides microscale evidence for ancient immiscible silica‐rich melt on the Moon [ABSTRACT FROM AUTHOR]

Abstract—Analysis of zircons from Early Paleozoic calc-alkaline granitoids in the central part of the Angara–Vitim Batholith revealed two geochemically different zircon varieties. Central unaltered domains have homogenous BSE images, "magmatic" REE distribution pattern, and the moderate content of trace elements. Altered zones of zircon are characterized by more gentle patterns owing to the growth of LREE and MREE, as well as by the elevated contents of U, Th, Ca, Sr, and Ba. Such compositional peculiarity could be related to the influx of fluid, which caused a metasomatic alteration of granites during their microclinization. Geochemical features of zircons, together with their internal structure, should be taken into account during geochronological study of zircon. [ABSTRACT FROM AUTHOR]

Quantifying the timescales of Archean ultrahigh temperature (UHT) metamorphism is essential for constraining the style of plate tectonics on the early Earth. However, such timescales can be difficult to quantify, due to the antiquity of Archean rocks and the extreme thermal conditions of UHT metamorphism. We constrain the timescales of Archean UHT metamorphic processes recorded by a single rock sample from the Pikwitonei granulite domain (northwestern Superior Province), through the integration of two U–Pb zircon petrochronologic techniques. In this study we combine: (1) high-spatial resolution laser ablation split-stream inductively coupled mass spectrometry (LASS) on in situ zircon (in thin section) and hand-picked zircon; and (2) high-precision isotope dilution thermal ionization mass spectrometry (ID-TIMS) analyses on microsampled fragments from the same hand-picked zircon analysed by LASS. Phase equilibria modelling and Zr-in-rutile thermometry suggest the rock followed a P–T path characterized by decompression at > 960 °C, followed by near-isobaric cooling at ∼0·8 GPa. In situ LASS zircon analyses could be interpreted to record zircon growth at broadly ∼2665 Ma, though the large uncertainties on isotopic dates make potentially distinct growth episodes difficult to distinguish. ID-TIMS U–Pb dates of zircon fragments reveal a polyphase zircon growth history over a 24 Ma duration, from 2673 to 2649 Ma. Zircon trace element compositions, textures, and microstructural relationships, as well as evaluation of zircon-garnet equilibrium, suggest zircon grew during melt crystallization, after UHT decompression and garnet resorption. Variable Ti concentrations within zircon domains indicate: (1) zircon crystallized through the temperature interval of ∼875 °C to ∼730 °C, potentially in isolated rock domains with variable zircon saturation temperature; and/or (2) zircon crystallized over a narrower temperature interval in isolated rock domains with variable a TiO2 and/or a SiO2. Collectively, the data suggest the west-central Pikwitonei granulite domain reached peak UHT conditions prior to 2673 Ma, after which suprasolidus conditions in the lower crust persisted for at least 24 Ma. Such an interpretation would be impossible if based on either the LASS or ID-TIMS zircon data alone, which highlights the utility of applying both techniques in tandem to constrain metamorphic timescales in ancient UHT terranes. [ABSTRACT FROM AUTHOR]

The chemical compositions of magmatic zircon growth zones provide powerful insight into evolving magma compositions due to their ability to record both time and the local chemical environment. In situ U-Pb and Hf isotope analyses of zircon rims from Oligocene--Miocene leucogranites of the Bhutan Himalaya reveal, for the first time, an evolution in melt composition between 32 and 12 Ma. The data indicate a uniform melt source from 32 Ma to 17 Ma, and the progressive addition of an older source component to the melt from at least ca. 17 Ma. Age-corrected εHf ratios decrease from between -10 and -15 down to values as low as -23 by 12 Ma. Complementary whole-rock Nd isotope data corroborate the Hf data, with a progressive decrease in εNd(t) from ca. 18 to 12 Ma. Published zircon and whole-rock Nd data from different lithotectonic units in the Himalaya suggest a chemical distinction between the younger Greater Himalayan Series (GHS) and the older Lesser Himalayan Series (LHS). The time-dependent isotopic evolution shown in the leucogranites demonstrates a progressive increase in melt contribution from older lithologies, suggestive of increasing LHS involvement in Himalayan melting over time. The time-resolved data are consistent with LHS material being progressively accreted to the base of the GHS from ca. 17 Ma, facilitated by deformation along the Main Central thrust. From 17 Ma, decompression, which had triggered anatexis in the GHS since the Paleogene, enabled melting in older sources from the accreted LHS, now forming the lowermost hanging wall of the thrust. [ABSTRACT FROM AUTHOR]

• U-Pb CA-ID-TIMS dates of zircon from plumbing system of a Permian caldera. • Distribution of ages interpreted through a new zircon saturation model. • Relative decrease of zircon mass with time implies monotonic cooling. • Late peak in zircon crystallization indicates episodic increase in heat supply. • Evidence for open-system processes preserved in zircon record of super-eruptions. The emplacement history and thermal evolution of subvolcanic magma reservoirs determine their longevity, size, and ability to feed volcanic eruptions. As zircon saturation is dependent on melt temperature and composition, quantitative analysis of zircon age distributions provides insight into the timing and magnitude of intensive parameter variations during the lifetime of a magma reservoir. Here we present chemical abrasion-isotope dilution-thermal ionization mass spectrometry (CA-ID-TIMS) U-Pb zircon crystallization ages and in-situ zircon trace-element geochemistry for a suite of caldera-related, coeval plutonic and volcanic units of the Permian Sesia Magmatic System (northern Italy). This dataset documents the protracted growth and evolution (∼1 Myr) of a voluminous (>1000 km3), upper crustal (3.5–2.0 kbar) silicic magma reservoir. Systematic changes in zircon composition with time reveal episodic intrusions of new magma into a single, progressively differentiating reservoir which was dominantly kept at high crystallinity conditions (>60 vol.%). The volcanic and plutonic units both show dispersed and heterogeneous CA-ID-TIMS age distributions. A stochastic, thermodynamics-based zircon saturation model accounting for fractional crystallization, recharge and thermal rejuvenation effects on zircon growth and stability in a rhyolitic magma body reproduces the observed distributions of zircon U-Pb ages. Model results suggest that zircon compositional variability and crystallization age heterogeneity, characteristic of the Sesia and other large silicic systems, distinguish open- and closed-system magmatic processes. Specifically, an increase of the mass of crystallized zircons over time is the hallmark of thermally and chemically mature magma reservoirs, capable of producing voluminous eruptions upon changes in the thermal and mechanical state of the system. Conversely, a decrease in crystallized zircon mass over time characterizes systems where crystallization dominates over magma mobility, hindering substantial mass release during eruptive events. We suggest that quantitative analyses of dispersed zircon crystallization age distributions obtained with high-precision techniques can be applied to the plutonic and volcanic record to identify mature silicic magma reservoirs whose properties and storage conditions allowed for catastrophic caldera-forming eruptions. This work provides the petrologic community with a new tool to investigate the genesis and evolution of zircon-bearing intermediate to silicic intrusive magmatism and caldera-forming volcanism through time and across tectonic settings. [ABSTRACT FROM AUTHOR]

The recognition and evaluation of polycyclic processes in sedimentary units are critical for proper provenance analysis and sedimentary system interpretation. The chemical composition and textural maturity of detrital tourmalines and zircons allow identification of sediment source areas, transport, and deposition. This study investigates the origin and history of post-Gondwanan sediments of the Tupanciretã Formation in southern Brazil, which lacks provenance studies. The Tupanciretã Formation is in a similar setting of the Bauru Supersequence at the uppermost portion of the Paraná Basin. Detrital zircon ages indicate sediment provenance from the Transamazonian, Grenvillian, and Brasiliano orogenic cycles of the Rio Grande do Sul Shield and younger grains (280-128 Ma) record contribution from the Choiyoi and Serra Geral igneous events, with a maximum deposition age of 127 Ma. Detrital tourmaline chemical analyses points to the Sul-riograndense Shield as the ultimate source, with metapelitic, metapsamitic and granitic origins. The predominant degrees of roundness are well rounded to rounded suggest evidence of sediment recycling from sedimentary units of the Paraná Basin, with important aeolian reworking involved. Zircon U–Pb signatures are compatible with the eastern sector of the Botucatu Formation in Rio Grande do Sul as the immediate source and the northeastern Sul-riograndense Shield as the ultimate source. Intermediate sources between the Sul-riograndense Shield and the Tupanciretã Formation were Gondwanan sedimentary units of the Paraná Basin, with possible participation from the Camaquã Basin. • The grains indicate important recycling of sediments with multiple sources, With important analysis of detrital zircons. • Detrital tourmalines indicate the participation of multiple basement rocks as the ultimate source. • There was an ancient drainage percolating from SSE to NNW, carrying polycyclic sedimentary rock material. • The high degrees of grain roundness indicate polycyclic sedimentary events, with a maximum deposition age of 127 Ma. [ABSTRACT FROM AUTHOR]

The fluid-fluxed melting of igneous protoliths provides an opportunity to assess the role of fluid for the formation and modification of continental crust during high-temperature metamorphism. In order to investigate such an anatexis in the Buncheon granitic gneiss, Yeongnam Massif, we combined field, microstructural, and geochemical studies with the U-Pb and oxygen isotopic analyses of zircon and monazite. The granitic gneisses comprise metatexitic migmatites containing leucosomes, although neither melanosomes nor peritectic phases are associated with neosomes. These migmatites underwent syn -kinematic wet melting in the presence of ca. 0.9–1.4 wt% H 2 O (estimated from the pseudosection modeling) via the reaction, plagioclase + K-feldspar + quartz + H 2 O = melt, that took place at ∼650–750 °C and 4–6 kbar. The leucosomes differ in the degree of Eu anomalies and have variable amounts of rare earth elements, Zr, Y, and Th. Such variations are attributed to the segregation and migration of melts as well as the entrainment of residual phases. Sensitive high-resolution ion microprobe (SHRIMP) U-Pb ages of zircon and monazite were determined from two granitic gneisses and three leucosomes together with an adjacent, undeformed Hongjesa granite. Zircon grains are oscillatory-zoned, except for homogeneous overgrowth rims rarely present in two leucosomes. Both zircon domains were dated at ca. 1.98–1.97 Ga and ca. 1.86 Ga, respectively, suggesting that igneous protoliths were partly recrystallized during the late Orosirian. Monazites from two gneiss samples contain submicroscopic polycrystalline inclusions of K-feldspar + quartz + apatite, reflecting the presence of former melts, and yielded a pooled 207Pb/206Pb age of 1859 ± 6 Ma (n = 30). In contrast, monazites from a leucosome are inclusion-free, and yielded the youngest age of 1840 ± 16 Ma (n = 6). This result is interpreted to represent the melt crystallization at ca. 1.84 Ga following the ca. 1.86 Ga anatexis. On the other hand, monazite from the Hongjesa granite, yielded a weighted mean 207Pb/206Pb age of 1878 ± 5 Ma (n = 11), most likely reflecting a prograde metamorphic growth. The δ18O values of ca. 1.98–1.97 Ga igneous zircon in granitic gneisses are 7.1–7.2 ‰, but those from the leucosome are reduced at 5.9–6.7 ‰. The latter is largely identical to 5.7–6.7 ‰ estimated from ca. 1.86 Ga domains of zircon in the leucosome and monazite in the granitic gneiss; in contrast, a slightly lower δ18O value of 5.46 ± 0.61 ‰ is recorded in the ca. 1.84 Ga monazite of leucosome. The relatively low δ18O values are most likely accounted for by an influx of fluid that has apparently triggered partial melting in the granitic gneiss, and the fluid itself is possibly linked to the crystallization of mafic magmas in an arc complex. Taken together, in contrast to the majority of zircons preserving the crystallization age of igneous protoliths, monazites are more susceptible to recrystallization during the fluid-present melting and permit us to decode a protracted (∼20 m.yr.) episode from partial melting to melt crystallization in the Yeongnam Massif. Such a longevity of melt-present system typifies the prolonged crustal reworking of Paleoproterozoic Korean arc situated at the eastern margin of the North China Craton. • Partial melting of granitic gneiss occurred due to an influx of external fluids. • The melting occurred at 1.86–1.84 Ga following protolith emplacement at 1.98 Ga. • The interaction with low δ18O fluids in association with the crystallization of mafic magmas. • The protracted melting typifies the crustal reworking of the Paleoproterozoic Korean arc. [ABSTRACT FROM AUTHOR]

The Southernmost Brasília Orogen surrounds the southern margins of the São Francisco Craton. It exposes a structural window with a WNW-ESE direction formed by the Archean-Paleoproterozoic basement reworked by the Campo do Meio Shear Belt. Using metamorphic modeling, geothermobarometry, and U Pb dating of zircon and monazite, this study established the pressure-temperature-time (P-T -t) evolution of the Colônia metapelite, one of the main units of the Campo do Meio Shear Belt. This revealed a clockwise path with metamorphic peak conditions at 706 ± 16 °C and 9.7 ± 0.7 kbar on a staurolite-kyanite-muscovite-garnet-biotite schist, with cooling at ∼600 °C and ∼ 6 kbar. Forward metamorphic modeling based on the whole-rock composition of this sample supports partial melting in the staurolite stability field, facilitated by water influx. Water-fluxed anatexis promoted dissolution of detrital zircon grains. These processes, occurring during prograde metamorphism, are influenced by temperature, crystal size-distribution, bulk-rock composition, and the permanence of the rock at the thermal peak. Analysis of the zircon overgrowth zones, which were linked to peak metamorphic conditions, produced an age of 605 ± 7 Ma. The monazite age of 580 ± 5 Ma was associated with later syntectonic melt crystallization. The clockwise P-T -t path of the Colônia metapelite is similar to the evolution of Neoproterozoic units from the Southernmost Brasília Orogen. However, the degree of dissolution in detrital zircon grains restricts accurate evaluation of the possible stratigraphic correlations proposed in the literature. • Staurolite stability can exceed the solidus curve in the fluid-saturated melt. • Kyanite stabilization can occur after melting into low-Al metapelites. • Water-fluxed melting promotes dissolution-recrystallization in detrital zircon. • Metamorphic ages overlap the ages of likely source areas. • Sedimentary geochronological approach for melting-bearing rocks may be unfeasible. [ABSTRACT FROM AUTHOR]

• Coqen zircon xenocrysts were originated from ancient recycled continental crustal. • Zircons record the temporal evolution of magmatism and crustal thickness in Coqen. • Lhasa terrane evolutionary process is restored by these zircon xenocrysts. The Cenozoic volcanic rocks of Coqen are located in the western central Lhasa subterrane, where knowledge of the regional lithospheric architecture and related magmatic processes is still lacking. To address this issue, we used in situ U–Pb dating, Lu–Hf isotopic and mineral inclusion analysis in zircon xenocrysts among trachyandesite. These zircons from volcanic samples yielded wide U–Pb ages from 18 Ma to 2424 Ma, showing three significant age peaks at ∼ 246 Ma, 193 Ma, and the most intense one at 128 Ma, which represent three major magmatic processes that developed in the area. The earliest zircon dates suggest the age of volcanic eruption in the Coqen area was not earlier than 18 Ma. Zircon xenocrysts trace elements data point to the continental crust origin of central Lhasa subterrane. We provide the evidence for evolutive magmatism of the Lhasa terrane by calculating ΔFMQ, and show that the oxygen fugacity goes from reduced to oxidized (Cambrian to Miocene). The very low ε Hf (t) indicate a long-term magmatic event sequence, with the Zenong Group having the most vigorous magmatic activity. The old U–Pb ages and T DM C confirmed that an ancient basement of the Precambrian exist in the middle Lhasa terrane. Our work also restores the tectonic and crustal thickness evolutionary process of Coqen area even entire Lhasa terrane. In the back of a series of thickening and thinning processes, the Tibetan crust drastically thickened at ∼ 54 Ma, and gradually created what is now believed to be the thickest crust in the world. [ABSTRACT FROM AUTHOR]

Petrographic and geochemical studies combined with U-Pb SHRIMP II analyses of zircons from three granitoid rocks in northwest Argentina reveal new data to enhance the understanding of the margin of western Gondwana. The I-type granite at Pomán ('Granito Pomán'), with a typical continental arc geochemical signature, has been intruded into schists and gneisses of the regional basement during the Lower Cambrian (535 ± 5 Ma; MSDW = 0.024). This supports the existence of a volcanic arc of Lower Cambrian age evolving possibly contemporary to some successions of the Puncoviscana Complex. Two deformed and metamorphosed, granitoid bodies (Chacritas and San Ignacio-Los Pinos granitoids) derived from metamorphic (metasedimentary?) rocks, contain few euhedral Mesoproterozoic zircon crystals, which show no sign of reworking. Most of these euhedral zircons have rims of younger ages (Neoproterozoic to Permian) with Th/U ratios mostly lower than 0.001. Both, the S-type granite from Chacritas and the San Ignacio-Los Pinos granitoid from Balcozna and their protoliths, may represent the previously unidentified local source for the abundant late Mesoproterozoic detrital zircons reported in Neoproterozoic to Paleozoic sedimentary sequences of NW Argentina. This would imply Mesoproterozoic basement, alike the Arequipa Massif (in Peru and Bolivia) and the Western Sierras Pampeanas, in northwest Argentina. [ABSTRACT FROM AUTHOR]

The Salem Mafic–Ultramafic Complex occurs within the northern part of Cauvery Suture Zone (CSZ), Southern Granulite Terrane (SGT), India. The complex occurs as semicircular to elongated linear body with a thick mantle section and comparatively well‐developed crustal section comprising different lithological units, also referred to as the Chalk Hills of Salem. The major rock types in the complex comprise ultramafic cumulates of dunite, peridotite, wherlite, pyroxenite, and hornblendite, mafic and felsic intrusions of gabbros and amphibolites, and quartzo–feldspathic alkaline rocks together with several ultrapotassic dykes. Geochemical studies of amphibolites from this complex indicate tholeiitic parent magma with enrichment of LIL elements (Rb, Ba, Th, and Sr) and are relatively more enriched than N‐MORB as compared with arc‐related rocks. The enrichment of LIL elements over the HFS elements and with distinct Nb, Ta, and Ti depletion relative to other HFS elements suggest the involvement of subduction‐related components in the depleted mantle source and that the magmatism occurred in an oceanic convergent realm. The mineral chemistry of dunite and peridotite shows high content of forsterite (86.9–92.2) in olivine and high Cr# value (80.85–98.73) for spinel. The tectonic discrimination plots of spinel and olivine mineral chemistry together with clinopyroxene chemistry of amphibolites reveal arc signature typical of Alaskan type of complex. The U–Pb zircon analysis of quartz monzonite intrusion within the hornblendite from the complex yielded a weighted mean age of 819 ± 2.4 Ma, suggesting that the complex formed during the Neoproterozoic and can be correlated to the Alaskan‐type complexes described from the Arabian–Nubian Shield. [ABSTRACT FROM AUTHOR]

In order to understand the sedimentary age and geotectonic environment characteristics of the Ruyang Group in geological history, this study, with the LA-ICP-MS method, focuses on the study of U-Pb isotope geochronology and geotectonic environment analysis of detrital zircons in the bottom of Xiaogoubei Formation of Ruyang Group in Daimeishan of Henan. Results show that the ages of detrital zircons of Xiaogoubei Formation range from 1720 Ma to 2727 Ma, the youngest detrital zircon age near the harmonic line is 1720 ±65 Ma, the main peak age is 2547 Ma, and the second peak ages include 2178 Ma and 1832 Ma. Therefore, we consider that the lower age limit of Xiaogoubei Formation is ~1720 Ma; the sediment sources of Xiaogoubei Formation mainly come from the geological bodies of the interior of the North China craton in the late Neoarchean, early Paleoproterozoic, middle Paleoproterozoic, late Paleoproterozoic and early Neoproterozoic. At the same time, the detrital zircon age of samples has a good response relationship with the Precambrian geological events in North China Craton, which reveals the then construction environment. [ABSTRACT FROM AUTHOR]

Laser ablation inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U–Pb geochronology of shocked zircon grains in a vesicular‐fluidal impact melt rock from the ≥54 km Charlevoix impact structure, Québec, Canada, suggests an Ordovician to Silurian age of 450 ± 20 Ma for the impact. This age is anchored by concordant U–Pb results of ~450 Ma for a U‐rich, cryptocrystalline zircon grain in the melt rock, interpreted as a recrystallized metamict zircon crystal; the U–Th–Pb system of the metamict grain was seemingly chronometrically reset by the Charlevoix impact, but withstood later tectonometamorphic events. The new zircon age for Charlevoix is in agreement with a stratigraphically constrained Late Ordovician maximum age of ~453 Ma and corroborates earlier suggestions that the impact occurred most likely in the Ordovician, and not ~100 Myr later, as indicated by previous K/Ar and 40Ar/39Ar geochronologic results. The latter may reflect postimpact thermal overprint of impactites during the Salinian (Late Silurian to Early Devonian) and/or Acadian (Late Devonian) orogenies. U–Pb geochronology of zircon crystals in anorthosite exposed in the central uplift of the impact structure yielded a Grenvillian crystallization age of 1062 ± 11 Ma. The preferred Ordovician age for the Charlevoix impact structure, which is partially overthrusted by the Appalachian front, suggests the impact occurred during a phase of Taconian tectonism and an episode of enhanced asteroid bombardment of the Earth. Our results, moreover, demonstrate that (recrystallized) metamict zircon grains may be of particular interest in impact geochronology. [ABSTRACT FROM AUTHOR]