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Abstract Supercritical heat transfer mechanisms and heat transfer correlations are firstly reviewed in present paper. The heat transfer characteristics of S-CO 2 in circumferentially non-uniform heated vertical upward flow are then numerically studied and the fundamental mechanisms are discussed. The abnormal heat transfer for S-CO 2 is believed to be caused by the comprehensive effect of thermophysical property variations. For S-CO 2 with non-uniform heating and large mass flow rate, the enhanced heat transfer is mainly related to the large specific heat in the near wall region while the deteriorated heat transfer is dominated by the thickening viscous sublayer induced by the viscosity increase. Besides, the buoyancy effect induced by the density variation is still prominent to axial velocity distribution even in the forced convection. Finally a new correlation with higher accuracy is developed for S-CO 2 circumferentially average heat transfer by introducing the correction parameters of viscosity, specific heat, axial flow-acceleration and non-uniform heat flux. Highlights • Supercritical heat transfer mechanisms and correlations are comprehensively reviewed. • Heat transfer of S-CO 2 under non-uniform heating is numerically studied. • The relation between thermophysical property variation and abnormal heat transfer is examined. • An average heat transfer correlation for S-CO 2 under non-uniform heating is proposed and evaluated. [ABSTRACT FROM AUTHOR]

• Recent advances in supercritical carbon dioxide power system are summarized. • The general and unique problems in coupling of supercritical carbon dioxide power cycle and different heat sources are identified. • The multiscale features of supercritical carbon dioxide power system are demonstrated. • Applications of supercritical carbon dioxide power system in nuclear, solar energy and fossil fuel are discussed. • An outlook on technical challenges is presented to promote industrial applications. Under the background of carbon reduction, the development of efficient power conversion system has drawn more important attention. The advantages of high efficiency and compactness have triggered increasing industrial interests in the applications of supercritical carbon dioxide power system for broad heat sources. However, when the supercritical carbon dioxide power cycle is coupled with different heat sources, there exist both general problems mainly associated with the supercritical carbon dioxide cycles and unique problems due to the heating processes of supercritical carbon dioxide. Moreover, the multiscale features of the supercritical carbon dioxide power system lead to significant challenges to theoretical analysis and engineering design. This review work provides the recent advances of supercritical carbon dioxide power systems, especially for the applications in heat sources of nuclear, solar and fossil fuel. With a focus on the category of general problems and unique problems, the current studies concerning the coupling of supercritical carbon dioxide power cycle with a specific heat source are further divided into three scales of system, component and process. The designs of the reactor core in nuclear, the receiver in concentrated solar power plant and the boiler in coal-fired power plant are discussed in detail at the scales of system, component and process. Future research directions for supercritical carbon dioxide power system are identified at different scales and more accurate integrated modelling for the coupling of supercritical carbon dioxide power cycle with specific heat sources are encouraged. The present work will benefit the in-depth understanding and further promotion of supercritical carbon dioxide power systems in industrial applications. [ABSTRACT FROM AUTHOR]

Printed circuit heat exchangers (PCHEs) are widely used as recuperators in the supercritical carbon dioxide (S-CO2) Brayton cycle design. The variation of heat sources will have a great impact on the heat transfer effect of the recuperator. It is of interest to study the fast calculation of flow and heat transfer performance of PCHEs under different operating conditions to obtain the optimal comprehensive performance and provide guidance for the operation control strategy analysis. Herein, a fast calculation method is established through a one-dimensional model of a PCHE based on Modelica. The effects of working medium mass flow rate and inlet temperature on the flow and heat transfer process are analyzed from the three aspects of heat transfer rate, flow pressure drop, and comprehensive performance, and the mass flow rate matching optimization is realized. The results show that increased mass flow rate increases heat transfer rate and flow pressure drop. The efficiency evaluation coefficient (EEC) has a maximum value at which the mass flow rate values of the cold and hot channels are best matched, and the comprehensive performance is optimal. When the mass flow rate of the heat channel is 4.8 g/s, the maximum EEC is 1.42, corresponding to the mass flow rate of the cold channel, 4.2 g/s. Compared with the design condition, the heat transfer rate increases by 62.1%, and the total pump power increases by 14.2%. When the cold channel inlet temperature increases, EEC decreases rapidly, whereas EEC increases when the hot channel inlet temperature increases. The conclusions can provide theoretical support for the design and operation of PCHEs. [ABSTRACT FROM AUTHOR]

The Supercritical carbon dioxide (S–CO 2) Brayton cycle is considered as a promising alternative to traditional steam Rankine cycle due to its high efficiency and compactness. However, in coal-fired power system, the S–CO 2 temperature at cooling wall entrance is newly recognized quite high, leading to an over-temperature crisis. A coupled model of combustion and S–CO 2 heat transfer was established to predict cooling wall temperature of a 1000 MW S–CO 2 Brayton coal-fired boiler. Based on the module arrangement in S–CO 2 boiler, the "cold S–CO 2 -hot fire matching and cascaded temperature control" principle in 1D model was proposed to reduce the cooling wall temperature. Three methods were examined including the low-temperature fluid matching high heat flux burner region, the counterflow, and more cold fluid in circulation drained to match high heat flux zone. The results show that the optimal arrangement can significantly reduce the temperature in overheated region 12–44 °C and eliminate the local hot spot. In addition, the 3D model was developed to obtain the maximum wall temperature and the uneven temperature in the circumferential direction. The employment of spiral cooling wall could alleviate circumferential unevenness and reduce wall temperature. The present work can provide important guidance to design of S–CO 2 Brayton coal-fired power system. • A coupled model of combustion and S–CO 2 heat transfer was established to predict cooling wall temperature. • The "cold S–CO 2 -hot fire matching and cascaded temperature control" principle in 1D model was proposed. • The uneven temperature distribution in circumferential direction of cooling wall in 3D model was calculated. • The spiral tubes of cooling wall could effectively relieve uneven problem and reduce wall temperature. [ABSTRACT FROM AUTHOR]

• The seriousness of the HTD problems in large-diameter tubes is highlighted experimentally. • SST k-ω model for S-CO 2 heat transfer prediction is experimentally validated within ±15% error range. • HTD mechanism is revealed by comprehensive comparisons between simulations and experiments. • Pseudo-nucleate boiling concept is proposed to further develop the pseudo-boiling theory for S-CO 2. • Conical strips insert can prevent HTD problems and achieve high PEC of 1.21-1.35. Heat transfer deterioration (HTD) problems can undermine the thermal safety of heating tubes for supercritical carbon dioxide (S-CO 2) flows. Relevant experimental evidence is highly desired, but most cases were investigated for small tube diameters (below 10 mm) and under limited operation parameters, far from the industry-scale applications. In the present work, large tubes (24 mm) are investigated experimentally with pressures of 7.5–15 MPa, mass flow rates of 100–1200 kg·m−2·s−1 and heat fluxes of 30–350 kW·m−2. The seriousness of HTD in large tubes was experimentally confirmed, and the mechanism is explored via a carefully-designed comprehensive comparison between present numerical simulations and experimental tests. Detailed analysis of vapor-like film development inspires us to mitigate the problem using structured-inner-surface, from the viewpoint of "supercritical pseudo-boiling". This inspiration is further evaluated numerically: five types of enhancement structures are proposed to interfere with the development of vapor-like film. It was found that the proposed methods can fully prevent HTD problems, and especially the conical strips can achieve a high heat transfer performance (with performance evaluation criteria PEC of 1.21–1.35) and are thus recommended for HTD prevention in vertical large-diameter tubes under near-critical conditions. Overall, the experimental tests and numerical explorations can deliver more evidence on the theory and applications of supercritical fluid flow and heat transfer. [ABSTRACT FROM AUTHOR]

• Integration and conversion of supercritical carbon dioxide coal-fired power cycle and high efficiency energy storage cycle are discussed. • A three-step strategy is proposed and various cycles are presented and assessed. • First step: the tri-compression coal-fired integrated energy storage cycle has a high efficiency. • Second step: the integrated energy storage cycle with various heat sources needs to consider the trade-off of performance criteria. • Third step: the high efficiency split expansion adiabatic energy storage cycle is proposed. The emission peak/carbon neutrality calls for significantly improved coal-fired power plants. Sustainability of the power plants is critical to meeting the net zero targets in 2050/2060. In this context, it is necessary to investigate the integration and conversion of the supercritical carbon dioxide coal-fired power cycle and the supercritical carbon dioxide energy storage cycle. In this work, the thermodynamic model and performance criteria are firstly presented. After comparison of the two cycles, a three-step strategy for the development of the power cycle is proposed and assessed. First step: when coal still plays an important role as a main energy resource, the integrated tri-compression coal-fired supercritical compressed carbon dioxide energy storage cycle has the highest round-trip efficiency of 56.37%. Second step: with the challenge in utilization of coal energy, a trade-off among the performance criteria must be struck in the integrated cycle with various heat sources. Third step: the adiabatic supercritical compressed carbon dioxide energy storage cycle is proposed, and a high round-trip efficiency of 72.34% is achieved in the split expansion cycle. The present research provides not only a new prospect of the conventional power plants but also design guidance for the supercritical carbon dioxide energy storage cycle. [ABSTRACT FROM AUTHOR]

Supercritical carbon dioxide (S–CO 2) coal-fired power systems have been widely investigated due to its high efficiency and compactness. These power systems can range between 50 and 1000 MW and thus the corresponding boilers actually operate under dramatically different conditions. It is necessary to investigate the inherent relationship among different capacity S–CO 2 boilers, which not only bring new theoretical understandings but also help improve practical designs. In this work, a unified model is proposed to investigate both thermal-hydraulic and thermodynamic performance. Furthermore, it is applied to evaluate the relationship between power capacity and boiler configuration. It is shown that small capacity furnaces suffer from overheating in the furnace wall and the optimized cooling wall is suggested to tackle this issue. Moreover, it is found that high pressure drop in the cooling wall of large capacity furnaces results in significant penalty on the cycle efficiency. For the popular 1000 MW boiler, an optimized configuration is suggested by moving the second reheating into the horizontal flue of boiler, achieving a lower pressure drop and an improved cycle efficiency from 35.4% to 50.09%. Finally, three recommendations for the capacity-dependent configurations are presented. • A unified model for different capacity S–CO2 coal-fired boilers is established. • Overheating of cooling wall in boilers of small capacity is illustrated and an optimization is proposed. • Pressure drop penalty worsens in cooling wall of large capacity furnaces and results in a cycle efficiency reduction. • Three recommendations for the capacity-dependent configurations are demonstrated. [ABSTRACT FROM AUTHOR]

In this work, the heat transfer characteristics of supercritical pressure CO2 in vertical heating tube with 10 mm inner diameter under high mass flux were investigated by using an SST k-ω turbulent model. The influences of inlet temperature, heat flux, mass flux, buoyancy and flow acceleration on the heat transfer of supercritical pressure CO2 were discussed. Our results show that the buoyancy and flow acceleration effect based on single phase fluid assumption fail to explain the current simulation results. Here, supercritical pseudo-boiling theory is introduced to deal with heat transfer of scCO2. scCO2 is treated to have a heterogeneous structure consisting of vapor-like fluid and liquid-like fluid. A physical model of scCO2 heat transfer in vertical heating tube was established containing a gas-like layer near the wall and a liquid-like fluid layer. Detailed distribution of thermophysical properties and turbulence in radial direction show that scCO2 heat transfer is greatly affected by the thickness of gas-like film, thermal properties of gas-like film and turbulent kinetic energy in the near-wall region. Buoyancy parameters Bu < 10−5, Bu* < 5.6 × 10−7 and flow acceleration parameter Kv < 3 × 10−6 in this paper, which indicate that buoyancy effect and flow acceleration effect has no influence on heat transfer of scCO2 under high mass fluxes. This work successfully explains the heat transfer mechanism of supercritical fluid under high mass flux. [ABSTRACT FROM AUTHOR]

The S–CO 2 Brayton cycle has been considered as a promising alternative in coal-fired power plants due to its high efficiency and high compactness. However, the high inlet temperature and low heat transfer coefficient of S–CO 2 in the cooling wall tubes arranged in the furnace could lead to thermal fragile in practical operation. In present study, thermal-hydraulic-structural evaluation on S–CO 2 cooling wall tubes is investigated. Firstly, it is found that the stress distribution is mainly dominated by the circumferential temperature gradient. Secondly, a new criterion, the thermal deviation factor (TDF), is proposed to evaluate the tube thermal stress. It indicates the plastic deformation if exceeding the critical value of TDF = 1, which is more efficient than conventional structural analysis. Thirdly, based on the TDF , two typical methods of inserting twisted tapes and unilaterally arranging dimples inside the tube are proposed to reduce the thermal stress. A novel configuration of elliptic dimple with rounded corners is finally proposed to reduce the local stress concentration efficiently. The results show that the elliptic dimples have the highest comprehensive performance, which is recommended as the heat transfer enhancement structures in S–CO 2 cooling wall tubes. • Thermal-hydraulic-structural performance of S–CO 2 cooling wall tube is investigated. • A new thermal deviation factor (TDF) is proposed to evaluate thermal stress. • Twisted tapes and unilaterally arranged dimples are used to reduce thermal stress. • A novel elliptic dimple can release local stress concentration and improve comprehensive performance. [ABSTRACT FROM AUTHOR]