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Coal seam water injection is one of the important technical means to prevent mine disasters. It can effectively change the mechanical properties of coal, prevent dust, coal and gas outburst, and reduce gas concentration. In order to expand the range of coal seam water injection, make coal seam water injection more effective in wetting coal mass, and determine the effective type of ionic surfactant required for coal seam water injection, triaxial seepage experiments and spontaneous imbibition experiments are conducted on the long flame coal samples from Houwenjialiang Coal Mine in Ordos City, Inner Mongolia Autonomous Region, China in this paper. Moreover, the effects and mechanisms of different ionic surfactants on the seepage and wetting stages of coal seam water injection are studied, which provides a theoretical basis for on-site coal seam water injection. After analysis and discussion, it is found that the influence of cationic surfactants on the seepage stage of coal seam water injection first decreases and then increases while the influence of anionic surfactants on the seepage stage of coal seam water injection shows a gradually increasing trend. Furthermore, both cationic and anionic surfactants show more significant wetting effects as the concentration of the surfactants increases. In addition, the adsorption of cations to coal molecules is stronger than that of anions, and the water solubility of cations is better than that of anions. [ABSTRACT FROM AUTHOR]