10,381 results on '"VISCOELASTICITY"'
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2. Molecular Machines: A Materials Science Approach
- Author
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Zocchi, Giovanni, author and Zocchi, Giovanni
- Published
- 2018
- Full Text
- View/download PDF
3. A tracer microrheology for determination of viscoelasticity of dilute ovalbumin colloids
- Author
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YilmazMustafa Tahsin, TaylanOsman, DemirciMehmet, ElobeidTahra, BakhshAhmed, OzmenDuygu, MeralRaciye, and AvciEsra
- Subjects
Microrheology ,Materials science ,Digital storage ,Optical ,Viscoelasticity ,chemistry.chemical_compound ,Colloid ,Rheology ,TRACER ,Viscoelastic properties ,Dynamic light-scattering ,?r ,General Materials Science ,biology ,Polymer science ,thermal properties ,Laplace transforms ,Dynamic-light scatterings ,Light scattering ,Molecular properties ,Condensed Matter Physics ,Ovalbumins ,Ovalbumin ,chemistry ,Sols ,biology.protein ,rheology ,Melamine ,Micro particles - Abstract
This study seems to be the first effort to determine the viscoelastic properties of dilute ovalbumin colloids using dynamic-light-scattering-based optical microrheology using carboxylated melamine microparticles as the tracer probe. A generalized form of the Stokes-Einstein equation constructed based on Laplace transformation of the mean square displacement, ??r 2(t)?, was employed to compute the viscoelastic moduli (storage modulus, G?, and loss modulus, G?). ??r 2(t)? was determined to increase with time by reaching a maximum plateau at a time between 10-3 and 10-1 s with no further increase, revealing the elastic nature of dilute ovalbumin colloids within the given time. On the other hand, ovalbumin colloids exhibited different viscoelastic properties at two different frequency ranges. The measurements and interpretation of data revealed that the technique used seems to ensure a fast and effective method for measuring the viscoelastic properties of ovalbumin colloids at very low concentration levels. © 2021 ICE Publishing: All rights reserved. King Abdulaziz University, KAU: 135-197-D1439; Deanship of Scientific Research, King Saud University This work was funded by the Deanship of Scientific Research (DSR), King Abdulaziz University, Jeddah, under grant number 135-197-D1439. The authors, therefore, gratefully acknowledge the DSR technical and financial support.
- Published
- 2022
4. Frequency characteristics of viscoelastic damper models and evaluation of a damper influence on induced oscillations of mechanical system elements
- Author
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Yury S. Legovich, Yury Maximov, and Dmitry Maximov
- Subjects
Frequency response ,Materials science ,business.industry ,Differential equation ,Mechanical Engineering ,Structural engineering ,Dynamic mechanical analysis ,Condensed Matter Physics ,Viscoelasticity ,Damper ,Mechanics of Materials ,Kelvin–Voigt material ,Dynamic modulus ,business ,Elastic modulus - Abstract
A generalized model of the damper is proposed in the form of the equivalent Voigt model for viscoelastic materials, which fully correlates with the differential equation for induced oscillations in the system with a damper. The relations of parameters of the differential equation and parameters of the equivalent Voigt model with parameters of various models for viscoelastic materials and with components of the complex elastic modulus of these models are established. An approach for the assessment of the damper influence on the oscillation level of various elements in the analyzed system that occur under the impact of a coercive force of different frequencies is proposed for the mechanical system. It is presented in the form of the model with lumped parameters. Parameters of viscoelastic materials, which are suitable for use in dampers in the designed mechanical system, are determined based on obtained estimations. Thus, the proposed approach to the analysis of the behaviour of viscoelastic dampers allows us to determine the requirements for viscoelastic materials suitable for use in the designed systems. Also, it allows us to determine frequency response characteristics of dampers with known frequency dependences of storage modulus and loss modulus of the used viscoelastic materials.
- Published
- 2021
5. Towards a universal shear correction factor in filament stretching rheometry
- Author
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Ruth Cardinaels, F. P. A. van Berlo, Gerrit W. M. Peters, Patrick D. Anderson, Group Anderson, Processing and Performance, ICMS Affiliated, and ICMS Core
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Materials science ,Shear correction factor ,Computer simulation ,Rheometry ,Rheometer ,Viscoelasticity ,Mechanics ,Numerical simulation ,Condensed Matter Physics ,Finite element method ,Extensional viscosity ,Shear (sheet metal) ,Physics::Fluid Dynamics ,Condensed Matter::Soft Condensed Matter ,Rheology ,Filament stretching rheometer ,General Materials Science - Abstract
Filament stretching rheometry is a prominent experimental method to determine rheological properties in extensional flow whereby the separating plates determine the extension rate. In literature, several correction factors that can compensate for the errors introduced by the shear contribution near the plates have been introduced and validated in the linear viscoelastic regime. In this work, a systematic analysis is conducted to determine if a material-independent correction factor can be found for non-linear viscoelastic polymers. To this end, a finite element model is presented to describe the flow and resulting stresses in the filament stretching rheometer. The model incorporates non-linear viscoelasticity and a radius-based controller for the plate speed is added to mimic the typical extensional flow in filament stretching rheometry. The model is validated by comparing force simulations with analytical solutions. The effects of the end-plates on the extensional flow and resulting force measurements are investigated, and a modification of the shear correction factor is proposed for the non-linear viscoelastic flow regime. This shows good agreement with simulations performed at multiple initial aspect ratios and strain rates and is shown to be valid for a range of polymers with non-linear rheological behaviour.
- Published
- 2021
6. Synergistic ionic interactions in EMAA ionomer blends: A rheological and mechanical property investigation
- Author
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Savvas G. Hatzikiriakos, Benjamin M. Yavitt, and Marina Najm
- Subjects
chemistry.chemical_classification ,Materials science ,Mechanical Engineering ,Ionic bonding ,Dynamic mechanical analysis ,Condensed Matter Physics ,Viscoelasticity ,chemistry.chemical_compound ,Reptation ,chemistry ,Chemical engineering ,Methacrylic acid ,Rheology ,Mechanics of Materials ,General Materials Science ,Counterion ,Ionomer - Abstract
The rheological and mechanical (tensile) properties of ethylene methacrylic acid (EMAA) ionomers neutralized by Na, Li, and Zn are investigated in binary combinations of two pure ionomers with different counterions. Molecular weight, methacrylic acid content, degree of neutralization, and ion type are tested as experimental parameters to investigate the composition that leads to the largest enhancement in rheological and mechanical properties. Binary cation blend components with low molecular weight and high neutralization reveal enhancement in rheological and mechanical properties beyond a linear mixing combination of material properties such as zero-shear viscosity, relaxation time, and Young’s modulus. The sticky reptation model is applied to EMAA ionomer blends of binary counterions to calculate the timescales of chain dynamics delayed by ionic associations. The ionic clusters of binary cations have longer-lasting ionic associations forming a reinforced reversible crosslink network. The experimental analysis consists of linear and nonlinear viscoelastic experiments, uniaxial extension, and dynamic mechanical analysis, which reveal the conditions and extent of synergism seen in binary EMAA ionomer blends.
- Published
- 2021
7. Modeling vorticity stretching of viscoelastic droplets during shearing flow
- Author
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T. B. Bini and Abdulwahab S. Almusallam
- Subjects
Shearing (physics) ,Materials science ,Velocity gradient ,Mechanical Engineering ,Mechanics ,Deformation (meteorology) ,Vorticity ,Condensed Matter Physics ,Capillary number ,Viscoelasticity ,Physics::Fluid Dynamics ,Viscosity ,Mechanics of Materials ,Newtonian fluid ,General Materials Science - Abstract
In the present work, we focus on the large deformation of a viscoelastic droplet suspended in a Newtonian matrix. We use the constrained volume model as a basic theoretical framework for the description of droplet shape evolution, and we account for the viscoelasticity of the droplet phase using the single-mode Giesekus model. The velocity gradient term describing flow inside the droplet is modified by the viscoelastic stresses, and the resulting model—we herein call the non-Newtonian constrained volume model—is calibrated by matching its predictions to those of the model of Yu et al. [J. Rheol. 48, 417–438 (2004)] at small deformation and slow flow conditions. The non-Newtonian constrained volume model is then examined under conditions of large deformation and/or fast flow, and its predictions are compared against experimental results. The new model shows the growth of the droplet's width in the vorticity direction at conditions of large capillary number, moderate-to-large viscosity ratio, and small elastocapillary number.
- Published
- 2021
8. The yielding of defect-entangled dispersions in a nematic solvent
- Author
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N. Katyan, Tiffany Wood, and Andrew B. Schofield
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Materials science ,Condensed matter physics ,Mechanical Engineering ,Homeotropic alignment ,Disclination ,Condensed Matter Physics ,Thermotropic crystal ,Viscoelasticity ,Rheology ,Mechanics of Materials ,Liquid crystal ,Phase (matter) ,General Materials Science ,Complex fluid - Abstract
Oscillatory rheology, at both small (SAOS) and large (LAOS) amplitude, was performed to measure the dynamic response of a soft-solid, formed on dispersing colloids into a thermotropic nematic liquid crystal at volume fractions φ >18%. Due to weak homeotropic anchoring of nematogens at colloid surfaces, a Saturn-ring defect-line, known as a ‘disclination’, encircles each particle and entangles with neighbouring Saturn-ring disclinations[1]. We present the first experimental investigation of the yielding behaviourof the resulting gel to reveal the underpinning physics. Results reveal the frequency response of the composite is independent of the volume fraction φ; an indication that the dispersed phase simply increases the density of disclinations spanning the composite without further effect. Beyond the linear viscoelastic regime (LVR), LAOS experiments indicate the composite is an elastoplastic fluid exhibiting both strain-hardening and shear-thinning behaviour, with Chebyshev coefficients e3>0 and ν31, generating a strain-hardening response since the Frank elasticity resists reorientation of molecular alignment within confined nematic domains. Above a critical frequency ωc the loss modulus G′′ increases slowly due to enhanced viscosity within confined nematic domains, G′′∝ω ½ [2]. Observation of this behaviour in a small-molecule nematic solvent provides insights into the physics of flow behaviour in other, more complex, defect-mediated liquid crystalline structures exhibiting similar properties [3–5].
- Published
- 2021
9. Transient and steady shear rheology of particle-laden viscoelastic suspensions
- Author
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Anika Jain and Eric S. G. Shaqfeh
- Subjects
Materials science ,Steady state ,Mechanical Engineering ,Constant Viscosity Elastic (Boger) Fluids ,Mechanics ,Condensed Matter Physics ,Viscoelasticity ,Physics::Fluid Dynamics ,Shear (sheet metal) ,Viscosity ,Rheology ,Mechanics of Materials ,Volume fraction ,Particle ,General Materials Science - Abstract
We study the transient and steady shear rheology of rigid particle suspensions in Boger fluids via complete 3D numerical simulations and experiments. We calculate the transient per-particle extra viscosity and primary stress coefficients for suspensions at different particle volume fractions ϕ for a range of Weissenberg numbers (Wi). The per-particle viscosity ( ηp) and the primary normal coefficient ( ψ1p) increase monotonically to steady state in body-fitted (BF) simulations (for dilute suspensions) and immersed boundary (IB) simulations (for nondilute suspensions). We also present experimental measurements including small amplitude oscillatory shear, steady shear, and transient shear measurements at different particle volume fraction suspensions in a Boger fluid. The simulations and experiments suggest that longer strains are needed to achieve steady state at higher ϕ and Wi. We also show the comparison of the BF and the IB simulations with experimental data for the per-particle viscosity and find excellent quantitative agreement between simulations and experiments at Wi=3 but the IB simulations underpredict the steady values at higher Wi=6. Nevertheless, the IB simulations show an increase in the per-particle viscosity with ϕ as witnessed in the experiments. To understand this behavior, we examine the particle-induced fluid stress (PIFS) and the stresslet contributions using a novel method developed for the IB simulations in this work. We find that the PIFS is independent of ϕ but the stresslet values increase with ϕ. Thus, the particle-particle hydrodynamic interactions in nondilute suspensions affect the stresslet and, in turn, the per-particle viscosity at a given Wi.
- Published
- 2021
10. Onset of transient shear banding in viscoelastic shear start-up flows: Implications from linearized dynamics
- Author
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Shweta Sharma, Yogesh M. Joshi, and Viswanathan Shankar
- Subjects
Physics ,Mechanical Engineering ,Fluid Dynamics (physics.flu-dyn) ,FOS: Physical sciences ,Physics - Fluid Dynamics ,Mechanics ,Condensed Matter - Soft Condensed Matter ,Condensed Matter Physics ,Viscoelasticity ,Condensed Matter::Soft Condensed Matter ,Physics::Fluid Dynamics ,Shear (sheet metal) ,Stress (mechanics) ,Viscosity ,Mechanics of Materials ,Shear stress ,Soft Condensed Matter (cond-mat.soft) ,General Materials Science ,Transient (oscillation) ,Shear flow ,Linear stability - Abstract
We analyze transient dynamics during shear start-up in viscoelastic flows between two parallel plates, with a specific focus on the signatures for the onset of transient shear banding using the Johnson-Segalman, non-stretching Rolie-Poly and Giesekus models. We explore the dynamics of shear start-up in monotonic regions of the constitutive curves using two different methodologies: (i) the oft-used `frozen-time' linear stability (eigenvalue) analysis, wherein we examine whether infinitesimal perturbations imposed on instantaneous stress components (treated as quasi steady states) exhibit exponential growth, and (ii) the more mathematically rigorous fundamental-matrix approach that characterizes the transient growth via a numerical solution of the time-dependent linearized governing equations, wherein the linearized perturbations co-evolve with the start-up shear flow. Our results reinforce the hitherto understated point that there is no universal connection between the overshoot and subsequent decay of shear stress in the base state and the unstable eigenvalues obtained from the frozen-time stability analysis. It may therefore be difficult to subsume the occurrence of transient shear banding during shear start-up within the ambit of a single model-independent criterion. Our work also suggests that the strong transients during shear start-up seen in earlier work could well be a consequence of consideration of the limit of small solvent viscosity in the absence of otherwise negligible terms such as fluid inertia., 46 pages, 13 figures
- Published
- 2021
11. On energy absorption of the light-weight curved composite panel used in vehicle's roof
- Author
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Mohammad Amin Oyarhossein, Ping Yang, Zhaoli Lin, and Aghil Shavalipour
- Subjects
Materials science ,Mechanical Engineering ,General Mathematics ,Composite number ,Aerospace Engineering ,Micromechanics ,Ocean Engineering ,Condensed Matter Physics ,Viscoelasticity ,Mechanics of Materials ,Energy absorption ,Automotive Engineering ,In vehicle ,Composite material ,Roof ,Sandwich-structured composite ,Civil and Structural Engineering - Abstract
In this study, the dynamic stability and energy absorption of a novel type of sandwich panels with an extensive application in light vehicles are investigated. The curved panels are laminated multi...
- Published
- 2021
12. Heat and mass transfer effects on MHD mixed convection flow of viscoelastic fluid with constant viscosity and thermal conductivity
- Author
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Kankanala Sharada
- Subjects
Fluid Flow and Transfer Processes ,Boundary layer ,Viscosity ,Materials science ,Thermal conductivity ,Combined forced and natural convection ,Mass transfer ,Mechanics ,Condensed Matter Physics ,Constant (mathematics) ,Non-Newtonian fluid ,Viscoelasticity - Published
- 2021
13. Time-temperature superposition of flexural creep response of carbon fiber PEKK composites manufactured using different prepreg stacking sequence
- Author
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Tayyab Khan, Rehan Umer, Irfan, RA Alia, and Wesley J. Cantwell
- Subjects
Materials science ,Creep ,Flexural strength ,Time–temperature superposition ,Ceramics and Composites ,Stacking ,Composite material ,Condensed Matter Physics ,Viscoelasticity - Abstract
In this work, the long-term creep response of high-performance carbon fiber PEKK (CF/PEKK) composites was evaluated by performing extrapolated short-term flexural creep tests at various temperatures. The time-temperature superposition principle (TTSP) with vertical as well as horizontal shifting was used to generate master curves at reference temperatures of 120°C. Satin weave-based CF/PEKK prepregs were used to manufacture eight-layer composites via compression molding, with three different stacking sequences: (a) zero-direction [0]8 (b) cross-ply [0, 90]4 and (c) quasi-isotropic [90, −45, 45, 0]2 s. The flexural properties under three-point bending arrangement in a universal testing machine were also evaluated. A dynamic mechanical thermal analyzer (DMTA) in three-point bending mode was used to evaluate the temperature-dependent viscoelastic properties of the three types of composites. The creep and creep-recovery behavior was evaluated at 40°C, 80°C, 120°C, 160°C and 200°C. To construct a master curve, extrapolated short-term isothermal creep tests were performed from 120°C to 180°C at the intervals of 10°C. The predicted master curve represents the creep behavior of composites over more than 10 years. It was shown that the quasi-isotropic CF/PEKK composites exhibited 27% and 12% higher creep resistance at 120°C as compared to zero-direction and cross-ply laminates, respectively. Higher flexural modulus (23%) and flexural strengths (33%) were also exhibited by the quasi-isotropic CF/PEKK composites. The final thickness of quasi-isotropic laminates was 8% lower than the 0o laminates. After analyzing the cross-sections of the composites, it was proposed that the superior mechanical properties of the quasi-isotropic laminates could be due to enhanced nesting between neighboring prepreg layers during the compression molding process, which resulted in closer packing of the fibers. It has been shown that the prepreg stacking sequence could affect the creep behavior and flexural properties of the compression-molded CF/PEKK composites.
- Published
- 2021
14. Volumetric evolution of elastic turbulence in porous media
- Author
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Daniel W. Carlson, Kazumi Toda-Peters, Amy Q. Shen, and Simon J. Haward
- Subjects
porous media ,Mechanics of Materials ,microscale transport ,Mechanical Engineering ,Applied Mathematics ,Condensed Matter Physics ,viscoelasticity - Abstract
Viscoelastic flow instability, which is compelled by elastic effects rather than inertia, can be driven to a chaotic state termed elastic turbulence (ET) manifested as strong velocity fluctuations with an algebraic decay in the frequency spectrum and increased mixing. We report the first spatiotemporally complete description of ET by considering a broad volume within a novel three-dimensional ordered porous medium, reconstructing flow at a micrometre characteristic length scale ( $\text {Reynolds numbers} \ll 1$ ) via time-resolved microtomographic particle image velocimetry. Beyond a critical Weissenberg number of 2, we observe an elastic flow instability accompanied by an enhanced pressure drop with spectral characteristics typical of ET. Polymer chains in the ET flow state are advected along increasingly curved streamlines between pores such that they accumulate strain and generate a local flow instability evaluated per an established instability criterion based on local evaluation of elastic tensile stress and streamline curvature. The onset of ET leads to increased pore-scale resistance and positive feedback on upstream streamline curvature. ET is thus characterized by a continuous evolution between states of laminar and unstable flow: pores with unstable flow flood their adjacent peers and thus encourage straightened streamlines and flow stability across the array, while positive feedback from flow resistance on streamline curvature results in the instability propagating upstream along the array. By employing a geometrically ordered medium, we permit flow state communication between pores, yielding generalized insights highlighting the significance of spatial correlation and flow history, and thus provide new avenues for explaining the mechanisms of ET.
- Published
- 2022
15. Effects of bulk elasticity on sheet formation and expansion
- Author
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Mariana Rodríguez-Hakim, Laura Stricker, and Jan Vermant
- Subjects
Impinging jets ,History ,Polymers and Plastics ,Applied Mathematics ,Mechanical Engineering ,General Chemical Engineering ,Extensional flow ,Viscoelasticity ,Upper convected Maxwell model ,Condensed Matter Physics ,Industrial and Manufacturing Engineering ,Fluid sheets ,General Materials Science ,Business and International Management - Abstract
The destabilization, fragmentation, and atomization of thin fluid sheets governs processes such as the aerosolization of sneeze ejecta, agrochemical spraying, and fuel injection in liquid rocket engines. Although the evolution, stability, and breakup of fluid sheets composed of a Newtonian liquid has been extensively studied, the morphology and dynamics of viscoelastic fluid sheets remains poorly understood. This manuscript provides a theoretical and numerical framework that integrates the effects of fluid elasticity, surface tension, inertia, and viscosity to predict the morphology, velocity, and stress within stable fluid sheets composed of viscoelastic fluids as a function of the dimensionless Weber, Reynolds, and Weissenberg numbers. We find a non-monotonic behavior in the sheet's size, velocity, and stress distribution as a function of the ratio between the Weissenberg and the Weber numbers. In particular, a minimum in the sheet's size and a maximum in the stress occur when such a ratio is of the order of unity. We interpret these results as the consequence of the competing effects of the growth-favoring inertia and the restoring elastic forces acting within the sheet., Journal of Non-Newtonian Fluid Mechanics, 308, ISSN:0377-0257, ISSN:1873-2631
- Published
- 2022
16. Viscoelastic hydromagnetic oscillatory flow in a channel in the presence of sinusoidal pressure gradient and linear motion of the plate
- Author
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Kharabela Swain, Kanaka Lata Ojha, and Pratikshya Dash
- Subjects
Fluid Flow and Transfer Processes ,Materials science ,Linear motion ,Mechanics ,Condensed Matter Physics ,Porous medium ,Oscillatory flow ,Viscoelasticity ,Pressure gradient ,Communication channel ,Volumetric flow rate - Published
- 2021
17. Mechanical, viscoelastic and sorption behaviour of acrylonitrile–butadiene–styrene composites with 0D and 1D nanofillers
- Author
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G. Rammanoj, K. Arunkumar, Alessandro Pegoretti, Karingamanna Jayanarayanan, T. Hariprasanth, and Nanoth Rasana
- Subjects
Nanocomposite ,Materials science ,Polymers and Plastics ,Acrylonitrile butadiene styrene ,Modulus ,General Chemistry ,Carbon nanotube ,Dynamic mechanical analysis ,Condensed Matter Physics ,Viscoelasticity ,law.invention ,chemistry.chemical_compound ,chemistry ,law ,Ultimate tensile strength ,Materials Chemistry ,Composite material ,Elastic modulus - Abstract
This work presents an investigation on the morphology, mechanical, viscoelastic and transport properties of acrylonitrile–butadiene–styrene (ABS) nanocomposites reinforced with nanosilica (NS) and multiwalled carbon nanotubes (MWCNTs). The nanofillers content was varied from 1 to 5 wt%. Morphological and mechanical investigations revealed a better dispersion and effective stress transfer in carboxyl-treated MWCNT composites with respect to silane-treated NS. The highest values of tensile strength and Young’s modulus were reached for 5 wt% of MWCNT. Theoretical modelling of elastic modulus of the composites with carbon nanotubes (CNT) was in good agreement with experimental data. On the other hand, in the case of composites with NS an interfacial modulus of 2.5 GPa was assumed in the model to approach the experimental data. The highest value of storage modulus was reported at a MWCNT content of 5 wt% followed by 3 wt% which discloses the stiffening effect of long curly CNTs in comparison with NS. The damping behaviour indicated a lowering and broadening of tan δ peak induced by CNT. The storage modulus and damping behaviour of the nanocomposites were analysed using theoretical models in which aspect ratio, stiffening effect, adhesion and entanglement phenomena were included. The lowest solvent diffusivity and permeability was exhibited by composite with MWCNT at 5 wt% owing to the tortuosity, higher adhesion and aspect ratio of the filler and revealed a decrement in permeability by 62% with regard to neat ABS.
- Published
- 2021
18. Analysis of Sound Absorption Performance of Underwater Acoustic Coating considering Different Poisson’s Ratio Values
- Author
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Yuanwei Yan, Tao Li, Zhou Zhou, and Zhuhui Luo
- Subjects
Absorption (acoustics) ,Materials science ,Article Subject ,Physics ,QC1-999 ,Mechanical Engineering ,Acoustics ,engineering.material ,Geotechnical Engineering and Engineering Geology ,Condensed Matter Physics ,Poisson distribution ,Noise (electronics) ,Finite element method ,Poisson's ratio ,Viscoelasticity ,symbols.namesake ,Coating ,Computer Science::Sound ,Mechanics of Materials ,Attenuation coefficient ,engineering ,symbols ,Civil and Structural Engineering - Abstract
Viscoelastic material acoustic coating plays an important role in noise and vibration control of underwater equipment. The dynamic mechanical properties of the viscoelastic material have a direct effect on the sound absorption performance of the acoustic coating. The influence of Poisson’s ratio on sound absorption performance is studied. A finite element model was established to calculate the sound absorption performance of three typical acoustic coatings: homogeneous acoustic coatings, Alberich acoustic coatings, and trumpet cavity acoustic coatings, and the influence of Poisson’s ratio on the sound absorption performance of the three kinds of acoustic coatings was analyzed. The results show that when Poisson’s ratio varies from 0.49 to 0.4999, the larger Poisson’s ratio is, the larger the frequency of the first absorption peak is, the smaller the absorption coefficient below the frequency of the first absorption peak is, and the smaller the average absorption coefficient in the whole analysis frequency range is. The dynamic Poisson’s ratio with the change of frequency is obtained by interpolating the test results and static Poisson’s ratio finite element calculation results. The calculation results show that the dynamic Poisson’s ratio can get more accurate calculation results. This work can provide a reference for researchers to set Poisson’s ratio in theoretical analysis and finite element analysis of acoustic coating.
- Published
- 2021
19. Energy Dissipation in Viscoelastic Multilayered Inhomogeneous Beam Structures: An Analytical Study
- Author
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Victor Rizov
- Subjects
Materials science ,Mechanics of Materials ,Mechanical Engineering ,General Materials Science ,Mechanics ,Bending ,Dissipation ,Condensed Matter Physics ,Beam (structure) ,Viscoelasticity - Abstract
The present work is concerned with analysis of the dissipated energy in viscoelastic multilayered inhomogeneous beam structure. The layers of the beam are continuously inhomogeneous along the thickness. The Maxwell mechanical model is used for treating the viscoelastic behaviour of the beam. The moduli of elasticity and the coefficients of viscosity vary continuously along the thickness of each layer. The dissipated energy is obtained by integrating of the unit dissipated energy in the volume of the beam. A parametric investigation of the dissipated energy is carried-out by applying the solution derived in order to evaluate the influence of various factors.
- Published
- 2021
20. Viscoelastic damped response of laminated composite shells subjected to various dynamic loads
- Author
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M. Fatih Sahan, Ali Dogan, Mühendislik ve Doğa Bilimleri Fakültesi -- İnşaat Mühendisliği Bölümü, and Doğan, Ali
- Subjects
Composite number ,Free Vibration ,Forced vibration analysis ,Transient analysis ,Truncated method ,General Boundary Conditions ,Laminating ,ANSYS finite element method ,Laplace transforms ,Laminated composite shells ,Dynamic behaviors ,Viscoelasticity ,Inverse Laplace transform ,Thick ,Mechanics ,Condensed Matter Physics ,Mechanics of Materials ,Sandwich panels ,Numerical results ,Higher order terms ,Laminated composites ,Numerical stability ,Elastic-deformation ,Materials science ,General Mathematics ,Vibrations ,Dynamic loads ,Time domain analysis ,Time-dependent partial differential equations ,Aerospace Engineering ,Ocean Engineering ,Governing equations ,Shells (structures) ,Truncated equations ,Civil and Structural Engineering ,Viscoelastic damping ,Curvature ,Mechanical Engineering ,Shear ,Partial differential equations ,Automotive Engineering ,Laminated composite shell ,Numerical methods ,Cylindrical-shells ,Cylindrical Shells ,Plates - Abstract
In this study, viscoelastic damped dynamic behaviors of laminated composite shells (LCS) under different dynamic loads were investigated. In order to obtain better numerical stability, the truncated series method was used in the formation of equations governing the system. While deriving the equations governing the system, the z/R terms are usually neglected, whereas only 3 and higher order terms are truncated here. The method of truncated equations has been used for the first time as suggested here to obtain viscoelastic damped behavior of dynamically loaded LCS. The governing equation of composite shells was obtained with the help of Hamilton's principle. Afterwards, time dependent partial differential equations were obtained by applying Navier solution method to these valid equations. These equations were transformed into Laplace space in order to solve time dependent partial differential equations. The transformation of the resulting calculations from Laplace domain into the time domain was conducted with the help of Modified Durbin algorithm. In addition, one of the goals of this research is to highlight the importance of including the (1+z/R) part in the equations to account for the curvature effect of the shells. The addition of these effects and truncated series method to the equations and the investigation of their effects are the originalities of the present study. The present work obtained values were compared with the results obtained with Newmark's approach and ANSYS finite element methods. The numerical results showed that the proposed approach is a highly effective and efficient solution that can be easily applied to laminated viscoelastic shell problems.
- Published
- 2021
21. Compressible and nonisothermal viscoelastic flow between eccentrically rotating cylinders
- Author
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Timothy Nigel Phillips and A. T. Mackay
- Subjects
Fluid Flow and Transfer Processes ,Physics ,Constitutive equation ,General Engineering ,Computational Mechanics ,Mechanics ,Elasticity (physics) ,Condensed Matter Physics ,Compressible flow ,Viscoelasticity ,Finite element method ,Unstructured grid ,Physics::Fluid Dynamics ,Compressibility ,Galerkin method - Abstract
A Taylor–Galerkin finite element time marching scheme is derived to numerically simulate the flow of a compressible and nonisothermal viscoelastic liquid between eccentrically rotating cylinders. Numerical approximations to the governing flow and constitutive equations are computed over a custom refined unstructured grid of piecewise linear Galerkin finite elements. An original extension to the DEVSS formulation for compressible fluids is introduced to stabilise solutions of the discrete problem. The predictions of two models: the extended White–Metzner and FENE-P-MP are presented. Comparisons between the torque and load bearing capacity predicted by both models are made over a range of viscoelastic parameters. The results highlight the significant and interacting effects of elasticity and compressibility on journal torque and resultant load, and the stability of the journal bearing system.
- Published
- 2021
22. Wave dispersion in viscoelastic FG nanobeams via a novel spatial–temporal nonlocal strain gradient framework
- Author
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Farzad Ebrahimi, Ali Dabbagh, and Kimia Khosravi
- Subjects
Physics ,Condensed Matter::Materials Science ,Nanostructure ,Spacetime ,Condensed matter physics ,Wave propagation ,General Engineering ,Physics::Optics ,General Physics and Astronomy ,Condensed Matter::Mesoscopic Systems and Quantum Hall Effect ,Strain gradient ,Viscoelasticity - Abstract
There is a correlation between nonlocal time and space in the nanostructures which are attacked by waves whose length lies in the range of the nanostructure’s intrinsic characteristic lengths. This...
- Published
- 2021
23. Heat and mass transfer of triple diffusive convection in viscoelastic liquids under internal heat source modulations
- Author
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Subbarama Pranesh, Sameena Tarannum, and S. Noor Arshika
- Subjects
Fluid Flow and Transfer Processes ,Convection ,Materials science ,Sinusoidal waveform ,Mass transfer ,Mechanics ,Condensed Matter Physics ,Internal heating ,Sherwood number ,Nusselt number ,Viscoelasticity - Published
- 2021
24. Experimental evidence of the effect of aging on the yielding and pre-yielding behavior of bentonite and laponite suspensions
- Author
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Jonathan Galdino, Elis M. S. Wendt, Admilson T. Franco, Diogo E. V. Andrade, and Rubens Rosario Fernandes
- Subjects
Thixotropy ,Yield (engineering) ,Materials science ,Mechanical Engineering ,Condensed Matter Physics ,Viscoelasticity ,Shear rate ,Stress (mechanics) ,Brittleness ,Creep ,Mechanics of Materials ,General Materials Science ,Composite material ,Elastic modulus - Abstract
Thixotropic yield stress materials show a shear-induced solid-liquid transition at the yielding point, characterized by yield stress and yield strain. It is well known in the literature that the elastic modulus and the yield stress of thixotropic materials increase with aging time. In the current work, we propose a discussion on the brittleness of a suspension of swollen bentonite in water, focusing mainly on the role of aging times on the yield strain and on the critical strain at the linear to nonlinear viscoelastic transition of the material. The yield strain was measured in creep and constant shear rate start-up experiments, whereas the linear to nonlinear viscoelastic transition was evaluated from Fourier transforms on transient data in oscillatory shear stress amplitude sweeps. We show that aging increases material brittleness since the yield strain decreases with the resting time. On the other hand, the linear to nonlinear viscoelastic transition strain is surprisingly unaffected by the aging process. Other thixotropic systems were also investigated: 8 and 10 wt. % suspensions of bentonite in water and a 2 wt. % suspension of Laponite® in tap water. These lead to similar observations, showing constant linear to nonlinear viscoelastic strains and decreasing yield strains over increasing aging times. These findings bring relevant information to the intricate open-discussion issue on how to describe the behavior of thixotropic materials below the yield stress.
- Published
- 2021
25. Regularities of Nonisothermal Crystallization in the Formation of a Plane Viscoelastic Film
- Author
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A. V. Baranov
- Subjects
chemistry.chemical_classification ,Materials science ,Plane (geometry) ,Kinetics ,General Engineering ,Finite difference method ,Thermodynamics ,Polymer ,Condensed Matter Physics ,Viscoelasticity ,Condensed Matter::Soft Condensed Matter ,Viscosity ,Crystallinity ,chemistry ,Heat transfer - Abstract
A study is made of the processes of heat transfer and nonisothermal crystallization during the formation of a plane viscoelastic polymer film with the upper-convected Maxwell model, in which the thermophysical properties, viscosity, and relaxation time of the polymer depend on its temperature and the degree of crystallinity. The mathematical model is supplemented with the equation of nonoisthermal-crystallization kinetics. The problem is solved by the finite difference method.
- Published
- 2021
26. Numerical simulations of small amplitude oscillatory shear flow of suspensions of rigid particles in non-Newtonian liquids at finite inertia
- Author
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Massimiliano M. Villone, Luca Brandt, Marco E. Rosti, Outi Tammisola, Villone, Massimiliano M., Rosti, Marco E., Tammisola, Outi, and Brandt, Luca
- Subjects
SAOS flow ,Materials science ,Mechanical Engineering ,Constitutive equation ,Mechanics ,Condensed Matter Physics ,FLUID ,Non-Newtonian fluid ,Viscoelasticity ,SPHERES ,Deborah number ,numerical simulations ,Physics::Fluid Dynamics ,Condensed Matter::Soft Condensed Matter ,non-Newtonian liquids ,RHEOLOGY ,Rheology ,Mechanics of Materials ,RESOLVED SIMULATIONS ,Dynamic modulus ,suspensions ,General Materials Science ,Suspension (vehicle) ,viscoelasticity ,Stokes number - Abstract
We perform immersed-boundary-method numerical simulations of small amplitude oscillatory shear flow of suspensions of monodisperse noncolloidal rigid spherical particles in non-Newtonian liquids from the dilute to the concentrated regime. We study the influence of suspending liquid inertia and rheology and particle concentration on the computationally measured storage and loss moduli of the suspensions. In particular, the rheology of the suspending liquid is modeled through the inelastic shear-thinning Carreau-Yasuda constitutive equation and the viscoelastic Giesekus and Oldroyd-B constitutive equations. The role of inertia is quantified by the Stokes number, St, whereas the relevance of the non-Newtonian effects of the suspension matrix is measured through the Carreau number, Cu, for the Carreau-Yasuda liquid and the Deborah number, De, for the viscoelastic liquids. In suspensions with a Carreau-Yasuda matrix, both the storage and the loss modulus increase with St and decrease with Cu, yet the order of magnitude of Cu has to be greater than unity for these effects to be visible. In suspensions with a viscoelastic matrix, both the moduli increase with St and have a nonmonotonic trend with De, showing a maximum with no quantitative differences between the results pertaining suspensions with Giesekus and Oldroyd-B constitutive equations.
- Published
- 2021
27. Payne effect of carbon black filled natural rubber nanocomposites: Influences of extraction, crosslinking, and swelling
- Author
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Wanjie Wang, Zhongjia Xu, Yihu Song, and Qiang Zheng
- Subjects
Materials science ,Nanocomposite ,Mechanical Engineering ,Modulus ,Carbon black ,Condensed Matter Physics ,Viscoelasticity ,Payne effect ,Natural rubber ,Mechanics of Materials ,Phase (matter) ,visual_art ,visual_art.visual_art_medium ,medicine ,General Materials Science ,Swelling ,medicine.symptom ,Composite material - Abstract
Rubber nanocomposites experiencing dynamic shears at large strain amplitudes (γ) exhibit the nonlinear Payne effect featured by decays of storage and loss moduli (G′ and G″) or by G′ decay accompanied with G″ overshoot near a critical strain amplitude. The occurrence of the Payne effect has been assigned to damages of “filler network” and rubber-filler interfacial interactions for a long time and to Rouse dynamics of rubber chains recently. To solve the dispute, influences of extraction, crosslinking, and paraffin swelling on the Payne effect of carbon black filled natural rubber nanocomposites are investigated systematically. Master curves of G′ as a function of γ could be always created, and overshoot of G″ in the filled vulcanizates weakens with increasing filler content and intensifies by dilution via paraffin swelling, suggesting that the Payne effect is not mainly rooted in the “filler network” and rubber-filler interfacial interactions. The filler reduces the onset strain amplitude of the Payne effect by amplifying microscopic strain amplitude of the rubber phase, irrespective of whether the matrix is crosslinked or not and whether the crosslinked matrix is swollen or not. Partial removal of bound rubber by compounding the paraffin swollen compounds could lower modulus and eliminate G″ overshoot of the deswollen vulcanizates without influence on the mechanism of G′ decay accompanying Payne effect. The overshoot is found to be closely related to the overall viscous characteristic of the vulcanizates in the linear viscoelastic regime. Provided herein are new insights for recognizing the important roles of the viscoelastic rubber phase on the Payne effect of the nanocomposites.
- Published
- 2021
28. Excluded volume effects and fractional viscoelasticity in polymers
- Author
-
Mahdi Hassani, Somayeh Mashayekhi, Eugenia Stanisauskis, and William S. Oates
- Subjects
Physics ,State variable ,Mechanical Engineering ,Condensed Matter Physics ,Fractal dimension ,Viscoelasticity ,Fractional calculus ,Condensed Matter::Soft Condensed Matter ,Matrix (mathematics) ,Fractal ,Mechanics of Materials ,Excluded volume ,Time derivative ,Statistical physics - Abstract
The excluded volume effect is added to a fractional viscoelastic model for modeling fractal polymers. This reveals a physical connection between the fractional time derivative, fractal geometry, and excluded volume effect. This derivation is a general theoretical framework based on the Scott-Blair fractional model of viscoelasticity when the excluded volume and the hydrodynamic interaction are explicitly taken into account to derive the microscopic stress within the molecular theory of Rouse and Zimm. The methodology extends the generalized molecular theory of Zimm by adding the effect of excluded volume where the new relaxation formulation contains internal state variables that naturally depend on the fractional time derivative of deformation. The modified distribution of the end-to-end vector of a monomer contained within a polymer network is used for pre-averaging approximations of the mobility matrix in the Zimm model. The pre-averaging approximation is important since the mobility matrix is a nonlinear function and it is difficult to explicitly calculate. Through application of thermodynamic laws, we derive the linear fractional model of viscoelasticity based on its spectral dimension, fractal dimension, and the excluded volume parameter for fractal media. This derivation shows how the order of the fractional derivative in the linear fractional model of viscoelasticity is strongly correlated with fractal structure and excluded volume effects.
- Published
- 2021
29. The influence of the negative wake on the deformation and breakup of viscoelastic droplets
- Author
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Bernardo Figueroa-Espinoza, Fernando Carril-Naranjo, Didier Samayoa, Antonio Guerrero, and Baltsar Mena
- Subjects
Materials science ,technology, industry, and agriculture ,Viscoelastic fluid ,Mechanics ,Wake ,Deformation (meteorology) ,Condensed Matter Physics ,Breakup ,negative wake ,Viscoelasticity ,eye diseases ,Article ,Physics::Fluid Dynamics ,PIV ,tail breakup ,Newtonian fluid ,General Materials Science ,Elongation ,viscoelastic droplets - Abstract
Experiments were performed using visual and PIV techniques in order to study the appearance of a negative wake as well as its influence upon the deformation and breakup of droplets rising in viscoelastic fluids. In this report, Newtonian and viscoelastic drops were injected through different viscoelastic fluids; the deformation of the droplets was then followed and analyzed. In the case of Newtonian drops traveling through a viscoelastic fluid, a tail appears which later breaks into satellite droplets; a negative wake is present on the sides of the tail. The viscoelastic drops also exhibit a tail which is more resistant to rupture and the negative wake appears after the tail; additionally, a bump appears at the tip of the tail which enhances its elongation and determines the onset of breakup.
- Published
- 2021
30. Cubic and Hexagonal Mesophases for Protein Encapsulation: Structural Effects of Insulin Confinement
- Author
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Francesco Vita, Paola Astolfi, Stefania Pucciarelli, Diego Romano Perinelli, Serena Logrippo, Marco Parlapiano, Giulia Bonacucina, Michela Pisani, Oriano Francescangeli, Lisa Vaccari, Elisabetta Giorgini, and Fabrizio C. Adamo
- Subjects
Diffraction ,Materials science ,Hexagonal phase ,Temperature ,Infrared spectroscopy ,Mesophase ,Surfaces and Interfaces ,Condensed Matter Physics ,Viscoelasticity ,Article ,Protein Structure, Secondary ,Oleic acid ,chemistry.chemical_compound ,Crystallography ,chemistry ,Rheology ,X-Ray Diffraction ,Spectroscopy, Fourier Transform Infrared ,Electrochemistry ,Insulin ,General Materials Science ,Protein secondary structure ,Spectroscopy - Abstract
Monoolein-based cubic and hexagonal mesophases were investigated as matrices for insulin loading, at low pH, as a function of temperature and in the presence of increasing amounts of oleic acid, as a structural stabilizer for the hexagonal phase. Synchrotron small angle X-ray diffraction, rheological measurements, and attenuated total reflection-Fourier transform infrared spectroscopy were used to study the effects of insulin loading on the lipid mesophases and of the effect of protein confinement in the 2D- and 3D-lipid matrix water channels on its stability and unfolding behavior. We found that insulin encapsulation has only little effects both on the mesophase structures and on the viscoelastic properties of lipid systems, whereas protein confinement affects the response of the secondary structure of insulin to thermal changes in a different manner according to the specific mesophase: in the cubic structure, the unfolding toward an unordered structure is favored, while the prevalence of parallel β-sheets, and nuclei for fibril formation, is observed in hexagonal structures.
- Published
- 2021
31. A memory-dependent thermal-viscoelastic model and its application in heating-induced nonlocal response analysis of a polymer microbeam
- Author
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Wei Peng, Tianhu He, and Like Chen
- Subjects
chemistry.chemical_classification ,Materials science ,Mechanical Engineering ,General Mathematics ,Response analysis ,Aerospace Engineering ,Ocean Engineering ,Microbeam ,Polymer ,Condensed Matter Physics ,Viscoelasticity ,chemistry ,Mechanics of Materials ,Automotive Engineering ,Thermal ,Composite material ,Civil and Structural Engineering - Published
- 2021
32. Effect of heat source on Rayleigh–Bénard convection in rotating viscoelastic liquids
- Author
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G. Jayalatha and N. Suma
- Subjects
Fluid Flow and Transfer Processes ,Materials science ,Mechanics ,Condensed Matter Physics ,Viscoelasticity ,Rayleigh–Bénard convection - Published
- 2021
33. Nonlinear oscillatory shear tests of pressure-sensitive adhesives (PSAs) designed for transdermal therapeutic systems (TTS)
- Author
-
Berenika Hausnerova, Esther Ramakers-van Dorp, Michael Meurer, Bernhard Möginger, and Roland Kádár
- Subjects
Dilatant ,Materials science ,Rheometer ,Diffusion ,Condensed Matter Physics ,Viscoelasticity ,chemistry.chemical_compound ,Silicone ,Rheology ,chemistry ,General Materials Science ,Adhesive ,Composite material ,Transdermal - Abstract
Transdermal therapeutic systems (TTS) based on pressure-sensitive adhesives (PSAs) allow for the application of pharmaceutical substances via diffusion through the skin. The rheological performance of PSA is largely investigated within small amplitude oscillatory shear (typically up to 1 %), although the skin motions exceed strains beyond 40 %. In this paper, amine-compatible (AC) and non-amine-compatible (NAC) silicone-based PSA compounds differing in the resin content were subjected to strain amplitude sweeps in a twin drive rheometer. Carreau-Yasuda-like fitting of storage and loss moduli curves intercepts the substantial effect of resin content on both compounds; up to four times higher, moduli of AC compounds were determined in SAOS, and their higher molecular mass combined with enhanced interactions contributed to an earlier transition to the nonlinear viscoelastic region. In the nonlinear range, elastic and viscous properties are affected by strains in a different manner with the trend favorable for the PSA application as TTS. The third relative higher harmonic from Fourier transformation I3/1 as well as intra-cycle strain stiffening and shear thickening ratios provide information relevant for an optimization of PSA subjected to large deformations.
- Published
- 2021
34. Effect of sonication and succinylation on rheological properties and secondary structures of date palm pollen protein concentrate
- Author
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Hamadi Attia, Sirine Karra, Christophe Blecker, Haifa Sebii, Romdhane Karoui, Souhail Besbes, Gembloux Agro-Bio Tech [Gembloux], Université de Liège, Transfrontalière BioEcoAgro - UMR 1158 (BioEcoAgro), Université d'Artois (UA)-Université de Liège-Université de Picardie Jules Verne (UPJV)-Université du Littoral Côte d'Opale (ULCO)-Université de Lille-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-JUNIA (JUNIA), and Université catholique de Lille (UCL)-Université catholique de Lille (UCL)
- Subjects
Thixotropy ,Chemistry ,[SDV]Life Sciences [q-bio] ,Sonication ,Beta sheet ,Condensed Matter Physics ,Viscoelasticity ,Succinylation ,Rheology ,Chemical engineering ,[SDE]Environmental Sciences ,General Materials Science ,Thermal stability ,Protein secondary structure ,ComputingMilieux_MISCELLANEOUS - Abstract
The rheological properties and the secondary structures of date palm pollen concentrates were investigated in the present study. The sonication pretreatment and the succinylation procedure were applied to the native protein, as physical and chemical modifications, respectively. Each modification affected differently the native concentrate. In fact, in the flow measurement, results, fitted with the power low model, showed that sonication increased the consistency coefficient and decreased the flow index implying a more shear-thinning character. However, for succinylation modification, an increase of the flow index and a decrease of the consistency coefficient were noticed which convert the protein concentrate to a less viscous and more Newtonian-like state. Sonication also enhanced the thixotropic behavior which was expressed by the increase of the hysteresis loop, whereas the succinylation suppressed it, which was deduced from the disappearance of the loop area. The frequency sweep analysis proved that the sonicated concentrate was characterized by a strong gel structure while the succinylated protein had a viscoelastic liquid character. Only the native and the succinylated concentrates gelified, in the temperature sweep test, at 53.1 and 54.4 °C, respectively. All discerned differences were attributed to the secondary structure content. The findings revealed that the sonicated protein had a high β sheet content, leading to greater thermal stability which proved that a higher temperature is required to ensure the gelation of the protein. However, native and succinylated concentrates were found to have an equilibrium between α helix and β sheet which made it possible to form a stable gel at a lower temperature. The present study concluded that the modifications had a great impact on the rheological properties which was strongly attributed to the submitted structural changes.
- Published
- 2021
35. Rheological behavior of carboxymethylcellulose and cellulose nanocrystal aqueous dispersions
- Author
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Marcos Akira d’Ávila and Jéssica Heline Lopes da Fonsêca
- Subjects
chemistry.chemical_classification ,Thixotropy ,Aqueous solution ,Materials science ,Polymer ,Condensed Matter Physics ,Viscoelasticity ,Physics::Fluid Dynamics ,Condensed Matter::Soft Condensed Matter ,chemistry.chemical_compound ,Viscosity ,chemistry ,Nanocrystal ,Chemical engineering ,Rheology ,General Materials Science ,Cellulose - Abstract
This study investigated the rheological properties of cellulose nanocrystal (CNC) suspensions in carboxymethylcellulose (CMC) polymer solutions by studying steady shear viscosities, linear viscoelastic behaviors, applicability of the Cox–Merz rule, and time-dependent behavior. The rheological measurement showed that interactions between CNC and CMC resulted in liquid crystalline domains and a substantial increase in viscosity, shear-thinning, elasticity, and thixotropy. Depletion flocculation formed a percolated structure of liquid crystalline domains, resulting in a gel-like structure, which was evidenced by polarized optical microscopy. The strong effects on rheological properties by mixing small quantities of CMC and CNC suggest that this system may find applications where tunable rheological properties of aqueous polymeric systems are desirable.
- Published
- 2021
36. Analysis of parametric instability of a spring-attached pre-twisted beam with viscoelastic end support
- Author
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Dipesh Kumar Nayak, Madhusmita Pradhan, P. K. Jena, and Pusparaj Dash
- Subjects
Elastic beam ,Materials science ,Acoustics and Ultrasonics ,Mechanical Engineering ,02 engineering and technology ,Mechanics ,Condensed Matter Physics ,01 natural sciences ,Viscoelasticity ,Parametric instability ,020303 mechanical engineering & transports ,0203 mechanical engineering ,Mechanics of Materials ,Spring (device) ,0103 physical sciences ,General Materials Science ,Tapered beam ,010301 acoustics ,Beam (structure) - Abstract
This study investigated the parametric instability of a single elastic beam with spring attachment on the top and viscoelastic springs as end supports. The beam considered is pre-twisted with a pin connection at both ends that supports the beam. The analytical solution of the problem is expressed in the matrix form achieved from the implementation of Hamilton’s principle and General Galerkin’s method, from which both static and dynamic stability of the beam can be investigated. The results of various influential dimensionless parameters such as stiffness, mass, length, position of the spring attachment, and stiffness of the viscoelastic springs on both the stabilities are studied. This analysis concluded that the spring attachment on the system leads to substantial contribution in improving the stability. The viscoelastic springs also contribute in upsurging the beam’s stability. Three different profiles of the beam have been considered, and for each profile, three different types of springs have been examined. The results revealed that the beam with parabolic profile and stiffness of the spring attachment with parabolic variation is most effective towards strength-to-weight ratio.
- Published
- 2021
37. Inkjet Printability Assessment of Weakly Viscoelastic Fluid: A Semidilute Polyvinylpyrrolidone Solution Ink Case Study
- Author
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David John Dmonte, Pavol Suly, Ivo Kuritka, Jakub Sevcik, and Pavel Urbanek
- Subjects
chemistry.chemical_classification ,Work (thermodynamics) ,Materials science ,Drop (liquid) ,Surfaces and Interfaces ,Polymer ,Mechanics ,Condensed Matter Physics ,Breakup ,Viscoelasticity ,Surface tension ,Viscosity ,chemistry ,Electrochemistry ,Newtonian fluid ,General Materials Science ,Spectroscopy - Abstract
Here, we present an integrated approach to the weakly viscoelastic fluid printability assessment by using global dimensionless criteria (DC). The problem was studied on a model semidiluted polyvinylpyrrolidone water-based ink. For the study purpose, the ink composition was kept as simple as possible. First, the solution density, viscosity, and surface tension were determined. Obtained data were used for testing limitations of DC printability diagrams already available for Newtonian fluids. A replotted version of the original Kim and Baek's map was developed emphasizing the importance of surface tension in the drop formation process. Another set of DC (e.g., Ec and De) was also used for a real evaluation of the viscoelasticity effect on both jetting conditions and drop formation. The polymer relaxation time as a crucial parameter for viscoelasticity was shown to be calculated using the Kuhn segment length rather than from Zimm and Rouse theories for diluted polymer systems. Then, a two-dimensional diagram using four DC (Oh and De with Ec and El as parameters) is proposed based on the famous McKinley's work. The diagram describes the interplay of possible forces responsible for filament thinning and breakup processes. Obtained results were supported by further experiments involving drop ejection and formation, determination of critical polymer concentration, and others. The proposed diagram promises a useful initial step in further investigations of viscoelasticity of polymer compounds by inkjet printing.
- Published
- 2021
38. Three-dimensional static analysis of a viscoelastic rectangular functionally graded material plate embedded between piezoelectric sensor and actuator layers
- Author
-
M. Feri, Akbar Alibeigloo, and M. Krommer
- Subjects
Materials science ,Piezoelectric sensor ,Mechanical Engineering ,General Mathematics ,Aerospace Engineering ,Ocean Engineering ,Bending ,Condensed Matter Physics ,Piezoelectricity ,Functionally graded material ,Viscoelasticity ,Mathematics::Numerical Analysis ,Mechanics of Materials ,Electric field ,Automotive Engineering ,Composite material ,Actuator ,Layer (electronics) ,Civil and Structural Engineering - Abstract
The three-dimensional bending behavior of a viscoelastic functionally graded material (FGM) layer embedded between piezoelectric layers and subjected to an electric field as well as a uniform trans...
- Published
- 2021
39. Creation of Basalt Plastics with Different Types of Hybrid Matrices
- Author
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E. A. Kosenko, Natalya Baurova, and Vladimir Zorin
- Subjects
chemistry.chemical_classification ,Basalt ,0209 industrial biotechnology ,Materials science ,Structural material ,020502 materials ,Mechanical Engineering ,02 engineering and technology ,Polymer ,Condensed Matter Physics ,Viscoelasticity ,Cracking ,020901 industrial engineering & automation ,0205 materials engineering ,chemistry ,Mechanics of Materials ,Ultimate tensile strength ,Fracture (geology) ,General Materials Science ,Deformation (engineering) ,Composite material - Abstract
Basalt plastic, thanks to its complex of valuable operational properties, has a potential variety of applications. the article describes the technology of production of basalt plastics with various types of hybrid matrices, one of the components of which is cured in the molding process, and the second-like a binder in natural materials, retains its viscoelastic state. The viscoelastic component makes it possible to increase the deformation properties in the zones of their location, preventing cracking under increased loads. As a result of the conducted mechanical tensile tests, the average values of absolute breaking forces, tensile strength and elongation during fracture of basalt plastic samples with different types of hybrid matrices were obtained. The addition of viscoelastic components (such as technical wax, anaerobic, and organosilicon polymer materials) to the basalt plastic matrix allows to increase the elongation at fracture by 2...5%. Anaerobic polymer material in the basalt plastic matrix allows to increase the tensile strength of the composite material, as well as significantly reduce the dispersion of the measured values. This provides an effective prediction of the operational properties of the structural material in the design of products. On the basis of microanalysis of the structure of basalt plastics with different types of hybrid matrices, an explanation of the causes of changes in the mechanical properties of the resulting composite materials is given.
- Published
- 2021
40. Implementation of active probe rheology simulation technique for determining the viscoelastic moduli of soft matter
- Author
-
Pouria Nourian, Rajesh Khare, and Rafikul Islam
- Subjects
Microrheology ,Materials science ,Inertial frame of reference ,Mechanical Engineering ,Mechanics ,Condensed Matter Physics ,Viscoelasticity ,Condensed Matter::Soft Condensed Matter ,symbols.namesake ,Fourier transform ,Rheology ,Mechanics of Materials ,Harmonic ,symbols ,General Materials Science ,Soft matter ,Displacement (fluid) - Abstract
Although bead microrheology experiments are routinely used to characterize the viscoelasticity of complex matter, their simulation analog—probe rheology molecular simulations—has been scarcely used since the system characteristics required for its robust implementation are not established in the literature. We address this issue by analyzing an active probe rheology simulation setup consisting of a probe particle that is subjected to an external oscillatory force and a harmonic trapping force. We identify a set of eight conditions of the system properties that must be satisfied for the successful implementation of the probe rheology technique in molecular simulations. Among these criteria, the two most important are as follows: (1) The spring force constant for the trapping force should be sufficiently large such that the peak in the Fourier transform of the probe displacement occurs at the same frequency as that of the applied force. (2) System parameters should be chosen such that the magnitude of the external force used to drive the probe motion should be comparable to the magnitude of the hydrodynamic friction force experienced by the probe particle in the viscoelastic medium. Furthermore, a scaling relation that can be used to determine the frequency at which inertial effects set in for a given probe size is also established. The validity of our procedure is demonstrated by applying it to determine the viscoelastic properties of a weakly entangled polymer melt system.
- Published
- 2021
41. Rheological response of entangled isotactic polypropylene melts in strong shear flows: Edge fracture, flow curves, and normal stresses
- Author
-
Jiho Seo, Daniele Parisi, Aijie Han, and Ralph H. Colby
- Subjects
Materials science ,Shear thinning ,Rheometry ,Mechanical Engineering ,Rheometer ,Condensed Matter Physics ,Viscoelasticity ,Shear rate ,Shear (sheet metal) ,Viscosity ,Mechanics of Materials ,Fracture (geology) ,General Materials Science ,Composite material - Abstract
Isotactic polypropylene (iPP) melts are industrial semicrystalline polymers whose processing typically involves strong shear flows. The study of the rheological response of iPP melts, well beyond the linear viscoelastic limit, is limited by edge fracture, which manifests in rotational rheometers. In this work, we used a reflection polariscope under shear to detect the onset shear rate at which edge fracture is observed for various rotational rheometry fixture diameters. The onset shear rate for edge fracture was found to correlate with the zero-shear viscosity, thereby enabling the prediction of edge fracture by only knowing the zero-shear viscosity; a quantity that is easier to measure compared to the second normal stress difference. Edge fracture is then mitigated by using a cone-partitioned plate, which enabled the study of the first normal stress difference, and in combination with capillary rheometry, allowed the measurement of flow curves with a very well-resolved shear thinning region. For strongly polydisperse iPPs at high shear rates, we found that viscosity scales as the −0.7 power of the shear rate, while primary normal stress difference scales as the square root of the shear rate. The dependence of the shear thinning of iPPs on polydispersity was then unravelled, offering a broad set of data to develop and test molecular models.
- Published
- 2021
42. Molecular dynamics simulation of associative polymers: Understanding linear viscoelasticity from the sticky Rouse model
- Author
-
Nuofei Jiang, Hongdong Zhang, Ping Tang, and Yuliang Yang
- Subjects
chemistry.chemical_classification ,Work (thermodynamics) ,Mechanical Engineering ,Polymer ,Condensed Matter Physics ,Viscoelasticity ,Condensed Matter::Soft Condensed Matter ,Molecular dynamics ,chemistry ,Rheology ,Chain (algebraic topology) ,Mechanics of Materials ,General Materials Science ,Statistical physics ,Relaxation (approximation) ,Diffusion (business) - Abstract
Polymers bearing associative groups (APs) are characterized by their fantastic viscoelastic behaviors. In a work recently published by our group [Jiang et al., Macromolecules 53, 3438–3451 (2020)], a single chain sticky Rouse model (SRM) is proposed to describe the linear viscoelasticity of APs without the entanglement effect. In this work, equilibrium molecular dynamics simulation of an unentangled melt of an AP with uniformly distributed stickers is carried out, and the dynamic properties are simultaneously analyzed from the SRM. A chain model with capped stickers is proposed so that a well-defined association chemistry is promised in the simulation system. The relative effective frictional coefficient of stickers, which is the key parameter in the SRM, is extracted from the chain center-of-mass diffusion, and it is found to be consistent with the dynamics of associative reaction in the fully gelated network. Based on this, a linear relaxation modulus and segmental diffusion functions are predicted from the SRM without fitting parameters, and these are found to quantitatively agree with the simulation results, showing the effectiveness of the SRM in connecting the dynamic properties at different molecular levels. The change in relaxation modes and the definition of the effective chain center are found to be crucial in the scenario of the SRM. Finally, the above analysis from the SRM is successfully extended to the simulation system with asymmetric chains. All these simulation results strongly support the SRM as a molecular model for the linear rheology of AP.
- Published
- 2021
43. Vortex merging and splitting events in viscoelastic Taylor-Couette flow
- Author
-
Jose Manuel Lopez, Universitat Politècnica de Catalunya. Departament de Física, and Universitat Politècnica de Catalunya. DF-GeoTech - Dinàmica de Fluids i Aplicacions Geofísiques i Tecnològiques
- Subjects
Vòrtexs de Taylor ,Física [Àrees temàtiques de la UPC] ,Mechanical Engineering ,Applied Mathematics ,Fluid Dynamics (physics.flu-dyn) ,FOS: Physical sciences ,Viscoelasticitat ,Taylor vortices ,Viscoelasticity ,Physics - Fluid Dynamics ,Condensed Matter Physics ,Transition to turbulence ,Physics::Fluid Dynamics ,Mechanics of Materials ,Taylor–Couette flow - Abstract
Recent experiments have reported a novel transition to elasto-inertial turbulence in the Taylor--Couette flow of a dilute polymer solution. Unlike previously reported transitions, this newly discovered scenario, dubbed vortex merging and splitting (VMS) transition, occurs in the centrifugally unstable regime and the mechanisms underlying it are two-dimensional: the flow becomes chaotic due to the proliferation of events where axisymmetric vortex pairs may be either created (vortex splitting) or annihilated (vortex merging). In this paper, we present direct numerical simulations, using the FENE-P constitutive equation to model polymer dynamics, which reproduce the experimental observations with great accuracy and elucidate the reasons for the onset of this surprising dynamics. Starting from the Newtonian limit and increasing progressively the fluid's elasticity, we demonstrate that the VMS dynamics is not associated with the well-known Taylor vortices, but with a steady pattern of elastically induced axisymmetric vortex pairs known as diwhirls. The amount of angular momentum carried by these elastic vortices becomes increasingly small as the fluid's elasticity increases and it eventually reaches a marginal level. When this occurs, the diwhirls become dynamically disconnected from the rest of the system and move independently from each other in the axial direction. It is shown that vortex merging and splitting events, along with local transient chaotic dynamics, result from the interactions among diwhirls, and that this complex spatio-temporal dynamics persists even at elasticity levels twice as large as those investigated experimentally., 45 pages, 22 figures. Accepted for publication in Journal of Fluid Mechanics
- Published
- 2022
44. Characterization of transient rheological behavior of soft materials using ferrofluid droplets
- Author
-
Danyil Azarkh, Melanie Geiger, Se-Hyeong Jung, Erik Noetzel, Rudolf Merkel, Andrij Pich, Uwe Schnakenberg, AMIBM, and RS: FSE AMIBM
- Subjects
Ferrofluid droplet ,Polyacrylamide ,FLOW ,PUMP ,Metals and Alloys ,Viscoelasticity ,Condensed Matter Physics ,MAGNETIC TWEEZERS ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,MANIPULATION ,Magnetic Bond number ,Electrical and Electronic Engineering ,ddc:620 ,Rheology ,Instrumentation ,Interfacial tension - Abstract
Physical material properties, such as elasticity, viscosity, or viscoelasticity, can be characterized by using rheometers or stick-type solenoid electromagnets. In this work, we developed a magnet measurement setup based on a Helmholtz arrangement of electromagnets. While applying homogeneous magnet fields to ferrofluid droplets inside a soft material of interest, the deformations of the ellipsoidal deformed droplets were measured. Kelvin-Voigt models and corresponding analytical descriptions were used to calculate the values of viscosity and Young's modulus of materials under test. For calibration purposes of the developed setup, glycerin/water mixtures and methylcellulose/water solutions were characterized as viscous and polyacrylamide gels as elastic materials, respectively. In addition, the interfacial tensions were calculated with respect to the magnetic Bond number from the droplet deformations. For the first time, the transient rheological behavior of viscoelastic material was measured using the method of ferrofluid droplet deformation. When polyacrylamide gel with a shear modulus of 230 Pa was evacuated for less than 40 min during preparation, it showed a strong time-depending viscoelastic behavior several minutes after starting the measurements. Here, Young's modulus increased up to the value of elastic behavior, whereas the values for viscosity decreased to a baseline. The developed setup can favorably be used in future applications to investigate local and also time-dependent rheological properties of soft materials.
- Published
- 2022
45. Fluidisation of yield stress fluids under vibration
- Author
-
Matthias Heil, Beccy Smith, Anne Juel, Ashish Garg, and Nico Bergemann
- Subjects
Materials science ,Yield (engineering) ,010304 chemical physics ,Applied Mathematics ,Mechanical Engineering ,General Chemical Engineering ,Drop (liquid) ,FOS: Physical sciences ,Mechanics ,Forcing (mathematics) ,Condensed Matter - Soft Condensed Matter ,Condensed Matter Physics ,01 natural sciences ,Viscoelasticity ,010305 fluids & plasmas ,Vibration ,Stress (mechanics) ,Physics::Fluid Dynamics ,Acceleration ,Sessile drop technique ,0103 physical sciences ,Soft Condensed Matter (cond-mat.soft) ,General Materials Science - Abstract
Motivated by the industrial processing of chocolate, we study experimentally the fluidisation of a sessile drop of yield-stress fluid on a pre-existing layer of the same fluid under vertical sinusoidal oscillations. We compare the behaviours of molten chocolate and Carbopol which are both shear-thinning with a similar yield stress but exhibit very different elastic properties. We find that these materials spread when the forcing acceleration exceeds a threshold which is determined by the initial deposition process. However, they exhibit very different spreading behaviours: whereas chocolate exhibits slow long-term spreading, the Carbopol drop rapidly relaxes its stress by spreading to a new equilibrium shape with an enlarged footprint. This spreading is insensitive to the history of the forcing. In addition, the Carbopol drop performs large-amplitude oscillations with the forcing frequency, both above and below the threshold. We investigate these viscoelastic oscillations and provide evidence of complex nonlinear viscoelastic behaviour in the vicinity of the spreading threshold. In fact, for forcing accelerations greater than the spreading threshold, our drop automatically adjusts its shape to remain at the yield stress. We discuss how our vibrated-drop experiment offers a new and powerful approach to probing the yield transition in elastoviscoplastic fluids., Comment: 38 pages, 22 figures
- Published
- 2022
46. A thin-film equation for a viscoelastic fluid, and its application to the Landau–Levich problem
- Author
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Charu Datt, Minkush Kansal, Jacco H. Snoeijer, Physics of Fluids, and MESA+ Institute
- Subjects
Condensed Matter::Soft Condensed Matter ,Physics::Fluid Dynamics ,Landau–Levich problem ,Condensed Matter::Materials Science ,Thin-film equation ,Applied Mathematics ,Mechanical Engineering ,General Chemical Engineering ,Condensed Matter::Superconductivity ,UT-Hybrid-D ,General Materials Science ,Viscoelasticity ,Condensed Matter Physics - Abstract
Thin-film flows of viscoelastic fluids are encountered in various industrial and biological settings. The understanding of thin viscous film flows in Newtonian fluids is very well developed, which for a large part is due to the so-called thin-film equation. This equation, a single partial differential equation describing the height of the film, is a significant simplification of the Stokes equation effected by the lubrication approximation which exploits the thinness of the film. There is no such established equation for viscoelastic fluid flows. Here we derive the thin-film equation for a second-order fluid, and use it to study the classical Landau–Levich dip-coating problem. We show how viscoelasticity of the fluid affects the thickness of the deposited film, and address the discrepancy on the topic in literature.
- Published
- 2022
47. Solution of magnetohydrodynamic flow and heat transfer of radiative viscoelastic fluid with temperature dependent viscosity in wire coating analysis.
- Author
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Khan, Zeeshan, Khan, Muhammad Altaf, Siddiqui, Nasir, Ullah, Murad, and Shah, Qayyum
- Subjects
- *
MAGNETOHYDRODYNAMICS , *HEAT transfer , *VISCOELASTICITY , *VISCOSITY , *COATING processes , *ELECTRIC insulators & insulation - Abstract
Wire coating process is a continuous extrusion process for primary insulation of conducting wires with molten polymers for mechanical strength and protection in aggressive environments. In the present study, radiative melt polymer satisfying third grade fluid model is used for wire coating process. The effect of magnetic parameter, thermal radiation parameter and temperature dependent viscosity on wire coating analysis has been investigated. Reynolds model and Vogel’s models have been incorporated for variable viscosity. The governing equations characterizing the flow and heat transfer phenomena are solved analytically by utilizing homotopy analysis method (HAM). The computed results are also verified by ND-Solve method (Numerical technique) and Adomian Decomposition Method (ADM). The effect of pertinent parameters is shown graphically. In addition, the instability of the flow in the flows of the wall of the extrusion die is well marked in the case of the Vogel model as pointed by Nhan-Phan-Thien. [ABSTRACT FROM AUTHOR]
- Published
- 2018
- Full Text
- View/download PDF
48. Molecular constitutive equation for unentangled branch copolymers
- Author
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Zhongqiang Xiong and Wei Yu
- Subjects
Physics ,Viscosity ,Work (thermodynamics) ,Chain (algebraic topology) ,Constitutive equation ,Relaxation (NMR) ,Brownian dynamics ,General Materials Science ,Statistical physics ,Condensed Matter Physics ,Viscoelasticity ,Moduli - Abstract
The dynamics and linear viscoelasticity of the heterogeneous polymeric system with complex molecular topology and semiflexibility are studied in this work. From the viewpoint of the bead-spring chain, the multi-intensity springs, multi-friction beads, and multi-site restrictions are systematically considered for the heterogeneity of the chain. These heterogeneities are incorporating into a general constitutive equation without entanglement effect based on graph theory, the maximum entropy principle, and Brownian dynamics. The general constitutive equation is validated for a series of bottlebrush copolymers. The predictions of the dynamic moduli, the longest relaxation time, and the zero-shear viscosity are well consistent with experimental observations. Besides, we provide a method to separate the modulus of local chain segments (such as arm or backbone) from the apparent modulus. The dependencies of the distribution of eigen relaxation modes and the dynamic moduli on the heterogeneities are also discussed.
- Published
- 2021
49. The orthotropic viscoelastic characterisation of sub-zero 3D-printed poly(vinyl alcohol) cryogel
- Author
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Daniel M. Espino, Lauren Thomas-Seale, Melanie M. Britton, and J P Crolla
- Subjects
Vinyl alcohol ,Materials science ,Additive manufacturing ,0206 medical engineering ,Nozzle ,02 engineering and technology ,Orthotropic material ,Viscoelasticity ,chemistry.chemical_compound ,Perpendicular ,General Materials Science ,Composite material ,Polymer ,chemistry.chemical_classification ,Original Paper ,Tension (physics) ,Mechanical Engineering ,Biomaterial ,3D printing ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,020601 biomedical engineering ,chemistry ,Mechanics of Materials ,0210 nano-technology - Abstract
Abstract Poly(vinyl alcohol) cryogel (PVA) is a versatile biomaterial used to replicate the biomechanics of tissues. Additive manufacture (AM) at sub-zero (°C) temperatures enables the manufacture of PVA with complex geometry; however, the effect of processing parameters on the mechanical properties of PVA has not been evaluated. The aim of this study is to understand the impact of print nozzle diameter and orientation on the viscoelastic mechanical properties of PVA. Samples of sub-zero AM PVA, with different filament thicknesses, were tested under tension relative to the print direction, to calculate the storage and loss moduli. As the nozzle size was decreased, AM PVA exhibited more pronounced orthotropic properties; the smallest size showed a 33% decrease in storage moduli when tested perpendicular to the print direction, as opposed to parallel. This study has demonstrated the ability of sub-zero AM to tailor the orthotropic properties of PVA. Graphic abstract
- Published
- 2021
50. Primitive Chain Network Simulations of Entangled Melts of Symmetric and Asymmetric Star Polymers in Uniaxial Elongational Flows
- Author
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Giovanni Ianniruberto, Giuseppe Marrucci, Yuichi Masubuchi, Masubuchi, Y., Ianniruberto, G., and Marrucci, G.
- Subjects
Chemical Physics (physics.chem-ph) ,Nonlinear rheology ,Molar mass ,Materials science ,Polymer dynamic ,Mechanical Engineering ,FOS: Physical sciences ,Viscoelasticity ,Linear molecular geometry ,Mechanics ,Condensed Matter - Soft Condensed Matter ,Star (graph theory) ,Condensed Matter Physics ,Stress (mechanics) ,Nonlinear system ,Viscosity ,Experimental uncertainty analysis ,Molecular simulation ,Mechanics of Materials ,Physics - Chemical Physics ,Soft Condensed Matter (cond-mat.soft) ,Branched polymer ,General Materials Science - Abstract
Ianniruberto and Marrucci developed a theory whereby entangled branched polymers behave like linear ones in fast elongational flows. In order to test such prediction, Huang et al. performed elongational measurements on star polymer melts, indeed revealing that, in fast flows, the elongational viscosity is insensitive to the molecular structure, provided the molecular weight of the backbone is the same. Inspired by these studies, we here report on results obtained with multi-chain slip-link simulations for symmetric and asymmetric star polymer melts, as well as calculations of the Rouse time of the examined branched structures. The simulations semi-quantitatively reproduce the experimental data if the Kuhn-segment orientation-induced reduction of friction (SORF) is accounted for. The observed insensitivity of the nonlinear elongational viscosity to the molecular structure for the same span molar mass may be due to several factors. In the symmetric case, the calculated Rouse time of the star marginally differs from that of the linear molecule, so that possible differences in the observed stress fall within the experimental uncertainty. Secondly, it is possible that the flow-induced formation of hooked star pairs makes the effective Rouse time of the aggregate even closer to that of the linear polymer because the friction center moves towards the branchpoint of the star molecule. In the asymmetric case, it is shown that the stress contributed by the short arms is negligible with respect to that of the long ones. However, such stress-reduction is balanced by a dilution effect whereby the unstretched arms reduce SORF as they decrease the Kuhn-segment order parameter of the system. As a result of that dilution, the stress contributed by the backbone is larger. The two effects compensate one another so that the overall stress is virtually the same as the other architectures., 19 pages, 6 figures
- Published
- 2021
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