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The axial tensile properties of FRP mesh-reinforced ECC composites (TRE) were investigated experimentally under the consideration of four influencing factors: grid type, number of reinforcement layers, ECC matrix thickness, and sticky sand treatment on the grid surface. The test results showed that the axial stiffness and tensile strength of the composite were significantly increased, and the tensile properties were significantly improved under the effect of FRP grid reinforcement. Increasing the thickness of the ECC matrix can obviously improve the crack resistance of composites. The ultimate tensile strength of FRP lattice-reinforced ECC composites increased significantly with the increase in the number of lattice layers, but had no significant effect on the crack resistance. The tensile properties of CFRP grid-reinforced ECC composites were slightly better compared to BFRP grid-reinforced ECC composites. The crack resistance and ultimate tensile strength of the composites were slightly improved by impregnating the surface of the FRP grid with adhesive-bonded sand treatment. Based on the experimental data, the tensile stress–strain constitutive model of FRP grid-reinforced ECC composites is established. The calculation results show that the theoretical values of the model agree well with the experimental values. Therefore, it can be used to reflect the stress–strain change state of FRP lattice-reinforced ECC composites during axial tension.

The paper presents the results of experimental testing of six masonry rings built to technical scale and strengthened with CFRP strips and sheets and also with an FRCM system with PBO, glass, basalt and carbon fibers. The rings were subjected to tensile loads induced by four hydraulic jacks. The assumption is that the masonry rings are a representative simplification of domes, especially their structural support. Both single layered domes and ribbed domes are exposed to tensile stress in up to one third of their height.During the tests, the following information was collected: loads, displacements, strains of composites and failure modes. In some cases, an initial prestressing of reinforcements was carried out. Recommendations and limitations related to the use of the materials tested for reinforcing round, masonry structures under tensile stresses are discussed. The criterion for choosing the best solution was not only based on comparing the tensile strength of the reinforcement but also its stiffness. A strengthening efficiency index is proposed. The assessment of strengthening effectiveness was carried out, taking into account also heritage building conservation standards. Adopting the EF indicator as the criterion for assessing the effectiveness of reinforcement, it can be concluded that the application of the following methods should be considered in the structural maintenance of historical buildings: PBO mesh reinforcement in the PBO-FRCM system, carbon mesh reinforcement in the C-FRCM system and also basalt reinforcement in the B-FRCM system.

Composites can be manufactured in numerous ways. Among the available methods, Automated Fiber Placement (AFP) is the most advanced and latest technology utilized by companies for aerospace and other projects. Although it offers many benefits, it has unique manufacturing challenges and quality issues. The presence of tow placement defects such as tow gaps, tow overlaps, twisted tows, incomplete tows, and missing tows in the AFP process are causes for concern as these lead to a decrease in the mechanical performance of the fabricated parts. Although it is not possible to completely avoid the occurrence of defects, optimizing key process parameters is a possible way to minimize them. Roller pressure is one such parameter. If it is too high, it can lead to wider and thinner tows and if it is too low, the towpreg may not stick properly to the substrate and hence, not conform to curvatures. In this work, test layups of different configurations using carbon (T700SC-24K-50C) towpreg with epoxy (UF 3376-100) as the matrix system were prepared at different compaction roller pressures (2 bar, 3.5 bar, and 5 bar), with and without the presence of base prepreg layers. Tensile and bending tests were respectively carried out according to ASTM D3039 and ASTM D7264 to study the effects of these process parameters on the layup defects. From the test results, it is found that using a compaction roller pressure of 3.5 bar and a base prepreg layer of the same material as the towpreg, leads to minimum defects, and hence, to the best tensile and bending properties.

A multiscale approach comprising laminate-scale finite-element (FE) analysis and fiber-diameter-scale periodic unit cell (PUC) analysis was developed to predict matrix microcracking in quasi-isotropic laminates; further, this method was validated through comparison of our predictions with experimental results. In the mesoscopic FE analysis, the nonlinear deformation in the unidirectional laminae was incorporated to reproduce the deformation behavior of the laminate and obtain deformation histories at the locations of expected crack initiation in the laminate. In the microscopic analysis, the nonlinear behavior and crack initiation in the matrix resin were simply modeled by an elasto-viscoplastic law and a stress-based failure criterion, respectively. To predict crack initiation considering both the macroscopic deformation fields and the microscopic heterogeneity of the material, the mesoscopic FE analysis was conducted first. Subsequently, the microscopic PUC analysis was undertaken based on the strain histories obtained from the mesoscopic analysis. Our multiscale approach was applied to quasi-isotropic laminates with several laminate configurations to predict the matrix cracks in the 90∘ ply of the laminates. In addition to referring to experimental data cited in literature, initial and transverse cracks were observed when conducting tensile tests of quasi-isotropic laminates using the in situ replication technique and ex situ X-ray computed tomography. Through comparison of the predicted values with experimental results quoted in literature and obtained in this work, we validated the prediction capability of our multiscale analysis and evaluated the process of crack formation from the mesoscopic and microscopic points of view. Moreover, we examined the sensitivity of the predicted results to fiber arrangement and the influence of constitutive and failure modeling of the two-scale analysis on the predicted cracking strains. The reported method can predict initial and transverse cracks on quasi-isotropic laminates; further, it depicts the damage progress wherein microcrack nucleation and coalescence occurring before the full-width transverse cracking in laminated composites are observed under tensile loading conditions.

The file attached to this record is the author's final peer reviewed version. The Publisher's final version can be found by following the DOI link. Digital manufacturing was employed to 3D print continuous Carbon, Glass and Kevlar fibre reinforced composites in Unidirectional (UD) [0°], Off-axis ±45° and Cross-ply [0°/90°] layup sequence. These 3D printed composites were subjected to quasi-static, in-plane tension and out-of-plane (compression and shear) loading. The tensile strength of 3D printed Carbon, Glass and Kevlar UD laminates was significantly lower than that of 3D printing filaments used to manufacture them. The type of fibre (brittle/ductile) reinforcement was found to be governing the shear yield strength of 3D printed composites despite having the same Nylon matrix in all the composites. Out-of-plane compressive strength of the 3D printed Carbon and Glass fibre reinforced composites was independent of specimen size. Contrary to that, Kevlar fibre composites showed a pronounced size effect upon their out-of-plane compressive strength. A combination of X-ray tomography and pressure film measurements revealed that the fibres in 3D printed composites failed by ‘indirect tension’ mechanism which governed their out-of-plane compressive strength. To gain further insights on the experimental observations, Finite Element (FE) simulations were carried out using a pressure-dependent crystal plasticity framework, in conjunction with an analytical model based on shear-lag approach. Both FE and analytical model accurately predicted the out-of-plane compressive strength of all (Carbon, Glass and Kevlar fibre reinforced) 3D printed composites.

Development of composite materials has increased rapidly in different fields of sciences. This offers new structures of reinforcement materials and risen. More recently, the use of nanomaterials as reinforcement materials has proliferated. This research studies the mechanical properties and electrical characteristics of hybrid composite materials. Glass reinforced epoxy (GRE) was used as a basic composite in addition to the nanomaterial which was mixed with the risen using different percentages. Multi-wall carbon nanotubes (MWCNT) and Silica (Silicon Dioxide SiO2) were used as nano-particles. The ratios of nano-particles used to reinforce the Epoxy were (0.1, 0.2, and 0.5%) of weight ratio for MWCNT and (1, 2, and 5%) of weight ratio for Silica nanoparticles (SiO2). The results showed that the ultimate strength for GRE with 0.1 wt%MWCNT-1 wt%SiO2 was the highest, while Young’ modulus for GRE with 0.2 wt%MWCNT-2 wt%SiO2 was the highest. In addition, the samples with 0.1 wt%MWCNT-1 wt%SiO2 showed a magnificent value of electric conductivity. Having finished the mechanical tests, the fracture surfaces were comparatively examined using scanning electron microscopy (SEM).

In recent years, buried bellows have often had safety accidents such as pipeline bursts and ground subsidence due to the lack of adequate mechanical properties and other quality problems. In order to improve the mechanical properties of bellows, fly ash (FA) was used as a reinforced filler in high density polyethylene (HDPE) to develop composites. The FA was surface treated with a silane coupling agent and HDPE-g-maleic anhydride was used as compatibilizer. Dumbbell-shaped samples were prepared via extrusion blending and injection molding. The cross-section morphology, thermal stability and mechanical properties of the composites were studied. It was observed that when 10% modified FA and 5% compatibilizer were added to HDPE, the tensile yield strength and tensile breaking strength of the composites were nearly 30.2% and 40.4% higher than those of pure HDPE, respectively, and the Young’s modulus could reach 1451.07 MPa. In addition, the ring stiffness of the bellows was analyzed using finite element analysis. Compared with a same-diameter bellows fabricated from common commercially available materials, the ring stiffness increased by nearly 23%. The preparation method of FA/HDPE is simple, efficient, and low-cost. It is of great significance for the popularization of high-performance bellows and the high value-added utilization of FA.

open access article Municipal solid waste (MSW) contains plastic waste that can be used as a sustainable green substitute to reduce oil footprints, CO2 emissions, and environmental pollution. This study aims to recycle plastic waste by manufacturing wood-plastic composites and to improve its mechanical properties by using additives, coupling agents, and lubricants. These composites are prepared by mixing 40–70% of wood flour with 20–25% of a polymer matrix. Wood was degraded at 220 C, and then the composites were processed at 50 C. The manufacturing process carried out in the study involved wood waste meshing, drying, shredding, drying, trimming, filling, blending, compounding, and extrusion moulding. The compounding of composites was accomplished in twin-screw extruders. Once the mixture was uniformly mixed, its final shape was given by a two-step extrusion moulding. Previously, researchers aimed at enhancing the mechanical properties of the composites, but our research focus was to improve their durability for different industrial applications. The results suggest that the impact strength is 17 MPa with 50% of wood powder ratio while the maximum value for the tensile strength is 32.5 MPa. About 50% of an increase in wood powder resulted in 8.1% bending strength increase from 26.1 to 32.8 MPa. Reducing the plastic matrix and the woodparticles water swelling ratio resulted in better mechanical properties. The wood species also affected the mechanical properties with their excellent dimensional stability and less variability. A high proportion of wood fibre tends to increase its steady-state torque and viscosity. The mechanical properties against different wood-flour proportions indicate that composite materials exhibit superior water swelling behaviour and extrusion quality.

In this study, Young’s modulus of henequen fibers was estimated through micromechanical modeling of polypropylene (PP)-based composites, and further corroborated through a single filament tensile test after applying a correction method. PP and henequen strands, chopped to 1 mm length, were mixed in the presence of maleic anhydride grafted polypropylene (MAPP). A 4 wt.% of MAPP showed an effective enhancement of the interfacial adhesion. The composites were mold-injected into dog-bone specimens and tensile tested. The Young’s modulus of the composites increased steadily and linearly up to 50 wt.% of fiber content from 1.5 to 6.4 GPa, corresponding to a 327% increase. Certainly, henequen fibers showed a comparable stiffening capacity of PP composites than glass fibers. The intrinsic Young’s modulus of the fibers was predicted through well established models such as Hirsch or Tsai-Pagano, yielding average values of 30.5 and 34.6 GPa, respectively. The single filament test performed to henequen strands resulted in values between 16 and 27 GPa depending on the gauge length, although, after applying a correction method, a Young’s modulus of 33.3 GPa was obtained. Overall, the present work presents the great potential for henequen fibers as PP reinforcement. Moreover, relationships between micromechanics models and filament testing to estimate Young’s modulus of the fibers were explored.

Elastic hydrogel is a promising material category for designing biological muscles, repairable building materials, flexible electronic devices, and vulcanized rubber substitutes, which is required to have a long life, good self‐healing performance and extreme temperature tolerance. Herein, a super‐elastic mineral hydrogel is developed with long‐lasting moisture, based on dynamic physical crosslinking between hydrated calcium ion clusters and amide groups of polyacrylamide (PAM). The complex hydrogel exhibits a super stretchability of 13 600% at room temperature, and can maintain the super flexibility in a wide temperature range of −40–50 °C or for a long period of 28 days. Particularly, the soft material cannot be ignited under an open flame at 400–500 °C, because of coupling dual flame retardant mechanisms containing the endothermic effect of liquid water evaporation and the barrier effect of calcium mineral salt on oxygen. In conclusion, the novel complex hydrogel with excellent tensile property, stability in extreme temperature or long operating time, and flame retardancy may become a promising candidate in the fields of agriculture, food, construction, medicine, and machinery., Dynamic physical crosslinking of calcium (II) with in situ polymerized polyacrylamide provides a new mechanism for stress/energy dispersion of soft materials during stretching. As‐prepared complex hydrogel exhibits stable mechanical performance for a long‐term or under extreme temperature, and has ideal flame‐retardant ability due to the water‐locking effect of calcium (II) and barrier effect on oxygen.

In this work, to fabricate a novel composite consisting of chitosan/poly-lactic acid doped with graphene oxide (CS/PLA-GO), composites were prepared via solution blending method to create various compositions of CS and PLA (90/10, 70/30 and 50/50CS/PLA-GO). Graphene oxide (GO) was added into a PLA solution prior to blending it with chitosan (CS). The surface morphology and structural properties of synthesized composites were characterized using FT-IR, SEM and XRD analysis. The performances of synthesized composites on thermal strength, mechanical strength, water absorption, and microbial activity were also evaluated through standard testing methods. The morphology of 70/30CS/PLA-GO became smoother with the addition of GO due to enhanced interfacial adhesion between CS, PLA and GO. The presence of GO has also improved the miscibility of CS and PLA and has superior properties compared to CS/PLA composites. Moreover, the addition of GO has boosted the thermal stability of the composite, with a significant enhancement of Td and Tg. The highest Td and Tg were accomplished at 389 °C and 76.88 °C, respectively, for the 70/30CS/PLA-GO composite in comparison to the CS and PLA that recorded Td at 272 °C and 325 °C and Tg at 61 °C and 60 °C, respectively. In addition, as reinforcement, GO provided a significant influence on the tensile strength of composites where the tensile modulus showed remarkable improvement compared to pure CS and CS/PLA composites. Furthermore, CS/PLA-GO composites showed excellent water-barrier properties. Among other compositions, 70/30CS/PLA revealed the greatest decrement in water absorption. From the antibacterial results, it was observed that 90/10CS/PLA-GO and 70/30CS/PLA-GO showed an inhibitory effect and had wide inhibition zones which were 8.0 and 8.5 mm, respectively, against bacteria Bacillus Subtillis B29.

International audience; Retting of fibrous plants such as flax is an essential step in the extraction of fibre bundles and their transformation into textiles and reinforcement fabrics for use in garments and composites. Dew-retting is traditionally performed from Northwest France to the Netherlands, as the climate is highly favourable for this process. Hemp is a plant that can be grown almost all over Europe with a low environmental impact. A retting step is also required to facilitate the separation of the hemp fibres before their transformation into textiles for garments or for 1D to 3D reinforcement composites, which requires thoroughly separated fibres. Dew-retting is currently used in flax production zones. The present work demonstrates that dew retting can be conducted under different climates on different soils, from dry Mediterranean environments up to the cooler regions of eastern France. If the ternary combination of moisture, temperature and solar radiation is appropriate, field retting (dew-retting) can be as short as about three weeks. In less favourable conditions, such as in dryer areas or when retting is performed late in the season after seed maturity (cooler temperatures), it lasts longer, but it can reach suitable levels. When conducted with care and with proper monitoring of the retting level, the dew-retting process does impact neither the tensile properties of elementary hemp fibres (by degrading crystalline cellulose I) nor the tensile properties of unidirectional and injected composite materials. Consequently, if extracted with a suitable process such as scutching and hackling, fibres suitable for load-bearing composites can be produced from dew-retted hemp stems produced in a wide range of climates and locations, therefore not limited to the conventional “dew retting zone” of flax production areas.

A spring element model that takes into account the dynamic effects associated with fibre failure in composite materials is presented. The model is implemented in a parallel environment to allow a better performance in the prediction of the complex mechanisms associated with longitudinal tensile failure. The model is used to identify the changes in the stress fields around a broken fibre representing fibre failure as a dynamic phenomenon. In light of these changes in the stress fields, the cluster formation and failure development is analysed and the results are compared with the static spring element model. It is observed that the stress redistribution around a broken fibre is strongly dependent on the dynamic effects and it varies with the material in study, specially if the matrix is considered linear elastic. The changes in local stress redistribution are seen to affect the materials tensile behaviour and cluster formation, being this changes higher for a material with an elastic matrix.

This paper presents an analytical model to predict the stress redistribution around broken fibres in hybrid polymer composites. The model is used under the framework of a progressive failure approach to study the load redistribution around breaks in hybrid composites. The outcomes of the model are validated by comparing it with a spring element model. Moreover, the approach is further used to study the tensile behaviour of different hybrid composites. The results obtained show that the load redistribution around breaks depends on the stiffness ratio between both fibres as well as the matrix behaviour considered and the hybrid volume fraction. Furthermore, the different material parameters have a large effect on the tensile behaviour, with an increase of ductility achieved if the failure process of the two fibres is gradual.

In this paper, as-extruded ( $\sim \!\!1\mu \text{m}\,\,+\!\sim \!\!60$ nm) bimodal size SiC particle (SiCp) reinforced magnesium matrix composite was subjected to step-by-step tensile treatment. The microstructure evolution and fracture characteristic of the composites were investigated. The experimental results indicated that the dislocations were accumulated mainly around the particles. Meanwhile, dislocation density increased with the strain increasing from 0% to 2.6% and hence, improved the tensile strength of the composite. According to the observation of the fracture process for the composites, the twinning was observed (away from the $\sim 1\mu \text{m}$ SiCp). The dominant microcrack nucleation easily occurred at the interface between $\sim 1\mu \text{m}$ SiCp( $\alpha $ -SiCp) and Mg matrix due to the stress concentration (which was caused by large size particle and the polygonal morphology). However, a good interface bonding between nano SiCp ( $\beta $ -SiCp) and matrix was indicated, and no microcracks were initiated around $\beta $ -SiCp. The fracture features of the composite show that the existence of $\beta $ -SiCp is helpful to improve the tensile properties, which is explained by the mechanisms such as the crack-propagation, obstruction, and crack blunting.

© 2018. This version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ Fabric Reinforced Cementitious Matrix (FRCM) is a composite strengthening material used to strengthen masonry and concrete structures in a passive way due to the requirement of crack activation. Prestressing fabric is proposed to overcome this limitation, to increase the cracking strength and to obtain a stiffer response. With this aim, over 200 tensile tests on FRCM specimens were performed to analyse the influence of prestressing fabrics. Other variables, like fixation system, testing speed, matrix material and fabric material, were also discussed. Evidences lead to conclude that prestressing fabric of FRCM is an effective way to increase its tensile cracking strength (over 30%) and tensile stiffness.

In this work, boron carbide and graphene nanoparticle composite material (B4C–G) was investigated using an experimental approach. The composite material prepared with the two-step stir casting method showed significant hardness and high melting point attributes. Scanning electron microscopy (SEM), along with energy dispersive X-ray spectroscopy (EDS) analysis, indicated 83.65%, 17.32%, and 97.00% of boron carbide + 0% graphene nanoparticles chemical compositions for the C-atom, Al-atom, and B4C in the compound studied, respectively. The physical properties of all samples’ B4C–G like density and melting point were 2.4 g/cm3 density and 2450 °C, respectively, while the grain size of B4C–G was in the range of 0.8 ± 0.2 µm. XRD, FTIR, and Raman spectroscopic analysis was also performed to investigate the chemical compositions of the B4C–G composite. The molding press composite machine was a fabrication procedure that resulted in the formation of outstanding materials by utilizing the sintering process, including heating and pressing the materials. For mechanical properties, high fracture toughness and tensile strength of B4C–G composites were analyzed according to ASTM standard designs. The detailed analysis has shown that with 6% graphene content in B4C, the composite material portrays a high strength of 134 MPa and outstanding hardness properties. Based on these findings, it is suggested that the composite materials studied exhibit novel features suitable for use in the application of shielding frames.

Many models for prediction of longitudinal tensile failure of unidirectional (UD) composites have been developed in the last decades. These models require significant assumptions and simplifications, but their consequences for the predictions are often not clearly understood. This paper therefore presents a blind benchmark of seven different models applied to two virtual materials. Reliably capturing the localisation of stress concentrations was vital in predicting the effect of matrix stiffness and strength on composite failure strain and strength as well as fibre break and cluster development. Although the models have different assumptions regarding stress redistributions around fibre breaks, the 2-plet (clusters of two fibre breaks) development was similar. Distance-based criteria were shown to be inadequate for monitoring cluster development. The discussions provide detailed insight into how the model assumptions are linked to the differences in the predictions. European Union’s Horizon 2020 research and innovation programme published

In this paper, an extensive simulation program is conducted to find out the optimal ANN model to predict the shear strength of fiber-reinforced polymer (FRP) concrete beams containing both flexural and shear reinforcements. For acquiring this purpose, an experimental database containing 125 samples is collected from the literature and used to find the best architecture of ANN. In this database, the input variables consist of 9 inputs, such as the ratio of the beam width, the effective depth, the shear span to the effective depth, the compressive strength of concrete, the longitudinal FRP reinforcement ratio, the modulus of elasticity of longitudinal FRP reinforcement, the FRP shear reinforcement ratio, the tensile strength of FRP shear reinforcement, the modulus of elasticity of FRP shear reinforcement. Thereafter, the selection of the appropriate architecture of ANN model is performed and evaluated by common statistical measurements. The results show that the optimal ANN model is a highly efficient predictor of the shear strength of FRP concrete beams with a maximum R2 value of 0.9634 on the training part and an R2 of 0.9577 on the testing part, using the best architecture. In addition, a sensitivity analysis using the optimal ANN model over 500 Monte Carlo simulations is performed to interpret the influence of reinforcement type on the stability and accuracy of ANN model in predicting shear strength. The results of this investigation could facilitate and enhance the use of ANN model in different real-world problems in the field of civil engineering.

We performed in-situ tensile tests on two carbon fibre/epoxy composites with continuous scanning using synchrotron computed tomography (CT). Both composites were cross-ply laminates, and two specimens were tested for each compos- ite. The voxel size was sufficiently small to recognize individ- ual fibres and fibre breaks. For each test, 16-19 volumes were reconstructed, cropped down to the 0° plies and analysed to track fibre break and cluster development. This dataset provides the last CT volume before failure for each of the four specimens as well as the individual fibre break locations in all reconstructed volumes. These data are then plotted against predictions from six state-of-the-art strength models. The target is that these data become a benchmark for the development of new models, inspiring researchers to set up refined experiments and develop improved models. © 2021 Published by Elsevier Inc. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/)

Carbonized elastomer-based composites (CECs) possess a number of attractive features in terms of thermomechanical and electromechanical performance, durability in aggressive media and facile net-shape formability, but their relatively low ductility and strength limit their suitability for structural engineering applications. Prospective applications such as structural elements of micro-electro-mechanical systems MEMS can be envisaged since smaller principal dimensions reduce the susceptibility of components to residual stress accumulation during carbonization and to brittle fracture in general. We report the results of in situ in-SEM study of microdeformation and fracture behavior of CECs based on nitrile butadiene rubber (NBR) elastomeric matrices filled with carbon and silicon carbide. Nanostructured carbon composite materials were manufactured via compounding of elastomeric substance with carbon and SiC fillers using mixing rolling mill, vulcanization, and low-temperature carbonization. Double-edge notched tensile (DENT) specimens of vulcanized and carbonized elastomeric composites were subjected to in situ tensile testing in the chamber of the scanning electron microscope (SEM) Tescan Vega 3 using a Deben microtest 1 kN tensile stage. The series of acquired SEM images were analyzed by means of digital image correlation (DIC) using Ncorr open-source software to map the spatial distribution of strain. These maps were correlated with finite element modeling (FEM) simulations to refine the values of elastic moduli. Moreover, the elastic moduli were derived from unloading curve nanoindentation hardness measurements carried out using a NanoScan-4D tester and interpreted using the Oliver–Pharr method. Carbonization causes a significant increase of elastic moduli from 0.86 ± 0.07 GPa to 14.12 ± 1.20 GPa for the composite with graphite and carbon black fillers. Nanoindentation measurements yield somewhat lower values, namely, 0.25 ± 0.02 GPa and 9.83 ± 1.10 GPa before and after carbonization, respectively. The analysis of fractography images suggests that crack initiation, growth and propagation may occur both at the notch stress concentrator or relatively far from the notch. Possible causes of such response are discussed, namely, (1) residual stresses introduced by processing, (2) shape and size of fillers, and (3) the emanation and accumulation of gases in composites during carbonization.

Initial fibre misalignment is recognised to be one of the precursors leading to longitudinal compressive failure in fibre-reinforced composites. Thus, to properly model their mechanical behaviour, an accurate spatial representation of the fibrous reinforcements must be assured. This work presents a three-dimensional micromechanical framework that is capable of analysing in detail the longitudinal tensile and compressive failure mechanisms which are inherent in unidirectional composites. This is achieved through the incorporation of initial fibre waviness via a combination of a stochastic process and an optimisation procedure. A robust micro-scale framework is developed by assigning, to both constituents and their interface, proper thermodynamically consistent damage models. Several microstructures having different degrees of misalignment are modelled and a clear trend is observed for the longitudinal compressive load case, i.e. by increasing initial fibre misalignment, the overall performance of the material decreases. In contrast, the models subjected to longitudinal tension exhibit a similar overall response, despite the misalignment. However, local mechanisms seem to change with the degree of friction and fibre misalignment, but these smaller-scale mechanisms do not play a decisive role on the overall longitudinal tensile performance of the material.

The need to protect the environment has generated, in the past decade, a competition at the producers&rsquo, level to use, as much as possible, natural materials, which are biodegradable and compostable. This trend and the composite materials have undergone a spectacular development of the natural components. Starting from these tendencies we have made and studied from the point of view of mechanical and chemical properties composite materials with three types of hybrid matrix based on the Dammar natural hybrid resin and two types of reinforcers made of flax fabric. We have researched the mechanical properties of these composite materials based on their tensile strength and vibration behavior, respectively. We have determined the characteristic curves, elasticity modulus, tensile strength, elongation at break, specific frequency and damping factor. Using SEM (Scanning Electron Microscopy) analysis we have obtained images of the breaking area for each sample that underwent a tensile test and, by applying FTIR (Fourier Transform Infrared Spectroscopy) and EDS (Energy Dispersive Spectroscopy) analyzes, we have determined the spectrum bands and the chemical composition diagram of the samples taken from the hybrid resins used as a matrix for the composite materials under study. Based on the results, we have suggested that these composite materials could be used in different fields of activity.

When obtaining environment-friendly hybrid resins made of a blend of Dammar natural resin, in a prevailing volume ratio, with epoxy resin, it is challenging to find alternatives for synthetic resins. Composite materials reinforced with waste paper and matrix made of epoxy resin or hybrid resin with a volume ratio of 60%, 70% and 80% Dammar were studied. All samples obtained have been submitted to tensile tests and Scanning Electron Microscopy (SEM) analysis. The tensile response, tensile strength, modulus of elasticity, elongation at break and the analysis of the fracture surface were determined. The damping properties of vibrations of bars in hybrid resins and in the composite materials under study were also examined. The mechanical properties of the four types of resins and of the composite materials were compared. The chemical composition for a hybrid resin specimen were obtained using the Fourier Transformed Infrared Spectroscopy (FTIR) and Energy, Dispersive X-ray Spectrometry (EDS) analyzes.

The utilization of polymer-based materials is quickly expanding. The enterprises of today are progressively seeking techniques to supplant metal parts with polymer-based materials as a result of their light weight, simple support and modest costs. The ceaselessly developing requirement for composite materials with new or enhanced properties brings about the preparation of different polymer mixes with various arrangements, morphologies and properties. Fused filament fabrication processes such as 3D-printing are nowadays shaping the actual pathway to a full pallet of materials, from art&ndash, craft to biomaterials. In this study, the structural and mechanical behavior of three types of commercially available filaments comprised of synthetic poly(acrylonitrile-co-butadiene-co-styrene) (ABS), poly(lactic acid) (PLA) and poly(lactic acid)/polyhydroxyalkanoate reinforced with bamboo wood flour composite (PLA/PHA BambooFill) were assessed through mechanical testing and optical microscopy, aiming to understand how the modifications that occur in the printed models with internal architecture are influencing the mechanical properties of the 3D-printed material. It has been determined that the material printed from PLA presents the highest compression strength, three-point bending and shock resistance, while the ABS shows the best tensile strength performance. A probability plot was used to verify the normality hypothesis of data for the tensile strength, in conjunction with the Anderson&ndash, Darling statistic test. The results of the statistic indicated that the data were normally distributed and that there is a marked influence of the internal architecture of the 3D-printed models on the mechanical properties of the printed material.

International audience; Knowledge of fibre strength is crucial for understanding the failure behaviour of fibre-reinforced composite materials and structures. Measuring the properties of technical fibres has been known to be very challenging, and the different challenges associated with single fibre characterisation are illustrated in this article. An improved and automated experimental methodology for tensile testing of single fibres is described. This process has been used to generate fibre strength data for T700 carbon fibres at three different gauge lengths of 4, 20 and 30 mm. The variability in strength and modulus of short fibres was found to be much larger than that of longer fibres. Statistical analysis of this large data set has also highlighted the limitations of the standard Weibull distribution for representing fibre strength behaviour. The need for a better statistical representation of the fibre strength data in order to provide a more accurate description of the fibre strength behaviour has been emphasized.

The strength of the interphase between the reinforcements and the matrix has a major role in the mechanical properties of natural fiber reinforced polyolefin composites. The creation of strong interphases is hindered by the hydrophobic and hydrophilic natures of the matrix and the reinforcements, respectively. Adding coupling agents has been a common strategy to solve this problem. Nonetheless, a correct dosage of such coupling agents is important to, on the one hand guarantee strong interphases and high tensile strengths, and on the other hand ensure a full exploitation of the strengthening capabilities of the reinforcements. The paper proposes using topographic profile techniques to represent the effect of reinforcement and coupling agent contents of the strength of the interphase and the exploitation of the reinforcements. This representation allowed identifying the areas that are more or less sensitive to coupling agent content. The research also helped by finding that an excess of coupling agent had less impact than a lack of this component This research was funded by the Chair on Sustainable Industrial Processes of the University of Girona, ref 01/2019

Despite the good mechanical properties of natural fibre composites, their use in load-bearing components is still limited, which may be due to lack of knowledge and confidence in calculating the performance of the composites by mechanical models. The present study is providing an experimental evaluation of stiffness predictions of multiaxial flax fibre composite by classical laminate theory (CLT). The experimental base is (i) multiaxial flax fibre composites fabricated with two types of biaxial non-crimp fabrics, having a nominal yarn orientation of ±45°, and (ii) uniaxial flax fibre composites fabricated with the same flax yarn as used in the fabrics. The fabricated composites are characterised by volumetric composition, yarn orientation and tensile properties. A fast and easy operational Fast Fibre Orientation (FFO) method is developed to determine the actual yarn orientation in fabrics and composites. It is demonstrated that the FFO method is a robust method, giving repeatable results for yarn orientations, and it can be used both on fabrics and composites. CLT predictions of stiffness of the multiaxial flax fibre composites are shown to be in good agreement with the measured stiffnesses of the composites in three testing directions (0°, 45°, and 90°). The use of the actual yarn orientations measured by the FFO method, instead of the nominal yarn orientations of ±45°, is shown to result in improved CLT predictions of stiffness with a mean deviation between predictions and measurements on 0.2 GPa. Altogether, it is demonstrated that stiffness of multiaxial flax fibre composites can be accurately predicted by CLT, without any fitting constants, based on independently determined stiffness parameters of the related uniaxial flax fibre composite, and based on measured yarn orientations in the flax fibre fabric.

In this article, with the aim of promoting sustainability, contributing to the circular economy and the fight against climate change, the production of composite materials from Bio-polyethylene reinforced with corn stover fibers has been studied. The behavior of the materials obtained has been studied experimentally and by mathematical models of micromechanics. The composite materials were produced by extrusion and then injection with from 10 to 50 wt.% of fibers. The creation of a good fiber-matrix interface was studied by the incorporation of coupling agent between (0&ndash, 8 wt.%). Increase of 131.2% on tensile strength for 40wt.% reinforcement was achieved by adding 6 wt.% of coupling agent. The correct interface was demonstrated by a correlation of 0.99 between the experimental results and the results of the mathematical models used.

Thermal properties of acrylate-based composite combined with alumina-based particles were investigated. The composites were made of poly (methyl methacrylate) (PMMA) modified with dimethyl itaconate (DMI) as a matrix. Neat alumina particles (Al2O3) and alumina doped with iron oxide (Al2O3-Fe) modified with 3-aminopropyl-trimethoxylane (AM) and flax oil fatty acid methyl esters (biodiesel - BD) were used as reinforcement. Thermal conductivity measurements showed that composite with alumina particles with the highest alpha phase content had the highest thermal conductivity values. Mechanical properties (tensile strength, modulus of elasticity and elongation at break) were improved by the addition of modified alumina particles to PMMA/DMI matrix. The thermal properties are the most improved for composite with 3 wt.% Al2O3-Fe-AM particles that had the lowest temperature in a crack zone was noticed (10.28 %) compared to PMMA added due to the better stiffness and highest thermal conductivity.

© 2018 Elsevier Ltd The failure mechanism of ‘indirect tension’ is explored for cross-ply IM7/8552 carbon fibre/epoxy laminates subjected to quasi-static, out-of-plane compressive loading. The sensitivity of compressive response to strain rate and to the state of cure is measured, motivated by the hypothesis that the out-of-plane compressive strength is sensitive to the matrix shear strength. A pressure-sensitive film is placed between specimen and loading platen, and reveals that a shear lag zone of reduced compressive traction exists at the periphery of the specimen, giving rise to a size effect in compressive strength. The width of the shear lag zone reduces with increasing shear strength of the matrix. The laminates fail by the indirect tension mechanism: out-of-plane compressive loading generates tension in the fibre direction for each ply and ultimately induces fibre tensile failure. Finite element (FE) simulations and an analytical model are developed to account for the effect of matrix shear strength, specimen geometry, and strain rate on the out-of-plane compressive strength. Both the FE simulations and the analytical model suggest a recipe for increasing the through-thickness compressive strength.

In this work, conventional sulfur and two types of organic peroxides (dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB)) curing systems were used to investigate the possibility for tailoring of the performance properties of GTR/NBR blends reinforced with a variable content of highly dispersive silica (0–30 phr). The curing characteristics, static mechanical and acoustical properties, swelling behavior, thermal stability, and microstructure of the prepared composites were investigated. The results show that regardless of the curing system used, increasing the content of highly dispersive silica resulted in the improvement of the mechanical properties of the studied materials. It was observed that sulfur-based systems are the best choice in terms of cross-linking efficiency determined based on torque increment and cross-link density parameters. However, further analysis of the physico-mechanical properties indicated that the cross-linking efficiency does not match the performance of specimens, and the materials obtained using organic peroxides show higher tensile properties. This is due to the improved physical interactions between the GTR/NBR matrix and highly dispersive silica when using peroxide systems. It was confirmed using the analysis of the Wolff activity coefficient, indicating the enhanced synergy.

The present paper focuses on the configuration possibilities of post -processor influencing mechanical properties of a given test sample produced by the FDM printer from different materials. The research consists of assessing the composite material configurations through a static tensile test conducted on 80 samples produced. The samples were produced based on ISO 527-2 standard, type 1A, with a horizontal position and a layer height of 0.2 mm. The individual samples consisted of four basic groups of materials—the pure Polylactic acid (PLA) plastic (reference sample), and three composite samples with admixtures—PLA matrix with a copper admixture, PLA matrix with an iron admixture, and PLA matrix with a steel admixture. The static tensile test was conducted at a test speed of 5 mm/min. During the research, reference samples (pure PLA) were assessed in five orientations. Samples made of the PLA composite materials with admixtures were manufactured, tested, and evaluated only in the 0° orientation. The paper concludes by comparing the results of measurement with the original material, free from additives, and with the researched influence of the orientation of the prints on the resulting mechanical properties of shear samples and their surface structure. In the conducted experiments, the lowest tensile strength has been demonstrated in test samples the orbital transitions and the upper surface layers of which were parallel to the infill.

Stable silicon carbide whisker (SiCw) dispersion was obtained and used for the preparation of SiCw-modified cement-based composites. Strength tests including compression test, flexural test, split tensile and “8” shape tensile tests were carried out on the composites. Fracture properties of the material were measured by the pre-notched three-point bending test based on digital image correlation (DIC) method. The microstructure of the SiCw-modified cement mortar was observed by SEM. The results showed that SiCw could obviously improve tensile strength of the cement-based material. The addition of SiCw significantly improved fracture toughness of the cement-based material, as there was a crack deflection of the materials occurring during crack growth.

The results of four different bond tests, conducted on specimens made of bricks and fabric-reinforced cementitious matrix (FRCM) composite strips, are presented in this article. The composites consisted of a basalt textile embedded in four types of inorganic matrices: a commercial product made of lime mortar and three different mortars properly prepared in the laboratory. Bond tests were carried out to highlight variations in the bond behavior of the four composites. The experimental campaign, for all the tested composites, confirmed that the debonding mechanism occurs at the textile-matrix interface with large differences, in terms of load carrying capacity, between the four typologies of FRCM composite. In particular, composites made up of a commercial matrix were demonstrated to be the best ones to fully exploit the tensile strength, whereas composites made up of cement-lime mortar showed the worst bond behavior. Furthermore, the results of the four bond tests conducted on the same type of composite were compared to evaluate the reliability of the different types of bond tests. Among the apparatus used to conduct the four bond tests, the single shear test was demonstrated to be the most effective for determining the actual bond performances of FRCM composites.

The study focuses on the effect of alkaline and silane treatment of hemp fibers on mechanical and thermal conductivity. Hemp fibers were treated with sodium hydroxide solutions at different concentration, and then analysed by infrared Fourier transform spectroscopy, the X-ray diffraction, mechanical tensile test; and a scanning electron microscope. The alkali fibers were subsequently treated with silane solutions and then analysed by the same techniques. Analysis results showed that the most changes caused by this treatment are, the elimination of a certain amount of lignin, wax and oils spanning the cell wall of the fibers and the transformation of some quantity of alpha to beta cellulose. These changes are at the origin of improvement on tensile strength and young's modulus of about 39% and 23% respectively when the concentration of treatment reaches 8%. This modification revealed a strong increase in the Interfacial adhesion of the fibers-polyurethane composite from 1.26 MPa for untreated fibers up to 3.18 for the alkali fibers and 5.16 for silane fibers. Moreover, the measurement of the thermal conductivity has proved that the chemical treatment increase the fibers thermal conductivity from 42.22 mW/m°K for untreated fibers to 47, 92 mW/m°K for the alkali fiber at 8%.

The paper presents the assessment of a metakaolin-slag-sodium-silicate GeoPolymer (GP) grout as a matrix for bonding four bidirectional meshes made of basalt, glass, carbon fibres and two unidirectional ultra-high tensile strength steel fabrics to soft mud and strong extruded clay bricks for strengthening purposes. A detailed chemical/physical characterization of the geopolymer is given, evidencing the completion of the geopolymerization reaction and the good stability of the geopolymer to leaching, freeze-thaw cycles and high temperature treatments as well as its adequate mechanical properties. Pull-off tests proved the excellent adhesion strength of the geopolymer grout, also embedding meshes and fabric, to both types of clay bricks.

Despite cheap and sustainable in nature, the use of natural fiber composites is limited due to their high moisture absorption, poor fiber-matrix interface, and lack of data on evolution of properties when subjected to environmental factor such as temperature and humidity. The aim of this research is to study the interdependence of moisture regain, hydrophobic treatment, and the mechanical properties of jute fiber-reinforced composite materials. Composite samples made from treated and untreated jute fiber-reinforced composites were exposed to humid environment and their moisture regain, mechanical properties and fiber-matrix interface was tested at given time intervals until four weeks. The composites produced with hydrophobic treated reinforcement showed lesser moisture regain and improvement in the tensile and flexural strengths compared to untreated fabric composite. A clear improvement in fiber-resin interface was observed by scanning electronic microscopy. The dynamic mechanical analysis of treated and untreated composites was conducted in a temperature range 20-140 degrees C. An increase in the storage modulus of treated composite materials was noted as compared to untreated ones. Furthermore, it was concluded that developed composite loss their mechanical properties linearly with immersion time. However, this aging was slow in treated fabric composites especially hybrid fluorocarbon and fluorocarbon. Higher Education Commission of Pakistan - NRPU 4239

The current physical goods economy produces materials by extracting finite valuable resources without taking their end of the life and environmental impact into account. Modernity leaves us with devasted landscapes of depleted resources, waste landfill, queries, oil platforms. At the time of the Anthropocene, the various effects the human role has on the constitution of the soils create an acceleration of material entropy. It is the terrestrial entanglement of fungal materials that we investigate in this paper by offering an alternative fabrication paradigm based on the growth of resources rather than on extraction. Unlike the latter, biologically augmented building materials can be grown by combining micro-organisms such as fungal mycelium with agricultural plant-based waste. In this study, we investigate the production process, the mechanical, hygrothermal and chemical properties of mycelium-based composites with different types of lignocellulosic reinforcement fibres combined with a white rot fungus, Trametes versicolor. Together, they form an interwoven three-dimensional filamentous network binding the feedstock into a lightweight material. The mycelium-based material is heat-killed after the growing process. This is the first study reporting the dry density, the Young’s modulus, the compressive stiffness, the stress-strain curves, the thermal conductivity, the water absorption rate and a complete FTIR analyse of mycelium-based composites by making use of a disclosed protocol with T. versicolor and five different type of fibres (hemp, flax, flax waste, softwood, straw) and fibre conditions (loose, chopped, dust, pre-compressed and tow). These experimental results show that mycelium-composites can fulfil the requirements of thermal insulation. The thermal conductivity and water absorption coefficient of the mycelium composites with flax, hemp, and straw have an overall good insulation behaviour in all the aspects compared to conventional unsustainable materials. The conducted tests reveal that the mechanical performances of the mycelium-based composites depend more on the fibre condition, size, and processing than on the chemical composition of the fibres.Abstract FigureGraphical abstractHighlightsThe type of fibre influences the colonisation of mycelium: samples containing flax, hemp, straw and flax-waste resulted in a well-developed compositeThe type of fibre has a smaller influence on the compressive stiffness than the fibre processing and size.Pre-compression and chopped fibres (particle size The thermal conductivity and water absorption coefficient of the mycelium composites with flax, hemp, and straw have an overall good insulation behaviour in all the aspects compared to conventional unsustainable materials.