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Catalytic oxidation technology is a promising strategy to eliminate carbon monoxide (CO), volatile organic compounds (VOC) and other emissions from industrial boilers and to address ammonia (NH 3) escape. Herein, we demonstrate the potential of copper-cerium-zirconium mixed oxides or those supported on TiO 2 or ZSM-5 substrates for the simultaneous catalytic removal of CO, toluene and NH 3. Among them, CuCeZr/ZSM-5 exhibits the best co-processing ability for mixed gases. In situ infrared spectroscopy analyses suggest that there is a competitive adsorption among CO, toluene and NH 3 , and the inhibition is in descending order of toluene＞CO＞NH 3. Based on the physical-chemical characterizations, the Cu-Ce interfacial structure plays an important role in CO ignition at low temperatures. More importantly, the abundant acidic sites on the ZSM-5 support can improve the stability of adsorbed NH 3 at high temperatures, resulting in the best NH 3 catalytic oxidation performance of CuCeZr/ZSM-5 with no secondary pollutants of NO x. This study provides a strategy for the catalyst design to eliminate multiple pollutants targeting the properties of pollutants. [Display omitted] • Simultaneous removal of CO, toluene and NH 3 was achieved by CuCeZr based catalyst. • The best mixed gas treatment was observed for CuCeZr/ZSM-5 catalyst. • Cu-Ce interfacial structure allows preferential ignition of CO at low temperature. • The acidic sites on the ZSM-5 promoted the adsorption and oxidation of NH 3. [ABSTRACT FROM AUTHOR]