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Sixth generation (6G) wireless networks operating in terahertz frequency region are significant solutions to the increasing number of telecommunication devices and the demand for faster data transmission. However, few dielectric materials exhibiting an ultralow relative dielectric constant (εr), loss tangent (tanδ), and high mechanical strength are found suited for 6G telecommunication. In this study, we developed lightweight ceramic foams by directly sintering glass hollow spheres. The effects of sintering temperatures on their mechanical performance, and terahertz optical and dielectric properties were systematically investigated. The final compositions of ceramic foams contain glass, cristobalite, quartz, and wollastonite. The crystalline content increases with increasing sintering temperature. The ceramic foams sintered at low temperatures of 700–850°C exhibit a high porosity ranging from 74.6% to 87.3%, ultralow εr ranging from 1.41 to 1.83, and tanδ of ∼0.011 at 0.5 THz, as well as high compressive strength ranging from 10.1 to 27.4 MPa, which could be promising materials for 6G telecommunication. [ABSTRACT FROM AUTHOR]

Microwave and terahertz communications are increasingly significant, however, the lack of material information in terahertz band limits their development. Moreover, few lightweight materials with a high relative dielectric constant (εr) are found suited for satellite communication and wearable devices. In this study, we developed lightweight porous Ba4[(Sm0.1Nd0.9)0.9Bi0.1]28/3Ti18O54 (BSNBT) ceramics exhibiting a total porosity ranging from 6.3% to 26.5% (bulk density ranging from 5.47 to 4.29 g/cm3) and relatively high εr ranging from 85.6 to 56.8, which were obtained by sacrificial template method using polymethyl methacrylate spheres (PMMAs) of varying average particle sizes, from 9 to 34 μm, as sacrificial materials. A high refractive index ranging between 7.5 and 8.9 and a low absorption coefficient of approximately 17 cm−1 at 0.3 THz were obtained for the porous ceramics with different total porosities derived from PMMAs with average particle sizes of 9 and 19 μm. Furthermore, effective medium and Mie scattering theories were applied to understand the effects of porous structure on the dielectric properties in microwave and terahertz frequency ranges, respectively, owing to the different wavelengths in the BSNBT matrix. The results of this study suggest that introducing a porous structure can effectively exploit lightweight microwave dielectric ceramic materials and provide valuable information on their terahertz response mechanism. [ABSTRACT FROM AUTHOR]

In situ coagulation for yttria‐stabilized zirconia (YSZ) suspension via polyvinyl pyrrolidone (PVP) crosslink is reported. PVP is used to prepare sterically stabilized YSZ suspension. Influence of PVP on the dispersion of YSZ suspension was investigated. It indicates that well disperse YSZ suspension with 0.3 wt % PVP can be prepared. Dimethyl sulfate (DMS) was added at 40 °C to coagulate the suspension after degassing. Influence of DMS content and coagulation temperature on coagulation process and properties of green bodies were investigated. It indicates that sufficiently high viscosity to coagulate the suspension is achieved with the addition of 1 vol % DMS at 60~80 °C. The coagulation mechanism is proposed that the YSZ suspension is destabilized by the self‐crosslink of PVP. Coagulated samples with the highest wet compressive strength of 6.34 MPa could be demolded without deformation by treating 50 vol % YSZ suspension at 60 °C. Dense YSZ ceramics with relative density above 99.1% and flexural strength of 920 ± 90 MPa had been prepared by this method sintered at 1450 °C for 3 h. © 2020 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48889. [ABSTRACT FROM AUTHOR]

The weak compressive strength of dried ceramic foams is a disadvantage of fabricating ultralight ceramic foams, especially for the ceramic foams with porosity exceeding 95%. In this study, dried alumina foams were enhanced by agar and PVA-freezing-thawing using sodium dodecyl sulfate as surfactant. It is found that the two additives have no negative influence on adsorption of sodium dodecyl sulfate on alumina particles as well as the hydrophobic character of alumina particles. Stable alumina particle-stabilized foams were prepared with less than 0.5 wt% agar and 1.0 wt% PVA. High additive concentration above the critical values weakens stability of wet foams, which is probably due to the aggregate of alumina particles caused by long-chain molecules connecting. The compressive strength of dried alumina foams has a significant improvement with the employment of agar and PVA-freezing-thawing. The dried foams prepared with 1wt% PVA assisted by freezing-thawing has porosity of 97.1% and compressive strength of 0.16 MPa, which could maintain integrity of dried foams without destruction in the fabricating process. [ABSTRACT FROM AUTHOR]