Search

Your search keyword '"Lan, Yu"' showing total 1 results

Refine your results

1 results on '"Lan, Yu"'

1. With metal or not? a computationally predicted rule for a dirhodium catalyst in [3+3] cycloadditions of triazole with thiirane.

Author

Li, Shi-Jun, Li, Xue, Mo, Huilin, Qu, Ling-Bo, Wei, Donghui, and Lan, Yu

Subjects
*RHODIUM catalysts, *DENSITY functional theory, *RING formation (Chemistry), *CATALYSTS, *METALS, *CARBOXYLATES
Abstract

A mixture of pathways including the use of catalyst was proposed for a dirhodium-mediated triazole activation–cycloaddition. This proposal was supported by the results of density functional theory (DFT) calculations, and was indicated to involve a non-catalyzed cleavage of the triazole N–N bond followed by a dirhodium-assisted denitrogenation. Electron-deficient carboxylates were found to be favourable for the rate-determining denitrogenation step. [ABSTRACT FROM AUTHOR]

Published
2020
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results