1. Imidazole-imidazolate pair as organo-electrocatalyst for CO2 reduction on ZIF-8 material.
- Author
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Sassone, Daniele, Bocchini, Sergio, Fontana, Marco, Salvini, Clara, Cicero, Giancarlo, Re Fiorentin, Michele, Risplendi, Francesca, Latini, Giulio, Amin Farkhondehfal, M., Pirri, Fabrizio, and Zeng, Juqin
- Subjects
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ELECTROLYTIC reduction , *CARBON dioxide , *COMPUTER-aided design , *STANDARD hydrogen electrode , *DENSITY functional theory , *ACTIVATION (Chemistry) , *CARBON nanotubes - Abstract
[Display omitted] • The submitted work is of great interest for the Journal Applied Energy due to its peculiar theme, the electrochemical CO 2 reduction, and for its approach in the investigation. Indeed, a complete ab initio modelling guided the experimental synthesis and testing of a molecular electrocatalyst which shows great performances for the CO2RR. • This work elucidate the possibility to activate the CO 2 through organic molecules and, moreover, shows the feasibility of this approach to be completely integrated inside a TRL 3–4 electrolysis cell. The electrochemical reduction of CO 2 to value-added products is hindered by its thermodynamic stability and by the large energy required to chemically activate the molecule. With this respect, forcing CO 2 in a non-linear geometry would induce an internal electron charge rearrangement which would facilitate further electrochemical transformations. In this work, we achieved this goal through the design of a dual function electro-organocatalyst, which exploits the ability of the imidazolate (Im-) lone pair to bind CO 2 via nucleophilic attack and then electrochemically reduce it. To give structural stability to the Im- based catalyst, the imidazoles species are incorporated into a solid structure, namely ZIF-8. Once activated by the organic Im- ligand, CO 2 is electrochemically reduced to CO when a bias is applied to ZIF-8. The catalyst proposed in our study was first devised by computer aided design based on Density functional Theory simulations and then realized in laboratory. Our results demonstrate that ZIF-8 supported on conductive CNTs presents surface Im- active sites which convert CO 2 into CO with a high faradaic efficiency (70.4 %) at −1.2 V vs reversible hydrogen electrode, by combining chemical activation with electrochemical catalysis. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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