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Here, Fe- and Mn-modified biochar (BC-Fe–Mn) was applied to simultaneously stabilize As and Cd in the contaminated soil. The removal efficiencies for NaHCO3-extractable As and DTPA-extractable Cd by BC-Fe–Mn were 60.8% and 49.6%, respectively. The speciation analyses showed that the transformation to low-crystallinity Fe-bound (F3) As, Fe–Mn oxide-bound (OX) of Cd, and residual As and Cd was primarily attributed to stabilizing the two metal(loid)s. Moreover, the correlation analyses showed that the increase of As in F3 fraction was significantly and positively associated with the increase of OX fraction Mn (r = 0.64). Similarly, OX fraction Cd was increased notably with increasing OX fraction Fe (r = 0.91) and OX fraction Mn (r = 0.76). In addition, a novel dialysis experiment was performed to separate the reacted BC-Fe–Mn from the soil for intensively investigating the stabilization mechanisms for As and Cd by BC-Fe–Mn. The characteristic crystalline compounds of (Fe0.67Mn0.33)OOH and Fe2O3 on the surface of BC-Fe–Mn were revealed by SEM–EDS and XRD. And FTIR analyses showed that α-FeOOH, R-COOFe/Mn+, and O–H on BC-Fe–Mn potentially served as the reaction sites for As and Cd. A crystalline compound of MnAsO4 was found in the soil treated by BC-Fe–Mn in the dialysis experiment. Thus, our results are beneficial to deeper understand the mechanisms of simultaneous stabilization of As and Cd by BC-Fe–Mn in soil and support the application of the materials on a large scale. [ABSTRACT FROM AUTHOR]

Existing classic methods of analysing the monetary policy of the central bank, such as the aggregate response function, explain the behavior of the ECB in a rather simplified way. This is the result of the fact that classical methods do not consider the regional features of the members of the European Monetary Union and the structure of the system of central banks. The study of monetary policy with the involvement of macroeconomic theories of organization, theories of teams and coalition behavior, which are new for a macroeconomic subject, can make a significant contribution to the research process of European monetary integration. Since European integration is declared as a strategic direction of Ukraine's economic development, the analysis and generalization of the problem of the modern European economy in the context of the impact of Russia's war against Ukraine from 2022 is relevant. Therefore, in order to understand the problems and prospects of modernization of the functioning of the monetary and credit system in the EU, it is important to research and scientifically substantiate the stabilization mechanisms for Ukraine. The article investigates some stabilization mechanisms that are Ukraine Facility and Multi-Agency Donor Coordination Platform. Funding by Ukraine Facility is analysed through its pillars, components and implementation of main conditions for receiving benefits on the way of Ukrainian economy recovery. Multi-Agency Donor Coordination Platform for Ukraine, as innovative instrument for coordinating activities of its members, is researched on the base of its existing funding mechanisms: the G7 Finance Track, the G7+ Coordination Group on energy infrastructure and the International Financial Institutions (IFIs) Coordination Group. [ABSTRACT FROM AUTHOR]

Landslide dams, especially stable landslide dams, have been recognised as important contributors to regional geomorphological evolution. The eastern edge of the Tibetan Plateau provides good conditions for the formation of stable landslide dams. To identify stable landslide dams on the eastern margin of the Tibetan Plateau, the Google Earth Engine (GEE) was first used to map water surfaces in the study area. Then, stable landslide dams were identified using high-precision remote sensing images provided by Google Earth. A field investigation and a sampling of typical stable landslide dams were also adopted to characterise the landslide dams. The results show that 101 stable landslide dams are present in the study area, covering an area of 27.75 × 104 km2. There are four types of stable landslide dams, as follows: (1) landslides, (2) rock avalanches, (3) moraines, and (4) debris flows. The morphological parameters of a dam, which include dam height, dam width, dam volume, and catchment area, can be fitted with different relationship curves, with respect to the number of landslide dams. The source areas of landslide dams are generally located in the upper-middle and upper sections of adjacent mountains. The stability of a landslide dam is mainly controlled by the structure of the dam and the relationship between the dam volume and catchment area. Structurally, large rocks with large particle sizes are difficult to activate using river water and the large gaps between the rocks provide sufficient channels for the flow of river water. In regard to the relationship between the dam volume and catchment area, a river with a small catchment area in the study area is commonly blocked by a large dam volume. This study provides a unique opportunity to study the spatial distribution and clarify the factors influencing the stability of stable landslide dams. [ABSTRACT FROM AUTHOR]

AbstractThe potential utilization of starch as a particle-based emulsifier in the preparation of Pickering emulsions is gaining interest within the food industry. Starch is an affordable and abundant functional ingredient, which makes it an excellent candidate for the stabilization of Pickering emulsions. This review article focuses on the formation, stabilization, and properties of Pickering emulsions formulated using starch-based particles and their derivatives. First, methods of isolating and modifying starch-based particles are highlighted. The key parameters governing the properties of starch-stabilized Pickering emulsions are then discussed, including the concentration, size, morphology, charge, and wettability of the starch-based particles, as well as the type and size of the oil droplets. The physicochemical mechanisms underlying the ability of starch-based particles to form and stabilize Pickering emulsions are also discussed. Starch-based Pickering emulsions tend to be more resistant to coalescence than conventional emulsions, which is useful for some food applications. Potential applications of starch-stabilized Pickering emulsions are reviewed, as well as recent studies on their gastrointestinal fate. The information provided may stimulate the utilization of starch-based Pickering emulsions in food and other industries. [ABSTRACT FROM AUTHOR]

Stabilization mechanisms of partially premixed H 2 /air flames on a coaxial dual swirl injector are investigated at atmospheric conditions. Hydrogen is injected through a central duct, and the air by the outer annular channel. Both channels are swirled and two stabilization modes are observed depending on the geometrical configuration of the injector and on the operating conditions. In certain regimes, the H 2 /air flame stabilizes on the injector lips as a diffusion flame. For other operating conditions, the flame is lifted from the injector and burns mainly in partially premixed regime leading to limited NOx emissions. PIV measurements in cold flow conditions and direct observations of the flame indicate that the flame stabilization mode is mainly controlled by the inner hydrogen swirl level, the injector recess and the hydrogen velocity. For a given air flowrate, a minimum hydrogen velocity to lift the flame is determined for each combination of inner swirl level and injector recess. Assuming the flame close to the injector lips behaves like an edge flame, a model for flame stabilization based on the triple flame speed and the location of the stoichiometric mixture fraction line is built. According to this model, the flame is anchored to the injector if the triple flame can propagate to the inner injector lips, i.e., if the velocity along the stoichiometric line is lower than the triple flame speed. The model is tested using hydrogen diluted with argon and air diluted with nitrogen. Two cases producing predicted opposite trends are verified. First, the stoichiometric line is moved in the direction of lower velocity zone keeping the triple flame speed constant in order to anchor a lifted flame. Next, the stoichiometric line is kept constant and the triple flame speed is reduced in order to lift an anchored flame. The mechanisms driving flame stabilization are discussed. [ABSTRACT FROM AUTHOR]

The gel‐type emulsified muscle products improve fatty acid composition, maintain the oxidative stability, and achieve a better sensory acceptability. This review emphasizes the stabilization mechanisms of these emulsified muscle products. In particular, factors associated with the stability of the emulsified muscle systems are outlined, including the processing conditions (pH and heating), lipids, and emulsifiers. Besides, some novel systems are further introduced, including the Pickering emulsions and organogels, due to their great potential in stabilizing emulsified gels. Moreover, the promising prospects of emulsion muscle products such as improved gel properties, oxidative stability, freeze–thaw stability, fat replacement, and nutraceutical encapsulation were elaborated. This review comprehensively illustrates the considerations on developing gel‐type emulsified products and provides inspiration for the rational design of emulsified muscle formulations with both oxidatively stable and organoleptically acceptable performance. [ABSTRACT FROM AUTHOR]

As a one of the focuses of ecological research, understanding the regulation of plant diversity on community stability is helpful to reveal the adaption of plant to environmental changes. However, the relationship between plant diversity and community stability is still controversial due to the scale effect of its influencing factors. In this study, we compared the changes in community stability and different plant diversity (i.e., species, functional, and phylogenetic diversities) between three communities (i.e., riparian forest, ecotone community, and desert shrubs), and across three spatial scales (i.e., 100, 400, and 2500m2), and then quantified the contribution of soil properties and plant diversity to community stability by using structural equation model (SEM) in the Ebinur Lake Basin Nature Reserve of the Xinjiang Uygur Autonomous Region in the NW China. The results showed that: (1) community stability differed among three communities (ecotone community > desert shrubs > riparian forest). The stability of three communities all decreased with the increase of spatial scale (2) species diversity, phylogenetic richness and the mean pairwise phylogenetic distance were higher in ecotone community than that in desert shrubs and riparian forest, while the mean nearest taxa distance showed as riparian forest > ecotone community > desert shrubs. (3) Soil ammonium nitrogen and total phosphorus had the significant direct negative and positive effects on the community stability, respectively. Soil ammonium nitrogen and total phosphorus also indirectly affected community stability by adjusting plant diversity. The interaction among species, functional and phylogenetic diversities also regulated the variation of community stability across the spatial scales. Our results suggested that the effect of plant diversities on community stability were greater than that of soil factors. The asynchronous effect caused by the changes in species composition and functional traits among communities had a positive impact on the stability. Our study provided a theoretical support for the conservation and management of biodiversity and community functions in desert areas. [ABSTRACT FROM AUTHOR]

An experimental study on the influence of porosity and hydrogen enrichment on the stabilization of premixed CH 4 -Air flames in Porous Media Burners (PMBs) is presented. Flame stabilization is analyzed via direct flame front tracking, which is made possible by a novel experimental apparatus. The use of additive manufacturing for computer-generated topologies allows making optically-accessible PMBs featuring see-through directions. This methodology also enables topology tailoring which is here exploited to study the influence of porosity on the performance of the burner. Flame front tracking reveals a different stabilization trend in highly H 2 -enriched flames. A comparison with a theoretical model is used to remove the effect of preheating and focus on other fuel properties. This suggests a flame-speed enhancement mechanism driven by Lewis number effects in Le < 1 mixtures. Together with recent 3D Direct Numerical Simulations, these results provide evidence that preferential diffusion effects are key in the stabilization of flames in PMBs. These phenomena, not considered in state-of-the art 1D-Volume Averaged Models, remain crucial for the design of efficient PMB using hydrogen as a fuel. [ABSTRACT FROM AUTHOR]

The aim of this research was to perform a new evaluation of stabilizers dedicated to ethylene-norbornene copolymer (EN). The aging and stabilization processes of the EN polymer filled with natural (xanthone, naringenin) or synthetic (Rianox 626, Rianox 1726, Rianox 3114) antioxidants with different chemical structure were thoroughly analyzed and the suitability of the methods described in the literature to study these processes was assessed. EN is successfully used in optics, electronics or packaging sectors, but like any other organic material, it will degrade under the influence of environmental factors. The EN films were subjected to thermo- and photooxidation for 150, 300, 450, and 600 h. We observed that all composites exhibited an excellent resistance to thermo-oxidation, but as expected, much greater differences were noted after exposure to ultraviolet radiation. The performed tests: thermal analysis, FTIR spectroscopy, contact angles determination, color change measurements, static and dynamical mechanical tests proved the high effectiveness of the used antioxidants for the EN stabilization. However, in the case of the EN-xanthone sample, during the FTIR analysis, a higher value of the carbonyl index in comparison with the reference EN was obtained, and a greater change in the glass transition temperature (T g) compared to the other used stabilizers was observed. These changes could be caused by xanthone oxidation on the polymer surface and its plasticization because of aging, as evidenced by the increased T g value. In addition, we also discussed possible stabilization mechanisms of EN through the use of selected antioxidants. Interestingly, based on the obtained results, Rianox 626 containing phosphite groups in its structure turned out to be the most effective stabilizer for the ethylene-norbornene copolymer, even though it is a secondary antioxidant. It can therefore be suggested that the propagation stage plays a leading role in the degradation of this polymer, in which antioxidants decompose hydroperoxides. In the case of Rianox 626, phosphite groups reacted with hydroperoxides, thus creating the phosphate form of this stabilizer and alcohols, which are more stable and non-radical products. [Display omitted] • Polymer products based on ethylene-norbornene copolymer show high thermal resistance. • Natural stabilizers of plant origin can be a green alternative to synthetic antioxidants. • Chemical structure of antioxidant can affect the aging process of the polymer. • Rianox 626 is a highly effective stabilizer dedicated to EN polymer (Topas E−140). [ABSTRACT FROM AUTHOR]

• Pickering emulsions based on gliadin/arabinoxylan nanoparticles (GANPs) were fabricated. • GANPs with different gliadin/arabinoxylan (G/AX) ratios had distinct effects on emulsion properties. • Pickering emulsion with G/AX ratio of 1:4 showed strongest oxidative stability. • Percolating gel net-work mechanism conferred the emulsion superior stabilization. In the present work, the Pickering emulsions with enhanced oxidation stability were fabricated using gliadin (G)/arabinoxylan nanoparticles (GANPs). The influence of different G/AX ratios on the properties of GANPs and corresponding physicochemical characteristics of Pickering emulsions were investigated. Results indicated that the droplet size and ζ-potential of Pickering emulsions declined with the decrease of G/AX ratios. Pickering emulsion with the smallest G/AX ratio (1:4) exhibited excellent oxidative and coalescence stability due to the formation of viscoelastic gel network, which was supported by confocal laser scanning microscopy (CLSM) images. Furthermore, the increase of salt ions in a lower concentration (0–0.2 M) was conducive to the flocculation of the droplets, while further increasing the NaCl concentration impaired the emulsion stability. Such elements revealed that G/AX complex is a promising stabilizer of Pickering emulsions with prominent antioxidant activity, which have favorable potential applications in protecting the functional properties of polyunsaturated fatty acids (PUFAs). [ABSTRACT FROM AUTHOR]

Nanocelluloses in recent years have garnered a lot of attention for their use as stabilizers of liquid-liquid and gas-liquid interfaces. Both cellulose nanocrystals (CNCs) and cellulose nanofibers (CNFs) have been used extensively in multiple studies to prepare emulsions and foams. However, there is limited literature available that systematically discusses the mechanisms that affect the ability of nanocelluloses (modified and unmodified) to stabilize different types of interfaces. This review briefly discusses key factors that affect the stability of Pickering emulsions and foams and provides a detailed and systematic analysis of the current state knowledge on factors affecting the stabilization of liquid-liquid and gas-liquid interfaces by nanocelluloses. The review also discusses the effect of nanocellulose surface modifications on mechanisms driving the Pickering stabilization of these interfaces. [Display omitted] • Factors affecting the stabilization of interfaces by nanocelluloses • Stabilization mechanisms of Pickering emulsions and foams containing nanocelluloses • Properties of liquid-liquid and gas-liquid interfaces with adsorbed nanocelluloses • Effect of surface modification on the behavior of nanocelluloses at interfaces [ABSTRACT FROM AUTHOR]

Lithium-rich transition metal oxides (LLOs) can deliver high specific capacity over 250 mAh g -1 , stemming from additional contribution of oxygen redox. However, the formation of O (2- n )- (0 < n < 2) species and even oxygen gas during the deep oxidation stage leads to progressive structural transformation that cause voltage decay/hysteresis, sluggish kinetics, and poor thermostability, preventing real-world application of LLOs. Therefore, the substantive key relies on enhancing the anionic redox stability in LLOs. Here, a sulfuration procedure of LLOs (S-LLOs) is proposed, in which sulfur anions are incorporated into oxygen sites in the lattice structure and form polyanions on the surface. Proved by structural characterizations and density functional theory (DFT) calculations, sulfur anions in the interior lattice can reversibly participate in the redox process and enhance the integral coordination stability by mitigating undesired oxygen redox. Moreover, S polyanions at the surface form a protecting layer for interfacial stability. The electrochemical measurements indicate that S-LLO demonstrates a high discharge capacity of 307.8 mAh g -1 , an outstanding capacity retention rate of 91.5% after 200 cycles, along with excellent voltage maintenance, rate capability, and thermostability. The sulfuration process of LLOs with multianionic redox mechanism highlights a promising strategy to design novel high-energy-density cathode materials with superior cycling performance., (© 2022 Wiley-VCH GmbH.)