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Green iron tea nanoparticles (GT-Fe NPs) were used as persulfate(PS) activators to oxidize rhodamine B (RhB) in this study. Optimized oxidative degradation condition was 0.033 mM Fe, 5 mM PS at pH 3.0 and 298 K with an initial RhB content of 50 mg/L. After 120 min of RhB degradation utilizing GT-Fe NPs activated PS, 99% of RhB reduction was achieved, while 98% RhB reduction with PS activated by citric acid-Fe

To determine the competitive adsorption characteristics and influencing factors of chlorinated and aromatic hydrocarbons on the aquifer medium, toluene, benzene, 1,2−dichloropropane, and 1,2,3−trichloropropane (TCP) were selected as typical pollutants for adsorption tests. The results showed that the adsorption process of pollutants on the aquifer medium conformed to the first−order kinetic and Henry linear model equation, and the adsorption capacity decreased in the order of toluene, benzene, 1,2−dichloropropane, and TCP. Benzene promoted the adsorption of toluene on the aquifer medium, while toluene reduced the adsorption of benzene conversely. 1,2−dichloropropane restrained the adsorption of TCP, and TCP had no significant effect on the adsorption of 1,2−dichloropropane. The adsorption capacity of TCP on the aquifer increased with the concentration of toluene. TCP acted as a stimulus for the adsorption of toluene when the initial concentration of toluene was lower than 2 mg/L. In contrast, TCP served as an inhibitor for the adsorption of toluene on the aquifer medium. Furthermore, the adsorption of all pollutants increased with decreasing medium size. The promotion rates for aromatic and chlorinated hydrocarbons were 7.2~41.1% and 2.7~27.1%, suggesting that the promotion effect on aromatic hydrocarbons was stronger than that on chlorinated hydrocarbons. Natural organic matter (NOM) inhibited the adsorption of pollutants on the aquifer medium (especially for high concentrations of chlorinated hydrocarbons), and the adsorption rate increased by more than 60% when OM decreased from 0.25% to 0.08%. Clay minerals improved the adsorption of organic pollutants in different compound pollution systems, and montmorillonite exhibited a stronger promoting effect than kaolin.

With the rapid development of the economy, urbanization and industrialization gradually become an important driving force of groundwater chemical evolution. In this study, Lanzhou City, which is one of the biggest industrial cities in northwest China, was selected to investigate the impacts of city development on groundwater quality. Several hydrochemical methods together with principal component analysis (PCA) were used for the hydrochemistry evolution characteristics and sensitive factors of groundwater chemistry in different urban functional areas of Lanzhou City. The results show that 96% of the groundwater in the study area cannot meet the groundwater quality standards of China. The main factors affecting the quality are SO42−, TDS, total hardness, Mg2+ and Na+. Urbanization and industrialization lead to further deterioration of the already naturally high TDS groundwater. NO3−, Cl− and NH4+ are the characteristic factors of human input sources for commercial residential areas; total Fe and NO3− are the characteristic factors of new urban areas in the urban-rural junction; and SO42−, NO3−, Cl−, Total Fe, Mn2+, F−, I−, Pb2+, Cr6+ and As3+ are the characteristic factors of industrial areas. Domestic sewage infiltration and manure infiltration are the main driving factors of groundwater quality deterioration in commercial residential areas. Nitrate fertilizer infiltration and sewage irrigation are the main factors leading to the increase in nitrate nitrogen in groundwater in the new urban area. Industrial wastewater leakage and organic pollution that promote the dissolution of minerals in the aquifer (the dissolution of fluorine-containing minerals and reductive dissolution of iron manganese oxides) are the main driving factors for the deterioration of groundwater quality in the petrochemical industrial area.

The vegetation deterioration and pollution expansion from non-ferrous metal tailings pond have been found in many countries leading to water soil erosion and human health risk. Conventional ecological remediation technologies of mine tailings such as capping were costly and elusive. This study provided an economic and effective model as an alternative by substrate amelioration and vegetation restoration. A field experiment was carried out on a silver tailings pond in southwest China. Tailings substrate was ameliorated by adding organic matter (decomposed chicken manure, DCM), structural conditioner (polyacrylamide, PAM), water-retaining agent (acrylic acid-bentonite water-retaining agent, AAB), and heavy metal immobilizer (biofuel ash, BFA), which were optimized by laboratory experiment. Native heavy metal hyperaccumulator, Bidens pilosa, was colonized. Vegetation coverage and plant height of Bidens pilosa reached about 80% and over 30 cm respectively after 3 months, and the turbidity of tailings leaching solution decreased by 60%. The practice showed that the proportion of available heavy metals in tailings substrate was significantly lower than that in the soil surrounding mining area. Immobilization didn't have stabilization effect on Cd, Zn, and Pb, and As was only 0.002%, phytoremediation had stabilization effect of Cd, Zn, As, and Pb were 2.5-3.5%, 1-2%, 0.25-0.5%, and 0.25-0.75%. Phytoremediation was more effective significantly in controlling heavy metal pollution risk of tailings than immobilization. These results provided a new ecological remediation OSA-NHC model, meaning a combination of optimal substrate amelioration and native hyperaccumulator colonization, which could achieve vegetation restoration and augment heavy metal pollution control in non-ferrous metal tailings pond.

This paper investigated the micron-scale activated carbon (MAC) immobilized diesel-oil-degrading bacteria (bio-MAC) used as remediation materials for the removal of diesel-oil-contaminated water. The high-efficiency indigenous diesel-oil-degrading bacteria were firstly screened and enriched, then the MAC was used as a diesel oil sorbent and biocarrier for the immobilization of degrading bacteria to prepare the bio-MAC material. The removal performance of the bio-MAC was evaluated via a comparison with the freely degrading bacteria and MAC. The SEM results demonstrated that the diesel-oil-degrading bacteria were effectively immobilized and grew well on the surfaces of MAC particles. The concentration of MAC significantly influenced the growth and activity (DHA and LPS) of immobilized bacteria, and the MAC addition of 3.0 g/L was proven to be an optimum amount for the preparation of bio-MAC. The high-throughput sequencing analysis further indicated that the bacteria immobilized on MAC showed higher abundance levels and diversities index values compared to freely suspended bacteria, such as Pseudomonas, Rhodococcus, Bacillus and Microbacterium. The FTIR spectroscopy results showed that the bio-MAC could effectively degrade the aliphatic hydrocarbons, alkenes and aromatic compounds of diesel oil to carboxylic acids, esters, alcohols and other metabolites. When the concentration of diesel oil was 1 g/L, the removal efficiency for the diesel oil of bio-MAC reached 86.35% after 15 days, while only 23.82% and 70.97% of the diesel oil was removed using the same amount of free bacteria and MAC, respectively. The prepared bio-MAC showed a synergic effect of adsorption and biodegradation and efficiently removed diesel oil from wastewater.