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The purpose of this article is to examine the impact of rural population aging on farmers’ cleaner production behavior through the intervening effects of three aspects (learning capacity, factor substitution and behavior imitation). The data used in this article were collected from a questionnaire survey of 916 farmers in the main grain producing provinces of the North China Plain. First, confirmatory factor analysis was carried out, and then data were analyzed through structural equation modeling using the bootstrap methodology in AMOS 24. The findings indicate that rural population aging inhibits farmers’ cleaner production behavior through learning capacity. In contrast, rural population aging promotes farmers’ cleaner production behavior through factor substitution and behavior imitation. From the perspective of both challenges and opportunities, this article investigates the impact mechanism and comprehensive effect of rural population aging on farmers’ cleaner production behavior, so as to explore new ways to promote cleaner agricultural production under the background of an accelerated aging the of rural labor force and provide reference for the formulation of relevant policies.