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Nanometer-sized crystals (nanolites) play an important role in controlling eruptions by affecting the viscosity of magmas and inducing bubble nucleation. We present detailed microscopic and nanoscopic petrographic analyses of nanolite-bearing and nanolite-free pumice from the 2021 eruption of Fukutoku-Oka-no-Ba, Japan. The nanolite mineral assemblage includes biotite, which is absent from the phenocryst mineral assemblage, and magnetite and clinopyroxene, which are observed as phenocrysts. The boundary between the nanolite-bearing brown glass and nanolite-free colorless glass is either sharp or gradational, and the sharp boundaries also appear sharp under the transmitted electron microscope. X-ray absorption fine structure (XAFS) analysis of the volcanic glass revealed that the nanolite-free colorless glass records an oxygen fugacity of QFM + 0.98 (log units), whereas the nanolite-bearing brown glass records a higher apparent oxygen fugacity (~ QFM + 2). Thermodynamic modelling using MELTS indicates that higher oxygen fugacities increase the liquidus temperature and thus induced the crystallization of magnetite nanolites. The hydrous nanolite mineral assemblage and glass oxygen fugacity estimates suggest that an oxidizing fluid supplied by a hot mafic magma induced nanolite crystallization in the magma reservoir, before the magma fragmentation. The oxidation-induced nanolite crystallization then enhanced heterogeneous bubble nucleation, resulting in convection in the magma reservoir and triggering the eruption.

Primary andesitic magmas could be an important component of arc magma genesis and might have played a key role in the advent of continents. Recent studies hypothesized that primary andesitic magmas occur in the oceanic arc, where the crust is thin. The Kermadec arc has the thinnest crust among all the studied oceanic arcs (<15 km in thickness); however, there are no studies that corroborate the formation of primary andesitic magmas in the arc. The aim of this study is to develop a better understanding of primary andesites in oceanic arcs through the petrology of the Kermadec arc. Here, we present the petrology of volcanic rocks dredged from the Kibblewhite Volcano in the Kermadec arc during the R/V SONNE SO-255 expedition in 2017. Magma types range from andesite to rhyolite at the Kibblewhite Volcano, but basalts dominate at the neighboring cones. This study focuses on magnesian andesites from the northeastern flank of this volcano. The magnesian andesites are nearly aphyric and plagioclase free but contain microphenocrysts of olivine (Fo84–86) and clinopyroxene (Mg# = 81–87). Using olivine addition models, the primary magmas were estimated to contain 55–56 wt % SiO2 and 10–12 wt % MgO, similar to the high-Mg andesites observed in other convergent plate margins, indicating the generation of primary andesitic magma beneath the Kibblewhite Volcano. The trace element and isotopic characteristics of the magnesian andesites are typical of volcanic rocks from the Kermadec arc. This indicates that the subduction of a young plate or melting of a pyroxenitic source is not necessary to produce magnesian andesites. Instead, we propose that the magnesian andesites were produced by the direct melting of the uppermost mantle of the Kermadec arc. The thin crust of the Kermadec arc should yield low-pressure conditions in the uppermost mantle, allowing the sub-arc mantle to generate primary andesitic melts. This study supports the hypothesis that primary andesitic magmas generate

The relationship between plutonic and volcanic components of magmatic plumbing systems continues to be a question of intense debate. The Oki-Dōzen Islands, Sea of Japan, preserve outcrops of temporally associated plutonic, hypabyssal, and volcanic rocks. Post-intrusion uplift juxtaposed Miocene syenites in inferred faulted contact with volcanic trachytes that are cut by rhyolite hypabyssal dikes. This provides a window deep into the timing and origins of magma storage architecture and dynamics. Zircon is ubiquitous in all samples; our aim is to determine what its age and composition can reveal about the plutonic-volcanic connection. Here we show magma source characteristics are recorded in zircon Hf isotopes; source composition and assimilation of heterogeneous hydrothermally altered crust in zircon O isotopes; and extensive fractional crystallization in zircon trace elements. Combined with new UTh-Pb SHRIMP zircon ages, 6.4–5.7 Ma, compositional data show pluton formation was by protracted amalgamation of discrete magma pulses. The rhyolite dike preserves an evolved fraction segregated from these discrete magmas. Synchronous with plutonism was a volcanic eruption of trachyte magma derived from the same source, which may have stalled at a relatively shallow depth prior to eruption. Stalling occurred at least above the amphibole stability zone because amphibole-compatible Sc and Ti were not depleted in the trachyte melt resulting in elevated values of these in volcanic compared to plutonic zircon. Identifying smaller episodic magma pulses in a larger magmatic complex places constraints on potential magma fluxes and eruptible volumes. High-flux, large volume, plume-related ocean island magmatic systems may have extensive vertically distributed multi-stage magmatic reservoirs and subduction-related systems transcrustal magma reservoirs. By contrast, Oki-Dōzen was a low-flux system with incremental pluton growth and small- to moderate-scale eruptions.

It is common knowledge that the Moho is the boundary between the crust and the Earth's mantle. Here we show along several seismic profiles through the Pacific Plate that a correlation exists between the strength of Moho reflections, crustal thickness, and water depth. Where the Moho can be detected clearly, the overlying oceanic crust is systematically thicker and the water depths are shallower. We suggest that two end-members of oceanic crust exist in fast spreading environments: one thick, underlain by a clear Moho; the other thinner, without a Moho; with all intermediate situations. In the Oman ophiolite, the best-preserved on-land analogue of fossil oceanic lithosphere created by fast-spreading, the boundary between the mantle peridotites and the lower crustal gabbros mainly consists of a dunitic transition zone (DTZ) ranging from a few meters to a few hundred meters in thickness. A sudden influx of seawater down to the base of the crust at the mid-ocean ridge (MOR) results in the hydrous (re-)melting of mantle peridotites, producing a dunitic residue at the crust-mantle boundary that represents the most reflective Moho. At the same time, the hydrous melting, in addition to the normal decompression melting, beneath the MOR, increases the thickness of the oceanic crust by enhancing magma production. In the absence of hydrous melting, the DTZ is thin or absent at the crust-mantle boundary, and instead the uppermost mantle harzburgite is intruded by gabbros, and/or the overlying crustal gabbro is intruded by numerous wehrlite bodies, which will be seismically gradational.