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A new approach for the extraction of organic phosphorus (Po) from freshwater sediments, which can be used in solution 31P nuclear magnetic resonance spectroscopy (31P NMR), has been developed and optimized. This approach addresses three important factors for sediment extraction: pH, organic matter (OM), and paramagnetic ions. We classified the sediments according to the pH, OM, and paramagnetic ions (acidic: pH < 7, alkaline: pH > 7; low OM: OM < 100 g·kg−1, high OM: OM > 100 g·kg−1; non-calcareous: Ca/(Fe + Al) < 0.5, calcareous: Ca/(Fe + Al) > 0.5). The 0.25 and 0.5 mol·L−1 NaOH were optimum concentration for acidic and alkaline sediment extracted, respectively. The ratio of sediment to extraction remains at 1:10 (w:v) which exhibited higher extraction efficiency compared with 1:5 and 1:20 for both low and high OM sediments. Use of 25 mmol·L−1 and 50 mmol·L−1 ethylenediaminetetraacetic acid (EDTA) was optimal for Po extraction from non-calcareous and calcareous sediments, respectively. A useful extraction ratio table was developed through systematic orthogonal experiment. This new approach will allow 31P NMR to be more efficiently used for freshwater Po analysis and will help answer questions regarding to the fate and function of Po in freshwater sediments. [ABSTRACT FROM AUTHOR]

Heavy metal sediment pollution has become an increasingly serious problem associated with industrial development, so extensive studies have been conducted concerning their removal. Biochar has recently shown good potential for in-situ remediation of heavy metal-contaminated sediments. The heavy metal adsorption capacity of inexpensive biochar can be improved by loading it with metal oxides. In this study, manganese-modified biochar (MBC) was prepared by KMnO 4 -modified waste-activated sludge biochar and applied to immobilize Pb and Cd in sediments. Its effects on the sediment microbial community were also investigated. The Results showed that manganese modification of the biochar made it more conducive to the adsorption of heavy metals, owing to its higher specific surface area and graphitization structure, more active sites and oxygen-containing groups, and the presence of Mn 2 O 3 crystal structure on the surface. The maximum adsorption capacities of this material for Pb 2+ and Cd 2+ in solution were 176.9 mg/g and 44.0 mg/g, respectively. The application of MBC to the remediation of heavy metal-contaminated sediments transformed Pb and Cd in the sediments from exchangeable to residual state. The F4 content of Pb in the sediments increased from 40.52%-42.36% to 49.11%-51.14% after application of 1% MBC, and to 63.94%-64.49% after application of 5% MBC. Correspondingly, the F1 content of Pb in the sediments decreased from 29.09%-30.68% to 17.43%-17.69% after the application of 5% MBC. Furthermore, MBC efficiently enriched the microbial biodiversity and affected the microbial population structure within 60 days. The relative abundance of uncultured f Symbiobacteraceae and Fonticella communities significantly increased after incubation. The results may provide empirical support for the combination of metal oxides and biochar for the remediation of heavy metal-contaminated sediments., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)