Search

Antiwear additives permit energy-efficient lubrication of gearboxes, bearings, and other tribological interfaces. We study zirconia (ZrO2) nanocrystal additives, which readily form protective tribofilms in tribological contacts. Our prior work demonstrated cooperative antiwear performance between ZrO2 and the S- and P-based co-additives in fully formulated hydrocarbon gear oils. Here, we extend that work by examining the growth kinetics of the ZrO2 tribofilms, including the influence of the co-additives. In the boundary lubrication regime for mixed rolling-sliding contacts, the initial phase of ZrO2 tribofilm growth is soon overtaken by removal processes, phenomena whose importance has gone unnoticed in prior work. Tribofilm removal affects the steady-state thickness and morphology of the tribofilm as well as its growth kinetics. The S- and P-based co-additives are incorporated into the ZrO2 tribofilm, and alter the competition between the growth and removal processes, increasing initial net growth rates per contact cycle and contributing to a more polished final interface. This work highlights the significance of removal processes in determining tribofilm antiwear performance, and suggests several routes for improving tribofilm growth kinetics using co-additives. [ABSTRACT FROM AUTHOR]

We provide experimental observations of the nucleation and growth of water capillary bridges in nanometer gaps between a laterally moving atomic force microscope probe and a smooth silicon wafer. We find rising nucleation rates with increasing lateral velocity and a smaller separation gap. The interplay between nucleation rate and lateral velocity is attributed to the entrainment of water molecules into the gap by the combination of lateral motion and collisions of the water molecules with the surfaces of the interface. The capillary volume of the full-grown water bridge increases with the distance between the two surfaces and can be limited by lateral shearing at high velocities. Our experimental results demonstrate a novel method to study in situ how water diffusion and transport impact dynamic interfaces at the nanoscale, ultimately leading to friction and adhesion forces at the macroscale. [ABSTRACT FROM AUTHOR]

This paper presents a comprehensive investigation into the impact of key parameters on contact adhesion layer properties using numerical simulations, addressing fundamental questions in contact mechanics. Aiming to explore interfacial penetration and contact pressure dynamics between a wavy punch and an adhesive-coated body, the study focuses on the influence of adhesive layer thickness, elasticity modulus, and punch geometry on mechanical behavior. The study includes the application of Green's function to address deficiencies in existing models, revealing how contact stiffness, influenced by the flexibility relationship between the coating and substrate, affects the size of the contact area. Finally, conclusions are drawn that adjusting coating factors can induce full contact conditions. Quantitative analysis shows a 2.23-fold increase in load-bearing capacity with a 2 mm increase in adhesive layer thickness, and a 23-fold increase with a toughness ratio rise from 0.1 to 5. These findings are recommended for optimizing adhesive layer properties, contributing to advancements in materials science and innovation. [ABSTRACT FROM AUTHOR]

The materials involved in geotechnical engineering are objects of concern in granular mechanics. In order to study the influence of the sliding friction coefficient corresponding to different-sized elements in the discrete element method (DEM) on the simulation results, we establish a two-dimensional DEM model based on the experimental method to analyze a slope example. The correctness of the DEM model is verified by comparing the sliding surface of a finite element method (FEM) model and the DEM slope model. A sliding friction coefficient algorithm based on the experimental method is embedded into the DEM slope model and compared with the original model. The comparison results show that embedding the DEM model into the sliding friction coefficient algorithm leads to an increase in displacement. The reason for this is that the contact information between elements of different sizes has changed, but the displacement trend is the same. Different sliding friction coefficients should be set based on different-sized elements in the DEM, as they can improve simulation accuracy. [ABSTRACT FROM AUTHOR]

To address the lack of reliable measurement methods for identifying wear mechanisms and predicting the state of mechanical seal tribo-parts, this study proposes a method for characterizing tribological behavior based on measuring face vibration acceleration. It aims to uncover the source mechanism of mechanical seal face vibration acceleration influenced by tribology and dynamic behavior. This research delves into the dynamic behavior characteristics and vibration acceleration of the mechanical seal stationary ring. We explored the variation pattern of face vibration acceleration root mean square (RMS) with rotation speed, sealing medium pressure, and face surface roughness. The results indicate that under constant medium pressure, an increase in rotation speed leads to a decrease in acceleration RMS and an increase in face temperature. Similarly, under constant rotation speed, an increase in medium pressure results in nonlinear changes in acceleration RMS, forming an "M" shape, along with an increase in face temperature. Furthermore, under conditions of constant medium pressure and rotation speed, an increase in the surface roughness of the rotating ring face corresponds to an increase in acceleration RMS and face temperature. Upon starting the mechanical seal, both acceleration RMS and temperature initially increase before decreasing, a trend consistent with the Stribeck curve. [ABSTRACT FROM AUTHOR]

Archard’s wear law encounters challenges in accurately predicting wear damage and volumes, particularly in complex situations like asperity–asperity collisions. A modified model is proposed and validated, showcasing its ability to predict wear in adhesive contacts with better accuracy than the original Archard’s wear law. The model introduces an improved wear coefficient linked to deformation energy, creating a spatially varying relationship between wear volume and load and imparting a non-linear characteristic to the problem. The improved wear model is coupled with the Boundary Element Method (BEM), assuming that the interacting surfaces are semi-infinite and flat. The deformation energy is calculated from the normal contact pressure and displacements, which are the common outputs of BEM. By relying solely on these outputs, the model can efficiently predict the correct shape and volume of the adhesive wear particle, without resorting to large and often slow models. An important observation is that the wear coefficient is expected to increase based on the accumulated deformation energy along the direction of frictional force. This approach enhances the model’s capability to capture complex wear mechanisms, providing a more accurate representation of real-world scenarios. [ABSTRACT FROM AUTHOR]

The tribological behaviors of nanoparticles (NPs) have attracted widespread attention in the fields of nano‐lubrication and ultra‐precision manufacturing. The frictional and dynamic behaviors of SiO2 NPs acting with the single asperity were studied on silicon surface utilizing atomic force microscope. The friction forces of NPs, both static and kinetic, exhibit an initial decrease followed by an increase as the normal load increases (0–300 nN). The nonmonotonic load‐dependence of friction behavior corresponds to the dynamic transformation of "sliding‐rolling‐sliding" motion state of the manipulated NPs, which can be predicted by a Double‐Hertz model and further confirmed by nanoindentation‐marked NPs. This research has a significant implication for regulating dynamic behaviors of NPs in contemporary three‐body abrasive tribology. [ABSTRACT FROM AUTHOR]

Structural superlubricity refers to the lubrication state in which the friction between two crystalline surfaces in incommensurate contact is nearly zero; this has become an important branch in recent tribological research. Two-dimensional (2D) materials with structural superlubricity such as graphene, MoS2, h-BN, and alike, which possess unique layered structures and excellent friction behavior, will bring significant advances in the development of high-performance microelectromechanical systems (MEMS), as well as in space exploration, space transportation, precision manufacturing, and high-end equipment. Herein, the review mainly introduces the tribological properties of structural superlubricity among typical 2D layered materials and summarizes in detail the underlying mechanisms responsible for superlubricity on sliding surfaces and the influencing factors including the size and layer effect, elasticity effect, moiré superlattice, edge effect, and other external factors like normal load, velocity, and temperature, etc. Finally, the difficulties in achieving robust superlubricity from micro to macroscale were focused on, and the prospects and suggestions were discussed. [ABSTRACT FROM AUTHOR]

The microstructure is a critical factor governing the functionality of ceramic materials. Meanwhile, microstructural analysis of electron microscopy images of polycrystalline ceramics, which are geometrically complex and composed of countless crystal grains with porosity and secondary phases, has generally been performed manually by human experts. Objective pixel-based analysis (semantic segmentation) with high accuracy is a simple but critical step for quantifying microstructures. In this study, we apply neural network-based semantic segmentation to secondary electron images of polycrystalline ceramics obtained by three-dimensional (3D) imaging. The deep-learning-based models (e.g., fully convolutional network and U-Net) by employing a dataset based on a 3D scanning electron microscopy with a focused ion beam is found to be able to recognize defect structures characteristic of polycrystalline materials in some cases due to artifacts in electron microscopy imaging. Owing to the training images with improved depth accuracy, the accuracy evaluation function, intersection over union (IoU) values, reaches 94.6% for U-Net. These IoU values are among the highest for complex ceramics, where the 3D spatial distribution of phases is difficult to locate from a 2D image. Moreover, we employ the learned model to successfully reconstruct a 3D microstructure consisting of giga-scale voxel data in a few minutes. The resolution of a single voxel is 20 nm, which is higher than that obtained using a typical X-ray computed tomography. These results suggest that deep learning with datasets that learn depth information is essential in 3D microstructural quantifying polycrystalline ceramic materials. Additionally, developing improved segmentation models and datasets will pave the way for data assimilation into operando analysis and numerical simulations of in situ microstructures obtained experimentally and for application to process informatics. [ABSTRACT FROM AUTHOR]

Oil-based drilling fluids are usually assumed to provide lower friction compared to their water-based alternatives. However, clear evidence for this has only been presented for steel–rock and steel–steel contacts, which are representative of the interface between the drillstring and the borehole or casing. Another crucial interface that needs to be lubricated during drilling is that between the cutter (usually diamond) and the rock. Here, we present pin-on-disc tribometer experiments that show higher boundary friction for n-hexadecane-lubricated diamond–granite contacts than air- and water-lubricated contacts. Using nonequilibrium molecular dynamics simulations of a single-crystal diamond tip sliding on α-quartz, we show the same trend as in the experiments of increasing friction in the order: water < air < n-hexadecane. Analysis of the simulation results suggests that the friction differences between these systems are due to two factors: (i) the indentation depth of the diamond tip into the α-quartz substrate and (ii) the amount of interfacial bonding. The n-hexadecane system had the highest indentation depth, followed by air, and finally water. This suggests that n-hexadecane molecules reduce the hardness of α-quartz surfaces compared to water. The amount of interfacial bonding between the tip and the substrate is greatest for the n-hexadecane system, followed by air and water. This is because water molecules passivate terminate potential reactive sites for interfacial bonds on α-quartz by forming surface hydroxyl groups. The rate of interfacial bond formation increases exponentially with normal stress for all the systems. For each system, the mean friction force increases linearly with the mean number of interfacial bonds formed. Our results suggest that the expected tribological benefits of oil-based drilling fluids are not necessarily realised for cutter–rock interfaces. Further experimental studies should be conducted with fully formulated drilling fluids to assess their tribological performance on a range of rock types. [ABSTRACT FROM AUTHOR]

We report the results of atomistic simulations of friction between two-dimensional titanium carbide Ti2C (MXene) and a silver nanoparticle located on its surface. Numerical experiments were performed within classical molecular dynamics methods using a previously developed scheme for simulations of interactions between MXenes and metal nanoparticles. In the computer experiments performed, both tangential and shear forces were applied to the Ag nanoparticle to initiate its sliding on the surface of the Ti2C MXene. During the simulations, the nanotribological parameters of the studied system, such as the friction force, contact area, friction coefficient, and tangential shear, were computed. It is shown that, for the studied system, the friction coefficient does not depend on the velocity of nanoparticle movement or the contact area. Additionally, the sliding friction of the nanoparticle on the flexible substrate was considered. The latter case is characterized by a larger friction coefficient and contact area due to the formation of wrinkles on the surface of the substrate. [ABSTRACT FROM AUTHOR]

The evolution of fault friction during the interseismic period affects the mechanics of a future earthquake on the same fault patch. Frictional aging has been previously tied to time‐dependent contact area growth through observations made on rock analogs. However, our understanding of the processes that control frictional aging is limited and is dependent on experiments that explore only numerous mechanisms. We conduct slide‐hold‐slide experiments with a dual‐axis nanoindenter on single‐crystal surfaces of quartz and calcite. Our results show that frictional aging in diamond‐quartz contacts is independent of time and contact area, in stark contradiction to past experiments done on quartz‐quartz contacts in rocks. Diamond‐calcite contacts show modest frictional aging, but still well below previous reported values from calcite‐calcite contacts. These results suggest that frictional aging of like‐on‐like minerals may be of chemical origin, as suggested in recent studies with atomic force microscopy and molecular dynamics simulations. Plain Language Summary: Frictional aging is the process of re‐strengthening of frictional contacts, either by an increase in contact area or by an increase in shear strength of the contact. Aging is important in the earthquake cycle where it affects the mechanical response of a future earthquake. Frictional aging has been studied extensively in the past through slide‐hold‐slide (SHS) experiments in rocks where the contact is slid at a constant velocity, then held stationary for a predetermined 'hold time', after which sliding resumes. These experiments show that the static friction measured at the end of the hold, as sliding commences, scales with the logarithm of hold time. This result is commonly interpreted as being due to contact area growth as observed in rock‐analogue materials (such as polymers). We conducted SHS experiments with a nanoindenter capable of inducing frictional sliding of a diamond tip over a substrate while continuously monitoring contact area. Experiments performed on single crystals of quartz and calcite show no or minimal frictional aging even though contact area grows with the logarithm of hold time. Our results suggest that frictional aging of these mineral contacts is due to a chemical mechanism and not explicitly due to contact area growth. Key Points: Diamond‐quartz and diamond‐calcite contacts show time‐dependent contact area growthQuartz surfaces do not exhibit frictional aging, suggesting that aging is of chemical originCalcite surfaces exhibit modest frictional aging with contact area, but significantly lower than in experiments on calcite rocks [ABSTRACT FROM AUTHOR]

The focus of the present study is to simulate the indentation type contact behaviour of single walled carbon nanotube (SWCNT) based nanocomposite. The contact system consists of a deformable Aluminium matrix, reinforced with a group of SWCNTs, and a conical indenter which is assumed as rigid. Downward and upward displacement is imparted on the conical indenter in order to simulate the loading and unloading phases of the contact. The model has been developed using APDL code on the ANSYS platform. Adequacy and validity of the model has been established by comparison with results from already published papers available in literature and the matching between the two sets of results is found to be excellent. In terms of results, contact forces, contact area, contact pressure and deformation behaviour are extracted from the analysis with varying wall thickness of CNTs. Detailed analysis of the obtained results has been carried out and it is found that sink in and pile up (in one particular scenario) behaviour is exhibited. It is also found that due to high deformation of the tubes at high indentation depth, there is material flow towards the axis of symmetry and creation of small elastic zones in the matrix material. [ABSTRACT FROM AUTHOR]

Atomic force microscopes are used, besides their principal function as surface imaging tools, in the surface manipulation and measurement of interfacial properties. In particular, they can be modified to measure lateral friction forces that occur during the sliding of the tip against the underlying substrate. However, the shape, size, and deformation of the tips profoundly affect the measurements in a manner that is difficult to predict. In this work, we investigate the contribution of these effect to the magnitude of the lateral forces during sliding. The surface substrate is chosen to be a few-layer AB-stacked graphene surface, whereas the tip is initially constructed from face-centered cubic gold. In order to separate the effect of deformation from the shape, the rigid tips of three different shapes were considered first, namely, a cone, a pyramid and a hemisphere. The shape was seen to dictate all aspects of the interface during sliding, from temperature dependence to stick–slip behavior. Deformation was investigated next by comparing a rigid hemispherical tip to one of an identical shape and size but with all but the top three layers of atoms being free to move. The deformation, as also verified by an indentation analysis, occurs by means of the lower layers collapsing on the upper ones, thereby increasing the contact area. This collapse mitigates the friction force and decreases it with respect to the rigid tip for the same vertical distance. Finally, the size effect is studied by means of calculating the friction forces for a much larger hemispherical tip whose atoms are free to move. In this case, the deformation is found to be much smaller, but the stick–slip behavior is much more clearly seen. [ABSTRACT FROM AUTHOR]

Friction is a fundamental force that impacts almost all interface-related applications. Over the past decade, there is a revival in our basic understanding and practical applications of the friction. In this review, we discuss the recent progress on solid-liquid interfacial friction from the perspective of interfaces. We first discuss the fundamentals and theoretical evolution of solid-liquid interfacial friction based on both bulk interactions and molecular interactions. Then, we summarize the interfacial friction regulation strategies manifested in both natural surfaces and artificial systems, focusing on how liquid, solid, gas, and hydrodynamic coupling actions mediate interfacial friction. Next, we discuss some practical applications that are inhibited or reinforced by interfacial friction. At last, we present the challenges to further understand and regulate interfacial friction. [ABSTRACT FROM AUTHOR]

Tribotronics represents the modulation of friction via an external electric potential, a field with promising ramifications for intelligent devices, precision manufacturing, and biomedical applications. A profound elucidation of mechanisms that allow for potential-controlled friction is foundational to further research in this tribotronic domain. This article provides a comprehensive review of the research progress in electro-controlled friction over the past few decades, approached from the perspective of the boundary lubrication film at the friction interface, a direct influencer of electro-controlled friction performance. The mechanisms of potential-controlled friction are categorized into three distinct classifications, contingent on the formation mode of the boundary lubrication film: potential-induced interfacial redox reactions, interfacial physical adsorption, and interfacial phase structure transformations. Furthermore, an outlook on the application prospects of electro-controlled friction is provided. Finally, several research directions worth exploring in the field of electro-controlled friction are proposed. The authors hope that this article will further promote the application of electro-controlled friction technology in engineering and provide intellectual inspiration for related researchers. [ABSTRACT FROM AUTHOR]

Mechanochemical reactions at the sliding interface between a single-crystalline silicon (Si) wafer and a silica (SiO2) microsphere were studied in three environmental conditions: humid air, potassium chloride (KCl) solution, and KCl solution with an applied voltage. Compared to that from humid air, mechanochemical material removal from the silicon surface increased substantially in the KCl-immersed condition, and further increased when electrochemistry was introduced into the tribological system. By measuring the load dependence of the material removal rate and analyzing the results using a mechanically assisted Arrhenius-type kinetic model, the activation energy (Ea) and the mechanical energy (Em), by which this energy is reduced by mechanical activation, were compared qualitatively under different environmental conditions. In the KCl-immersed condition, mechanochemistry may decrease the required effective energy of reactions (Eeff = Ea − Em) and promote material removal mainly through improved catalysis of the mechanochemical reactions facilitated by greater availability of water molecules compared to the humid air condition. Thus, the effectiveness of the mechanochemistry is improved. In the electrochemical condition, electrochemically-accelerated oxidation of the silicon surface was confirmed by the X-ray photoelectron spectroscopy (XPS) characterization. The results strongly suggest that electrochemistry further stimulates mechanochemical reactions primarily by increasing the initial energy state of the surface via the facilitated formation of interfacial bonding bridges, i.e., a surface oxidation/hydroxylation process. [ABSTRACT FROM AUTHOR]

Dynamically controlling friction in micro- and nanoscale devices is possible using applied electrical bias between contacting surfaces, but this can also induce unwanted reactions which can affect device performance. External electric fields provide a way around this limitation by removing the need to apply bias directly between the contacting surfaces. 2D materials are promising candidates for this approach as their properties can be easily tuned by electric fields and they can be straightforwardly used as surface coatings. This work investigates the friction between single layer graphene and an atomic force microscope tip under the influence of external electric fields. While the primary effect in most systems is electrostatically controllable adhesion, graphene in contact with semiconducting tips exhibits a regime of unexpectedly enhanced and highly tunable friction. The origins of this phenomenon are discussed in the context of fundamental frictional dissipation mechanisms considering stick slip behavior, electron-phonon coupling and viscous electronic flow. Electric fields achieved by applying electrical bias directly between the sliding surfaces are commonly used to tune friction. Here, the authors reveal that friction between graphene and a semiconductor is sensitive to the charge density of graphene while influenced by an indirect electric field. [ABSTRACT FROM AUTHOR]

This work investigates the friction between polydimethylsiloxane (PDMS) and silicon oxide (SiOx) in single asperity sliding contact by atomic force microscopy (AFM). Two friction dependences on the normal force are identified: a tensile regime and a compressive regime of normal forces. In the compressive regime, friction is governed by the shear deformation and rupture of junctions between PDMS and SiOx. In this case, the shear strength τ ≈ 10 MPa is comparable with the cohesive strength of PDMS under compressive loading. In contrast, friction in the tensile regime is also affected by the elongation of the junctions. The single SiOx-asperity follows a stick-slip motion on PDMS in both normal force regimes. Statistical analysis of stick-slip as a function of the normal force allows determining the necessary amount of energy to break a SiOx/PDMS junction. Friction between a SiOx-asperity and a PDMS surface can be rationalized based on an energy criterion for the deformation and slippage of nanometer-scale junctions. [ABSTRACT FROM AUTHOR]

Hardness is a powerful property to evaluate the deformation behavior of materials. It serves as confident quality control for several processes, especially in the heat treatment of metals. With the advent of depth-sensing indentation, this technique embraces the determination of other mechanical properties. As proof, recognized standards are available to guide the evaluation of Young's modulus using instrumented indentation. However, there are continuous efforts to describe the strength using hardness apparatus. This critical review aims to compile all ways of correlation between hardness and uniaxial strength. This relationship is usually addressed by a single value, called constraint factor, vastly recognized in metals as approximately 3. From a theoretical point of view, this value works well for materials with rigid-plastic behavior, where hardening effects can be discharged. Divergent variations presented herein show difficulties in incorporating the effect of plastic properties on the constraint factor determination. In the same way, the empirical determinations did not consider the differences in hardening exponents, putting in the same statistical analysis diverse microstructures. A specific section discusses the constraint factor for nonmetallic materials. There are critical doubts for determining strength from hardness values in this case. The existence of several approaches to estimate the constraint factor in brittle materials did not assure yet a unique value for the same material, which put in evidence the lack of a robust physical basis to understand the plastic deformation under indentation. Future trends are indicated along with these observations to become practical the recent developments that have allied hardness and strength. The most important aspect is to combine adequately the experimental and simulation approaches, which can be supported by an analysis of residual imprints of hardness and finite element model. [ABSTRACT FROM AUTHOR]

Friction is the force resisting relative motion of objects. The force depends on material properties, loading conditions and external factors such as temperature and humidity, but also contact aging has been identified as a primary factor. Several aging mechanisms have been proposed, including increased “contact quantity” due to plastic or elastic creep and enhanced “contact quality” due to formation of strong interfacial bonds. However, comparatively less attention has been given to other mechanisms that enhance the “contact quantity”. In this study, we explore the influence of crystal faceting on the augmentation of “contact quantity” in cubic silicon carbide, driven by the minimization of surface free energy. Our observations reveal that the temporal evolution of the frictional aging effect follows a logarithmic pattern, akin to several other aging mechanisms. However, this particular mechanism is driven by internal capillary forces instead of the normal force typically associated with friction. Due to this fundamental distinction, existing frictional aging models fail to comprehensively explain the observed behavior. In light of these findings, we derive a model for the evolution of contact area caused by diffusion-driven frictional aging, drawing upon principles from statistical mechanics. Upon application of a normal force, the friction force is increased due to plastic creep. This investigation presents an alternative explanation for the logarithmic aging behavior observed and offers the potential to contribute to the development of more accurate friction models. [ABSTRACT FROM AUTHOR]

The interfacial properties of silica determine the intrinsic behavior of sand and are of great importance due to its widespread application in geotechnical engineering. To investigate the sand behavior from a bottom-up perspective, the molecular dynamics approach is adopted for both dry and lubricated conditions. Friction simulations are performed using a virtual spring to pull the silica slider on the substrate at a wide range of velocities when different normal loads are applied. It has been found that the orientation of the silica surface influences dry friction. The friction force for the surface with normal vector along (001) direction is larger than that on (100) surface due to anisotropic energy corrugation, and the model with incommensurability has the smallest friction force. The Prandtl–Tomlinson model could explain the stick–slip phenomenon, and as the dominant friction mechanism shifts from thermal activation to phonon excitations and the delay effect of motion transmission, the velocity dependence of the friction crosses over from the logarithmic to the linear relationship at around 10 m/s. The Amontons law for adhering surface describes the silica interfacial friction behavior well. The friction force is linearly correlated with the external normal load and remains a finite value F0 when the external load equals 0. The lubricated friction results indicate that the friction coefficient decreases against the water content, while there is a non-monotonic relationship between F0 and water content. The friction coefficient and F0 increase with the velocity in both dry and lubricated conditions in the studied velocity range (0.1–100 m/s). It should be pointed out that the obtained force–displacement relationship is fundamental and can be applied to enhance current inter-particle laws of silica sand in micromechanics-based modeling approaches. [ABSTRACT FROM AUTHOR]

Adhesion between an elastic body and a smooth, rigid substrate can lead to large tensile stresses between them. However, most macroscopic objects are microscopically rough, which strongly suppresses adhesion. A fierce debate has unfolded recently as to whether local or global parameters determine the crossover between small and large adhesion. Here, we report simulations revealing that the dependence of the pull-off force Fn on the surface energy γ does not only have two regimes of high and low adhesion but up to four regimes. They are related to contacts, which at the moment of rupture consist of (i) the last individual Hertzian-shaped contact, in which is linear in γ, (ii) a last meso-scale, individual patches with super-linear scaling, (iii) many isolated contact patches with extremely strong scaling, and (iv) a dominating largest contact patch, for which the pull-off stress is no longer negligible compared to the maximum, microscopic pull-off stress. Regime (iii) can be seen as a transition domain. It is located near the point where the surface energy is half the elastic energy per unit area in conformal contact. A criterion for the transition between regimes (i) and (ii) appears difficult to grasp. [ABSTRACT FROM AUTHOR]

While ionic liquids (ILs) have gained wide interest as potential alternative lubricants able to meet the requirements of next-generation tribological systems owing to their unique physico-chemical properties and promising lubricating behavior, our understanding of the mechanisms by which ILs reduce friction and/or wear is still elusive. Here, we combine macroscale tribological experiments with surface-analytical measurements to shed light on the lubrication mechanisms of a class of halogen-free ILs, namely tetraalkylammonium orthoborate ILs, at steel/steel sliding contacts. The tribological results indicate an improvement of the friction-reducing properties of these ILs as the length of the alkyl chains attached to ammonium cations increases. X-ray photoelectron spectroscopy analyses provide further evidence for the dependence of the lubrication mechanism of tetraalkylammonium orthoborate ILs on the IL structure. In the case of tetraalkylammonium orthoborate ILs with asymmetric ammonium cations containing a long alkyl chain, no sacrificial tribofilms were formed on steel surfaces, thus suggesting that the friction-reducing ability of these ILs originates from their propensity to undergo a pressure-induced morphological change at the sliding interface that leads to the generation of a lubricious, solid-like layered structure. Conversely, the higher friction response observed in tribological tests performed with tetraalkylammonium orthoborate ILs containing more symmetric ammonium cations and short alkyl chains is proposed to be due to the inability of this IL to create a transient interfacial layer owing to the reduced van der Waals interactions between the cationic alkyl chains. The resulting hard/hard contact between the sliding surfaces is proposed to lead to the cleavage of boron-oxygen bonds in the presence of water to form species that then adsorb onto the steel surface, including trivalent borate esters and oxalic acid from the decomposition of orthoborate anions, as well as tertiary amines from the degradation of alkylammonium cations induced by hydroxides released during the orthoborate decomposition reaction. The results of this work not only establish links between the molecular structure of a class of halogen-free ILs, their lubricating performance, and lubrication mechanism, but also provide evidence for the existence of multiple mechanisms underpinning the promising lubricating properties of ILs in general. [ABSTRACT FROM AUTHOR]

This work attempts to investigate contact between two self-affine fractal surfaces with one being of a rigid solid and other of a FCC deformable body. A normal contact model between two self-affine fractal surfaces at the nanoscale is established. Effects of surface morphology on contact force, atomic structure, dislocation with normal displacement are investigated by simulating the contact process of self-affine surfaces. Results show that the normal force for rougher surfaces at initial contact yields the larger negative extremum due to effects of surface morphology on interatomic repulsion and attraction. Furthermore, the atomic structure change proportion varies monotonically with normal displacement whereas effects of surface morphology can be approximately ignored. However, the phase transition generated by too large atomic slip leads to a non-monotonic variation between total dislocation lines length and normal displacement. Differences in contact ratio-separation dependence between the classical micro-asperity model and the established model are compared. [ABSTRACT FROM AUTHOR]

Carbon-based materials are widely applied in various devices due to their outstanding mechanical and tribological behaviors. In recent years, more attention has been paid to clarifying the nanocontact mechanisms of carbon-based materials, in order to promote nanoscale applications. The in-situ TEM method is currently the only way that can combine contact behavior and real interface. However, there is still a lack of a systematic summary of in-situ TEM studies on carbon-based materials. Therefore, this work provides an overview of in-situ TEM mechanical and tribological studies on carbon-based materials, consisting of the quantitative actuation and detection for in-situ tests, the strength of fracture and yield, the adhesion between interfaces, the friction performance, and wear features of carbon-based materials with different nanostructures, such as carbon nanotube, graphene, graphite, amorphous, sp2 nanocrystalline, and ultrananocrystalline diamond. Nanostructures play a crucial role in determining mechanical and tribological behaviors. Perspectives on current challenges and future directions are presented, with the aim of promoting the advancement of in-situ TEM research. [ABSTRACT FROM AUTHOR]

The stability and lifetime of electrical contact pose a major challenge to the performance of microelectro-mechanical systems (MEMS), such as MEMS switches. The microscopic failure mechanism of electrical contact still remains largely unclear. Here conductive atomic force microscopy with hot switching mode was adopted to simulate the asperity-level contact condition in a MEMS switch. Strong variation and fluctuation of current and adhesion force were observed during 10,000 repetitive cycles, exhibiting an "intermittent failure" characteristic. This fluctuation of electrical contact properties was attributed to insulative carbonaceous contaminants repetitively formed and removed at the contact spot, corresponding to degradation and reestablishment of electrical contact. When contaminant film was formed, the contact interface became "metal/carbonaceous adsorbates/metal" instead of direct metal/metal contact, leading to degradation of the electrical contact state. Furthermore, a system of iridium/graphene on ruthenium (Ir/GrRu) was proposed to avoid direct metal/metal contact, which stabilized the current fluctuation and decreased interfacial adhesion significantly. The existence of graphene enabled less adsorption of carbonaceous contaminants in ambient air and enhanced mechanical protection against the repetitive hot switching actions. This work opens an avenue for design and fabrication of microscale electrical contact system, especially by utilizing two-dimensional materials. [ABSTRACT FROM AUTHOR]

Discrete dislocation plasticity (DDP) calculations are carried out to investigate the response of a single crystal contacted by a rigid sinusoidal asperity under sliding loading conditions to look for causes of microstructure change in the dislocation structure. The mechanistic driver is identified as the development of lattice rotations and stored energy in the subsurface, which can be quantitatively correlated to recent tribological experimental observations. Maps of surface slip initiation and substrate permanent deformation obtained from DDP calculations for varying contact size and normal load suggest ways of optimally tailoring the interface and microstructural material properties for various frictional loads. [ABSTRACT FROM AUTHOR]

An Extensive Literature Search (ELS) to collect and identify all studies published since 2010 and relevant to the topic mineral oil hydrocarbons in combination with the substance group characterisation, occurrence in food and toxicity was performed in the three databases PubMed, Web of Science and SciFinder® for six Areas. After combination of the searches from the three databases and removal of the duplicates, the total number of references is 2504. The evaluation of all retrieved references for relevance by screening the title and abstract and applying eligibility criteria (inclusion/exclusion) resulted in a total number of relevant references for Area 1 of 55, for Area 2 of 27, for Area 3 of 15, for Area 4 of 21 for Area 5 of 1 and for Area 6 of 6. The total number of relevant references was 93. However, for the substance group POH no relevant reference was identified. Additionally, there are 4 references additionally, which could not be clearly assigned. [ABSTRACT FROM AUTHOR]

Understanding and controlling interface friction are central to many science and engineering applications. However, frictional sliding is closely related to adhesion, surface roughness, surface chemistry, mechanical deformation of contact solids, which poses the major challenge to experimental studying and theoretical modeling of friction. Here, by exploiting the recent developed thermomechanical nanomolding technique, we present a simple strategy to decouple the interplay between surface chemistry, plastic deformation, and interface friction by monitoring the nanoscale creep flow of metals in nanochannels. We show that superhydrophobic nanochannels outperforming hydrophilic nanochannels can be up to orders of magnitude in terms of creep flow rate. The comparative experimental study on pressure and temperature dependent nanomolding efficiency uncovers that the enhanced creep flow rate originates from diffusion-based deformation mechanism as well as the superhydrophobic surface induced boundary slip. Moreover, our results reveal that there exists a temperature-dependent critical pressure below which the traditional lubrication methods to reduce friction will break down. Our findings not only provide insights into the understanding of mechanical deformation and nanotribology, but also show a general and practical technique for studying the fundamental processes of frictional motion. Finally, we anticipate that the increased molding efficiency could facilitate the application of nanoimprinting/nanomolding. Solid-solid interface friction usually becomes the bottleneck at micro/nanoscale. Here, Xiang and Liu show that the nanoscale creep flow rate of crystalline metals can increase by orders of magnitude when the contact metal is in diffusion deformation and the thermally activated boundary slip is active. [ABSTRACT FROM AUTHOR]

It has been demonstrated that in Hertzian and randomly rough surface contact problems, linearity between relative contact area a r and reduced pressure p ∗ ≡ p / (E ∗ g ¯ c) holds if the root mean square gradient g ¯ c is evaluated over the actual contact area. In this study, using Green's function molecular dynamics (GFMD), we show that for (1+1) dimensional contact simulations, the factor κ = a r / p ∗ cannot remain constant and scales linearly with the reduced thickness d ~ ≡ d / a r in the limit of small d ~ , where d is the thickness of elastic body. This linearity not only exists in contacts with smooth indenter with harmonic height profiles, but also in contacts with randomly rough surfaces. The asymptotic curves for both large and small d ~ are presented and validated with numerical simulations based on GFMD. [ABSTRACT FROM AUTHOR]

Using density-functional theory-based molecular dynamics simulations, we study stress and temperature-induced chemical reactions in bulk systems containing triphosphoric acid and zinc phosphate molecules. The nature of the products depends sensitively on the imposed conditions, e.g., isotropic and even more so shear stress create (zwitter-) ionic products. Free ions also emerge from thermal cycles, but the reactions are endothermic rather than exothermic as for stress-induced transitions and zinc atoms remain four-coordinated. Hydrostatic stresses required for reactions to occur lie well below those typical for tribological micro-contacts of stiff solids and are further reduced by shear. Before zinc atoms change their coordination under stress, proton mobility increases, i.e., hydrogen atoms start to change the oxygen atom they are bonded to within 10 ps time scales. The hydrostatic stress for this to occur is reduced with increasing shear. Our finding suggests that materials for which number, nature, and mobility of ions are stress sensitive cannot have a well-defined position in the triboelectric series, since local contact stresses generally depend on the stiffness of the counter body. Moreover, our simulations do not support the idea that chemical reactions in a tribo-contact are commonly those that would be obtained through heating alone. [ABSTRACT FROM AUTHOR]

Contact and friction are closely related as friction cannot happen without contact. They are widely used in mechanical engineering, traffic, and other fields. The real contact surface is not completely smooth, but it is made up of a series of tiny contact asperities as viewed in the micro-scale. This is just the complexity of the contact and friction behaviors of rough surfaces: the overall mechanical behavior is the result of all asperities which are involved during the contact. Due to the multiplicity of surface topography, the complexity of contact scale, and the nonlinearity of the constitutive material, there are still many open topics in the research of contact and friction behavior of rough surfaces. Based on the perspective of the macroscopic and micro-nano scale contact mechanics, this review gives a brief overview of friction for the latest developments and points out the existing issues and opportunities for future studies. [ABSTRACT FROM AUTHOR]

The application of oil-bearing joint that is widely used in various mechanical equipment can effectively improve the dynamic characteristics of integrated machineries. A fractal contact model of oil-bearing joint considering the effect of asperity interaction is proposed in this article. The equivalent stiffness and damping of oil-bearing joint are divided into a solid contact portion and a liquid contact portion. On the basis of elastic mechanics and fractal theory, the deformation of a single asperity of solid contact part is deduced. The stiffness and damping model considering the asperity interaction are obtained from the relationship between normal load and deformation. The stiffness and damping expression of the liquid contact part are also deduced based on the generalized Reynolds equation. It is concluded that the equivalent stiffness increases with the increase of the fractal dimension and the decrease of the fractal roughness parameter. At the same time, increasing the hydrodynamic viscosity can demonstrably improve the contact stiffness. Experiment shows that the proposed model is more in line with the actual load-stiffness relationship. The model considers the factor of asperity interaction and provides a theoretical basis for predicting the dynamic characteristics of oil-bearing joint. An accurate theoretical model of the dynamic characteristics for the oil-bearing joint surface was established. Identification of the dynamic properties of the oil-bearing joint surface using frequency response functions. The factors influencing the stiffness of solid portion and liquid portion were studied, respectively. [ABSTRACT FROM AUTHOR]

Material hardness of natural fiber composites depends upon the orientation of fibers, ratio of fiber to matrix, and their mechanical and physical properties. Experimentally finding the material hardness of composites is an involved task. The present work attempts to explore the deformation mechanism of natural fiber composites subjected to post-yield indentation by a spherical indenter through a two-dimensional finite element analysis. In the present work, jute-polypropylene, sisal-polypropylene, and banana-polypropylene composites are considered. The analysis is attempted by varying the properties of Young's modulus of fiber and matrix, diameter of fiber, and horizontal and vertical center distance between the fibers. The analyses results showed that as the distance between the fiber's center increases, the bearing load capacity of all composite increases nonlinearly. The jute fiber composite shows predominate load-carrying capacity compared to other composites at all L / D ratios and interference ratios. The influence of subsurface stress in lateral direction is minimal and gets reduced as the distance between the fiber centers increases. The variation in diameter of fiber influences significantly, i.e., beyond the L / D ratio of 1.0; for the same contact load ratio, the bearing area support is double for jute-polypropylene composite compared to sisal-polypropylene composite. Compared to the sisal-polypropylene composite, for the same interference ratio, the load-carrying capacity is two times high for banana-polypropylene composite, whereas four times high for jute-polypropylene composite, but this effect decreases as the L / D ratio decreases. In all the composites, the subsurface stress gets distributed as the L / D ratio increases. The ratio of fibers center distance to diameter of fiber influences marginally on the contact load and contact area and significantly on the contact stress for all the fiber-reinforced composites. [ABSTRACT FROM AUTHOR]

The contact behavior of hemisphere pressed by a rigid flat is analyzed based on the finite element method under the condition of independent varying elastic moduli (E) and yield strengths (Y). The contact behavior is related to the ratio of E/Y. The mean contact pressure (p*) first increases and then decreases with the increasing interference, and this trend is more obvious for the contact of materials with the comparatively small ratio of E/Y. The end of the elastoplastic range or the inception of the fully plastic range is determined according to the interference corresponding to the peak value of the p*. The contact load and area in elastoplastic and fully plastic ranges are determined by the interference and the ratio of E/Y. Then, a new contact model to accurately predict the contact load and area for a wide range of E and Y is proposed, and compared with the previous models. The correctness of the current model is verified by the experimental measurement results recorded in previous literature. [ABSTRACT FROM AUTHOR]

The contact behaviour between an ellipsoid and a rigid plane is significant in research on bearing and assembly joint surfaces. However, an empirical relationship between an elastic–plastic ellipsoid and a rigid plane has not been established. In this study, the elastic–plastic contact behaviour between a deformable ellipsoid and a rigid plane was investigated by establishing a new finite element model. The proposed elastic–plastic ellipsoid contact model was designed considering the effects of the ellipticity and strain-hardening rate of the ellipsoid. The strain-hardening rate and ellipticity of the ellipsoid affected the contact area, load and mean pressure. Furthermore, the effect gradually increased with an increase in interference. New dimensionless empirical formulas for determining the contact load and contact area were proposed based on the analysis. The proposed model was validated by comparing the obtained results with previous experimental results and those of theoretical models. This study can be used to predict the elastic–plastic contact parameters between a single ellipsoid and a rigid body, such as bearings, gears and cams. It can also be used to investigate the elastic–plastic contact behaviour between anisotropic rough surfaces composed of asperities with different radii of curvature. [ABSTRACT FROM AUTHOR]

The fascinating tribological phenomenon of carbon nanotubes (CNTs) observed at the nanoscale was confirmed in our numerous macroscale experiments. We designed and employed CNT-containing nanolubricants strictly for polymer lubrication. In this paper, we present the experiment characterising how the CNT structure determines its lubricity on various types of polymers. There is a complex correlation between the microscopic and spectral properties of CNTs and the tribological parameters of the resulting lubricants. This confirms indirectly that the nature of the tribological mechanisms driven by the variety of CNT–polymer interactions might be far more complex than ever described before. We propose plasmonic interactions as an extension for existing models describing the tribological roles of nanomaterials. In the absence of quantitative microscopic calculations of tribological parameters, phenomenological strategies must be employed. One of the most powerful emerging numerical methods is machine learning (ML). Here, we propose to use this technique, in combination with molecular and supramolecular recognition, to understand the morphology and macro-assembly processing strategies for the targeted design of superlubricants. [ABSTRACT FROM AUTHOR]

By seamlessly integrating the wearing comfortability of textiles with the biomechanical energy harvesting function of a triboelectric nanogenerator (TENG), an emerging and advanced intelligent textile, i.e., smart textile TENG, is developed with remarkable abilities of autonomous power supply and self-powered sensing, which has great development prospects in the next-generation human-oriented wearable electronics. However, due to inadequate interface contact, insufficient electrification of materials, unavoidable air breakdown effect, output capacitance feature, and special textile structure, there are still several bottlenecks in the road towards the practical application of textile TENGs, including low output, high impedance, low integration, poor working durability, and so on. In this review, on the basis of mastering the existing theory of electricity generation mechanism of TENGs, some prospective strategies for improving the mechanical-to-electrical conversion performance of textile TENGs are systematically summarized and comprehensively discussed, including surface/interface physical treatments, atomic-scale chemical modification, structural optimization design, work environmental control, and integrated energy management. The advantages and disadvantages of each approach in output enhancement are further compared at the end of this review. It is hoped that this review can not only provide useful guidance for the research of textile TENGs to select optimization methods but also accelerate their large-scale practical process. [ABSTRACT FROM AUTHOR]