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(2060) Chiron is a large centaur that has been reported active on multiple occasions including during aphelion passage. Studies of Chirons coma during active periods have resulted in the detection of C(triple)N and CO outgassing. Significant work remains to be undertaken to comprehend the activation mechanisms on Chiron and the parent molecules of the gas phases detected. This work reports the study of the ices on Chirons surface and coma and seeks spectral indicators of volatiles associated with the activity. Additionally, we discuss how these detections could be related to the activation mechanism for Chiron and, potentially, other centaurs. In July 2023, the James Webb Space Telescope (JWST) observed Chiron when it was active near its aphelion. We present JWST/NIRSpec spectra from 0.97 to 5.27 microns with a resolving power of 1000, and compare them with laboratory data for identification of the spectral bands. We report the first detections on Chiron of absorption bands of several volatile ices, including CO2, CO, C2H6, C3H8, and C2H2. We also confirm the presence of water ice in its amorphous state. A key discovery arising from these data is the detection of fluorescence emissions of CH4, revealing the presence of a gas coma rich in this hyper-volatile molecule, which we also identify to be in non-local thermal equilibrium (nonLTE). CO2 gas emission is also detected in the fundamental stretching band at 4.27 microns. We argue that the presence of CH4 emission is the first proof of the desorption of CH4 due to a density phase transition of amorphous water ice at low temperature in agreement with the estimated temperature of Chiron during the JWST observations (61 K). Detection of photolytic and proton irradiation products of CH4 and CO2 on the surface, in the coma ice grains, or in the ring material is also detected via a forest of absorption features from 3.5 to 5.3 microns., Comment: 4 figures in paper plus 2 more in the appendix. Accepted as A&A Letter

We observed Sedna, Gonggong, and Quaoar with the NIRSpec instrument on the James Webb Space Telescope (JWST). All three bodies were observed in the low-resolution prism mode at wavelengths spanning 0.7 to 5.2 $\mu$m. Quaoar was also observed at 10x higher spectral resolution from 0.97 to 3.16 $\mu$m using medium-resolution gratings. Sedna's spectrum shows a large number of absorption features due to ethane (C$_2$H$_6$), as well as acetylene (C$_2$H$_2$), ethylene (C$_2$H$_4$), H$_2$O, and possibly minor CO$_2$. Gonggong's spectrum also shows several, but fewer and weaker, ethane features, along with stronger and cleaner H$_2$O features and CO$_2$ complexed with other molecules. Quaoar's prism spectrum shows even fewer and weaker ethane features, the deepest and cleanest H$_2$O features, a feature at 3.2 $\mu$m possibly due to HCN, and CO$_2$ ice. The higher-resolution medium grating spectrum of Quaoar reveals several overtone and combination bands of ethane and methane (CH$_4$). Spectra of all three objects show steep red spectral slopes and strong, broad absorptions between 2.7 and 3.6 $\mu$m indicative of complex organic molecules. The suite of light hydrocarbons and complex organic molecules are interpreted as the products of irradiation of methane. We infer that the differences in apparent abundances of irradiation products are likely due to their distinctive orbits, which lead to different timescales of methane retention and to different charged particle irradiation environments. In all cases, however, the continued presence of light hydrocarbons implies a resupply of methane to the surface. We suggest that these three bodies have undergone internal melting and geochemical evolution similar to the larger dwarf planets and distinct from all smaller KBOs., Comment: 32 pages, 9 figures, 5 tables, accepted for publication in Icarus

James Webb Space Telescope's NIRSpec infrared imaging spectrometer observed the outer solar system dwarf planets Eris and Makemake in reflected sunlight at wavelengths spanning 1 through 5 microns. Both objects have high albedo surfaces that are rich in methane ice, with a texture that permits long optical path lengths through the ice for solar photons. There is evidence for N2 ice absorption around 4.2 um on Eris, though not on Makemake. No CO ice absorption is seen at 4.67 um on either body. For the first time, absorption bands of two heavy isotopologues of methane are observed at 2.615 um (13CH4), 4.33 um (12CH3D), and 4.57 um (12CH3D). These bands enable us to measure D/H ratios of (2.5 +/- 0.5) x 10-4 and (2.9 +/- 0.6) x 10-4, along with 13C/12C ratios of 0.012 +/- 0.002 and 0.010 +/- 0.003 in the surface methane ices of Eris and Makemake, respectively. The measured D/H ratios are much lower than that of presumably primordial methane in comet 67P/Churyumov-Gerasimenko, but they are similar to D/H ratios in water in many comets and larger outer solar system objects. This similarity suggests that the hydrogen atoms in methane on Eris and Makemake originated from water, indicative of geochemical processes in past or even ongoing hot environments in their deep interiors. The 13C/12C ratios are consistent with commonly observed solar system values, suggesting no substantial enrichment in 13C as could happen if the methane currently on their surfaces was the residue of a much larger inventory that had mostly been lost to space. Possible explanations include geologically recent outgassing from the interiors as well as processes that cycle the surface methane inventory to keep the uppermost surfaces refreshed.

The NASA Lucy mission is aimed at the study of the very interesting population of Jupiter Trojans, considered as time capsules from the origin of our solar system. During its journey, the mission will pass near a main belt asteroid, Donaldjohanson. Recently, NASA has announced that a new asteroid in the belt will also be visited by Lucy: 152830 Dinkinesh (1999 VD57). The main goal of this work is to characterise this newly selected target, asteroid Dinkinesh, in order to provide critical information to the mission team. To achieve it, we have obtained visible spectra, colour photometry, and time-series photometry of Dinkinesh, using several telescopes located at different observatories. For the spectra we used the 10.4m Gran Telescopio Canarias (GTC), in the island of La Palma (Spain); for the colour photometry the 4.3m Lowell Discovery Telescope (LDT), near Happy Jack, Arizona (USA) was used; and for the time-series photometry we used the 82cm IAC80 telescope located in the island of Tenerife (Spain). Both visible spectrum and reflectance values computed from colour photometry show that Dinkinesh is an S-type asteroid, i.e., it is composed mainly of silicates and some metal. According to observations done by the NEOWISE survey, S-type asteroids have typical geometric albedo of $p_V$ = 0.223 $\pm$ 0.073. From our time-series photometry, we obtained an asteroid mean magnitude $r'$ = 19.99 $\pm$ 0.05, which provides an absolute magnitude $H_{r'}$ = 17.53 $\pm$ 0.07 assuming $G$ = 0.19 $\pm$ 0.25 for S-types. Using our colour-photometry, we transformed $H_{r'}$ to $H_V$ = 17.48 $\pm$ 0.05. This value of absolute magnitude combined with the geometric albedo provides a mean diameter for Dinkinesh of $\sim$900 m, ranging between a minimum size of 542 m and a maximum size of 1309 m., Comment: 4 pages, 3 figures, Accepted for publication in A&A