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Unitarity sets upper limits on partial-wave elastic and inelastic cross-sections, which are often violated by perturbative computations. We discuss the dynamics underlying these limits in the non-relativistic regime, namely long-range interactions, and show how the resummation of the 2-particle-irreducible diagrams arising from squaring inelastic processes unitarizes both elastic and inelastic cross-sections. We provide a simple prescription to obtain the unitarized cross-sections from those that do not include resummation of the squared inelastic processes. Our results are model-independent, apply to all partial waves, and affect elastic and inelastic cross-sections, with extensive implications for new physics scenarios, such as dark-matter freeze-out, indirect detection and self-interactions., Comment: 12 pages, 4 figures; v2. discussion expanded, published version

The formation and decay of metastable bound states can deplete significantly the density of multi-TeV thermal-relic dark matter. The effect depends on the interplay of bound-state formation, ionisation, transition and decay processes. Existing calculations take into account bound-state ionisation and excitations due to the radiation of the thermal bath. However, the dynamics of Hydrogen recombination suggests that the resonant radiation produced in bound-state formation or de-excitations may backreact, ionising or exciting the bound states thus impeding recombination. In this paper we examine this effect in the context of dark-matter freeze-out. To this end, we employ the generalised Saha equilibrium equation for metastable bound states, and discuss its salient features. We show that, in sharp contrast to Hydrogen recombination, the radiation produced during dark matter freeze-out is more likely to thermalise or redshift, rather than ionise or excite the metastable bound states. This holds not only for the low-energy (resonant) radiation produced in bound-state formation and transition processes, but also for the high-energy radiation produced in dark-matter annihilations and bound-state decays. While our computations are carried out in a minimal dark $U(1)$ model, our conclusions only strengthen in more complex models., Comment: 30 pages, 8 figures, minor corrections, published version

The formation and decay of metastable bound states can significantly decrease the thermal-relic dark matter density, particularly for dark matter masses around and above the TeV scale. Incorporating bound-state effects in the dark matter thermal decoupling requires in principle a set of coupled Boltzmann equations for the bound and unbound species. However, decaying bound states attain and remain in a quasi-steady state. Here we prove in generality that this reduces the coupled system into a single Boltzmann equation of the standard form, with an effective cross-section that describes the interplay among bound-state formation, ionisation, transitions and decays. We derive a closed-form expression for the effective cross-section for an arbitrary number of bound states, and show that bound-to-bound transitions can only increase it. Excited bound levels may thus decrease the dark matter density more significantly than otherwise estimated. Our results generalise the Saha ionisation equilibrium to metastable bound states, potentially with applications beyond the dark matter thermal decoupling., Comment: v2: toy model added, discussion on validity of steady-state approximation improved; published in PLB