Search

A mixture DMSO-allyl bromide has been developed as a reagent for an atom economic one-pot N -allylation and aryl bromination under basic conditions. Utilizing this reagent, N -allylation-bromination of a number of 2°-aryl amines, aryl aminoamides, indoles, and 7-aza indoles has been achieved. The scope of the substrates and limitations, the synthetic utility of the products, and a plausible reaction mechanism have been proposed., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)