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As prominent abrupt climatic events during the last deglaciation and the early Holocene, the Younger Dryas (YD) and the 8.2 ka events have been intensely discussed to reveal the relationship between their phases and intensities, and their underlying mechanisms based on massive marine and terrestrial archives. However, the related paleoclimate records with sufficient resolution and/or precise age constraints from the Southern Hemisphere, especially East Africa, are relatively sparse, hindering our comprehensive understanding about the phases of these two events. Here, we provide a precisely dated record of an aragonite-calcite stalagmite covering 11.3–13.5 ka BP from northwest Madagascar to unravel the arid conditions during the YD, in contrast to the pluvial conditions in the 8.2 ka event that has been evidenced before. Changes in austral summer precipitation related to the Intertropical Convergence Zone (ITCZ) have always been interpreted to be the primary means of controlling regional rainfall amounts and thus the δ18O variations in stalagmite. However, ITCZ's meridional migration alone is not enough to interpret the opposite hydroclimatic conditions during the YD and the 8.2 ka events in northwest Madagascar. The variation in convection intensity within the ITCZ combined with the rainfall dipole mode in East Africa, and the redistribution of the duration of the ITCZ's presence at different latitudes might be responsible for this phenomenon. In addition, sea surface temperature could play a nonnegligible role. [ABSTRACT FROM AUTHOR]

The Marine Isotope Stage (MIS5e) is characterized by a warmer climate than that of the pre-industrial period, and serves as an analog for the Current Warm Period (CWP). However, uncertainties persist regarding its climatic stability. Here, we retrieved a stalagmite (WXB075) from Wanxiang Cave in the eastern Qinghai-Tibetan Plateau, and employed absolute 230Th dating and relative annual layer data to establish a high-precision chronological framework for reconstructing the history of the Asian summer monsoon (ASM) and environmental evolution during early MIS5e with multiple proxies. The findings indicate that the annually laminated stalagmite was formed during Cooling Event 27 (C27). The deposition of WXB075 experienced a hiatus (∼125.58 ka BP) due to a significant cooling event in the North Atlantic, which may be linked to the unstable climate in the Northern Hemisphere. Additionally, the impact of meltwater discharge in high northern latitudes results in a two-phase evolution of the ASM, i.e., an initial weaker stage followed by a gradual increase (with the exception of deposition hiatus). The climatic instability of ASM is generally characterized by a quasi-60 year cycle that affects vegetation conditions, biological productivity, and karst hydroclimate dynamics. However, the increase in meltwater and decrease in temperature in the Northern Hemisphere have led to a weakened ASM and subsequent reduction in precipitation. Consequently, vegetation degradation above the cave has occurred along with a slowdown of karst hydroclimate. The vegetation conditions, organic matter content, and wet/drought of the karst hydroclimate were affected by both the large-scale monsoon circulation and local environment during extreme weakening (strengthening) of the monsoon when high-frequency climatic events of ASM occurred. A comparison of δ18O records between early MIS5e and the past 2000 years reveals that the climate during early MIS5e differed significantly from that of CWP, Medieval Warm Period (MWP), and Dark Age Cold Period (DACP) but was similar to Little Ice Age (LIA). Comparison with other geological records from the Northern Hemisphere indicates that climate instability was a widespread phenomenon during MIS5e. The power spectrum analysis of WXB075 δ18O reveals significant quasi-60 and 35 a cycles during the early MIS5e, which is consistent with the Atlantic Multidecadal Oscillation (AMO). The comprehensive results demonstrate that the ASM in the early MIS5e was closely linked to solar activity, Intertropical Convergence Zone (ITCZ) position, and Atlantic Meridional Overturning Circulation (AMOC). [ABSTRACT FROM AUTHOR]

The 8.2 ka event has been extensively studied, whereas its structure is ambiguous in North China. Here we present a high‐resolution (∼1 year) δ18O record from annual laminated speleothem from Beijing to characterize the detailed variability across this event in North China. Our record indicates a dry 8.2 ka event spanning 8.254–8.107 ka BP with a two‐stage structure superimposed by three prominent high δ18O excursions. The identical structure of speleothem δ18O records between North and central China during the event suggests a common forcing/response in East China, whereas the progressively increased offset between their average values may reflect changes in moisture source or rainout effect. A close comparison with the Greenland ice core records suggests a strong linear response of the Asian summer monsoon to the North Atlantic climate changes across the early and middle stages of the event, but a different mechanism in the termination processes. Plain Language Summary: As the most pronounced abrupt climate event in the Holocene, the 8.2 ka event has been studied using various geological archives worldwide, but its detailed structure in North China and its link to other climate systems remain poorly understood. Since the Beijing speleothem δ18O, a proxy of the precipitation δ18O, is sensitive to the Asian summer monsoon (ASM) variations, it allows us to establish precise timing and structure of the 8.2 ka event and estimate the cause of it. Our new speleothem δ18O record from Beijing reveals a two‐stage structure superimposed by three "V‐shape" excursions during the event and almost exactly covaries with another published speleothem record from central China, suggesting coherent climate changes over the east ASM domain in response to the same forcing. The gradually increased offset between them probably results from the changed atmospheric circulations. Our results suggest a fast climatic signal propagation from the North Atlantic to the ASM domain during the early and middle 8.2 ka event, and another forcing mechanism in the termination processes. Key Points: Annual laminated speleothem δ18O record from North China manifests a two‐stage 8.2 ka event superimposed by three positive excursionsHigh consistency in speleothem records from North and central China on interdecadal to multidecadal timescales indicates a common driverThe climate forcing for the termination process is different from the early and middle stages of the 8.2 ka event [ABSTRACT FROM AUTHOR]

The objective of this work is to propose a more effective way to prepare an in-house CO2 with known triple oxygen isotope compositions. The major experimental steps include: (1) the O2 is combusted to CO2 on a graphite rod at 750 °C with Pt-catalyst for 3–4 min; and (2) converted CO2 is subsequently purified by two cryogenic traps. The results show high reproducibility of δ13C and δ18O values of the converted CO2 within 0.010–0.020 ‰ and 0.006–0.010 ‰ (1σ, SD), and the identical δ18O value within error with that of the original O2. Additionally, we have measured the triple oxygen isotope compositions of converted CO2 using an O2–CO2 Pt-catalyzed oxygen-isotope equilibration method. The measured δ17O values of CO2 show high reproducibility within 0.006 ‰ (1σ, SD), and are identical within error with the original O2 as well. Notably, our experiments also found that the O2 with heavier oxygen isotope ratios (δ18O > 40 ‰, VSMOW) might have a lesser conversion efficiency, and this effect, combined with the lighter isotope preferential fractionations during the reaction processes of O2 to CO and CO to CO2, may explain the observed lower 17O/16O and 18O/16O ratios of the converted CO2 relative to the original O2. [ABSTRACT FROM AUTHOR]

The difficulty in constraining the large-scale Asian summer monsoon (ASM) variability in the Chinese monsoon region (CMR) during glacial Termination II lies in our limited knowledge of the western part, primarily due to sparse paleoclimate records. To get a better picture of the ASM during Termination II, we examined a precisely dated stalagmite δ18O record between 133.1 and 127.0 kyr B.P. from Wanxiang Cave located at the ASM's northern edge in western China. In combination with published δ18O data from this cave, we have identified the 'Weak Monsoon Interval' (WMI) in the Wanxiang δ18O record and confirmed that the Heinrich 11 cold event in the North Atlantic caused the weakened ASM over the CMR via reorganization of the large-scale ocean-atmospheric circulation. However, the post-WMI change in δ18O is gradual, in contrast with the abrupt shift shown in the other cave records from southern and northeastern China. The rapid northward migration of the westerly jet relative to the Qinghai-Tibet Plateau is probably responsible for this discrepancy. This northward-positioned westerly jet prevented the more 18O-depleted moisture from the Indian Ocean from reaching the study site. Simultaneously, it facilitated the earlier northward movement of the East Asian summer monsoon (EASM) rainband that carries positive precipitation δ18O to obscure the abrupt decrease in our δ18O record. After the onset of the last interglacial, no obvious Younger Dryas (YD)-like event was recorded in Wanxiang Cave. This result is consistent with most stalagmite δ18O records in the CMR and further suggests a minimal impact of the YD-like event on ASM variabilities. The relatively large amplitude of δ18O variations observed in Wanxiang Cave between the late penultimate glacial and the last interglacial corresponds to a dominant control of the Indian summer monsoon (ISM), whereas smaller δ18O amplitudes were recorded in cave sites mainly under the influence of both ISM and EASM. Therefore, we posit that the heterogeneity of the hydroclimate in the CMR during Termination II resulted from a combination of multiple processes, that is, the westerly jet, ISM and EASM, rather than a single one. • A precisely dated stalagmite from the ASM's northern edge in western China reveals ASM variability during Termination II. • Our δ18O records capture the WMI event, which corresponds well to the HS 11 period at northern high latitudes. • Gradually changes in δ18O at the onset of the last interglacial are due to the abrupt northward shift of the westerly jet. • The YD-like event did not have a far-reaching impact on ASM variabilities in the Chinese monsoon region. • Moisture sources cause the amplitude discrepancies in Chinese stalagmite δ18O records during the penultimate deglaciation. [ABSTRACT FROM AUTHOR]

Speleothem oxygen isotope (δ18O) constitutes one of key proxies to reconstruct the Indian and East Asian summer monsoon (ISM and EASM) hydroclimate history on a wide range of timescales. Here, we use three new well-dated speleothem δ18O records from Tianmen cave, in the south-central Tibetan Plateau (TP), together with previous records from the same cave, to reconstruct a composite Tianmen record spanning over the past 414,000 years. The Tianmen δ18O record follows Northern Hemisphere summer insolation (NHSI), broadly coherent with speleothem δ18O records from both ISM and EASM regimes. In comparison with previous model simulations and modern hydroclimate analyses, the Tianmen δ18O was interpreted primarily as a proxy indicating the ISM intensity. The Tianmen δ18O record comprises both high and low NHSI time periods, which reveals an exceptional large amplitude (∼14‰) of δ18O variations at the precession band, possibly resulted from a combination effect of precipitation amount, moisture source, transport pathway, high elevation and rainout. Besides, a broad consistency on orbital-scale variability among Tianmen δ18O, δ13C and trace element records is found, suggesting that the ISM intensity regulates the effective rainfall at the cave site as well. Notably, Tianmen speleothem growth occurred merely during warm-wet interglacial periods, even during low NHSI times near the precession maximum, and in contrast, hiatuses persistently occurred throughout cold-dry glacial periods. This pattern is similar to that found in travertine formations in the region, both suggesting that the interglacial temperature might be a prerequisite for speleothem/travertine formations in the region, while the strong ISM precipitation in turn provides a sufficient condition. Our new Tianmen record, combined with a large set of speleothem records from both Asian Westerlies and Asian monsoon domains, gives further evidence to reinforce a previous hypothesis: a consistent temporal pattern in the δ18O of precipitation on orbital and millennial scales over the vast Asian monsoon and Westerlies regimes. As such, in order to reconcile the precipitation δ18O variations between speleothem and TP ice cores, we argue that the Guliya ice-core chronology may have a basal age of ∼70 ka BP , which is supported by recent dating results from the Guliya ice cap. • Speleothem δ18O records from the south-central Tibetan Plateau primarily indicate the Indian summer monsoon (ISM) intensity. • Combined effect results in a large amplitude (∼14‰) of Tianmen cave δ18O variations at the precession band. • Interglacial temperature and high ISM precipitation are critical factors for the speleothem formations in the region. [ABSTRACT FROM AUTHOR]

The Sansha Yongle Blue Hole (SYBH) is the deepest (301.19 m) blue hole known in the world and is a water-filled karst opening in the intertidal reef flats of the eastern Yongle Atoll, Xisha Islands, South China Sea. It is differentiated from the surrounding environment by its deep blue colour as observed when viewed from above. The SYBH exhibits extremely rare karst networks and speleothems and differs from the blue holes of the Bahamas and Bermuda, indicating a different development process. Here, we present the morphology and U Th ages of the SYBH, which document the evolution of the coastal cave over time. Morphology and lithostratigraphy indicate that the hole resulted from dissolution via ascending acidic water/gas followed by subsequent collapse. The adjacent volcanoes surrounding the eastern Yongle Atoll are the most likely source of these ascending fluids. U Th ages of the cemented carbonate sand underlying the entrance constrain an upper limit of the opening time of the SYBH to be up to 111.7 ± 9.5 kyr BP. Deeply submerged speleothems at −116 m determine the lower collapse time of the SYBH to be 29.16 ± 0.17 kyr BP. The SYBH probably formed due to the upward release of volcanogenic acid water/gas through low-lying unconsolidated carbonate sediments, followed by buoyant collapses due to a 40-m fall in the sea level during 31–29 kyr BP. As the sea level rose to −15 m in the early Holocene, corals grew in the cave opening since 8.58 kyr BP and surrounded the entrance for the SYBH. • SYBH may be dissolved by volcanic related ascending acidified gases or waters. • SYBH could collapse at about 29 kyr BP due to a rapid sea-level fall. • Optical U Th dating suggests Pleistocene eolianites in the Xisha Islands deposited during MIS 5. [ABSTRACT FROM AUTHOR]

Large volumes of travertine deposits are preserved at hydrothermal spring sites on the Tibetan Plateau (TP). Yet, most of these deposits are under-researched with respect to their diagenetic and depositional history and there is still very limited understanding of the tectonic and climatic influences on travertine precipitation in the arid high-altitude setting of Tibet. In this study, a detailed uranium-series dating campaign was carried out for the Qiusang travertine (~4270 m above sea level), southern Tibet that has been previously dated back to 486 thousand years ago (ka). Based on 42 new 230Th/U ages, combined with geomorphological and sedimentological investigations, several travertine zones were identified and distinct travertine depositional phases constrained: 11.7–6.8 ka and ~ 13.4 ka (zone 1), 128–122 ka (zone 2), ~193 ka (zone 3), ~292 ka and 324 ka (zone 4), >317 ka (zone 5), ca. 415 to 470 ka (zone 6) and ca. 419 to 445 ka (zone 7). Comparison of these depositional phases with local and regional proxy records suggests that travertine accumulation at Qiusang occurred during main interglacials when monsoon precipitation peaked on the TP. This coincidence, together with a sensitive response of Tibetan hydrothermal spring activity to meteoric recharge, implies that climate controls the precipitation of large travertine volumes on orbital timescales on the plateau. We propose that (i) tectonic activity is of subordinate importance and influences travertine precipitation on the TP only episodically and on significantly shorter (i.e. centennial to millennial) timescales related to the recurrence rates of large earthquakes and that (ii) intensive monsoonal-driven groundwater recharge is required on top of tectonic activity for generating volumetrically significant travertine accumulations. Because of the high precipitation rates typical for hydrothermal spring carbonates, we conclude that travertine deposits on the TP could be utilized as valuable high-resolution proxy records of peak monsoon conditions in the currently arid to semi-arid landscape. Furthermore, the Qiusang travertine zone 7 is terraced and the travertine layers adjusted to a paleo-riverbed elevation ~30 m above the current river, allowing us to constrain fluvial incision to ~0.07 m/ka for the south-central sector of the TP since the Mid-Pleistocene. The abundant travertine occurrences in Tibet in combination with uranium-series dating can thus also provide detailed insights into earth surface dynamics and landscape evolution on the world highest plateau. • A detailed 230Th/U dating campaign was conducted for the Qiusang travertine, Tibet. • Travertine deposition is restricted to interglacial conditions with peak monsoon. • Climatic controls on Tibetan travertine growth are on top of tectonic influences. • U Th ages of terraced travertines constrain a fluvial incision rate of ~0.07 m/ka. [ABSTRACT FROM AUTHOR]

High-resolution and precisely dated hydroclimate records in the southeastern Tibetan Plateau (TP) remain sparse beyond the Holocene, which hampers our ability to understand the hydroclimate variability in this important Indian summer monsoon (ISM) fringe area and its global teleconnection. Here we present 3-y resolution δ18O and δ13C records from a laminated stalagmite (RG-3) from Rige Cave in the southeastern TP, spanning the Younger Dryas (YD). The records allow us to precisely characterize the timing, structure, and particularly centennial-scale events within the YD, and probe the control factors of precipitation δ18O (δ18O p) in the ISM fringe area. On centennial–millennial timescales, the Rige δ18O record shows coherent pattern with the East Asian summer monsoon (EASM) counterpart, combined with modeled δ18O p results and spatial analysis, suggesting that δ18O p in this part of the TP is largely controlled by the large-scale atmosphere circulation (or the ISM strength), and the altitude increase in the TP may not potentially result in an opposite δ18O p pattern at least in the monsoonal TP regime. We also found significant δ13C-δ18O covariation on the centennial timescale, suggesting a coincided ISM rainfall and biomass change during the YD. In the Rige records, one weak centennial-scale ISM event (namely the intra-Allerød cold period, IACP) and three strong centennial-scale ISM events within the YD (namely A1′-A2′-A3′) were prominent and occurred between ∼12,470 and 12,310 ± 14, ∼12,210–12,090 ± 12 and ∼12,010–11,920 ± 12 y BP (before present, where present = 1950 CE), respectively. Spectral analyses of Rige records also revealed a significant ∼200-y periodicity, which is nearly in-phase with observed centennial-scale variations of the North Atlantic temperature and mid-latitude westerly-jet during that time. These observations support the hypothesis that the solar de Vries cycle (207-y) triggered the centennial-scale climate variations in high northern latitude, leading to the ISM variations via fast atmospheric processes. • Precipitation δ18O and its millennial-centennial patterns in SE Tibet Plateau are controlled by large monsoon circulations • Centennial δ13C-δ18O covariations in Younger Dryas suggest a link of the local biomass to Indian summer monsoon rainfall • Centennial Indian summer monsoon events in Younger Dryas correlate precisely to the North Atlantic climate variations • Solar de Vries cycle (207-y) triggered centennial Indian summer monsoon variations via North Atlantic climate changes [ABSTRACT FROM AUTHOR]

Although the 8.2 ka event is a well-known globally documented abrupt climate event, its detailed expression in tropical southeastern Africa is poorly constrained. Here we present a high resolution and precisely dated record of the regional hydroclimatic variability between 8.5–7.5 ka BP from a polymorphic speleothem (ABC-1) from northwestern Madagascar. In combination with the exclusive recurrences of calcite layers (indicative of wetter conditions), the distinctly negative excursions in the ABC-1 δ18O record manifest a wet 8.2 ka event that spanned from 8.230 to 8.053 ka BP. The event is characterized by the replacement of shorter-term (interannual to interdecadal) δ18O-δ13C coherence with the longer-term (multidecadal to centennial) coherence, suggesting a stable and well-developed forest system during the 8.2 ka event. Our data reveal a two-stage structure of the 8.2 ka event, which is superimposed with two brief pluvial episodes in each stage. The widely documented two peaks/troughs during Stage-I suggest rapid propagation of climate signal through atmospheric processes triggered initially by the freshwater forcing, whereas the divergent behaviors of the peaks/troughs in Stage-II in different climate systems may suggest a different forcing. • Exclusively episodic deposition of the calcite layers and lower speleothem δ18O manifest a wet 8.2 ka event in NW Madagascar. • The 8.2 ka event in NW Madagascar exhibits a two-stage structure with each stage superimposed by two severe pluvial episodes. • The timescale variation of coherence between δ18O and δ13C indicates the resilience of the ecosystem to climate change. [ABSTRACT FROM AUTHOR]