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This paper presents the analytical process of porous functionally graded graphene-reinforced truncated conical shells subjected to hydrostatic pressure and axial tension. Three types of graphene platelet (GPL) dispersion and three patterns of porous distribution were considered. A modified model, in which the volume fraction of the pores is regarded as the essential parameter, was built to evaluate the material properties. The static stability equations of the shells, coupled with the effect of the combined forces, were derived. The Galerkin integrate technique was employed to obtain the critical buckling hydrostatic pressure and axial tension. After the present method was validated, the influences of pores, GPLs, and shell geometrical characteristics were investigated in the parametric studies. The results show that the critical hydrostatic pressure and axial tension can be elevated by increasing the porous coefficient, semi-vertex, and length–thickness ratio. On the contrary, the critical pressure and tension are decreased with the rise of GPL mass fraction. [ABSTRACT FROM AUTHOR]

Incorporation of flexible monomer is regarded as a valid way to the chemical modification of the highly brittle poly(cyclohexene carbonate) (PCHC), which derived from the copolymerization of CO2 and cyclohexene oxide (CHO). However, toxic metal catalyst such as cobalt dominates these terpolymerizations which against the green development philosophy. Here, a series of environmentally benign aluminum porphyrin catalysts with different steric and electronic effects for the terpolymerization of CO2, CHO, and terminal epoxides with various flexible pendant alkyl groups to adjust the properties of PCHC is reported. The resulting terpolymers display a random distribution of cyclohexene carbonate along the backbone with a regulated terminal epoxide insertion from 30% to 70%. Moreover, the mechanical properties can be well regulated in a wide range indicating the feasibility of the present approach. The present study provides a green way to chemical modification of rigid PCHC. [ABSTRACT FROM AUTHOR]