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New conception of adiabatic shear bands (ASB) and adiabatic shear failure mechanisms are proposed as special type of critical phenomen, structural-scaling transition, in the ensembles of microshears, governed by the characteristic non-linearity (metastability) of stored (free) energy of solid with mesodefects. Corresponding free energy release kinetics provides experimentally observed ASB induced staging of plastic strain localization and transition to adiabatic shear failure. ASB staging follows to collective properties of microshears ensemble given by the self-similar solutions of evolution equation providing spatial-temporal microshears localization, momentum transfer and damage localization. The criticality of ASB induced plastic strain localization and failure allows us to avoid the discrepancy in the interpretation of ASB effects as thermo-plastic instability in the balance of the stored energy and structural DRX transformation. The microshear ensemble is considered as the second phase and initiation of collective modes provide different staging according to the metastability decomposition and ASB scaling properties following to the self-similar solutions. Self-similar nature of microshears collective modes providing the ASB dynamics is analyzed as the mechanism of steady plastic wave front unversality in shocked materials. The dynamic split Hopkinson pressure bar tests were conducted with AlMg6 alloy combined with �in-situ� imaging of temperature kinetics by CEDIP Silver 450M high-speed infrared camera with conclusion of the secondary role of thermoplastic instability at the ASB staging. The microstructural study performed by an electron microscopy revealed the correlated behavior of the ensemble of defects, which can be classified as a structural transition and precursor of ASB induced strain localization and failure. The modeling reflecting the links of self-similar solutions in microshear ensembles with relaxation properies and damage localization was applied for the comparative analysis of ASB staging and temperature dynamics given be the infrared imaging

This paper is devoted to the study of active and stable nickel catalysts for methane dry reforming based on Pr-doped ceria–zirconia obtained via the solvothermal continuous method. Studies on the physicochemical and catalytic properties of the 5%Ni/Ce0.75Zr0.25−xPrxO2 series have showed that Pr introduction leads to an increase in the amount of highly reactive oxygen in the oxide lattice. Praseodymium-based catalysts showed significantly higher reactant conversions. In addition to the nature of support, the method of nickel introduction was also studied; Ni was added both using impregnation and the one-pot procedure with mixed oxide preparation. The method of Ni addition was shown to have significant effect on the morphology of its particles and Ni-support interaction, and, respectively, on catalytic activity and coking stability. The 5%Ni/Ce0.75Zr0.15Pr0.1O2 catalyst prepared by one-pot method showed stable operation in the MDR reaction for 30 h at CO2 and CH4 conversions of ~40% and an H2 yield of ~18% (T = 700 °C, τ = 10 ms).

Two series of Ni/Ce(Ti/Nb)ZrO2 catalysts were prepared using citrate route and original solvothermal continuous flow synthesis in supercritical isopropanol and studied in dry reforming of methane (DRM). TEM, XPS and FTIRS of adsorbed CO confirm influence of support composition and preparation method on the catalysts’ morphology and surface features. The oxygen mobility was studied by isotope heteroexchange with C18O2. After testing in DRM, carbon deposits after catalysts’ testing in DRM were investigated by temperature-programmed oxidation with thermo-gravimetric analysis. The lowest amounts of carbon deposits were obtained for unmodified Ni-CeZr and Ni-CeNbZr compositions. Ti addition lead to an increased amount of carbon, which was removed at higher temperatures. The use of supercritical supports also resulted in the formation of a higher amount of coke. Catalysts prepared by the supercritical synthesis were tested in DRM for 25 h. The highest activity drop was observed in the first three hours. For all compositions, close values of carbon deposits were revealed.