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The organizational complexity of biominerals has long fascinated scientists seeking to understand biological programming and implement new developments in biomimetic materials chemistry. Nonclassical crystallization pathways have been observed and analyzed in typical crystalline biominerals, involving the controlled attachment and reconfiguration of nanoparticles and clusters on organic templates. However, the understanding of templated amorphous silica mineralization remains limited, hindering the rational design of complex silica-based materials. Here, we present a systematic study on the stabilization of self-capping cationic silica cluster (CSC) and their assembly dynamics using DNA nanostructures as programmable attachment templates. By tuning the composition and structure of CSC, we demonstrate high-fidelity silicification at single-cluster resolution, revealing a process of adaptive templating involving cooperative adjustments of both the DNA framework and cluster morphology. Our results provide a unified model of silicification by cluster attachment and pave the way towards the molecular tuning of pre- and post-nucleation stages of sol-gel reactions. Overall, our findings provide new insights for the design of silica-based materials with controlled organization and functionality, bridging the gap between biomineralization principles and the rational design of biomimetic material.

DNA monolayers with inherent chirality play a pivotal role across various domains, including biosensors, DNA chips, and bioelectronics. Nonetheless, conventional DNA chiral monolayers, typically constructed from single-stranded DNA (ssDNA) or double-stranded DNA (dsDNA), often lack structural orderliness and design flexibility at the interface. Structural DNA nanotechnology emerges as a promising solution to tackle these challenges. In this study, we present a strategy for crafting highly adaptable twisted DNA origami-based chiral monolayers. These structures exhibit distinct interfacial assembly characteristics and effectively mitigate the structural disorder of dsDNA monolayers, which is constrained by a limited persistence length of ~50 nm of dsDNA. We highlight the spin-filtering capabilities of four representative DNA origami-based chiral monolayers, demonstrating a maximal one-order-of-magnitude increase in spin-filtering efficiency per unit area compared to conventional dsDNA chiral monolayers. Intriguingly, our findings reveal that the higher-order, tertiary, chiral structure of twisted DNA origami further enhances the spin-filtering efficiency. This work paves the way for the rational design of DNA chiral monolayers.

Federated learning is a distributed machine learning system that uses participants' data to train an improved global model. In federated learning, participants cooperatively train a global model, and they will receive the global model and payments. Rational participants try to maximize their individual utility, and they will not input their high-quality data truthfully unless they are provided with satisfactory payments based on their data quality. Furthermore, federated learning benefits from the cooperative contributions of participants. Accordingly, how to establish an incentive mechanism that both incentivizes inputting data truthfully and promotes stable cooperation has become an important issue to consider. In this paper, we introduce a data sharing game model for federated learning and employ game-theoretic approaches to design a core-selecting incentive mechanism by utilizing a popular concept in cooperative games, the core. In federated learning, the core can be empty, resulting in the core-selecting mechanism becoming infeasible. To address this, our core-selecting mechanism employs a relaxation method and simultaneously minimizes the benefits of inputting false data for all participants. However, this mechanism is computationally expensive because it requires aggregating exponential models for all possible coalitions, which is infeasible in federated learning. To address this, we propose an efficient core-selecting mechanism based on sampling approximation that only aggregates models on sampled coalitions to approximate the exact result. Extensive experiments verify that the efficient core-selecting mechanism can incentivize inputting high-quality data and stable cooperation, while it reduces computational overhead compared to the core-selecting mechanism.

Solving Nash equilibrium is the key challenge in normal-form games with large strategy spaces, where open-ended learning frameworks offer an efficient approach. In this work, we propose an innovative unified open-ended learning framework A-PSRO, i.e., Advantage Policy Space Response Oracle, as a comprehensive framework for both zero-sum and general-sum games. In particular, we introduce the advantage function as an enhanced evaluation metric for strategies, enabling a unified learning objective for agents engaged in normal-form games. We prove that the advantage function exhibits favorable properties and is connected with the Nash equilibrium, which can be used as an objective to guide agents to learn strategies efficiently. Our experiments reveal that A-PSRO achieves a considerable decrease in exploitability in zero-sum games and an escalation in rewards in general-sum games, significantly outperforming previous PSRO algorithms.

Transformers-based methods have achieved significant performance in image deraining as they can model the non-local information which is vital for high-quality image reconstruction. In this paper, we find that most existing Transformers usually use all similarities of the tokens from the query-key pairs for the feature aggregation. However, if the tokens from the query are different from those of the key, the self-attention values estimated from these tokens also involve in feature aggregation, which accordingly interferes with the clear image restoration. To overcome this problem, we propose an effective DeRaining network, Sparse Transformer (DRSformer) that can adaptively keep the most useful self-attention values for feature aggregation so that the aggregated features better facilitate high-quality image reconstruction. Specifically, we develop a learnable top-k selection operator to adaptively retain the most crucial attention scores from the keys for each query for better feature aggregation. Simultaneously, as the naive feed-forward network in Transformers does not model the multi-scale information that is important for latent clear image restoration, we develop an effective mixed-scale feed-forward network to generate better features for image deraining. To learn an enriched set of hybrid features, which combines local context from CNN operators, we equip our model with mixture of experts feature compensator to present a cooperation refinement deraining scheme. Extensive experimental results on the commonly used benchmarks demonstrate that the proposed method achieves favorable performance against state-of-the-art approaches. The source code and trained models are available at https://github.com/cschenxiang/DRSformer., Comment: Accepted as a highlight paper in CVPR 2023

Dislocations, line defects in crystalline materials, play an essential role in the mechanical[1,2], electrical[3], optical[4], thermal[5], and phase transition[6] properties of these materials. Dislocation motion, an important mechanism underlying crystal plasticity, is critical for the hardening, processing, and application of a wide range of structural and functional materials[1,7,8]. For decades, the movement of dislocations has been widely observed in crystalline solids under mechanical loading[9-11]. However, the goal of manipulating dislocation motion via a non-mechanical field alone remains elusive. Here, we present real-time observations of dislocation motion controlled solely by an external electric field in single-crystalline zinc sulfide (ZnS). We find that 30{\deg} partial dislocations can move back and forth depending on the direction of the electric field, while 90{\deg} partial dislocations are motionless. We reveal the nonstoichiometric nature of dislocation cores using atomistic imaging and determine their charge characteristics by density functional theory calculations. The glide barriers of charged 30{\deg} partial dislocations, which are lower than those of 90{\deg} partial dislocations, further decrease under an electric field, explaining the experimental observations. This study provides direct evidence of dislocation dynamics under a non-mechanical stimulus and opens up the possibility of modulating dislocation-related properties., Comment: https://www.nature.com/articles/s41563-023-01572-7

We present an effective and efficient method that explores the properties of Transformers in the frequency domain for high-quality image deblurring. Our method is motivated by the convolution theorem that the correlation or convolution of two signals in the spatial domain is equivalent to an element-wise product of them in the frequency domain. This inspires us to develop an efficient frequency domain-based self-attention solver (FSAS) to estimate the scaled dot-product attention by an element-wise product operation instead of the matrix multiplication in the spatial domain. In addition, we note that simply using the naive feed-forward network (FFN) in Transformers does not generate good deblurred results. To overcome this problem, we propose a simple yet effective discriminative frequency domain-based FFN (DFFN), where we introduce a gated mechanism in the FFN based on the Joint Photographic Experts Group (JPEG) compression algorithm to discriminatively determine which low- and high-frequency information of the features should be preserved for latent clear image restoration. We formulate the proposed FSAS and DFFN into an asymmetrical network based on an encoder and decoder architecture, where the FSAS is only used in the decoder module for better image deblurring. Experimental results show that the proposed method performs favorably against the state-of-the-art approaches. Code will be available at \url{https://github.com/kkkls/FFTformer}., Comment: Code will be available at \url{https://github.com/kkkls/FFTformer}