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In recent years, nanoparticles have emerged as an important player in a broad range of applications, especially thanks to recent advances in their synthesis. The silver and copper nanoparticles are often used due to their antibacterial and fungicidal activities, and this article presents the results of the nanoparticle synthesis using electrical glow discharge generated directly in a volume of their salt solutions. Therefore, there is no influence of air (i.e. reactive nitrogen species) as it is usual in other commonly used approaches. Nanoparticles were prepared under various experimental conditions, and they were characterized by ultraviolet/visible spectrometry, dynamic light scattering, X-ray photoelectron spectroscopy, and high-resolution scanning electron microscopy. Particles were produced without any surfactant or stabilizing agent, and some of them showed higher resistance against agglomeration during their short-term (days) storage. The nanoparticle formation mechanism was confirmed by the fast camera imaging. Thus, the developed approach can be applied for simple environmentally friendly nanoparticle production for various applications.

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The concrete has been and at the same time will be the most used construction material worldwide. It is exposed to various physical and chemical degradation processes that deteriorate its properties and shorten its service life in most applications. As most of the detrimental effects on concrete come from the ambient environment, the quality of concrete surface plays a key role in the overall concrete performance. It should be resistant to abrasion, free of microcracks and open pores to prevent ingress of water, aggressive solutions, and gases. To enhance the properties of the concrete surface, various approaches can be used. The treatment via silicate-based sealers is becoming increasingly popular in concrete technology, especially in preventing deterioration when exposed to highly aggressive environments. This contribution focuses on applying unconventional test methods (e.g. combined scratch/acoustic emission method) to detect the fundamental properties of the treated cementitious surfaces will also provide a new perspective approach of material testing, which may be in the future advantageously used in technical practice. The present combined scratch/acoustic emission test evaluation will provide an excellent insight into lithium silicate sealers’ physical behaviour on fine-grained cement-based materials during this test.

Superhydrophobic surfaces were prepared using a two-step method that involved the etching of AZ31 and AZ91 magnesium alloys and then modifying the etched alloys with stearic acid. Magnesium alloys etched with ZnCl2 and SnCl2 exhibited surfaces roughened with micro- and nanoscale hierarchical structures consisting of two chemically distinct regions (Zn/Zn(OH)2 or Sn/SnO2 and Mg(OH)2). An optimum etching time of ten minutes was chosen for both etchants. Superhydrophobic surfaces with the highest contact angle were prepared when stearic acid reacted with the etched alloys at 50 °C for 4 h. Stearic acid was bound as zinc stearate and magnesium stearate on Mg alloys etched with ZnCl2 and SnCl2 solutions, respectively. The superhydrophobic process on AZ31 alloys etched with ZnCl2 and SnCl2 improved the corrosion resistance in phosphate buffered saline (PBS) solution compared to bare AZ31 alloy, with the use of ZnCl2 etchant leading to better results. An improvement in the corrosion resistance of AZ91 alloy was observed when the stearic-acid-modified AZ91 alloy was etched with SnCl2. In contrast, the use of ZnCl2 etchant to pretreat AZ91 alloy resulted in a significant deterioration in corrosion properties compared to bare AZ91 alloy. The microstructure of the Mg alloy had an impact on the etching and modification process. On the basis of the findings, a characterization of the chemistry of etching magnesium alloys and the formation of superhydrophobic surfaces was proposed. Magnesium alloys were prepared with superhydrophobic surfaces, incorporating antibacterial metals, features which may increase their potential for use in medical applications. [ABSTRACT FROM AUTHOR]

The application of concrete surface treatment has been widely investigated in recent decades. Treatment with silicate-based sealers is becoming increasingly popular in concrete technology, especially in preventing deterioration when exposed to extremely aggressive environments. Nowadays, lithium silicate sealers have been growing in market share in comparison to sodium or potassium silicates. Therefore, this study is focused on the development of a new generation of lithium silicate sealers improved by selected organic admixture. Hexylene glycol was used as an effective improvement for the lithium silicate sealer in terms of controlling the gelation process, which is the crucial mechanism to block existing capillary pores on the concrete surface resulting in increase the impermeability of the concrete's surface layer and thus the durability of the entire system. The gelation process was studied by means of a rheological approach, whereas scanning electron microscopy equipped with EDS was chosen as a key method to observe and analyze the surface treatment. Subsequently, the treatment functionality was determined based on water permeability measurement. The gained knowledge helped to predict the service life of surface treated concrete and opened an opportunity to produce more sustainable building materials. [ABSTRACT FROM AUTHOR]

The study deals with the methodology for determining the chemical composition of alkaline silicate solutions. Nowadays, the most widely used method in the industry is the acid-base titration. This technique is very accurate for the determination of alkali content (e.g. Na2O, K2O, Li2O). However, the problem arises in the titration of SiO2, since the color change of the methyl red indicator is very slow and therefore the equivalence point is unclear. The main aim of this work is to present the benefits of conductometric titration, where the equivalence point is indicated by a sudden change of conductivity. The applicability of the method has been verified with other analytical techniques, such as ICP-OES and gravimetric analysis. The results mutually confirmed similar values of the obtained silicate module (molar ratio of SiO2 and alkaline oxide) both in the case of sodium, potassium and lithium water glasses. Contrary, the previous acid-base titration recorded deviations of a few percent. Based on the obtained results, one can say that the conductometry is a very promising method providing an accurate, fast, and instrumentally undemanding chemical characterization of alkaline silicate solutions. [ABSTRACT FROM AUTHOR]

The very early stages of alkaline activation of slag control its rheology and setting, but also affect its hydration, which occurs later. Simultaneously, these parameters are dictated by the nature and dose of the alkaline activator. Therefore, we investigated and compared the changes in slag particles (SEM, BET, laser diffraction), as well as in the pore solution composition (ICP–OES), pH, and conductivity, of alkali-activated slag (AAS) pastes containing the three most common sodium activators (waterglass, hydroxide, and carbonate) and water during the first 24 h of its activation. To ensure the best possible comparability of the pastes, a fairly nontraditional mixture design was adopted, based on the same concentration of Na+ (4 mol/dm3) and the same volume fraction of slag in the paste (0.50). The results were correlated with the pastes' hydration kinetics (isothermal calorimetry), structural build-up (oscillatory rheology), and setting times (Vicat). Great differences were observed in most of these properties, in the formation of hydration products, and in the composition of the pore solution for each activator. The results emphasize the role of the anionic groups in the activators and of the pH, which help predict the sample's behavior based on its calorimetric curve, and offer data for further comparisons and for the modelling of AAS hydration for specific activators. [ABSTRACT FROM AUTHOR]

The anisotropic nature of charge transport through organic materials requires high control over the self-assembly of the organic materials. This is particularly so for conductive polymers, where transport occurs mainly along the polymers' backbone. Herein, we demonstrate the use of self-assembled monolayers (SAMs) to influence the self-assembly of poly(3-adamantylmethylthiophene). We employ two different SAMs, which interact with either the adamantyl- or the thiophene-functionality, respectively, and acquire distinct topologies as compared to the unmodified Au(111) surface. We compare these results with unmodified glass and mica (muscovite) surfaces, which are typically employed in the field of optoelectronics. We prove the usefulness and applicability of epitaxial effects and adamantyl substituents for organic electronics. This presents a viable way toward improved electronic performance for the field as a whole., Competing Interests: The authors declare no competing financial interest., (© 2024 The Authors. Published by American Chemical Society.)