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This review proposes to carry out a state-of-the-art associated with micro-arc oxidation. Firstly, the different aspects of the growth mechanisms of the oxides are detailed. Then, the formation of micro-arcs and the case of soft-spark treatment are discussed. Then, the electrolytic reactions involved in the layer construction are outlined. We focused on the influence of aluminium alloys on the appearance of the coating and its characteristics before considering the electrolyte formulation. We have concentrated some of our efforts on silicate-based electrolytes, mainly used in research and industry. The importance of electrical parameters in layer formation is detailed later. The main factors studied in the literature are the current source, current density, treatment frequency and duration, and duty cycle. We have also noted the different phase compositions identified in the literature. Finally, since the process is particularly advantageous for protecting the surfaces of aluminium parts against wear, we conclude this review by presenting work on the tribological properties of this coating. In this final section, we highlight the work on the wear-reducing properties and tribological mechanisms identified in the literature. Particular attention is paid to the relationship between the nature of the substrates used, the role of the electrolyte and the counterpart choice on the friction and wear results.

Optimising the performance of materials requires, among other things, the characterisation of residual stresses during the design stage. Raman spectroscopy offers access to these residual stresses at the micrometre scale when this inelastic light scattering is active in these materials. In this case, the relationship between the Raman mode shift and the pressure must be known. High-pressure cells with diamond anvils or bending instruments coupled to Raman spectrometers are habitually used to determine this relationship. In this article, we propose a new method that involves a Hertzian contact to obtain this relationship. A device that compresses an alumina ball against a transparent glass plane is connected to a Raman spectrometer. Under these conditions, the contact pressure can be as high as 1.5 GPa. The contact between the glass plane and the ball is observed through a diaphragm. Several hundred Raman spectra are recorded depending on the contact diameter. The spectral profiles obtained represent the shift in the Raman modes of alumina and glass along the contact diameter. Hertz’s theory accurately describes the pressure profile as a function of position for elastic materials. Therefore, the contact diameter can be measured by fitting the spectral profile with a function identical to the Hertz profile. We then deduce the maximum pressure. Next, the calculated pressure profile along the contact diameter is correlated with the spectral profile. We obtain a pressure dependence of the Raman mode with a coefficient equal to 2.07 cm−1/GPa for the Eg modes of alumina at 417 cm−1, which is in good agreement with the literature. In the case of glass, we refine the measurement of the Q3 mode shift at 1096 cm−1 in the studied pressure range compared to the literature. We find a coefficient of 4.31 cm−1/GPa. This work on static contacts opens up promising prospects for investigations into dynamic contacts in tribology.