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Recent surveys have uncovered new young massive clusters that host dozens of red supergiants (RSGs) near the inner Galaxy. However, many of them have still not been fully studied. Using Very Large Telescope/X-shooter near-infrared spectra, we present the first radial velocity analysis for the putative members of the candidate RSG cluster Alicante-8. Our results show a large dispersion of radial velocities among the candidate member stars, indicating that Alicante-8 does not seem to be a real cluster, unlike Alicante-7 and Alicante-10, which are confirmed by the distribution of the radial velocities of their RSG members. Measuring the spectral indices reveals that the assumption that the candidate stars are RSGs was incorrect, leading to the misclassification of Alicante-8 as a candidate RSG cluster. Our results imply that spectral classification based on the widely used CO band at 2.3 μm alone is not a sufficient criterion, because both red giants and RSGs can attain similar CO equivalent widths, and that spectroscopic radial velocities are needed in order to confirm unambiguously the cluster membership. This research is supported in part by the FRG Grant P.I., R. Asa'd and the Open Access Program from American University of Sharjah. It is also partially supported by the Spanish Government Ministerio de Ciencia e Innovación and Agencia Estatal de Investigación (MCIN/AEI/10.13039/501100011033/FEDER, UE) under grants PGC2018-093741-B-C21/C22 and PID2021-122397NB-C21/C22, and by the Generalitat Valenciana under grants PROMETEO/2019/041 and ASFAE/2022/017.