The static and dynamic magnetic properties and the specific heat of K2Ni2TeO6 and Li2Ni2TeO6 were examined and it was found that they undergo a long-range ordering at TN = 22.8 and 24.4 K, respectively, but exhibit a strong short-range order. At high temperature, the magnetic susceptibilities of K2Ni2TeO6 and Li2Ni2TeO6 are described by a Curie–Weiss law, with Curie-Weiss temperatures Θ of approximately −13 and −20 K, respectively, leading to the effective magnetic moment of about 4.46 ± 0.01 µB per formula unit, as expected for Ni2+ (S = 1) ions. In the paramagnetic region, the ESR spectra of K2Ni2TeO6 and Li2Ni2TeO6 show a single Lorentzianshaped line characterized by the isotropic effective g-factor, g = 2.19 ± 0.01. The energy-mapping analysis shows that the honeycomb layers of A2Ni2TeO6 (A = K, Li) and Li3Ni2SbO6 adopt a zigzag order, in which zigzag ferromagnetic chains are antiferromagnetically coupled, because the third nearest-neighbor spin exchanges are strongly antiferromagnetic while the first nearest-neighbor spin exchanges are strongly ferromagnetic, and that adjacent zigzag-ordered honeycomb layers prefer to be ferromagnetically coupled. The short-range order of the zigzag-ordered honeycomb lattices of K2Ni2TeO6 and Li2Ni2TeO6 is equivalent to that of an antiferromagnetic uniform chain, and is related to the short-range order of the ferromagnetic chains along the direction perpendicular to the chains. © 2022 by the authors. Licensee MDPI, Basel, Switzerland. Russian Foundation for Basic Research, РФФИ; Ministry of Education, MOE: 2020R1A6A1A03048004; National Research Foundation of Korea, NRF; Russian Science Foundation, RSF: 22-42-08002; Government Council on Grants, Russian Federation: 075-15-2021-604 Funding: This work was supported by the grant 14-03-01122 from the Russian Foundation for Basic Research (VBN), by the Russian Scientific Foundation through Grant No. 22-42-08002, and by the Mega-grant program of the Government of Russian Federation through the project 075-15-2021-604. The work at KHU was financially supported by the Basic Science Research Program through the National Research Foundation (NRF) of Korea, which was funded by the Ministry of Education (2020R1A6A1A03048004).