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Abstract This study aims to evaluate the suitability of subsurface layers for infrastructure development using geophysical and geotechnical studies. Six seismic refraction and six 2D geoelectic profiles were conducted in the study area to analyze the geotechnical characteristics of the subsoil in order to assess its suitability for construction projects. According to the geophysical investigation, there are two main geoelectric strata, each with a different lithology and thickness. The first layer has high resistivity values of more than 200 (Ωm) and its thickness is between 3.5 and 6.3 m. The second layer's resistivity ranges from 0.3 to 200 (Ωm). The findings indicate that the near-surface area of the study site is composed of two layers in addition to the surface layer, which consists of semi-consolidated wadi fill deposits of gravel, sand, and silt with rock fragments. The first layer comprises fractured limestone with clay intercalation, followed by a second layer of marly limestone, which transitions into marl and clay. Both compressional (P) and shear (S) waves were detected and analyzed. The shallow seismic refraction technique indicates that the velocity waves (Vp) in the first and second layers range from 133 to 770 and 790 to 3100 m/s respectively. Various engineering parameters for the second layer were determined, including elastic moduli (bulk modulus, Poisson’s ratio, rigidity modulus, and Young’s modulus), competence scales (stress ratio, concentration index, material index and density gradient), and bearing capacity (ultimate and allowable). The average Poisson ratio for the first and second layers is 0.235. The ultimate bearing capacity (Qu) of the first layer ranges from 379.1 to 1031.2 gm/cm2 and between 1040.8 and 1548.5 gm/cm2 of the second layer. Allowable bearing capacity (Qall) for the first layer is between 126.4 and 343.7 gm/cm2, and for the second layer, it is between 346.9 and 516.2 gm/cm2. According to the geotechnical investigation's findings, the range of liquid limit (LL) values is between 41.20 and 86.30%, the range of plastic limit (PL) values is between 18 and 35.25%, the range of plasticity index (PI) values is between 14.17 and 51.45%, and the range of free swelling values is between 60 and 170%. However, the study identified high-risk areas in the study area. These zones are located in the first and second layers represented by strongly swelling clay layers and strongly fractured limestone, which will have a major impact on the road and buildings. Therefore, this study recommends addressing these problems before any development to protect these areas from subsidence and collapse.

The presence of potentially harmful metals in commercially available saltwater fish has been extensively documented in scientific literature. This has demonstrated the significance of monitoring the crucial copper (Cu) levels in fish fillets from a perspective focused on human health risks (HHR). This study aimed to evaluate the human health risk (HHR) associated with the presence of Cu in 40 different species of commercial marine fish purchased from Malaysia. The fish samples were gathered from various sources from April to May 2023. The 40 species of commercial marine fish had concentrations of Cu (0.72–82.3 mg/kg dry weight) that fell below acceptable levels defined by seafood safety recommendations. Therefore, these fish are considered good sources of the essential element. The target hazard quotient values for Cu were below 1, suggesting that the hazards of Cu from fish eating are non-carcinogenic. Furthermore, it was discovered that the computed values for the predicted weekly consumption were lower than the defined provisional tolerated weekly intake of Cu. Consuming fish purchased from Malaysia is unlikely to harm consumers’ necessary copper intake. However, it is crucial to consistently monitor the safety of consumers who heavily depend on commercially caught marine fish from Malaysia. This monitoring is an essential aspect of implementing environmental, social, and governance (ESG) practices, which industries are concerned about and report on annually.

The overconsumption of fossil fuels is leading to worsening environmental damage, making the generation of clean, renewable energy an absolute necessity. Two common components of electrochemical energy storage (EES) devices are batteries and supercapacitors (SCs), which are among the most promising answers to the worldwide energy issue. In this study, we introduce an exceptionally efficient electrode material for supercapacitors, composed of a hydrothermally synthesized composite known as MnNiS@MXene. We utilized XRD, SEM, and BET to analyze the material’s crystallinity, morphology, and surface area. The Qs of MnNiS@MXene was a remarkable 1189.98 C/g or 1983.3 F/g at 2 A/g under three electrode assemblies in 1 M KOH electrolyte solution. Activated carbon was used as the negative electrode, while MnNiS@MXene served as the positive electrode in the assembled supercapattery device (MnNiS@MXene//AC). This device showed exceptional performance, a specific capacity of 307.18 C/g, a power density of 1142.61 W/kg, and an energy density of 34.79 Wh/kg. Additionally, cyclic durability was evaluated through 7000 cycles of charging/discharging, demonstrating that it maintained approximately 87.57% of its original capacity. The successful integration of these materials can lead to electrodes with superior energy storage capabilities and efficient photoelectrochemical performance. The aforementioned findings suggest that MnNiS@MXene exhibits promising potential as an electrode material for forthcoming energy storage systems.

The green-lipped mussel Perna viridis’ sensitive nature and characteristic as a benthos organism that filters the sediment in its environment make it one of the possible bioindicators for pollution in the aquatic ecosystem. The present study aimed to determine the percentages of total shell deformities in comparison to the past data in the coastal waters of Peninsular Malaysia. It was found that several types of discontinuous, continuous, and unexplained shell abnormalities contributed to the overall range of shell deformities of 15.8–87.5%, which was greater in comparison to that (0.0–36.8%). The present study showed that the highest overall proportion of shell abnormalities occurred in Teluk Jawa, whereas the lowest percentages were found in Kampung (Kg.) Pasir Puteh. The regulative mechanisms at the well-known polluted sites at Kg. Pasir Puteh could be the explanation. Further research should be conducted to determine the degree of heavy metal that may be the source of these malformations in the mussel shells.

This study investigates the radiation shielding properties of glass samples within the xGd2O3-5SiO2-40Na2O-(54.5-x) B2O3:0.5CeF3 composition, where x varies from 0 to 10 mol.%, which is coded as GSNBCX (X = 1, 2, 3, and 4). The assessment is done through comprehensive Monte Carlo simulation and Phy-X/PSD software analyses. The primary objective of this study is to comprehensively evaluate the radiation shielding properties of glass compositions with varying Gd2O3 concentrations. This evaluation encompasses both the attenuation of gamma radiation within the broad energy range of 0.015 MeV to 15 MeV and the assessment of fast neutron removal cross sections, with a specific focus on simulations spanning energy levels from 0.5 to 10 MeV. By examining these parameters, we aim to elucidate the impact of Gd2O3 concentration on the material’s overall effectiveness in radiation shielding applications. The results reveal a significant variation in the mass attenuation coefficient (μm) across the investigated glass samples. For instance, μm values range from 3.244 to 0.019 cm2·g−1 for GSNBC1, 20.471 to 0.025 cm2·g−1 for GSNBC2, 27.245 to 0.027 cm2·g−1 for GSNBC3, and 32.223 to 0.029 cm2·g−1 for GSNBC4. Notably, GSNBC4, characterized by a substantial Gd2O3 concentration (10 mol.%), exhibits the highest values of both μm and linear attenuation coefficient (μ). Furthermore, the investigation delves into the fast neutron removal cross section (FNRCS), which displays values of 0.97, 0.95, 0.094, and 0.93 cm−1, respectively. GSNBC1, marked by its elevated B2O3 content (54.5 mol.%), showcases the highest FNRCS. These findings underscore the efficacy of Gd2O3-doped materials in shielding against gamma rays, holding promise for various applications in radiation protection, particularly in the medical and nuclear sectors. This study contributes valuable insights into developing effective radiation-blocking materials for diverse industrial and scientific contexts.

Kab Amiri granites are submitted to post-magmatic hydrothermal solutions through fracture and faults, causing several alteration processes. The most common processes are episyenitization, saussuritization, hematitization, sericitization, kaolinization, albitization, chloritization, silicification, and muscovitization. Kab Amiri granites are vuggy, with the vugs partially to completely refilled with new constituents. The least episyenitized granites have elevated amounts of Fe, P, Zr, Ni, U, Th, Ba, Y, Hf, Nb, and As, which are correlated with their mobilization from biotite, k-feldspar, plagioclase and metamict zircon. These elemental changes are related the partial albitization, muscovitization, desilicification and chloritizatiom, which lead to the mobilization of these elements and forming of specific mineral association in the least altered granites such as autonite, tripiolite, columbite, Zircon and galena. On the second stage, granites were subjected to intense alteration processes by mineralizing fluids, causing wholly muscovitization of biotite and feldspar, albitization of plagioclase, carbonitization and apatitization. Many elements were mobilized from these altered minerals, including Ti, Al, Mn, Mg, Ca, Na, K, Mo, Cu, Pb, Zn, Ag, Co, Sr, V, Cr, Sn, Rb, Ta, Li, Sc, W, S, In, and Tl, leading to definite mineralization as kaslite, monazite, xenotime, polycrase and apatite. The mineralizing fluids in the least and highly episyenitized granites are incorporated in some ore minerals like uranophane, fergusonite, bazzite and garnet. Notably, the presence of elements such as U, Th, and other heavy metals in Kab Amiri granites highlights the potential for these rocks in radiation shielding applications. The unique combination of elements and minerals resulting from the alteration processes can be leveraged for developing new materials or enhancing existing materials used in radiation shielding.

The current work aims to describe the physico-mechanical characteristics and shielding efficiency with reference to the mineralogical and geochemical compositions of the Neoproterozoic Um Had composite granitoid pluton in order to deduce their favorability as dimension stones. The Um Had granitoid pluton has an elliptical outline with a mean diameter of about 10 km. This pluton is a composite (ranging from white to reddish pink color), hard, massive, and medium- to coarse-grained granitoid body. It is classified as syenogranite according to their modal and bulk chemical compositions. Geochemically, the granitoid pluton is a highly calc-alkaline, peraluminous granite, formed by low degree partial melting of tonalitic source rock in a post-collisional tectonic setting. The physico-mechanical properties of the granitoid pluton under study satisfy the requirements of dimension stone in terms of their bulk density (from 2561 to 2564 kg/m3), and to some extent water absorption capacity (from 0.38% to 0.55%). However, their compressive strength values (50.4–113.4 MPa) do not achieve the minimum requirement for interior use and light duty exterior use. This study delves into the potential of some of our syenogranite samples (I, IIA, IIS, and 10) as gamma radiation shielding materials. We have assessed the mass attenuation coefficient (GMAC), effective atomic number (Zeff), exposure build-up factor (EBF), and energy absorption build-up factor (EABF) for each of these samples. The GMAC and Zeff calculations were performed using the Phy-X online software, across a photon energy range of 0.015–15 MeV. Our findings suggest an inverse relationship between photon energy and GMAC, with the highest values observed for the (I) granite sample (∼18). This study shows the promising radiation shielding capacity of our samples. The insights derived from GMAC, Zeff, EBF, and EABF can serve as a guide for the development of effective, naturally sourced radiation shielding materials.

Abstract For technical and radioprotection causes, it has become essential to find new trends of smart materials which used as protection from ionizing radiation. To overcome the undesirable properties in lead aprons and provide the proper or better shielding properties against ionizing radiation, the tendency is now going to use ferrite as a shielding material. The co-precipitation method was utilized to prevent any foreign phases in the investigated MZN nano-ferrite. X-ray diffraction (XRD) and Fourier transmission infrared spectroscopy (FTIR) methods were used to analyze the manufactured sample. As proven by XRD and FTIR, the studied materials have their unique spinel phase with cubic structure Fd3m space group. The DC resistivity of Mg–Zn ferrite was carried out in the temperature range (77–295 K), and its dependence on temperature indicates that there are different charge transport mechanisms. The Mössbauer spectra analysis confirmed that the ferrimagnetic to superparamagnetic phase transition behaviour depends on Zn concentration. The incorporation of Zn to MZF enhanced the nano-ferrite density, whereas the addition of different Zn-oxides reduced the density for nano-ferrite samples. This variation in density changed the radiation shielding results. The sample containing high Zn (MZF-0.5) gives us better results in radiation shielding properties at low gamma, so this sample is superior in shielding results for charged particles at low energy. Finally, the possibility to use MZN nano-ferrite with various content in different ionizing radiation shielding fields can be concluded.

Radiation shielding is crucial in many types of medical, industrial, and nuclear facilities due to the widespread usage of radioactive isotopes. In this research, we examine the impact of tellurite 65TeO2–(35-x)V2O5-xSm2O3 glasses, where x ranges from 0.1 to 5 mol%, for its nuclear security and radiation shielding versus gamma attenuation capabilities. For gamma, the effect that the systematic replacement of Sm2O3 with V2O5 has on the shielding qualities was dissected in great depth. In addition, comparative research was carried out using the most recent borate glasses and the typical shielding materials considered the industry standard. In this study, we utilized the FLUKA algorithm and the FLAIR graphical interface to calculate the attenuation coefficients of glass compositions in the 65TeO2–(35-x)V2O5-xSm2O3system. The gamma energies of 0.356, 0.662, 1.332, and 2.614 MeV, commonly used in gamma shielding investigations, were selected as the radiation source. A comparison between the simulation results by FLUKA and theoretical calculations for mass attenuation coefficients demonstrated excellent agreement, confirming the reliability and accuracy of the FLUKA simulation method. The findings of the current research point to the fact that the TVS5 sample has the highest GMAC and lowest GHVL and GMFP, among other glasses. This points to the possibility that the TVS5 sample might be used in radiation shielding activities, which would result in increased nuclear safety.

The current research study is aimed at studying the impact of sodium chloride on the performance of semi-arid soils in the Najran area of Saudi Arabia. Experimental work has been undertaken to investigate how adding salt to the semi-arid soil collected in the Najran area affects the boundaries of Atterberg, compaction characteristics, California bearing ratio, and shear strength. All testing was conducted on soil samples from different zones of the Najran area at varying depths of 1.5, 3, and 4.5 m along the soil profiles. The soil samples were analyzed individually and then compared with the same soil samples mixed with NaCl at different percentages of 5, 10, and 20% by weight of the dry soil. Using advanced techniques, such as the scanning electron microscope, energy dispersive x-ray analysis, and X-ray diffraction analysis, the stabilization process was examined. The findings revealed that NaCl significantly impacts the geotechnical characteristics of semi-arid soils. The maximum dry density increased from 1.995, 1.93, and 1.96 to 2.02, 1.99, and 2.03 g/cm3, and the optimal water content decreased from 9.47, 13.7, and 11.29 to 7.01, 9.58%, and 8.09% with 20% NaCl added at various depths, respectively. Shear resistance parameters were improved by adding 20% NaCl, where the soil cohesion increased from 0.1333, 0.0872, and 0.0533 to 0.1843, 0.1034, and 0.0372 kg/cm2, and the angle of internal friction increased from 24°, 25.5°, and 29° to 27.8°, 30°, and 33°, respectively. The liquid and plastic limits and, in turn, the plasticity index reduced as the added percentage of NaCl increased. Furthermore, the California bearing ratio percentages significantly increased and reached more than 50%. As a result, it is established that NaCl is an excellent stabilizer, especially at 20% concentration, and might be used as a sub-base substance in highway construction.

IntroductionWe report the breast and chest radiation dose assessment for mammographic examinations using a three-layer heterogeneous breast phantom through the MCNPX Monte Carlo code.MethodsA three-layer heterogeneous phantom along with compression plates and X-ray source are modeled. The validation of the simulation code is obtained using the data of AAPM TG-195 report. Deposited energy amount as a function of increasing source energy is calculated over a wide energy range. The behavioral changes in X-ray absorption as well as transmission are examined using the F6 Tally Mesh extension of MCNPX code. Moreover, deposited energy amount is calculated for modeled body phantom in the same energy range.Results and discussionsThe diverse distribution of glands has a significant impact on the quantity of energy received by the various breast layers. In layers with a low glandular ratio, low-energy primary X-ray penetrability is highest. In response to an increase in energy, the absorption in layers with a low glandular ratio decreased. This results in the X-rays releasing their energy in the bottom layers. Additionally, the increase in energy increases the quantity of energy absorbed by the tissues around the breast.

The current study assessed the ecological–health risks of potentially toxic arsenic (As) and antimony (Sb) in the vegetable Centella asiatica, topsoils, and mangrove sediments sampled from Peninsular Malaysia. The As concentrations ranged from 0.21 to 4.33, 0.18 to 1.83, and 1.32 to 20.8 mg/kg dry weight, for the leaves, stems, and roots of the vegetable, respectively. The ranges of Sb concentrations were 0.31–0.62, 0.12–0.35, and 0.64–1.61 mg/kg dry weight, for leaves, stems, and roots of the vegetable, respectively. The children’s target hazard quotient (THQ) values indicated no non-carcinogenic risks of As and Sb in both leaves and stems, although children’s THQ values were higher than those in adults. The calculated values of estimated weekly intake were lower than established provisional tolerable weekly intake of As and Sb for both children and adult consumers. The carcinogenic risk (CR) values of As for children’s intake of leaves and stems of vegetables showed more public concern than those of adults. The levels of Sb and As in the topsoils were generally higher (although not significantly) than those in the mangrove sediments, resulting in a higher geoaccumulation index, contamination factor and ecological risk, hazard index, THQ, and CR values. This indicated that the anthropogenic sources of Sb and As originated from the land-based activities before reaching the mangrove near the coast. The CR of As signifies a dire need for comprehensive ecological–health risks exposure studies, as dietary intake involves more than just vegetable consumption. Therefore, risk management for As and Sb in Malaysia is highly recommended. The present findings of the ecological–health risks of As and Sb based on 2010–2012 samples can be used as an important baseline for future reference and comparison.

The ophiolitic rocks, island arc metasediments, and granitic rocks are encountered in the study of the Allaqi province. The present study concentrated on ultramafic rocks and their various forms of hydrothermal alteration. Ophiolites commonly occur as dismembered rock sequences and have different types of hydrothermal alteration products. Ophiolites contain the essential type as serpentinites and talc-carbonate rocks, listwaenites, and amphibolites along shear zones and faults. Listwaenite is one of the most significant rocks in this area because it contains gold. The whole serpentinite rocks are affected by regional metamorphosis into greenschist facies. Geochemically, Neoproterozoic serpentinites fall into SSZ ophiolites, alpine-type peridotite, formed in the forearc peridotite tectonic environment. Regardless, the listwaenite and talc-carbonate rocks revealed that they trend to silica, carbonate, and talc. Listwaenites are classified into two types: carbonate-rich listwaenites and silica–carbonate-rich listwaenites. Magnetite, chromite, galena, and gold are the most typical ores recorded in this research.

PurposeThis study aimed to evaluate Artificial Neural Network (ANN) modeling to estimate the significant dose length product (DLP) value during the abdominal CT examinations for quality assurance in a retrospective, cross-sectional study.MethodsThe structure of the ANN model was designed considering various input parameters, namely patient weight, patient size, body mass index, mean CTDI volume, scanning length, kVp, mAs, exposure time per rotation, and pitch factor. The aforementioned examination details of 551 abdominal CT scans were used as retrospective data. Different types of learning algorithms such as Levenberg-Marquardt, Bayesian and Scaled-Conjugate Gradient were checked in terms of the accuracy of the training data.ResultsThe R-value representing the correlation coefficient for the real system and system output is given as 0.925, 0.785, and 0.854 for the Levenberg-Marquardt, Bayesian, and Scaled-Conjugate Gradient algorithms, respectively. The findings showed that the Levenberg-Marquardt algorithm comprehensively detects DLP values for abdominal CT examinations. It can be a helpful approach to simplify CT quality assurance.ConclusionIt can be concluded that outcomes of this novel artificial intelligence method can be used for high accuracy DLP estimations before the abdominal CT examinations, where the radiation-related risk factors are high or risk evaluation of multiple CT scans is needed for patients in terms of ALARA. Likewise, it can be concluded that artificial learning methods are powerful tools and can be used for different types of radiation-related risk assessments for quality assurance in diagnostic radiology.

This study highlights the use of 89Zr-oxalate in diagnostic applications with the help of WinAct and IDAC2.1 software. It presents the biodistribution of the drug in various organs and tissues, including bone, blood, muscle, liver, lung, spleen, kidneys, inflammations, and tumors, and analyzes the maximum amount of nuclear transformation per Bq intake for each organ. The retention time of the maximum nuclear transformation and the absorbed doses of the drug in various organs and tissues are also examined. Data from clinical and laboratory studies on radiopharmaceuticals are used to estimate the coefficients of transition. The accumulation and excretion of the radiopharmaceutical in the organs is assumed to follow an exponential law. The coefficients of transition from the organs to the blood and vice versa are estimated using a combination of statistical programs and digitized data from the literature. WinAct and IDAC 2.1 software are used to calculate the distribution of the radiopharmaceutical in the human body and to estimate the absorbed doses in organs and tissues. The results of this study can provide valuable information for the biokinetic modeling of wide-spectrum diagnostic radiopharmaceuticals. The results show that 89Zr-oxalate has a high affinity for bones and a relatively low impact on healthy organs, making it helpful in targeting bone metastases. This study provides valuable information for further research on the development of this drug for potential clinical applications.

The chemical and physical characteristics of several flavonoid compounds such as geraniol, thymoquinone, betaine, apigenin, N-acetylcysteine, catechin, l-carnosine, epigallocatachin, and saponarin were examined in this work. Numerous molecular properties of all flavonoid compounds used in this study were calculated using the Calculate Molecular Properties module of Accelrys Discovery Studio v20.1.0.19295.0. These properties included molecular polar surface area, total solvent accessible surface area, and heat of formation. We used the MCNPX general-purpose Monte Carlo code in combination with the Phy-X PSD software to determine gamma-ray interaction parameters such as attenuation coefficients, effective atomic numbers, and buildup factors. The findings indicate that the flavonoids’ elemental compositions have a direct effect on their chemical and physical properties. Additionally, a synergistic interaction of chemical and physical behaviors has been observed. Among the flavonoids studied, saporanin was shown to have the highest polar surface area and solvent accessible surface area, as well as the highest stability. Additionally, saporanin had the strongest gamma-ray attenuation characteristics across a broad photon energy range. It may be inferred that saporanin’s elemental structure enables a synergistic relationship between its chemical and physical characteristics. The findings of this study may contribute to the evaluation of saporanin’s hypoglycemic, antibacterial, and hepatoprotective effects.

In this study, the monotonic effect of Ta2O5 and ZrO2 in some selected borotellurite glasses was investigated in terms of their impact on gamma-ray-shielding competencies. Accordingly, three niobium-reinforced borotellurite glasses (S1 : 75TeO2 + 15B2O3 + 10Nb2O5, S2 : 75TeO2 + 15B2O3 + 9Nb2O5 + 1Ta2O5, and S3 : 75TeO2 + 15B2O3 + 8Nb2O5 + 1Ta2O5 + 1ZrO2) were modelled in the general-purpose MCNPX Monte Carlo code. They have been defined as an attenuator sample between the point isotropic gamma-ray source and the detector in terms of determining their attenuation coefficients. To verify the MC results, attenuation coefficients were then compared with the Phy-X/PSD program data. Our findings clearly demonstrate that although some behavioral changes occurred in the shielding qualities, modest improvements occurred in the attenuation properties depending on the modifier variation and its magnitude. However, the replacement of 2% moles of Nb2O5 with 1% mole of Ta2O5 and 1% mole of ZrO2 provided significant improvements in both glass density and attenuation properties against gamma rays. Finally, the HVL values of the S3 sample were compared with some glass- and concrete-shielding materials and the S3 sample was reported for its outstanding properties. As a consequence of this investigation, it can be concluded that the indicated type of additive to be added to borotellurite glasses will provide some advantages, particularly when used in radiation fields, by increasing the shielding qualities moderately.

We report the symmetry of mechanical and gamma-ray attenuation properties for some tellurite glasses through elastic moduli, mechanical, and transmission properties as a function of varied WO3 amount in glass configuration. Four glass samples, along with different molar compositions as well as WO3/GdF3 substitution ratios, are investigated. Transmission properties using several essential parameters, such as attenuation coefficients, half-value layers, effective atomic numbers, effective conductivity, and buildup factors, are calculated in the 0.015–15 MeV energy range. Moreover, elastic moduli and Poisson’s ratios (σ) of the studied glass are calculated using the Makishima–Mackenzie model. The M4 sample with the highest WO3 addition is found with superior photon attenuation properties among the glasses investigated. Poisson’s ratio (σ) is increased, while all elastic moduli are decreased. Young’s modulus is reported as 62.23 GPa and 36.45.37 GPa at the highest and lowest WO3 mol%, respectively. It can be concluded that WO3 is a functional and monotonic tool in ternary-tellurite glasses for multiple modifications and enhancement purposes on gamma-ray attenuation, elastic moduli, and mechanical properties. It can also be concluded that increasing the WO3 amount in tellurite glasses may be considered a tool in terms of providing symmetry for mechanical and gamma-ray attenuation properties.

Background: During mammography, a lead-acrylic protective screen is recommended to reduce radiation exposure to the unexposed breast. Objectives: This research study aimed to construct an Indium-(III)-oxide-rich tellurite-glass screen (TZI8) and compare its performance to that of lead acrylic. Materials and Methods: A three-layer heterogeneous-breast phantom was developed, using the MCNPX (version 2.7.0) Monte Carlo code. An MCNPX-simulation geometry was designed and implemented, using the lead-acrylic and TZI8 shielding screens between the right and left breast. Next, the reliability of the phantom and the variations in absorption between the lead-acrylic and TZI8 glass were investigated. Results: The findings show that the TZI8-protective-glass screen offers significantly greater radioprotection than the lead-acrylic material. The quantity of total dose absorbed in the unexposed breast was much lower for TZI8 than for lead-based acrylic. The TZI8-glass screen gives about 60% more radioprotection than the lead-acrylic screen. Conclusion: Considering the toxic lead in the structure that may be hazardous to the human tissues, the TZI8-glass screen may be used in mammography examination to provide greater radioprotection than the lead-acrylic screen, in order to greatly reduce the dose to the unexposed breast.

The main objective of this work is to recycle unwanted industrial waste in order to produce innovative nanocomposites with improved mechanical, tribological, and thermal properties for use in various industrial purposes. In this context, powder metallurgy (PM) technique was used to fabricate iron (Fe)/copper (Cu)/niobium carbide (NbC)/granite nanocomposites having outstanding mechanical, wear and thermal properties. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) examinations were used to investigate the particle size, crystal size, and phase composition of the milled samples. Additionally, it was investigated how different volume percentages of the NbC and granite affected the sintered specimens in terms of density, microstructure, mechanical and wear properties, and coefficient of thermal expansion (CTE). According to the findings, the milled powders included particles that were around 55 nm in size and clearly contained agglomerates. The results showed that the addition of 4 vol.% NbC and 8 vol.% granite nanoparticles caused a reduction in the Fe–Cu alloy matrix particle sizes up to 47.8 nm and served as a barrier to the migration of dislocations. In addition, the successive increase in the hybrid concentrations led to a significant decrease in the crystal size of the samples prepared as follows: 29.73, 27.58, 22.69, 19.95 and 15.8 nm. Furthermore, compared with the base Fe–Cu alloy, the nanocomposite having 12 vol.% of hybrid reinforcement demonstrated a significant improvement in the microhardness, ultimate strength, Young’s modulus, longitudinal modulus, shear modulus, bulk modulus, CTE and wear rate by 94.3, 96.4, 61.1, 78.2, 57.1, 73.6, 25.6 and 61.9%, respectively. This indicates that both NbC and granite can actually act as excellent reinforcements in the Fe alloy.

A newly synthesized partially phosphorylated polyvinyl phosphate derivative (PPVP) was functionalized to extract Zirconium (IV) from Egyptian zircon sand. The specifications for the PPVP composite were approved effectively via different techniques, namely, FT-IR, XPS, BET, EDX, TGA, 1H-NMR, 13C-NMR, GC-MS, XRD and ICP-OES analyses, which demonstrated a satisfactory synthesis of PPVP and zircon dissolution from Egyptian zircon sand. Factors controlling parameters, such as pH values, shaking time, initial zirconium concentration, PPVP dose, nitrate ions concentration, co-ions, temperature and eluting agents, have been optimized. At 25 °C, pH 0, 20 min shaking, 0.05 mol/L zirconium ions and 0.5 mol/L nitrate ions, PPVP has an exciting preservation potential of 195 mg/g, equivalent to 390 mg/L zirconium ions. From the extraction–distribution isotherm, the practical outcomes of Langmuir’s modeling are better than the Freundlich model. With a theoretical value of 196.07 mg/g, which is more in line with the experimental results of 195 mg/g. The zirconium ions adsorption onto the PPVP composite follows the pseudo-second-order kinetics with a theoretical capacity value of 204.08 mg/g. According to thermodynamic potential, the extraction process was expected to be an exothermic, spontaneous and beneficial extraction at low temperatures. The thermodynamic parameters ΔS (−0.03 kJ/mol), ΔH (−12.22 kJ/mol) and ΔG were also considered. As the temperature grows, ∆G values increase from −2.948 kJ/mol at 298 K to −1.941 kJ/mol at 338 K. Zirconium ions may be eluted from the working loaded PPVP by 0.025M HNO3, with a 99% efficiency rate. It was found that zirconium ions revealed good separation factors towards some co-ions such as Hf4+ (28.82), Fe3+ (10.64), Ti4+ (28.82), V5+ (86.46) and U6+ (68.17). A successful alkali fusion technique with NaOH flux followed by the extraction with PPVP is used to obtain a high-purity zirconia concentrate with a zircon content of 72.77 % and a purity of 98.29%. As a result of this, the improved factors could finally be used.

Tannery industries are one of the extensive industrial activities which are the major source of chromium contamination in the environment. Chromium contamination has been an increasing threat to the environment and human health. Therefore, the removal of chromium ions is necessary to save human society. This study is oriented toward the preparation of a new triazole Schiff base derivatives for the remediation of chromium ions. 4,4′-((1E)-1,2-bis ((1H-1,2,4-triazol-3-yl) imino)ethane-1,2-diyl) diphenol was prepared by the interaction between 3-Amino-1H-1,2,4-triazole and 4,4′-Dihydroxybenzil. Then, the produced Schiff base underwent a phosphorylation reaction to produce the adsorbent (TIHP), which confirmed its structure via the different tools FTIR, TGA, 1HNMR, 13CNMR, GC-MS, and Phosphorus-31 nuclear magnetic resonance (31P-NMR). The newly synthesized adsorbent (TIHP) was used to remove chromium oxyanions (Cr(VI)) from an aqueous solution. The batch technique was used to test many controlling factors, including the pH of the working aqueous solution, the amount of adsorbent dose, the initial concentration of Cr(VI), the interaction time, and the temperature. The desorption behaviour of Cr(VI) changes when it is exposed to the suggested foreign ions. The maximum adsorption capacity for Cr(VI) adsorption on the new adsorbent was 307.07 mg/g at room temperature. Freundlich’s isotherm model fits the adsorption isotherms perfectly. The kinetic results were well-constrained by the pseudo-second-order equation. The thermodynamic studies establish that the adsorption type was exothermic and naturally spontaneous.

This study evaluates the geological attributes of rocks within the Abu Ghalaga area using spatial, geochemical, and petrographic approaches. ASTER and Landsat imagery processed using band ratio and principal component analysis were used to map hydrothermal alterations, while a regional tectonic evaluation was based on automated extraction of lineaments from a digital elevation model. Geochemical and petrographic analyses were then employed for discrete scale evaluation of alteration patterns of rocks across the study location. Based on satellite image processing, alteration patterns across the study area are widespread, while evidence from lineament analysis suggests a dominant NW–SE tectonic trend accompanied by a less dominant ENE–WSW direction. The different rock units exposed in the studied district are arranged chronologically from oldest to youngest as arc metavolcanic group (basalt and rhyolite), arc metagabbro–diorite, gneissose granite (granodiorite and tonalite), and dykes (aplite and felsite). Various types of igneous and metamorphic rocks have propylitic, phyllic, and argillic zones. Geochemical data indicate that the studied rocks are classified into granite, granodiorite, gabbroic diorite, and gabbro. Geochemically, the rocks have a sub-alkaline magma type. The granodiorite–tonalite is derived from the calc–alkaline magma nature, while gabbro and diorite samples exhibit tholeiitic to calc–alkaline affinity. The tectonic setting of the studied rocks trends toward volcanic arc granite (VAG). Based on petrographic, geochemical, and remote analyses, sericitization, chloritization, epidotization, kaolinitization, carbonatization, and silicification are the main alteration types present in the study area. As a result of lineaments analysis, the existing fractures and structural planes form valid flow paths for mineral-bearing hydrothermal solutions.