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Nickel-based catalysts are of great importance for the generation of hydrogen from natural gas. Within this process, the conditions in which commercial NiO/Al2O3 is converted to Ni0 /Al2O3 catalyst should be further investigated. A widely used technique to identify Ni2+ reduction conditions and the different compounds or types of particles in which this element is present is temperature-programmed reduction. In this work, the type of nickel oxide particles occurring on Al2O3 and ZnO-Al2O3-based supports were studied by different techniques, such as energy-dispersive X-ray spectroscopy, FTIR, the BET method, X-ray diffraction (XRD), and Temperature Programmed Reduction (TPR). All materials were evaluated in the water gas shift reaction (WGS), and the influence of their characteristics on the catalytic activity was assessed. Solids were prepared at different temperatures and Ni/Zn molar ratios. The results showed the presence of NiO in all materials, as well as the presence of ZnO, NiAl2O4, and ZnAl2O4 in materials prepared at higher temperatures. In all the materials calcined at the lowest temperature, the formation of NiO particles that fail to interact with the supports was prioritized. As the calcination temperature increased, NiO aggregates were formed, which, to a greater degree, interacted with the supports, whereby nickel aluminate was detected in all materials prepared at 750 °C. Zinc increased the selectivity but decreased specific surface area and activity through the WGS reaction. The solid labeled AZ15-500 showed higher activity and selectivity, reaching values of 100% for the water gas shift reaction.

In the pediatric population, epilepsy is one of the most common neurological disorders that often results in cognitive dysfunction. It affects patients’ life quality by limiting academic performance and self-esteem and increasing social rejection. There are several interventions for the neurohabilitation of cognitive impairment, including LEGO®-based therapy (LEGO® B-T), which promotes neuronal connectivity and cortical plasticity through the use of assembly sets and robotic programming. Therefore, the aim of this study was to analyze the effect of LEGO® B-T on cognitive processes in pediatric patients with epilepsy. Eligible patients were identified; in the treatment group, an initial evaluation was performed with the NEUROPSI and BANFE-2 neuropsychological tests. Then, the interventions were performed once a week, and a final test was performed. In the control group, after the initial evaluation, the final evaluation was performed. An overall improvement was observed in the LEGO® B-T patients, with a significant increase in BANFE-2 scores in the orbitomedial, anterior prefrontal, and dorsolateral areas. In addition, in the gain score analysis, the orbitomedial and memory scores were significantly different from the control group. LEGO® B-T neurohabilitation is a remarkable option for epilepsy patients, who are motivated when they observe improvements.

Abstract Background Lignin is a naturally occurring and aromatic biopolymer with well-known antimicrobial and antioxidant properties. Thus, in this work, the use of cellulose nanofibers (CNF) and lignin to produce ultra-light aerogels for biomedical applications was studied. Aerogels containing varying amounts of lignin (0–30 wt%) and different concentrations of the crosslinking agent Fe3+ (25–100 mM) were developed. Results The different bioaerogels were fully characterized and their physical, mechanical and bioactive properties analyzed. It was observed that the bioaerogels soluble fraction tends to decrease as the lignin content increases for the different Fe3+ concentrations, due to lignin–CNF interactions through hydrogen bonds. The bioaerogels containing lignin showed remarkable radical scavenging activity as the DPPH concentration decreased with time. This confirms the benefits of including lignin in bioaerogels to impart antioxidant properties. To study the suitability of the produced bioaerogels for controlled drug release, the release of tetracycline (TC) was studied. All of the bioaerogels released TC in a sustained manner for 6 h and presented similar profiles. However, the bioaerogels containing higher concentrations of crosslinker showed a higher release of TC. The TC loading conferred clear antimicrobial activity against S. aureus as expected, unlike the insignificant antimicrobial activity of the bioaerogels without TC. The biocompatibility of the samples was demonstrated for all materials produced (with and without TC loading) by the Kruskal–Wallis test with multiple comparisons. After observation of cell morphology, no significant differences were evident suggesting that the CNF–lignin bioaerogels present optimal biocompatibility for use in the biomedical and pharmaceutical industry. Conclusions The CNF–lignin bioaerogels presented in this work highlights their promising application as biomedical applications, such as wound dressings due to their biocompatibility, antimicrobial and antioxidant properties, as well as their swelling and solubility properties. Graphical Abstract

Nanocellulose (NC) has recently emerged as of high interest in water purification because of its high surface area, aspect ratio, and versatile surface chemistry. In the present study, nanocellulose has been isolated from cellulose pulp, extracted from barley straw residues via a mechanical pulping treatment, through a combination of chemical and mechanical refining treatments. The obtained cellulose pulp and (ligno)cellulose nanofibrils (L)CNFs, in the form of papers and nanopapers, respectively, were characterized in terms of mechanical properties. Finally, (L)CNFs-based aerogels were developed, and adsorption tests at 25 °C using 0.1 g of aerogels in 50 mL of methylene blue (MB) dye solution at 10 mg/L were studied. The results revealed that CNF-based aerogels can be exploited as an effective eco-adsorbent for the removal of methylene blue dye and provide a new platform for dye removal.

The use of advanced modulation and control schemes for power converters, such as a Feedback Quantizer and Predictive Control, is widely studied in the literature. This work focuses on improving the closed-loop modulation scheme called Feedback Quantizer, which is applied to a three-phase voltage source inverter. This scheme has the natural behavior of mitigating harmonics at low frequencies, which are detrimental to electrical equipment such as transformers. This modulation scheme also provides good tracking for the voltage reference at the fundamental frequency. On the other hand, the disadvantage of this scheme is that it has a variable switching frequency, creating a harmonic spectrum in frequency dispersion, and it also needs a small sampling time to obtain good results. The proposed scheme to improve the modulation scheme is based on a Discrete Space Vector with virtual vectors to obtain a better approximation of the optimal vectors for use in the algorithm. The proposal improves the conventional scheme at a high sampling time (200 μs), obtaining a THD less than 2% in the load current, decreases the noise created by the conventional scheme, and provides a fixed switching frequency. Experimental tests demonstrate the correct operation of the proposed scheme.

(1) Background: Nanostructured cellulose has emerged as an efficient bio-adsorbent aerogel material, offering biocompatibility and renewable sourcing advantages. This study focuses on isolating (ligno)cellulose nanofibers ((L)CNFs) from barley straw and producing aerogels to develop sustainable and highly efficient decontamination systems. (2) Methods: (Ligno)cellulose pulp has been isolated from barley straw through a pulping process, and was subsequently deconstructed into nanofibers employing various pre-treatment methods (TEMPO-mediated oxidation process or PFI beater mechanical treatment) followed by the high-pressure homogenization (HPH) process. (3) Results: The aerogels made by (L)CNFs, with a higher crystallinity degree, larger aspect ratio, lower shrinkage rate, and higher Young’s modulus than cellulose aerogels, successfully adsorb and remove organic dye pollutants from wastewater. (L)CNF-based aerogels, with a quality index (determined using four characterization parameters) above 70%, exhibited outstanding contaminant removal capacity over 80%. The high specific surface area of nanocellulose isolated using the TEMPO oxidation process significantly enhanced the affinity and interactions between hydroxyl and carboxyl groups of nanofibers and cationic groups of contaminants. The efficacy in adsorbing cationic dyes in wastewater onto the aerogels was verified by the Langmuir adsorption isotherm model. (4) Conclusions: This study offers insights into designing and applying advanced (L)CNF-based aerogels as efficient wastewater decontamination and environmental remediation platforms.

An innovative colloidal approach is proposed here to carry out the customized functionalization of TEMPO-Oxidized Cellulose Nanofibers (CNF) incorporating non-noble inorganic nanoparticles. A heterocoagulation process is applied between the delignified CNF and as-synthetized CuO nanoparticles (CuO NPs) to formulate mixtures which are used in the preparation of aerogels with antibacterial effect, which could be used to manufacture membranes, filters, foams, etc. The involved components of formulated blending, CNF and CuO NPs, were individually obtained by using a biorefinery strategy for agricultural waste valorization, together with an optimized chemical precipitation, assisted by ultrasounds. The optimization of synthesis parameters for CuO NPs has avoided the presence of undesirable species, which usually requires later thermal treatment with associated costs. The aerogels-based structure, obtained by conventional freeze-drying, acted as 3D support for CuO NPs, providing a good dispersion within the cross-linked structure of the nanocellulose and facilitating direct contact of the antibacterial phase against undesirable microorganisms. All samples showed a positive response against Escherichia coli and Staphylococcus aureus. An increase of the antibacterial response of the aerogels, measured by agar disk diffusion test, has been observed with the increase of CuO NPs incorporated, obtaining the width of the antimicrobial “halo” (nwhalo) from 0 to 0.6 and 0.35 for S. aureus and E. coli, respectively. Furthermore, the aerogels have been able to deactivate S. aureus and E. coli in less than 5 h when the antibacterial assays have been analyzed by a broth dilution method. From CNF-50CuO samples, an overlap in the nanoparticle effect produced a decrease of the antimicrobial kinetic.

This work deals with the study of the open-source Arduino DUE board as a digital control platform for three-phase two-level Voltage-Source Converters (VSC) and Current-Source Converters (CSC), including ( $i$ ) the description of the power topologies, its connection to the load or the ac grid, and the electrical signals required for sensors and power valves, (ii) the description of the Arduino Due board, its features, and its connection with the sensors and power valves in the converter, and (iii) evaluation of the Arduino DUE’s processing time required for typical power converter algorithms, such as modulation, mathematical transforms, and linear controllers typically used in these converters. Experimental results are presented to validate the study, showing that the Arduino DUE is a feasible digital control platform for this type of power converter.

As a result of human population growth, the availability of residual lignocellulosic materials from agriculture, forestry, food- and wood-processing industries, and other waste streams is continuously increasing [...]

Cascaded H-bridge drives require using a significant-size capacitor on each cell to deal with the oscillatory power generated by the H-bridge inverter in the DC-link. This results in a bulky cell with reduced reliability due to the circulating second harmonic current through the DC-link capacitors. In this article, a control strategy based on a finite control set model predictive control and a proportional-resonant controller is proposed to compensate for the oscillatory power required by the H-bridge inverter through the cell’s input rectifier. With the proposed strategy, a DC-link second harmonic free operation is achieved, allowing for the possibility of reducing the capacitor size and, in consequence, the cell dimensions. The feasibility of the proposed control scheme is verified by experimental results in one cell of a cascade H-bridge inverter achieving an operation with a capacitance 141 times smaller than required by conventional control approaches for the same voltage ripple.

As a transition strategy towards sustainability, food packaging plays a crucial role in the current era. This, carried out in a biorefinery context of agricultural residues, involves not only obtaining desirable products but a comprehensive utilization of biomass that contributes to the circular bioeconomy. The present work proposes the preparation of bioactive absorbent food pads through a multi-product biorefinery approach from bay tree pruning waste (BTPW). In a first step, chitosan aerogels reinforced with lignocellulose and cellulose micro/nanofibers from BTPW were prepared, studying the effect of residual lignin on the material’s properties. The presence of micro/nanofibers improved the mechanical performance (up to 60%) in addition to increasing the water uptake (42%) when lignin was present. The second step was to make them bioactive by incorporating bay leaf extract. The residual lignin in the micro/nanofibers was decisive, since when present, the release profiles of the extract were faster, reaching an antioxidant power of more than 85% after only 30 min. Finally, these bioactive aerogels were used as absorbent pads for fresh meat. With the use of the bioactive aerogels (with ≥2% extract), the meat remained fresh for 10 days as a result of delayed oxidation of the food during storage (20% metmyoglobin proportion).

The hornification processes undergone by the fibers in the paper industry recycling processes lead to the loss of properties of the final products, which exhibit poor mechanical properties. Among the most promising solutions is the reinforcement of secondary fibers with cellulose nanofibers. The present work addresses two important issues: the efficient production of cellulose nanofibers from scarcely exploited agricultural wastes such as horticultural residues and vine shoots, and their application as a reinforcement agent in recycled linerboard recycling processes. The effect of the chemical composition and the pretreatment used on the nanofibrillation efficiency of the fibers was analyzed. Chemical pretreatment allowed a significantly higher nanofibrillated fraction (45–63%) than that produced by mechanical (18–38%), as well as higher specific surface areas (>430 m2/g). The application of the nanofibers as a reinforcing agent in the recycled linerboard considerably improved the mechanical properties (improvements of 15% for breaking length, 220–240% for Young’s modulus and 27% for tear index), counteracting the loss of mechanical properties suffered during recycling when using chemically pretreated cellulose nanofibers from horticultural residues and vine shoots. It was concluded that this technology surpasses the mechanical reinforcement produced by conventional mechanical refining used in the industry and extends the number of recycling cycles of the products due to the non-physical modification of the fibers.

The use of controlled power converters has been extended for high power applications, stacking off-the-shelve semiconductors, and allowing the implementation of, among others, AC drives for medium voltages of 2.3 kV to 13.8 kV. For AC drives based on power cells assembled with three-phase diode rectifiers and cascaded H-bridge inverters, a sophisticated input multipulse transformer is required to reduce the grid voltage, provide isolation among the power cells, and compensate for low-frequency current harmonics generated by the diode-based rectifiers. However, this input multipulse transformer is bulky, heavy, and expensive and must be designed according to the number of power cells, not allowing total modularity of the AC drives based on cascade H-bridges. This study proposes and evaluates a control strategy based on a finite control set-model predictive control that emulates the harmonic cancellation performed by an input multipulse transformer in a cascade H-bridge topology. Hence, the proposed method requires conventional input transformers and replaces the three-phase diode rectifiers. As a result, greater modularity than the conventional multicell converter and improved AC overall input current with a THD as low as 2% with a unitary displacement power factor are achieved. In this case, each power cell manages its own DC voltage using a nonlinear control strategy, ensuring stable system operation for passive and regenerative loads. The experimental tests demonstrated the correct performance of the proposed scheme.

Water pollution is one of the most serious problems worldwide. Nanocellulose-based aerogels usually show excellent adsorption capacities due to their high aspect ratio, specific surface area and surface charge, making them ideal for water purification. In this work, (ligno)cellulose nanofibers (LCNFs/CNFs) from wheat straw residues were obtained using two types of pre-treatments: mechanical (Mec) and TEMPO-mediated oxidization (TO), to obtain different consistency (0.2, 0.4, 0.6 and 0.8) bioaerogels, and their adsorption capacities as dye removers were further studied. The materials were characterized in terms of density, porosity and mechanical properties. An inversely proportional relationship was observed between the consistencies of the aerogels and their achieved densities. Despite the increase in density, all samples showed porosities above 99%. In terms of mechanical properties, the best results were obtained for the 0.8% consistency LCNF and CNF-Mec aerogels, reaching 67.87 kPa and 64.6 kPa for tensile strength and Young’s modulus, respectively. In contrast, the adsorption capacity of the aerogels was better for TEMPO-oxidized aerogels, reaching removal rates of almost 100% for the CNF-TO5 samples. Furthermore, the residual lignin content in LCNF-Mec aerogels showed a great improvement in the removal capacity, reaching rates higher than 80%, further improving the cost efficiency of the samples due to the reduction in chemical treatments.

The efficient and selective detection of volatile organic compounds (VOCs) provides key information for various purposes ranging from the toxicological analysis of indoor/outdoor environments to the diagnosis of diseases or to the investigation of biological processes. In the last decade, different sensors and biosensors providing reliable, rapid, and economic responses in the detection of VOCs have been successfully conceived and applied in numerous practical cases; however, the global necessity of a sustainable development, has driven the design of devices for the detection of VOCs to greener methods. In this review, the most recent and innovative VOC sensors and biosensors with sustainable features are presented. The sensors are grouped into three of the main industrial sectors of daily life, including environmental analysis, highly important for toxicity issues, food packaging tools, especially aimed at avoiding the spoilage of meat and fish, and the diagnosis of diseases, crucial for the early detection of relevant pathological conditions such as cancer and diabetes. The research outcomes presented in the review underly the necessity of preparing sensors with higher efficiency, lower detection limits, improved selectivity, and enhanced sustainable characteristics to fully address the sustainable manufacturing of VOC sensors and biosensors.

Films formulated with polyvinyl alcohol (PVA) (synthetic biopolymer) were reinforced with lignocellulose nanofibres (LCNF) from residues of vegetable production (natural biopolymer). The LCNF were obtained by mechanical and chemical pre-treatment by 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO) and added to the polyvinyl alcohol (polymer matrix) with the aim of improving the properties of the film for use in food packaging. The mechanical properties, crystallinity, thermal resistance, chemical structure, antioxidant activity, water barrier properties and optical properties (transparency and UV barrier), were evaluated. In general, with the addition of LCNF, an improvement in the studied properties of the films was observed. In terms of mechanical properties, the films reinforced with 7% LCNF TEMPO showed the best results for tensile strength, Young’s modulus and elongation at break. At the same LCNF proportion, the thermal stability (Tmax) increased between 5.5% and 10.8%, and the antioxidant activity increased between 90.9% and 191.8%, depending on the raw material and the pre-treatment used to obtain the different LCNF. Finally, a large increase in UV blocking was also observed with the addition of 7% LCNF. In particular, the films with 7% of eggplant LCNF showed higher performance for Young’s modulus, elongation at break, thermal stability and UV barrier. Overall, results demonstrated that the use of LCNF generated from agricultural residues represents a suitable bioeconomy approach able to enhance film properties for its application in the development of more sustainable and eco-friendly food packaging systems.

The petrographic characterization of ophiolitic sequence and metamorphized rocks of Calentura Arriba sector in Moa municipality, constitutes a contribution to the updating of the geological map of the southwestern part of cartographic sheet 5277-IV "Moa". Thin sections of those rocks were analyzed using a polarized light microscope. The ore paragenesis composed of enstatites + augite + labradorite + olivine + chlorite + garnierite + actinolite + tremolite + ilmenite + magnetite + sericite + saussurite in the metagabbro sequence was identified as well as the mineral paragenesis composed of olivine + orthopyroxenes + bastite + lizardite + chrysotile + actinolite + tremolite + antigorite + serpophite + chromite + magnetite in the serpentinite sequence. This sector was subjected to strong transformation processes reflected in the intense alterations that denote the occurrence of low-grade to high-grade metamorphism, matching with the Barrowian facies series. The metamorphic transformations are closely related to the activity of the Moa Fault and denote a regional character, extending at both ends of this fracture. [ABSTRACT FROM AUTHOR]

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There are interesting geological elements and structures that could be part of the nation's geological heritage in Maisí municipality; however, these Geosites lack an adequate assessment. This research focuses on diagnosing the state of these Geosites and classifying them in order to establish their heritage value. For this purpose, a methodology that quantitatively and qualitatively categorizes the Geosites from the quality assessment of 10 parameters, to which a weighted score is made to correspond based on 100 points, was adopted. As a result, it was possible to verify that 70% of Geosites are exposed to erosive agents and anthropic action, what is evident they need to be protected. Five Geosites are considered to have heritage value of national or international significance and eleven have regional or local value from 17 Geosites assessed. Among those with the greatest heritage value, three caves (Patana, La Parada and Patato) and two valleys (El Cupey and La Máquina) stand out. [ABSTRACT FROM AUTHOR]

The study focused on the influence of geological genesis and degree of crystallinity on the quantification of mineral phases and amorphous content in Cuban clays. Two clay deposits with different geological genesis were taken and the samples were characterized using X-ray diffraction and techniques for analyzing the clay fraction. Dominant paragenesis were established for each deposit, dominated by kaolinite, and useful relationships were found between structural and particle size differences with geological genesis, which can affect proper quantification. It was determined that the level of weathering conditions the degree of crystallinity, which in turn has a strong relationship with factors that affect proper quantification. Finally, the fundamental elements for formulating a comprehensive methodology for the proper characterization and quantification of clay phases were established. [ABSTRACT FROM AUTHOR]

La caracterización petrográfica de la secuencia de rocas metamorfizadas de Calentura Arriba en el municipio de Moa es el primer paso para establecer las implicaciones geológicas del desarrollo de esta roca en la región de Moa. Se prepararon muestras en secciones delgadas de las secuencias de rocas metamorfizadas de Calentura Arriba y fueron analizadas con un microscopio de luz polarizada modelo NP-400B, marca NOVEL. En la secuencia de metagabros se identificó la paragénesis, mineral compuesta por enstatitas+ augita + labradorita+ olivino+ clorita+ garnierita + actinolita + tremolita + ilmenita + magnetita + sericita+ saussurita. En la secuencia de serpentinitas se identificó la paragénesis, mineral compuesta por olivino+ ortopiroxenos+ bastita + lizardita + crisotilo + actinolita + tremolita + antigorita+ serpofita + cromita +magnetita. Este sector estuvo sometido a fuertes procesos de transformación reflejado en las intensas alteraciones desarrolladas que denotan la ocurrencia de metamorfismo de grado bajo a alto coincidiendo con la serie de las facies barrowiense. Las transformaciones metamórficas están en estrecha relación con la actividad de la Falla Moa y denotan un carácter regional extendiéndose en ambos extremos de esta fractura

There are interesting geological elements and structures that could be part of the nation's geological heritage in Maisí municipality; however, these Geosites lack an adequate assessment. This research focuses on diagnosing the state of these Geosites and classifying them in order to establish their heritage value. For this purpose, a methodology that quantitatively and qualitatively categorizes the Geosites from the quality assessment of 10 parameters, to which a weighted score is made to correspond based on 100 points, was adopted. As a result, it was possible to verify that 70% of Geosites are exposed to erosive agents and anthropic action, what is evident they need to be protected. Five Geosites are considered to have heritage value of national or international significance and eleven have regional or local value from 17 Geosites assessed. Among those with the greatest heritage value, three caves (Patana, La Parada and Patato) and two valleys (El Cupey and La Máquina) stand out.

Kaolinitic clays have broad prospects in cement production and as a source of pozzolanic materials. The present paper focused on the petrographic and mineragraphic analysis of the Dumañuecos kaolinitic clay deposit, in the municipality of Manatí, Las Tunas province. In the petrographic and mineragraphic characterization of the rocks, polarized light and reflected light microscopy were used. Petrographic analysis revealed the presence of quartz, feldspars and tourmalines; as well as the predominance of granoblastic and cataclastic textures. It was established, through mineragraphic analysis, that the main mineralogical association is quartz + hematite + goethite + pyrite and cement and zonal textures predominate. The occurrence of feldspar spherules with a fibrous-radial internal structure and traces of feldspar phenocrysts indicate the possibility that the source rock of the reservoir is lava with a rhyolitic composition.