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Bronchopulmonary dysplasia (BPD) is a chronic lung disease that affects premature infants and leads to long-term pulmonary complications. The pathogenesis of BPD has not been fully elucidated yet. In recent years, the microbiome and its metabolites, especially short-chain fatty acids (SCFAs), in the gut and lungs have been demonstrated to be involved in the development and progression of the disease. This review aims to summarize the current knowledge on the potential involvement of the microbiome and SCFAs, especially the latter, in the development and progression of BPD. First, we introduce the gut-lung axis, the production and functions of SCFAs, and the role of SCFAs in lung health and diseases. We then discuss the evidence supporting the involvement of the microbiome and SCFAs in BPD. Finally, we elaborate on the potential mechanisms of the microbiome and SCFAs in BPD, including immune modulation, epigenetic regulation, enhancement of barrier function, and modulation of surfactant production and the gut microbiome. This review could advance our understanding of the microbiome and SCFAs in the pathogenesis of BPD, which also helps identify new therapeutic targets and facilitate new drug development. [ABSTRACT FROM AUTHOR]

Pancreaticoduodenectomy (PD) is a complex surgery for the management of periampullary tumors. It is associated with significant morbidity and mortality of 20% and 3 to 5% respectively. While early complications like delayed gastric emptying, hemorrhage, and collections are common, late complications like biliary and pancreatic anastomotic stenosis are also known to occur. With the increase in cases of pancreatic and periampullary cancers, there is an upward trend seen even in the rates of surgery. Endoscopy has emerged over the years as a tool for both evaluation and management of various complications. In this narrative review, we aim to provide a primer for gastroenterologists who are likely to be called upon for endoscopic management of post-PD complications. [ABSTRACT FROM AUTHOR]

Objective To explore the prevention and treatment strategies for pancreatic fistula and pancreatic fistula combined with hemorrhage after pancreaticoduodenectomy. Methods We retrospectively reviewed 90 cases of pancreaticoduodenectomy at Guangdong Provincial People's Hospital from August 2019 to December 2022. According to whether postoperative pancreatic fistula occurred, the 90 patients were divided into a postoperative pancreatic fistula group (n = 35) and a postoperative non-pancreatic fistula group (n = 55). Among the 35 patients with postoperative pancreatic fistula, they were further categorized into two subgroups based on the presence of hemorrhage: the pancreatic fistula with hemorrhage group (n = 10) and the pancreatic fistula without hemorrhage group (n = 25). Chi-square test or Fisher's exact test was used for univariate analysis. Variables with statistical differences were selected for stepwise regression variable screening. Multivariate Logistic regression analysis was used to determine the independent risk factors for the occurrence of pancreatic fistula and postoperative pancreatic fistula with hemorrhage. Results All 90 patients successfully completed the pancreaticoduodenectomy. The incidence of postoperative pancreatic fistula was 38.9% (35/90). Significant differences were observed in pancreatic duct diameter (P = 0.013), intraoperative blood loss (P = 0.045), anastomosis type (P = 0.045), and residual pancreatic texture (P = 0.10) between the two groups (P < 0.05). Multivariate logistic regression analysis revealed that soft pancreas texture, pancreatic duct diameter < 3 mm, intraoperative blood loss ≥ 300 mL, and pancreatic-ojejunostomy were independent risk factors for postoperative pancreatic fistula. Among patients with postoperative pancreatic fistula, multivariate logistic regression analysis identified pancreatic fistula volume > 100 mL and duration of postoperative pancreatic fistula > 7 days as independent risk factors for hemorrhage. Conclusions The risk of pancreatic fistula after pancreatoduodenectomy is relatively high. Attention to preoperative pancreatic duct diameter and standardized evaluation of pancreatic texture can help identify postoperative pancreatic fistula. Careful hemostasis during operation and avoidance of early postoperative hemorrhage can reduce the incidence of grade B and C pancreatic fistulas. Patients with pancreatic fistula should be warned of the occurrence of combined hemorrhage when the fistula volume is greater than 100ml and the duration of postoperative pancreatic fistula is greater than 7 days. [ABSTRACT FROM AUTHOR]

Numbers of aggressive prostate cancer (aPC) cases are rising, but only a few risk factors have been identified. In this study, we introduce a systematic approach to integrate geospatial data into external exposome research using aPC cases from Pennsylvania. We demonstrate the association between several area-level exposome measures across five Social Determinants of Health domains (SDOH) and geographic areas identified as having elevated odds of aPC. Residential locations of Pennsylvania men diagnosed with aPC from 2005 to 2017 were linked to 37 county-/tract-level SDOH exosome measures. Variable reduction processes adopted from neighborhood-wide association study along with Bayesian geoadditive logistic regression were used to identify areas with elevated odds of aPC and exposome factors that significantly attenuated the odds and reduced the size of identified areas. Areas with significantly higher odds of aPC were explained by various SDOH exposome measures, though the extent of the reduction depended on geographic location. Some areas were associated with race (social context), health insurance (access), or tract-level poverty (economics), while others were associated with either county-level water quality or a combination of factors. Area-level exposome measures can guide future patient-level external exposome research and help design targeted interventions to reduce local cancer burden. [ABSTRACT FROM AUTHOR]

Alkynyl radicals and cations are crucial reactive intermediates in chemistry, but often evade direct detection. Herein, we report the direct observation of the phenylethynyl radical (C6H5C≡C˙) and its cation (C6H5C≡C+), which are two of the most reactive intermediates in organic chemistry. The radical is generated via pyrolysis of (bromoethynyl)benzene at temperatures above 1500 K and is characterized by photoion mass-selected threshold photoelectron spectroscopy (ms-TPES). Photoionization of the phenylethynyl radical yields the phenylethynyl cation, which has never been synthesized due to its extreme electrophilicity. Vibrationally-resolved ms-TPES assisted by ab initio calculations unveiled the complex electronic structure of the phenylethynyl cation, which appears at an adiabatic ionization energy (AIE) of 8.90 ± 0.05 eV and exhibits an uncommon triplet (3B1) ground state, while the closed-shell singlet (1A1) state lies just 2.8 kcal mol−1 (0.12 eV) higher in energy. The reactive phenylethynyl radical abstracts hydrogen to form ethynylbenzene (C6H5C≡CH) but also isomerizes via H-shift to the o-, m-, and p-ethynylphenyl isomers (C6H4C≡CH). These radicals are very reactive and undergo ring-opening followed by H-loss to form a mixture of C8H4 triynes, along with low yields of cyclic 3- and 4-ethynylbenzynes (C6H3C≡CH). At higher temperatures, dehydrogenation from the unbranched C8H4 triynes forms the linear tetraacetylene (C8H2), an astrochemically relevant polyyne. [ABSTRACT FROM AUTHOR]

The biphenyl molecule (C12H10) acts as a fundamental molecular backbone in the stereoselective synthesis of organic materials due to its inherent twist angle causing atropisomerism in substituted derivatives and in molecular mass growth processes in circumstellar environments and combustion systems. Here, we reveal an unconventional low-temperature phenylethynyl addition–cyclization–aromatization mechanism for the gas-phase preparation of biphenyl (C12H10) along with ortho-, meta-, and para-substituted methylbiphenyl (C13H12) derivatives through crossed molecular beams and computational studies providing compelling evidence on their formation via bimolecular gas-phase reactions of phenylethynyl radicals (C6H5CC, X2A1) with 1,3-butadiene-d6 (C4D6), isoprene (CH2C(CH3)CHCH2), and 1,3-pentadiene (CH2CHCHCHCH3). The dynamics involve de-facto barrierless phenylethynyl radical additions via submerged barriers followed by facile cyclization and hydrogen shift prior to hydrogen atom emission and aromatization to racemic mixtures (ortho, meta) of biphenyls in overall exoergic reactions. These findings not only challenge our current perception of biphenyls as high temperature markers in combustion systems and astrophysical environments, but also identify biphenyls as fundamental building blocks of complex polycyclic aromatic hydrocarbons (PAHs) such as coronene (C24H12) eventually leading to carbonaceous nanoparticles (soot, grains) in combustion systems and in deep space thus affording critical insight into the low-temperature hydrocarbon chemistry in our universe. [ABSTRACT FROM AUTHOR]

Background: Pregnancy is associated with an increased risk of pulmonary aspiration during general anaesthesia, but the incidence of this complication is not well defined. Methods: We performed a retrospective database review in a tertiary care university hospital to determine the incidence of pulmonary aspiration in pregnant patients undergoing endotracheal intubation, with and without Rapid Sequence Induction (RSI), as well as face-mask ventilation and supraglottic airway devices. We included Patients in the 2nd or 3rd trimester of pregnancy and immediate postpartum undergoing surgical procedures. The primary endpoint was the occurrence of pulmonary aspiration. Results: Data from 2,390 patients undergoing general anaesthesia for cerclage of cervix uteri, manual removal of retained placenta, repair of obstetric laceration, or postpartum bleeding were retrospectively evaluated. A supraglottic airway device or face-mask ventilation was used in 1,425/2,390 (60%) of patients, while 638/2,390 (27%) were intubated. RSI was used in 522/638 (82%) of patients undergoing tracheal intubation, or 522/2,390 (22%) of the entire cohort. In-depth review of the charts, including 54 patients who had been initially classified as "possible pulmonary aspiration" by anaesthetists, revealed that this adverse event did not occur in the cohort. Conclusions: In conclusion, in this obstetric surgery patient population at risk for pulmonary aspiration, supraglottic airway devices were used in approximately 60% of cases. Yet, no aspiration event was detected with either a supraglottic airway or endotracheal intubation. [ABSTRACT FROM AUTHOR]

This study investigates the phase equilibria of the Al-Mo-Hf ternary system at 400 °C and 600 °C using X-ray diffraction (XRD) and electron probe microanalysis (EPMA/WDS) techniques. Seven three-phase and five two-phase regions were identified at 400 °C, while eight three-phase and four two-phase regions were identified at 600 °C. Despite variations in the solid solubility ranges of certain compounds, the distribution of phase zones in the isothermal cross-section remained consistent at both temperatures. Using the experimental results and logical deductions, isothermal cross-sections were constructed for the Al-Mo-Hf ternary system at 600 °C and 400 °C. [ABSTRACT FROM AUTHOR]

We investigate the radiative QED corrections to the lepton (L = e, μ and τ) anomalous magnetic moment due to the contributions of diagrams with insertions of the photon vacuum polarisation operator consisting solely of four closed lepton (l = e, μ and τ) loops. Moreover, we focus on specific operators with two loops formed by leptons L of the same type as the external one, the other two formed by leptons ℓ different from L. The approach is essentially based on the employment of the Mellin–Barnes representation of the x -parametrization of the corresponding Feynman diagrams. This allows one to obtain, for the first time, exact analytical expressions for the radiative corrections of the tenth order w.r.t. the electromagnetic coupling constant e. Analytically, the radiative corrections are expressed in terms of the ratio r = m ℓ / m L of the internal to external lepton masses. The dependence on r is investigated numerically in the whole interval of r, 0 < r < ∞. To make comparisons with earlier published results possible, our exact analytical expressions are expanded as r → 0 and r → ∞ and compared with the corresponding asymptotic expansions known in the literature. [ABSTRACT FROM AUTHOR]

The exploration of the fundamental formation mechanisms of polycyclic aromatic hydrocarbons (PAHs) is crucial for the understanding of molecular mass growth processes leading to two- and three-dimensional carbonaceous nanostructures (nanosheets, graphenes, nanotubes, buckyballs) in extraterrestrial environments (circumstellar envelopes, planetary nebulae, molecular clouds) and combustion systems. While key studies have been conducted exploiting traditional, high-temperature mechanisms such as the hydrogen abstraction–acetylene addition (HACA) and phenyl addition–dehydrocyclization (PAC) pathways, the complexity of extreme environments highlights the necessity of investigating chemically diverse mass growth reaction mechanisms leading to PAHs. Employing the crossed molecular beams technique coupled with electronic structure calculations, we report on the gas-phase synthesis of phenanthrene (C14H10)—a three-ring, 14π benzenoid PAH—via a phenylethynyl addition–cyclization–aromatization mechanism, featuring bimolecular reactions of the phenylethynyl radical (C6H5CC, X²A1) with benzene (C6H6) under single collision conditions. The dynamics involve a phenylethynyl radical addition to benzene without entrance barrier leading eventually to phenanthrene via indirect scattering dynamics through C14H11 intermediates. The barrier-less nature of reaction allows rapid access to phenanthrene in low-temperature environments such as cold molecular clouds which can reach temperatures as low as 10 K. This mechanism constitutes a unique, low-temperature framework for the formation of PAHs as building blocks in molecular mass growth processes to carbonaceous nanostructures in extraterrestrial environments thus affording critical insight into the low-temperature hydrocarbon chemistry in our universe. [ABSTRACT FROM AUTHOR]

Iatrogenic injuries are unavoidable complications of surgeries and minimally invasive procedures. They are generally classified into vascular and nonvascular injuries and based on the time of injury into early and late injuries. Iatrogenic injuries, particularly vascular injuries, increase the mortality and morbidity, with prolongation of hospital-stay. Multidetector computed tomography (MDCT) is a highly sensitive, and often the first imaging modality in suspected iatrogenic injuries. This pictorial review elucidates the imaging considerations and appearances of iatrogenic injuries of the abdominopelvic organs on MDCT. [ABSTRACT FROM AUTHOR]

In the late Middle Ages, aristocratic and urban circles competed against each other for esteem, legitimacy, authority, and fame. Family chronicles gained significant importance in that process, but we can also identify a definite discourse on dynastic interests in historiographical terms in contemporary literature. This study illuminates in three cases how individual authors conceived of the notion of dynasty and traced the rise and/or fall of their protagonists. Even in the case of an utter demise, the topic itself, the emergence and development of a dynasty, appealed to the wider readership, as reflected in some of the major late medieval German prose narratives and novels. The concept of a mythical origin of the family was particularly attractive, but also the miraculous rise from a low social status to the rank of a king, unheard of in reality, of course. [ABSTRACT FROM AUTHOR]

Purpose: This paper assesses the impact of this program on the rural women's employment opportunities using data from the 2015 round of the household's living standard survey (HLSS) of Côte d'Ivoire. Design/methodology/approach: In 2013, in order to improve the living conditions of the rural population, the Ivorian government launched the National Program for rural electrification (PRONER) to electrify all localities with more than 500 inhabitants. Findings: The results show that PRONER, while reducing the time allocated to performing household chores, increases women's employment through the reallocation of time to full-time paid work in the agricultural and non-agricultural sectors. The authors also find that the allocation of men's time is not affected by this programme. A possible mechanism that would explain such a pro-women effect is the labour-saving technology introduced to home production as an effect of the reform. Research limitations/implications: As a limitation, it is important to note that these results were obtained in the specific context of PRONER in Côte d'Ivoire and are not necessarily applicable to rural electrification programmes in other contexts. Furthermore, the choice of other indicators to measure women's empowerment is limited by the quality of the data available. It would be interesting for future research to extend this analysis to include other aspects of women's empowerment and household welfare. Originality/value: This paper is the first to the author's knowledge to apply a robust econometric method by combining an inverse probability weighted regression adjustment model with Heckman sample selection method to access a robust causal effect of the PRONER in Côte d'Ivoire. [ABSTRACT FROM AUTHOR]

2-Cyanoindene has recently been identified in the interstellar medium, however current models cannot fully account for its formation pathways. Herein, we identify and characterize 2-naphthylnitrene, which is prone to rearrange to 2- and 3-cyanoindene, in the gas phase using photoion mass-selective threshold photoelectron spectroscopy (ms-TPES). The adiabatic ionization energies (AIE) of triplet nitrene (3A′′) to the radical cation in its lowest-energy doublet X~;+(2A′) and quartet ã+(4A′) electronic states were determined to be 7.72 ± 0.02 and 8.64 ± 0.02 eV, respectively, leading to a doublet–quartet energy splitting (ΔED–Q) of 0.92 eV (88.8 kJ mol−1). A ring-contraction mechanism yields 3-cyanoindene, which is selectively formed under mild pyrolysis conditions (800 K), while the lowest-energy isomer, 2-cyanoindene, is also observed under harsh pyrolysis conditions at 1100 K. The isomer-selective assignment was rationalized by Franck–Condon spectral modeling and by measuring the AIEs at 8.64 ± 0.02 and 8.70 ± 0.02 eV for 2- and 3-cyanoindene, respectively, in good agreement with quantum chemical calculations. [ABSTRACT FROM AUTHOR]

Assumptions of competitive structure are often crucial for marginal cost estimation and counterfactual predictions. This paper introduces tests for price competition among multi-product firms. The tests are based on the firm's revealed preference (revealed profit function). In contrast to other approaches based on estimated demand functions such as conduct parameter estimation, the proposed tests do not require any instrumental variables, even though the models can accommodate structural error terms. In this paper, I employ a demand structure introduced by Nocke and Schutz (Econometrica 86(2):523–557, 2018. https://doi.org/10.3982/ECTA14720), the discrete/continuous choice model, which nests the multinomial logit demand and CES demand functions. Any price and quantity data can be rationalized by price competition under a discrete/continuous choice model and increasing marginal costs. Adding more assumptions to the demand functions, such as logit, CES, or the co-evolving and log-concave property produces some falsifiable restrictions. [ABSTRACT FROM AUTHOR]

Let Γ be a congruence subgroup of Sp 2 n (ℤ). Using Poincaré series of K -finite matrix coefficients of integrable discrete series representations of Sp 2 n (ℝ) , we construct a spanning set for the space S m (Γ) of Siegel cusp forms of weight m ∈ ℤ > 2 n . We prove the non-vanishing of certain elements of this spanning set using Muić's integral non-vanishing criterion for Poincaré series on locally compact Hausdorff groups. Moreover, using the representation theory of Sp 2 n (ℝ) , we study the Petersson inner products of corresponding cuspidal automorphic forms, thereby recovering a representation-theoretic proof of some well-known results on the reproducing kernel function of S m (Γ). Our results are obtained by generalizing representation-theoretic methods developed by Muić in his work on holomorphic cusp forms on the upper half-plane to the setting of Siegel cusp forms of a higher degree. [ABSTRACT FROM AUTHOR]

Urban data deficits in developing countries impede evidence-based planning and policy. Could energy data be used to overcome this challenge by serving as a local proxy for living standards or economic activity in large urban areas? To answer this question, we examine the potential of georeferenced residential electricity meter data and night-time lights (NTL) data in the megacity of Karachi, Pakistan. First, we use nationally representative survey data to establish a strong association between electricity consumption and household living standards. Second, we compare gridded radiance values from NTL data with a unique dataset containing georeferenced median monthly electricity consumption values for over 2 million individual households in the city. Finally, we develop a model to explain intra-urban variation in radiance values using proxy measures of economic activity from Open Street Map. Overall, we find that NTL data are a poor proxy for living standards but do capture spatial variation in population density and economic activity. By contrast, electricity data are an excellent proxy for living standards and could be used more widely to inform policy and support poverty research in cities in low- and middle-income countries. [ABSTRACT FROM AUTHOR]

In current power markets, the bulk of electricity is sold wholesale and transported to consumers via long‐distance transmission lines. Recently, decentralized local energy markets have evolved, often as isolated networks based on solar generation. We analyze strategic pricing, investment, and welfare in local energy markets. We show that local energy markets yield competitive equilibrium prices and provide efficient investment incentives. Yet, we find that strategic behavior leads to allocative inefficiency. We propose a clearing mechanism that induces truth‐telling behavior and restores first‐best welfare. [ABSTRACT FROM AUTHOR]

Copyright of Natura Sloveniae: Revija za Terensko Biologijo / Journal of Field Biology is the property of Natura Sloveniae and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

This article shows that the unambiguous meaning representation of machine language must be inspired by human cognition to find a universal label for Natural Language Processing resources. We show, that the meaning representation is linked to the quality and not to the quantity of data, since the architecture of human symbolization, taken as a model, incorporates contextual elements in its dynamics. We argue that language, when conceived under this dynamic concept, must be analyzed in terms of sequence-by-sequence transformations, focusing on the structural bases of the meaning construction that: i) offers relative certainty for different possible responses; ii) provides more accurate and reliable input data; and iii) avoids the curse of dimensionality. We conclude by suggesting that the construction of databases should indicate the upper hierarchical structure based on the lower structures, referring to the string-to-meaning derivation in the fundamental tree of the language. This strategy, applied to meaning representation, frees the operator from dictating a specific sequence for each application. Thus, the construction of meaning in natural language processing becomes more contextualized and unambiguous. Based on the dynamic structure of the language, therefore, it is possible to develop semantic databases in any spoken language. [ABSTRACT FROM AUTHOR]

Copyright of Chirurgia Narzadów Ruchu i Ortopedia Polska - Polish Orthopaedics is the property of Polish Society for Orthopedic Surgery & Traumatology and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Purpose: In current clinical practice, intelligibility of dysarthric speech is commonly assessed by speech-language therapists (SLTs), in most cases by the therapist caring for the patient being diagnosed. Since SLTs are familiar with dysarthria in general and with the speech of the individual patient to be assessed in particular, they have an adaptation advantage in understanding the patient's utterances. We examined whether and how listeners' assessments of communication-related speech parameters vary as a function of their familiarity with dysarthria in general and with the diagnosed patients in particular. Method: Intelligibility, speech naturalness, and perceived listener effort were assessed in 20 persons with dysarthria (PWD). Patients' speech samples were judged by the individual treating therapists, five dysarthria experts who were unfamiliar with the patients, and crowdsourced naïve listeners. Adaptation effects were analyzed using (a) linear mixed models of overall scoring levels, (b) regression models of severity dependence, (c) network analyses of between-listener and between-parameter relationships, and (d) measures of intra- and interobserver consistency. Results: Significant advantages of dysarthria experts over laypeople were found in all parameters. An overall advantage of the treating therapists over nonfamiliar experts was only seen in listening effort. Severity-dependent adaptation effects occurred in all parameters. The therapists' responses were heterogeneous and inconsistent with those of the unfamiliar experts and the naïve listeners. Conclusions: The way SLTs evaluate communication-relevant speech parameters of the PWD whom they care for is influenced not only by adaptation benefits but also by therapeutic biases. This finding weakens the validity of assessments of communication-relevant speech parameters by the treating therapists themselves and encourages the development and use of alternative methods. [ABSTRACT FROM AUTHOR]

MPV17 is a mitochondrial inner membrane protein, and its deficiency can cause mitochondrial DNA (mtDNA) depletion, increase reactive oxygen species (ROS), and promote apoptosis in several cell types, suggesting that MPV17 plays a protective role in cells although the underlying mechanism remains unknown. To test whether MPV17 is also protective in diabetic kidney disease, we treated Mpv17-deficient mice with streptozotocin (STZ) and surprisingly found that they were resistant to diabetes. Mpv17 deficiency was also found to confer resistance to the diabetes induced by an insulin mutation (Ins2Akita), which represents a mouse model of monogenic diabetes characterized by proinsulin misfolding and ß-cell failure. In both STZ and Ins2Akita models, Mpv17 mutants had significantly less severe ß-cell loss and apoptosis compared with the wild-type mice. We next showed that MPV17 is expressed in ß-cells of mice normally, suggesting that MPV17 acts ß-cells autonomously to facilitate apoptosis. Consistently, Mpv17 knockdown improved the viability and ameliorated the apoptosis of cultured MIN6 cells treated with STZ and palmitic acid (PA), respectively, accompanied by prevention of caspase 3 activation. The proapoptotic effect of MPV17 in ß-cells is in contrast with its known anti-apoptotic effect in other cell types. Thus, we have identified a novel regulator of ß-cell death in diabetes development. [ABSTRACT FROM AUTHOR]

Objective The aim of the study was to assess the safety and efficacy of endovascular management for postpancreaticoduodenectomy hemorrhage. Materials and Methods A retrospective analysis of patients who underwent endovascular management for hemorrhage after pancreatic surgery between January 2015 to December 2020 was performed. Patient demographics, clinical presentation, angiography findings, endovascular procedure, technical success, clinical success, and complications were assessed. Results Seventeen patients, comprising 14 (82.4%) males and 3 (17.6%) females, aged 37 to 68 years underwent endovascular management for postpancreatectomy hemorrhage. Patients presented with hemorrhage on their postoperative days 4 to 22 (mean: 9.8th day; median: 8th day); the presentation was with extraluminal hemorrhage in 11 patients (64.7%) and intraluminal hemorrhage in 6 patients (35.2%). The gastroduodenal artery (GDA) stump (10 patients, 58.8%) was the most commonly involved artery. The majority of cases were treated using coils as embolizing agents (13/17 patients, 76.5%). The technical and clinical success rates were 100%. The complication rate was 5.9% (1/17) and the mortality rate was 11.8% (2/17). The relaparotomy rate was 23.5% (4/17); however, none of the relaparotomy was for hemorrhage. Conclusion Endovascular treatment provides a minimally invasive, safe, and effective method for the management of pancreaticoduodenectomy hemorrhage. [ABSTRACT FROM AUTHOR]

This article explores the grammatical features of African American Vernacular English (AAVE) in Justin Bieber's songs from 2009 to 2021. The study identifies and analyzes the most common AAVE features used by Bieber, such as negation forms, specialized auxiliaries, and copula absence. The research shows that the number of AAVE features has decreased in Bieber's songs over the years. This study provides valuable insights into the grammatical characteristics of AAVE and their impact on popular music. [Extracted from the article]

Copyright of Jahrbuch der Psychoanalys Psychosozial-Verlag GmbH & Co. KG (Psychosozial-Verlag GmbH & Co. KG) is the property of Psychosozial-Verlag GmbH & Co. KG and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The Brazilian cerrado is the biome with the greatest biodiversity in the world and fruit species-rich in bioactive compounds. Chemometric techniques can potentially group alternatives from natural sources of bioactive compounds reliably and intuitively. Thus, in the present study, the objective was to analyze fruits of 13 cerrado species for the profile of phenolic compounds, total phenolic compounds (TPC), vitamin C and antioxidant activity by six different methods and group them by chemometric techniques. The results confirm that cerrado fruits are important vehicles of vitamin C and TPC, with high antioxidant activity. The Principal Component (PCA) and Hierarchical Cluster (HCA) analysis, based on the contents of bioactive compounds and antioxidants in the fruits, allowed the species to be grouped into 6 clusters: (i) gabiroba (Campomanesia pubescens), (ii) bacaba (Oenocarpus bacaba Mart.), (iii) murici (Byrsonima crassiflora L.), mangaba (Hanconia speciosa Gomes) and marolo (Annona crassiflora Mart.), (iv) saborosa (Selenicereus setaceus Rizz.), curriola [Pouteria ramiflora (Mart.) Radlk.], marmelada espinho (Alibertia verrucosa), marmelada bola (Alibertia edulis) and araçá-boi (Eugenia stipitata Mc. Vaugh), (v) pequi (Caryocar brasiliense Camb.) and (vi) yellow puçá (Mouriri elliptica Mart.) and black puçá (Mouriri pusa Gardner). It is concluded that gabiroba, mangaba, and marolo stand out for their greater antioxidant potential and that chemometric techniques were effective in grouping the cerrado fruits according to TPC, vitamin C, and antioxidant activities, thus showing that the inclusion of these fruits in the daily diet as a source of bioactive compounds is viable. [ABSTRACT FROM AUTHOR]

Copyright of Bildung und Erziehung is the property of Vandenhoeck & Ruprecht GmbH & Co. KG and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The cranefly (Tipuloidea) fauna of the Western Balkans is still poorly known. In this study, occurrence data of 77 species is reported, of which two species are newly recorded for Albania, eight species for Bosnia and Herzegovina, twelve for Croatia, and seven for Slovenia, respectively. A new species, Baeoura neretvaensis Kolcsár & d’Oliveira, sp. nov. is described from Bosnia and Herzegovina, Montenegro, and Slovenia. Images of the habitus, wing, and male and female terminalia of the new species are provided. Furthermore, images of male terminalia and wings of thirteen additional species are presented. [ABSTRACT FROM AUTHOR]

Correction for 'Zinc(II) hydration in aqueous solution. A Raman spectroscopic investigation and an ab initio molecular orbital study' by Wolfram W. Rudolph et al., Phys. Chem. Chem. Phys., 1999, 1, 4583–4593, https://doi.org/10.1039/A904051J. [ABSTRACT FROM AUTHOR]

Background: Diabetes is a complex chronic health condition that can have a significant impact on physical health and psychological wellbeing. Diabetes management can be particularly difficult for young people (YP) with a diagnosis, and complications arising from poor diabetes self-care can be personally and economically costly. There are ongoing local and national priorities to improve diabetes care management (NHS England, 2016/2017) and streamline resources. A service evaluation was commissioned to understand YP's experiences of living with diabetes. Methods: A qualitative approach was used to elicit YP's (16-25) experiences of living with diabetes. Eight YP were interviewed using a semi-structured format. Results: Five themes were identified from the data: 1) Experience of diagnosis, 2) Day-to-day management, 3) Self-identity, 4) Interactions with staff and 5) Peer support. Conclusions: Overall, the findings of this evaluation indicated that YP found navigating and balancing the demands of diabetes and engagement in typical developmental activities a challenging process. These were sometimes at odds with the priorities of healthcare professionals (HCPs), and lead to differences in the perception of optimal diabetes management. This in turn often had a major impact on engagement and diabetes self-care. The evaluation identified that there is an important role for a psychology service to support the psychological wellbeing of YP with diabetes and to create a shared understanding between YP and HCPs to help increase engagement, collaboration and self-management. [ABSTRACT FROM AUTHOR]

Eleven complexes with the general formula [Tp*W(CO)L{η2-C2(PPh2)2}]n+ {Tp* = hydridotris(3,4,5-trimethylpyrazolyl)-borate, L = F−, Cl−, Br−, I−, MeS−, PhS−, pyCH2S−, CN− and TfO−; n = 0 and L = CH3CN and pyridine; n = 1} have been synthesized and fully characterized. Depending on L, the oxidation process from W(II) to W(III) is detected between −0.28 and +0.55 V vs. Fc/Fc+ and the spectroscopic properties (X-ray, IR, and NMR) are influenced according to the electron-rich or electron-poor character of the central metal. The basicity of the alkyne complex-based phosphine groups was estimated by the 31P/77Se coupling method of the corresponding diselenides. Selected examples of the dppa-complex ligands were converted into the corresponding κ2-PdCl2 chelate complexes and employed in a Sonogashira reaction in order to estimate the effect of L on the catalytic behaviour of the dinuclear complexes. While the spectroscopic properties show a good correlation with the redox potential in a mostly linear fashion, catalytic activity is influenced only slightly. The effect of PdCl2 coordination on the alkyne complex is evident from the W(II)/W(III) redox potentials measured by cyclic voltammetry supported by a change of the CO stretching frequency in IR. A comparison of the molecular structures of the alkyne complexes with terminal phosphine groups and the PdCl2 chelate complexes all determined by XRD shows the essential flexibility of the bend-back angles in the alkyne complex moiety. [ABSTRACT FROM AUTHOR]

With the highest albedo of the land surface, snow plays a vital role in Earth's surface energy budget and water cycle. Snow albedo is primarily controlled by snow grain properties (e.g., size and shape) and light-absorbing particles (LAPs) such as black carbon (BC) and dust. The mixing state of LAPs in snow also has impacts on LAP-induced snow albedo reduction and surface radiative forcing (RF). However, most land surface models assume that snow grain shape is spherical and LAPs are externally mixed with the snow grains. This study improves the snow radiative transfer model in the Energy Exascale Earth System Model version 2.0 (E3SM v2.0) Land Model (ELM v2.0) by considering non-spherical snow grain shapes (i.e., spheroid, hexagonal plate, and Koch snowflake) and internal mixing of dust–snow, and it systematically evaluates the impacts on the surface energy budget and water cycle over the Tibetan Plateau (TP). A series of ELM simulations with different treatments of snow grain shape, mixing state of BC–snow and dust–snow, and sub-grid topographic effects (TOP) on solar radiation are performed. Compared with two remote sensing snow products derived from the Moderate Resolution Imaging Spectroradiometer, the control ELM simulation (ELM_Control) with the default configurations of spherical snow grain shape, internal mixing of BC–snow, external mixing of dust–snow, and without TOP as well as the ELM simulation with new model features (ELM_New) can both capture the overall snow distribution reasonably. Additionally, ELM_New overall shows smaller biases in snow cover fraction than ELM_Control in spring when snowmelt is important for water management. The estimated LAP-induced RF in ELM_New ranges from 0 to 19.3 W m -2 with the area-weighted average value of 1.5 W m -2 that is comparable to the reported values in existing studies. The Koch snowflake shape, among other non-spherical shapes, shows the largest difference from the spherical shape in spring when snow processes related to the surface energy budget and water cycle have high importance. The impacts of the mixing state of LAP in snow are smaller than the shape effects and depend on snow grain shape. Compared to external mixing, internal mixing of LAP–snow can lead to larger snow albedo reduction and snowmelt, which further affect the surface energy budget and water cycle. The individual contributions of non-spherical snow shape, mixing state of LAP–snow, and local topography impacts on the snow and surface fluxes have different signs and magnitudes, and their combined effects may be negative or positive due to complex and nonlinear interactions among the factors. Overall, the changes in net solar radiation in spring due to individual and combined effects range from -28.6 to 16.9 W m -2 and -29.7 to 12.2 W m -2 , respectively. This study advances understanding of the role of snow grain shape and mixing state of LAP–snow in land surface processes and offers guidance for improving snow simulations and RF estimates in Earth system models under climate change. [ABSTRACT FROM AUTHOR]

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Paul the Deacon’s History of the Lombards is the main source for the history of Italy’s eastern frontiers. On the backdrop of further narratives from the age, the paper analyzes Paul’s account on the nature, location of the frontiers, together with their aristocracies between the sixth and eighth centuries. [ABSTRACT FROM AUTHOR]