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This paper presents the results of a photoelectrocatalytic study for a copper-silver system obtained in the form of microtubes using electrochemical template synthesis. CuOx/Cu hollow microtubes (HT) decorated with nanoscale silver particles by electrodeposition demonstrate the cathode photocurrent in 7.6 uAcm–2 when using LED light sources in the UVA-Vis spectral region and low polarization values. It was shown that the highest intensity of the photoresponse is achieved in the visible region at a wavelength of 450 nm. The stability test suggests that the retention of Ag/CuOx-HT is 95% after 12 hours of functioning.

Investment casting is a widely utilized casting technique that offers superior dimensional accuracy and surface quality. In this method, the wax patterns are employed in the layer-by-layer formation of a shell mold. As is customary, the patterns were created through the injection of molten or semi-solid wax into the die. The quality of the final casting is affected by the quality of the wax pattern. Furthermore, the filling of the die with wax can be associated with die-filling challenges, such as the formation of weld lines and misruns. In this study, the injection filling of the fluidity probe die with RG20, S1235, and S1135 pattern waxes was simulated using ProCast software. The thermal properties of the waxes, including thermal conductivity, heat capacity, and density across a wide temperature range, were determined with the assistance of a laser flash analyzer, a differential scanning calorimeter, and a dynamic mechanical analyzer. A favorable comparison of the acquired properties with those reported in the literature was observed. The Carreau model, which corresponds to non-Newtonian flow, was employed, and the parameters in the Carreau viscosity equation were determined as functions of temperature. Utilizing the thermal data associated with the wax patterns and the simulation outcomes, the interfacial heat transfer coefficients between the wax and the die were ascertained, yielding a value of 275–475 W/m2K. A strong correlation was observed between the experimental and simulated filling percentages of the fluidity probe across a wide range of injection temperatures and pressures. The analysis of the simulated temperature, fraction solid, viscosity, and shear rate in the wax pattern revealed that viscosity is a crucial factor influencing the wax fluidity. It was demonstrated that waxes with an initial high viscosity exhibit a low shear rate, which subsequently increases the viscosity, thereby hindering the wax flow.

In the investment casting process, the pattern made of wax is obtained in a die for further formation of a shell mold. The problem of die-filling by pattern wax is significant because it influences the quality of the final casting. This work investigates three commercial pattern waxes’ fluidity with a newly developed injection fluidity test. It was shown that the fluidity of waxes increased with increasing injection temperature and pressure, and the simultaneous increase in temperature and pressure gives a much more significant enhancement of fluidity than an increase in temperature or pressure separately. The rheological behavior of the waxes was also investigated at different temperatures using a rotational viscosimeter, and temperature dependences of waxes’ dynamic viscosity were determined. It was shown that wax viscosity is increased more than ten times with decreasing temperature from 90 to 60 °C. A good correlation between wax fluidity and its viscosity is observed, which is different from metallic alloys, where the solidification behavior is more critical. The difference in wax flow behavior in comparison with metallic melts is associated with the difference in dynamic viscosity, which for investigated waxes and metallic melts is 3000–27,000 mPa·s and 0.5–6.5 mPa·s, respectively. The difference in investigated filled waxes’ fluidity is observed, which can be associated with the type and amount of filler. The twice-increasing fraction of cross-linked polystyrene decreases fluidity twice. At the same time, terephthalic acid has a minor influence on wax fluidity.