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Global navigation satellite systems (GNSSs) provide a common positioning method that utilizes satellite signals to determine the spatial location of a receiver. However, there are several error factors in standalone GNSS positioning due to instrumental, procedural, and environmental factors that arise during the signal transmission process, and the final positioning error can be up to several meters or greater in length. Thus, real-time kinematic (RTK) correction and post-mission precise point positioning (PPP) processing technologies are proposed to improve accuracy and accomplish precise position measurements. To evaluate the geolocation accuracy of mosaicked UAV images of an abandoned mine site, we compared each orthomosaic image and digital elevation model obtained using standalone GNSS positioning, differential (RTK) GNSS positioning, and post-mission PPP processing techniques. In the three types of error evaluation measure (i.e., relative camera location error, ground control points-based absolute image mapping error, and volumetric difference of mine tailings), we found that the RTK GNSS positioning method obtained the best performance in terms of the relative camera location error and the absolute image mapping error evaluations, and the PPP post-processing correction effectively reduced the error (69.5% of the average total relative camera location error and 59.3% of the average total absolute image mapping error) relative to the standalone GNSS positioning method. Although differential (RTK) GNSS positioning is widely used in positioning applications that require very high accuracy, post-mission PPP processing can also be used in various fields in which it is either not feasible to operate expensive equipment to receive RTK GNSS signals or network RTK services are unavailable.