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A novel nanocomposite was prepared by hybridizing polyacrylic acid/maleic acid with nano copper oxide (PAACMA/CuO) for the sorption of 60Co (II) and 152+154Eu (III) radionuclides from an aqueous solution. Nano-CuO was biochemically produced by hydrolysing its salt in the presence of the Aspergillus terreus fungus. The PAACMA/CuO nanocomposite was characterized using a variety of analytical techniques. The optimum sorption conditions (pH 4.5 for 60Co and pH 3.53 for 152+154Eu, 24 h of equilibrium time at 20 oC) were applied. The kinetic mechanism of the sorption reaction was controlled by pseudo second order based on residual charts, coefficient of determination (R2), and corrected Akaike information Criterion (AICc). The sorption reaction mechanism was controlled by Langmuir model for linear regression using the coefficient of determination and the Dubinin-Radushkevich D-R model for the AICc and residual plots error functions. The reaction mechanism throughout non-linear regression was controlled by the D-R model due to the coefficient of determination, AICc, and residual charts. The PAACMA/CuO nanocomposite had a mono-layer adsorption capacity of 11.04 mg g− 1 for Co (II) and 21.54 mg g− 1 for Eu (III). According to desorption studies, Co (II) and Eu (III) could be recovered by 0.1 mol L− 1 EDTA with efficiencies 55.46% and 95.044%, respectively. According to thermodynamic studies, the sorption of Co (II) and Eu (III) on the prepared composite was endothermic and spontaneous.

Nitrogen (N) fertilizer has been intensively used to improve peanut productivity. However, the high cost of N fertilizer, and the need for sustainable alternative fertilizer sources have increased the strategic importance of nitrogen fixation (NF). Thus, field experiments were conducted in an experimental farm with a drip irrigation system, at the Atomic Energy Authority, Inshas, Egypt, in order to measure the impact of efficiency symbiotic Bradyrhizobium sp. and asymbiotic Azotobacter sp. on NF, from air and soil, in the presence or absence of plant residues on the growth and yield of peanut plant. All treatments received nitrogen fertilizer at a rate of 72 kg N per hectare. Nitrogen dose was applied using ammonium sulphate 15N labeled of 10% atom excess from the peanut. Results indicated that the application of Bradyrhizobium sp. with plant residues significantly increased fresh and dry weight/m2, pod and seed weight/plant−1,100- seed weight, and biological yield kg ha−1, where the highest mean values of seed yield (4648 and 4529 kg ha−1), oil % (52.29 and 52.21%), seed protein percentage (16.09 and 15.89%), as well as nitrogen derived from air (63.14 and 66.20%) in the first and second seasons were recorded under the application of Bradyrhizobium sp, respectively. Bradyrhizobium sp. inoculation showed nearly close portions of Ndfa to those recorded with Azotobacter sp., in both the presence and absence of plant residue application through the two seasons. The investigated yield signs and their properties were significantly enhanced by bacterial inoculation with plant residue application. The present study shows that both possibility of NF of peanut, and nitrogen uptake in the soil are enhanced by field inoculation with effective Bradyrhizobium sp. with plant residue application. In practice, inoculation is a great strategy to improve soil fertility for subsequent planting, since it helps boost the import of nitrogen from plant biomass into the soil.

Nano ZnO is biosynthesized using Lactobcillus sp. Poly Acrylic acid-co-Acrylonitrile/ZnO, PAACAN/ZnO, and poly Acrylic acid-co-Maleic acid/ZnO, PAACMA/ZnO, nancomposites were synthesized using 60Co γ-rays. PAACAN/ZnO and PAACMA/ZnO nanocomposites were characterized and used as sorbents for 60Co(II) radionuclide. The monolayer adsorption capacities of 60Co(II) onto PAACMA/ZnO and PAACAN/ZnO are 18.235, 7.105 mgg−1, respectively at pH 4.5 and 20 °C. The sorption reaction has a pseudo 2nd order mechanism. 0.1 M EDTA could be used as an eluent for desorption. The desorption efficiencies of 60Co(II) from PAACAN/ZnO and PAACMA/ZnO were 67.51 and 84.85%, respectively. The sorption process is endothermic and spontaneous.

The zygomatic bone, which includes the lateral and inferior orbital rims as well as the malar eminence, comprises the lateral part of the midface, giving it width and projection. Zygomatic arch fractures account for 10% to 15% of all facial fractures and are commonly caused by a direct blow to the face. Zygomatic fractures are most caused by blunt trauma. Paediatric zygomatic fractures are a rare complication in the continuum of craniofacial injuries that cosmetic and reconstructive surgeons deal with. The combination between etiology, force of damage, and stage of craniofacial development determines the location and distribution of facial fractures in children. The purpose of this research is to review the available information about the epidemiology, classification and management of zygomatic fractures in children. Although facial fractures especially zygomatic fractures in children are quite uncommon and rare, appropriate screening and diagnosis, as well as prompt treatment, are necessary to avoid consequences. Surgeons face tremendous hurdles when dealing with facial trauma associated with serious injuries, as there is a functional and aesthetic impact on the growing children, as well as a financial and emotional burden on the patient and family. The early management of zygomatic fractures in children, like any trauma, detects situations that require rapid treatment to avoid life-threatening consequences. Paediatric zygomatic fractures are quite uncommon due to the specific anatomic, physiologic, social, and environmental aspects that accompany craniofacial growth however the literature data is lacking and quite scarce, more epidemiological studies targeting age group of children are needed.