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The sources of fluids and metals in porphyry systems of continental-collision settings are poorly constrained. Mercury isotopes display unique mass-independent fractionation (expressed as Δ199Hg) and may provide important constraints on metal and volatile sources given that Hg is a highly volatile metal. Here, we report Hg isotope data on ore-forming porphyries, barren magmatic rocks, and mantle-derived mafic magmas from southern Tibet. The fertile porphyries and coeval mafic magmas display mainly positive Δ199Hg values (up to +0.25 per mil), while Δ199Hg values in barren magmatic rocks and mafic magmas are largely negative (-0.54 to 0.00 per mil). The positive Δ199Hg values observed here are consistent with seawater and marine sediments, suggesting that the ultimate source of fluids involved in the genesis of post-subduction porphyry copper deposits was the mantle lithosphere metasomatized by previous oceanic plate subduction. Our Hg isotope data provide an alternative view to current metallogenetic models on collisional porphyry systems that focus on melting of the lower continental crust. [ABSTRACT FROM AUTHOR]

We present coupled textural, elemental, and boron isotopic data of tourmaline from the large Zhunuo–Beimulang collision-related porphyry copper deposits (PCDs) located within the western Gangdese, Tibet. Based on morphology and high-resolution mapping, the tourmaline is classified into three paragenetic generations. The first generation of schorlitic Tur-1 occurs in the monzogranite porphyry as disseminations intergrown with porphyritic K-feldspar and plagioclase. It shows decreasing Fe and Ca and increasing Mg and Al contents from core to rim and has relatively homogeneous δ11B values (− 9.9 to − 8.6‰); low Fe3+/(Fe2+ + Fe3+), Cu, F, H2O, and Sr/Y ratios; and high rare earth elements. These features indicate Tur-1 formed in a low fO2 and metal-poor granitic magma during the pre-mineralization stage. The second generation of porphyritic euhedral Tur-2 is hosted in diorite porphyry enclaves and dikes, where it is intergrown with plagioclase and biotite. It forms part of the schorl-dravite solid solution, with high Fe3+/(Fe2+ + Fe3+), Cu, F, H2O, Sr/Y, and δ11B (− 9.7 to − 5.1‰) values. These features indicate it crystallized from a hydrous, oxidized, metal-, and volatile-rich diorite magma. The third generation of Tur-3 is the most volumetrically important and occurs as veinlets and disseminations in the porphyry, or around Tur-1 and Tur-2. It shows radial and oscillatory zoning and is locally intergrown with chalcopyrite and pyrite within the main mineralization assemblage. It has δ11B values (− 10.5 to − 6.0‰) that overlap with Tur-1 and Tur-2 values. Tur-3 also has variable Fe3+/(Fe2+ + Fe3+), Cu, and volatiles (F and H2O), indicating it crystallized from oxidized to relatively reducing metal- and volatile-rich hydrothermal fluids. Overall, the three generations of tourmaline show a narrow range of δ11B values between − 10.5 and − 5.1‰ that are indicative of a single magmatic source. The high Cu, ferric iron, volatiles, and δ11B values in Tur-2 are interpreted to reflect injection of diorite magma into an open crustal magma storage system that led to the formation of an oxidizing and metal-volatile-rich porphyry system. The three stages of tourmaline formation reflect evolution of the magmatic–hydrothermal system from low fO2 conditions towards more oxidizing, volatile-rich conditions and then a return to more reducing conditions that accompanied Cu precipitation. Overall, the injection of oxidized metal-rich magma into a long-lived magma reservoir is a critical driving force for the development of collision-related PCDs. [ABSTRACT FROM AUTHOR]

Chlorite is present extensively in many types of deposits. The mechanism underlying the chemical variations in chlorite remains unclear. The Naruo porphyry deposit is a giant copper porphyry deposit in the Duolong ore district of Tibet. Chlorite, which is abundant in this deposit, has yet to be studied systematically; hence, we used principal component analysis (PCA) to assess the correlation between chlorite elements and various types of mineral deposits. We then conducted a preliminary investigation into its mineralogy and geochemistry to better understand its formation process and identify potential prospecting indicators. The PCA method proved effective in discerning two distinctive element signatures within the chlorite and categorising them into four deposit types: orogenic Au deposits, granite-type U deposits, and skarn-type Sn deposits that exhibit high FeOand low MgO distinguishing them from porphyry copper deposits. The chlorite in the Naruo deposit is classified as either early metasomatic (M-type), consisting mainly of clinochlore, or late hydrothermal (H-type), primarily consisting of clinochlore and chamosite. This classification suggests that H-type chlorite formed in a reductive environment conducive to Cu precipitation at medium temperatures (255°C-342°C). Al-Si and Fe-Mg substitutions were found to be the primary processes involved in its generation. Additionally, from the mineralisation centre outwards, there was an observed decrease in Si content as well as the Fe/(Fe+Mg) ratio in H-type chlorite, along with decreases in temperature, sulphur, and oxygen fugacity of allchlorites; conversely, increases were observed for Al content along with Mg and Mn elements in H-type chlorite. Chlorite is useful for exploring porphyry copper systems as an indicator mineral. [ABSTRACT FROM AUTHOR]

The Yulong porphyry copper belt in eastern Tibet is located in the middle of Tethys–Himalayan metallogenic mega-province, which is one of the three major porphyry copper metallogenic mega-provinces. The Yulong copper belt belongs to the super porphyry copper belt and represents one of the most important copper mineralization prospecting areas in China. A significant quantity of research data shows that this study area belongs to the environment of intracontinental collision and compression, with a complex geological structure, magmatic rock development and excellent metallogenic geological background. However, because this area is located in an alpine and high-altitude area, it is difficult to carry out any traditional field geological surveys, and the existing studies of both prospecting and prediction are relatively weak. This study focused on information extraction for alteration minerals in the Yulong metallogenic belt and its surroundings based on multispectral data and hyperspectral data, establishing a spectral library of alteration minerals in this area. Based on Sentinel-1A radar data and Landsat-8 OLI color synthesis data, the linear structure of the study area was interpreted. On this basis, the information extraction results relating to alteration minerals obtained from multi-source remote sensing data, linear structure interpretation results and the geochemical exploration data of the study area were superimposed to comprehensively analyze the metallogenic geological conditions and mineralization characteristics in the area, establish remote sensing prospecting indicators there and optimize the potential areas for prospecting, providing technical support for the next step of prospecting and exploration in the area. [ABSTRACT FROM AUTHOR]

The Gangdese belt in Xizang has experienced both Jurassic subduction and Cenozoic continental collision processes, making it a globally renowned region for magmatic rocks and porphyry copper deposits. Numerous Jurassic intrusions have been identified in the belt. Apart from the quartz diorite porphyry in the large Xietongmen deposit, the Cu mineralization potential of other Jurassic intrusions in this belt remains unclear. This study presents zircon U–Pb dating and trace elements, apatite major and trace elements as well as published whole-rock geochemical and isotopic data of the Dongga tonalite in the central part of the Gangdese belt, aiming to reveal the petrogenesis, oxidation state, volatile content, and Cu mineralization potential of this intrusion. The Dongga tonalite has a zircon U–Pb age of 179.4 ± 0.9 Ma. It exhibits high whole-rock V/Sc values (8.76–14.6), relatively low apatite CeN/CeN* ratios (1.04–1.28), elevated zircon (Eu/Eu*)N values (an average of 0.44), high Ce4+/Ce3+ values (205–1896), and high ∆FMQ values (1.3–3.7), collectively suggesting a high magmatic oxygen fugacity. The Dongga tonalite features amphibole phenocrysts, relatively high whole-rock Sr/Y ratios (20.3–58.9), and lower zircon Ti temperatures (502–740 °C), reflecting a high magmatic water content. Estimation of magmatic sulfur content (0.002–0.024 wt%) based on apatite SO3 contents indicates an enriched magma sulfur content. Combined with previous studies and the collected Sr–Nd–Hf isotopes, the Dongga tonalite is derived from juvenile lower crust related with subduction of the NeoTethys oceanic slab. When compared with Xietongmen ore-bearing porphyries, the Dongga tonalite exhibits remarkable similarities with the Xietongmen ore-bearing porphyries in terms of magma source, tectonic background, magmatic redox state, and volatile components, which indicates that the Dongga tonalite has a high porphyry Cu mineralization potential, and therefore, provides important guidance for the future mineralization exploration. [ABSTRACT FROM AUTHOR]

The timing and extent of sulfide saturation have been suggested as controlling factors in the formation of economically significant porphyry Cu deposits in subduction zone settings. However, details on the sulfide saturation history in post-collisional porphyry systems remain ambiguous. Accordingly, we have characterized the whole-rock geochemistry, including platinum-group elements (PGE), of igneous intrusions in the post-collisional Chongjiang porphyry Cu–Mo–Au deposit (southern Tibet) and utilize this data in conjunction with zircon U–Pb geochronological results and sulfide chemistry to assess the timing of sulfide saturation, the nature and amount of magmatic sulfide produced. The Chongjiang intrusions (monzogranite, biotite monzogranite porphyry, granodiorite, dacite porphyry, and quartz diorite porphyry) and mafic microgranular enclaves (MMEs) have zircon U–Pb ages of 14.2 to 12.8 Ma. Covariations in whole-rock major and trace elements among the Chongjiang intrusions and MMEs, together with similarities in their Sr–Nd and zircon Hf isotope compositions, indicate that they are co-magmatic and crystallized from a juvenile lower crustal melt that mixed with mafic melt derived from the lithospheric mantle; this hybrid melt subsequently evolved via fractional crystallization. Trace-element ratios in zircon and temperature − ∆FMQ estimates of the different intrusions suggest that they all crystallized from oxidized (average ∆FMQ = 1.9–2.6) and water-rich magmas. Palladium contents and Pd/Pt ratios in the Chongjiang igneous intrusions increase with decreasing MgO up to 3.9 wt % MgO, after which they abruptly decrease. The initial increase in Pd/Pt ratios likely results from the fractionation of a Pt-rich mineral (e.g. Pt–Fe alloy). The decrease in Pd contents and Pd/Pt ratios at 3.9 wt % MgO likely results from sulfide saturation during magma evolution, but prior to volatile exsolution, which occurred at approximately 1.4 to 2.4 wt % MgO. The presence of magmatic sulfide inclusions in amphibole and magnetite in samples with 3.9 wt % MgO, and the geochemical compositions of sulfide inclusions suggest that they represented trapped sulfide liquid and intermediate solid solution. Results of Monte Carlo simulations demonstrate that 0.003 to 0.009 wt % magmatic sulfide is required to have fractionated from the magma to explain the decrease in Pd contents at 3.9 wt % MgO. Highly chalcophile elements, such as Pd, will be sequestered by the magmatic sulfide that saturates at depth, decreasing their concentrations in the residual silicate melt, whereas concentrations of the less chalcophile elements, such as Cu, Mo, and even Au, will not be as significantly affected. Consequently, sufficient concentrations of Cu–Mo–Au will remain in the residual melt and, upon reaching volatile saturation, can be transported by the vapor phase to form porphyry Cu–Mo–Au deposits. In the case of the Chongjiang deposit, sulfide saturation was likely triggered by the high pressures and/or depletion of FeO caused by the thick (~70 km) crust beneath the Gangdese belt. This contribution presents evidence of sulfide saturation in post-collisional magmatic systems, and demonstrates that the amount of magmatic sulfide produced is a critical factor in controlling the formation of post-collisional porphyry Cu deposits. [ABSTRACT FROM AUTHOR]

The Jiama deposit, a significant porphyry‐skarn‐type copper polymetallic deposit located within the Gangdese metallogenic belt in Tibet, China, exemplifies a typical porphyry metallogenic system. However, the mineral chemistry of its accessory minerals remains under‐examined, posing challenges for resource assessment and ore prospecting. Utilizing electron microprobe analysis and LA‐ICP‐MS analysis, this study investigated the geochemical characteristics of apatite in ore‐bearing granite and monzogranite porphyries, as well as granodiorite, quartz diorite, and dark diorite porphyries in the deposit. It also delved into the diagenetic and metallogenic information from these geochemical signatures. Key findings include: (1) The SiO2 content, rare earth element (REE) contents, and REE partition coefficients of apatite indicate that the dark diorite porphyry possibly does not share a cogenetic magma source with the other four types of porphyries; (2) the volatile F and Cl contents in apatite, along with their ratio, indicate the Jiama deposit, formed in a collisional setting, demonstrates lower Cl/F ratios in apatite than the same type of deposits formed in a subduction environment; (3) compared to non‐ore‐bearing rock bodies in other deposits formed in a collisional setting, apatite in the Jiama deposit exhibits lower Ce and Ga contents. This might indicate that rock bodies in the Jiama deposit have higher oxygen fugacity. Nevertheless, the marginal variation in oxygen fugacity between ore‐bearing and non‐ore‐bearing rock bodies within the deposit suggests oxygen fugacity may not serve as the decisive factor in the ore‐hosting potential of rock bodies in the Jiama deposit. [ABSTRACT FROM AUTHOR]

Shoshonitic rocks are widely distributed in post-collisional settings and provide key information on deep geodynamic mechanisms and magmatic evolution. In this paper, we present petrographic, zircon U-Pb age-related, trace elemental, Hf isotopic, bulk-rock elemental, and Sr-Nd isotopic data of the Dalongtan shoshonitic syenite porphyries (DSSPs) in central Yunnan, southeastern Tibet. The DSSPs formed at 33.2 ± 0.3 Ma in a post-collisional setting. They define linear trends on Harker diagrams, and they display similar trace element patterns and enriched bulk-rock Sr-Nd isotopes [(87Sr/86Sr)i = 0.70964–0.70968, εNd(t) = −12.9 to −12.7] and zircon Hf isotopes (εHf(t) = −15.7 to −13.1) to the coeval mantle-derived potassic mafic rocks. This suggests that the DSSPs were fractionated from the lithospheric mantle-derived mafic magmas. The DSSPs, along with the coeval felsic and mafic magmatic rocks (37.2–32.3 Ma), exhibit a planar distribution on the SE Tibet and predate the left-lateral shearing of the Ailaoshan–Red River shear zone (ARSZ) (32–22 Ma), suggesting that there are no genetic relationships between them. The DSSPs have geochemical characteristics similar to those of A-type granites, with high total alkalinity (10.39–11.17 wt.%), HFSE concentrations (Zr + Nb + Ce + Y = 890.2–1054.3 ppm), Ga/Al ratios (10,000 × Ga/Al = 2.95–3.46), whole-rock zircon saturation temperatures (906–947 °C), and oxygen fugacity (ΔFMQ = +3.30–+4.65), indicating that they are products of the high-temperature melting of the lithosphere as a result of asthenosphere upwelling in extensional settings. Based on our data and regional observations, it is proposed that the generation of the DSSPs may be linked to the convective thinning of the thickened lithospheric mantle following the India–Asia collision. [ABSTRACT FROM AUTHOR]

The large magma reservoirs underlying world-class porphyry deposits are one of the key factors in their formation, which thus led to the present study focusing on the unmineralized intrusive rocks underlying the porphyry molybdenum-copper orebody of the post-collisional Jiama porphyry-skarn copper-polymetallic deposit in southern Tibet. The Jiama porphyry intrusion comprises intermediate-silica quartz diorite, monzogranite, and granodiorite porphyries, as well a high-silica granite porphyry. The intrusive rocks suite exhibits similar whole-rock Sr-Nd isotopic compositions [εNd(t) = -3.9 to -0.8], suggesting a common, non-radiogenic magma source. Yet, these rocks have distinct geochemical characteristics. The intermediate-silica rocks are relatively enriched in Ba and Sr with minor Eu anomalies, and show adakite-like geochemical characteristics. In contrast, the high-silica granite porphyry is strongly depleted in Ba, Sr, and Eu, and lacks adakite-like geochemical characteristics. We propose that the high-silica granite porphyry represents highly fractionated melt extracted from a silicic mush reservoir (crystallinity of ∼40%-65%), and that the monzogranite and granodiorite porphyries constitute the complementary residual silicic cumulates. High crystallinity facilitates the formation of connected fluid pathways, allowing the efficient removal of volatiles from the remaining silicic melt and a rapid flux of the ore-forming fluids toward the apical parts of the large magma reservoir. Less-evolved mafic melt is believed to have repeatedly intruded the base of the magma reservoir, thereby releasing volatiles and water into the silicic mush systems. The volatiles migrated upward through the fluid channels and accumulated in the apical part of the magma reservoir, subsequently, as a result of the overpressure in the roof zone, ore-forming fluids and successive batches of magma were expelled together, thereby forming the Jiama porphyry-skarn deposit. [ABSTRACT FROM AUTHOR]

The Eocene Yulong porphyry copper belt (YPCB) in eastern Tibet contains more than 10 Mt of Cu metal, associated with subvolcanic to volcanic porphyry systems intruding Cenozoic sedimentary basins. Geochemical data analysis shows that all samples belonged to high-K calc-alkaline and shoshonite series with metaluminous–peraluminous characteristics, light rare earth elements and large ion lithophile elements enrichment, high field strength elements depletion, and share geochemical similarities to adakitic rocks. We have established a spatiotemporal evolution framework through geochronological data analysis, combined with calculated bulk zirconium saturation temperature, calculated crustal thickness and geophysical evidence. We identified three magmatic processes triggered by asthenospheric upwelling and thermal erosion of thickened crust: (1) ultrapotassic magma derived from metasomatized mantle; (2) coeval ultrapotassic melt that promoted the partial melting of eroded lower crust and the generation of high-K adakitic felsic melt; high-K and Mg# adakitic fertile magma was formed by interaction between the eroded sulfide-rich juvenile lower crust-derived melt and mantle peridotite; (3) high-K adakitic fertile magma was derived from sulfide-rich juvenile lower crust, triggered by injecting hydrous ultrapotassic magma into thinned lower crust. The difference between deposit size in the north/south section of Yulong belt may be caused by the temperature of magmatic source and the volume of coeval potassic–ultrapotassic magmatism. Our analysis of the YPCB suggests that magmatism after 175 Ma within Intermontane arc complex of the Canadian Cordillera has high potential for porphyry deposits. [ABSTRACT FROM AUTHOR]

Most large-scale porphyry-style mineralization is genetically associated with oxidized, sulfur-rich, and hydrous magmas, the sources of which were enriched in mantlederived or juvenile crust--derived materials. Geochemical indices for these features can distinguish fertile magmas and barren magmas. However, fertile magmas that generate different-sized porphyry deposits are usually geochemically indistinguishable, and the factors controlling the size of porphyry mineralization are poorly understood. Here, we used zircon H2O contents and the compositions of apatite hosted in zircon, phenocrysts, and groundmass to compare the water contents and volatile evolution of fertile magmas in the Yulong ore belt, Tibet, which generated giant-, large-, and medium-sized porphyry deposits. We found that these porphyries have comparable major- and trace-element and zircon Hf-O isotope compositions, with high oxygen fugacity and sulfur contents. A negative correlation between XClAp/XOHAp versus XFAp/XClAp of apatites suggests that the magmas consistently achieved H2O saturation before zircon crystallization, and zircon hydroxyl contents reveal that the water contents of the melt positively correlate with the size of the deposits, consistent with larger deposits achieving H2O saturation at deeper crustal levels. The deeper H2O saturation also caused larger amounts of Cl extraction, as indicated by the trends of increasing XFAp/XClAp and decreasing XClAp/XOHAp with larger deposit sizes. These data sets can be reconciled by magmas forming larger deposits having higher H2O contents and suggest that the H2O content is a key control on their fertility. Our study highlights the utility of integrated hydrous and nominally anhydrous mineral analyses for constraining enigmatic magmatic volatile processes in magmatic ore-forming systems. [ABSTRACT FROM AUTHOR]

The genetic link between subduction- and collision-related porphyry Cu deposits (PCD) is still not well understood. The Gangdese porphyry Cu belt (GPCB) in southern Tibet hosts two parallel E–W-oriented metallogenic subbelts, including a southern Jurassic subduction-related and a northern Miocene post-collision PCD subbelt. In this study, we combine new and published whole-rock major and trace element data, Cu isotopic compositions and zircon trace element data of Jurassic magmatic rocks from the GPCB. Combined Sr/Y and La/Yb crustal thickness proxies confirm the south to north geometry of the Jurassic arc-back-arc system across the GPCB. The southern Jurassic magmatic arc rocks have systematically higher whole-rock V/Yb ratios, δ65Cu values and zircon Eu/Eu* ratios compared to those of the northern back-arc region. This suggests that Jurassic southern arc magmas had higher oxygen fugacity and H2O concentration than the contemporaneous northern back-arc magmas, which was controlled by a steep subduction geometry of the Neo-Tethyan oceanic slab. Hydrous and oxidized magmas resulted in Cu enrichment during magma evolution and generation of Jurassic PCD in the southern magmatic arc by inhibiting early sulfide saturation at deep crustal levels. In contrast, the northern back-arc magmas were less oxidized and less hydrous, which triggered early sulfide saturation, resulting in segregation of Cu-bearing sulfides in lower crustal cumulates that provided a favorable metal source for later Miocene PCD in the northern subbelt. Our study indicates that the Jurassic subduction geometry controlled the formation and distribution of Jurassic subduction-related and Miocene post-collision-related PCD in the GPCB. [ABSTRACT FROM AUTHOR]

Highly fractionated granites are widely distributed in the crust and provide unique windows into magmatic evolution. This study reports petrography, zircon U–Pb ages, trace elemental, and Hf isotopic, as well as whole-rock elemental and Nd isotopic data of highly fractionated granite porphyries from the Shiguanshan area in western Yunnan, southeastern Tibet. The granite porphyries were formed at 34.0 ± 0.3 Ma in a post-collisional setting. They are strongly peraluminous (A/CNK = 1.95–2.80), have high SiO2 content (SiO2 = 78.16–79.13 wt.%) and zircon saturation temperatures (803–829 °C, average 819 °C), and low MgO, with pronounced enrichment in Pb, U, Th, and Rb, and depletion in Ti, Eu, P, Sr, and Ba, and belong to highly fractionated A-type granites. These rocks define linear trends on Harker diagrams and display similar enriched whole-rock Nd isotopic (εNd(t) = −12.8 to −12.3) and zircon Hf isotopic (εHf(t) = −10.4 to −8.8) compositions compared to the published data of coeval mantle-derived syenite porphyries, which can be attributed to fractional crystallization processes. A quantitative model suggests that the Shiguanshan granite porphyries likely formed through the fractionation process of a mineral assemblage consisting of plagioclase, K-feldspar, biotite, and amphibole (in a ratio of 40:30:25:5), with fractionation degrees of 50%–55%. The magmatic textures and zircons, decoupling between the REE tetrad effect and fractionation of twin-elements, along with the modeling result of Rayleigh fractionation, suggest that the REE tetrad effect in the Shiguanshan granite porphyries may be caused by fractionation of accessory minerals. Our data, along with regional observations, propose that the generation of these granite porphyries is possibly related to lithospheric removal following the Indo–Asia collision. [ABSTRACT FROM AUTHOR]

The Bangongco–Nujiang metallogenic belt of Tibet is a main suture zone in the Qinghai–Tibet Plateau, which is known as an important porphyry–epithermal–skarn Cu-polymetallic mineralization zone in China. The western part of the Bangongco–Nujiang metallogenic belt exposes several medium high-silica terrestrial alkaline volcanic rocks with strong alteration influenced by collision orogeny. Some research has shown that clues to mineralization such as malachite and gossan are found on the surface. However, volcanic rock areas with varied topography place a huge burden on geological investigation, and the existing research on predicting mineralization is relatively scarce. This paper describes the extraction of alteration mineral information based on medium spatial resolution and hyperspectral resolution images, establishing a spectral library of alteration minerals in this area. By analyzing radar data, digital elevation, and synthesis results of different spectral bands, we combine remote sensing with geographic information technology to establish crater markers. The extraction results from multisource and chemical exploration data are superimposed onto the analysis of mineralization characteristics and geological conditions so as to establish the mineralization signatures for terrestrial volcanic rock areas. Eighteen mineralization prospect areas were identified, which can provide technical support for future mineralization research in this belt. [ABSTRACT FROM AUTHOR]

Jiama is a giant, high‐grade porphyry copper system in the Gangdese metallogenic belt, Tibet. Multistage intermediate–felsic porphyries intruded in this deposit, some of which are strongly associated with copper‐polymetallic mineralization. These ore‐bearing porphyries include monzogranite, granodiorite, and quartz diorite porphyries. A new granite aplite dyke was found in the south of Jiama. Its age, genesis, and relationship with ore‐related magmatism are obscure. Here, its emplacement age and petrogenesis were determined using mineralogy, zircon U‐Pb dating, geochemistry, and Sr‐Nd‐Pb isotope studies. The zircon LA‐ICP‐MS U‐Pb age of the aplite dyke is 16.66 ± 0.21 Ma (n = 14, MSWD = 0.66), earlier than that of the ore‐bearing porphyries (∼15 Ma) in Jiama. Furthermore, the aplite exhibits high amounts of silicon (SiO2 = 73.39%–74.74%), potassium (K2O = 5.12%–6.61%), aluminum (Al2O3 = 14.25%–14.69%), and light/heavy rare earth elements (LREE/HREE = 12.12–16.19) as well as negative europium (δEu = 0.47–0.72) and weak negative cerium anomalies (δCe = 0.84–0.93). The aplite dyke is characteristic of metaluminous–peraluminous I‐type granite, which is rich in large‐ion lithophile elements (Rb, Ba, Th and U) and depleted in high‐field‐strength elements (Nb, P and Ti). The aplite dyke and ore‐bearing porphyries in the Jiama deposit are the results of a partial melting of the juvenile lower crust, according to whole‐rock geochemistry and Sr‐Nd‐Pb isotope data, but the dyke and ore‐bearing porphyries were emplaced from the same magma chamber at different times. Thus, the aplite dyke shows the composition of the early evolution stage of shallow magma in the Jiama deposit and is the product of rapid condensation and crystallization. [ABSTRACT FROM AUTHOR]

The statistical modeling with ILR-RPCA-back CLR has two problems when dealing with the closure effect of geochemical data. Firstly, after performing isometric logratio (ilr) transformation, robust principal component analysis (RPCA) is employed for processing. The double-plot diagram illustrates that the element sequence transformation occurs in the first and second principal components, while the unique principal component remains unattainable. Secondly, by transforming both the score and load into the centered logratio (CLR) space using the U matrix, it is possible to obtain a score result that corresponds to the original order of elements according to the CLR = ILR·U formula. However, for obtaining a load result that corresponds to the original order of elements, an alternative formula "CLR = UT·ILR" must be used instead. In order to determine the optimal element assemblage for porphyry copper deposits, this study conducted statistical analysis on mineral assemblages from discovered deposits in the Gangdese metallogenic belt and identified Cu, Mo, Au, Ag, W, and Bi as key elements associated with porphyry copper deposits. Subsequently, by analyzing the singularities of the composite elements, the spatial overlay of the combined element is carried out, and concentration-area (C-A) fractal filtering is applied to identify the anomaly and background areas. To facilitate comparison, we conducted an analysis of various mineral and ore deposit types, revealing the following findings: (1) Combination elements exhibit superior recognition capability than single elements in porphyry copper deposits; (2) Skarn-type copper deposits unrelated to porphyry show a high degree of dissimilarity compared to those related to porphyry; (3) this method offers advantages over the single element method in evaluating porphyry gold deposits by reducing anomaly levels and initial investment during the evaluation stage for porphyry copper anomalies; (4) However, this method has limited ability in distinguishing between porphyry copper and molybdenum deposits. [ABSTRACT FROM AUTHOR]

The Xiongcun Cu–Au ore district is in the southern middle Gangdese Metallogenic Belt, Tibet, and formed during Neo-Tethyan oceanic subduction. The Xiongcun ore district mainly comprises two deposits, the No. I and No. II deposits, which were formed by two individual mineralization events according to deposit geology and Re–Os isotopic dating of molybdenite. The No. I deposit is similar to a reduced porphyry copper–gold deposit, given the widespread occurrence of primary and/or hydrothermal pyrrhotite and common CH4-rich and rare N2-rich fluid inclusions. The No. II deposit, similar to classic oxidized porphyry copper–gold deposits, contains highly oxidized minerals, including magnetite, anhydrite, and hematite. The halogen chemistry of the ore-forming fluid from the No. I and No. II deposits is still unclear. Biotite geochemistry with halogen contents was used to investigate the differences in ore-forming fluid between the No. I and No. II deposits. Hydrothermal biotite from the No. I deposit, usually intergrown with sphalerite, is Mg-rich and classified as phlogopite and Mg-biotite, and hydrothermal biotite from the No. II deposit is classified as Mg-biotite. Hydrothermal biotite from the No. I deposit has significantly higher SiO2, MnO, MgO, F, Li, Sc, Zn, Rb, Tl, and Pb contents and lower Al2O3, FeOtot, Cl, Ba, Cr, V, Co, Ni, Y, Sr, Zr, Th, and Cu contents than the biotite from the No. II deposit. Hydrothermal biotites from the No. I and No. II deposits yield temperatures ranging from 230 °C to 593 °C and 212 °C to 306 °C, respectively. The calculated oxygen fugacity and fugacity ratios indicate that the hydrothermal fluid of the No. I deposit has a higher F content, oxygen fugacity, and log(fHF/fHCl) value and a lower log(fH2O/fHF) value than the hydrothermal fluid from the No. II deposit. The biotite geochemistry shows that the No. I and No. II deposits formed from different hydrothermal fluids. The hydrothermal fluid of the No. I deposit was mixed with meteoric waters containing organic matter, resulting in a decrease in oxygen fugacity and more efficient precipitation of gold. The No. I and No. II deposits were formed by a Cl-rich hydrothermal system conducive to transporting Cu and Au. The decreasing Cl, oxygen fugacity, and temperature may be the key factors in Cu and Au precipitation. Biotite geochemistry allows a more detailed evaluation of the halogen chemistry of hydrothermal fluids and their evolution within porphyry Cu systems. [ABSTRACT FROM AUTHOR]

Hydrothermal rutile (TiO2) is a widely distributed accessory mineral in hydrothermal veins or alteration assemblages of porphyry deposits and provides important information for further understanding hydrothermal fluid signatures. This study determines the geochemical composition and U-Pb dates of hydrothermal rutile from the Yulong porphyry Cu-Mo deposit in east Tibet, China. Three types of TiO2 polymorphs have been identified based on their Raman spectroscopic, textural, and chemical characteristics. (1) Brookite and anatase pseudomorphs after titanite in a fine-grained matrix, indicating low-temperature hydrothermal fluids destabilizing primary Ti-bearing minerals during argillic alteration (type-I). (2) Elongated and prismatic rutile present in hydrothermal veins or in clusters in accompanying alteration envelope characterized by weak zoning (type-II). And (3) rutile intergrown with sulfides in hydrothermal veins, characterized by well-developed patchy and sector zoning (type-III). In contrast to the type-I and type-II TiO2 polymorphs, tungsten is enriched in backscattered bright patches and sector zones in type-III rutile, which is due to the substitution of W6+ in the Ti4+ octahedral site. The mechanism of the enrichment of tungsten is efectively driven by the halogen-rich (F, Cl) aqueous fluids during hydrothermal mineralization. In situ U-Pb dating of the type-III rutile yields a lower intercept age of 41.8 ± 1.2 Ma, which brackets the timing of the Cu-Mo mineralization. The relationship between rutile textures and composition indicates that W-bearing rutile can serve as a recorder of hydrothermal processes in porphyry Cu deposits. [ABSTRACT FROM AUTHOR]

The Bangbule skarn lead‐zinc (Pb‐Zn) deposit (>1 Mt Zn + Pb) is located in the western Nyainqentanglha polymetallic metallogenetic belt, central Tibet. Lenticular orebodies are all hosted in skarn and developed in the contact zone between the quartz porphyry and carbonate strata of the mid Paleozoic Middle to Upper Chaguoluoma Formation as well as in carbonate and sandstone beds of the Upper Paleozoic Laga Formation. As a newly discovered skarn deposit, the geological background and metallogenesis of this deposit remain poorly understood. Detailed petrological, geochemical and geochronological data of the ore‐related quartz porphyry, helps constrain the mineralization age and contributes to discussion on the ore genesis of the Bangbule deposit. Both endoskarn and exoskarn are identified in the Bangbule deposit. From quartz porphyry to carbonate formation, the exoskarn is zoned from proximal garnet skarn to distal pyroxene skarn. Zircon U‐Pb dating results show that the quartz porphyry formed at 73.9 ± 0.8 Ma. Geochemical analysis results show that the quartz porphyry has high contents of SiO2 (71.40–74.94 wt%) and K2O + Na2O (3.76–8.46 wt%) with A/CNK values of 0.69 to 1.06. Besides, the quartz porphyry is enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) and have low εNd(t) (from –8.25 to –8.19) and high initial (87Sr/86Sr)i values (0.713611–0.714478). Major, trace elements and whole‐rock F concentration analysis results from the endoskarn samples show higher TFe2O3, MgO, CaO, Pb + Zn, W, Sn, Mo and F etc., and lower alkalis (K2O, Na2O, Sr and Ba) than those of fresh quartz porphyry, indicating that the early ore‐forming fluids were an Ca‐Fe‐F‐enriched fluid. Massive ore in the proximal skarn might be related to the high F content in the magma, which lowered the solidus temperature of the quartz porphyry magma and caused a lower temperature of the ore‐forming fluids, as well as facilitating the precipitation of sphalerite and galena. Based on the geochemical characteristics presented in this study, we propose that the ore‐related quartz porphyry was formed by partial melting of crust materials with some juvenile crustal component input. The partial melting of the middle‐upper crust after the initial enrichment of lead and zinc elements are important for the formation of Pb‐Zn deposits. The case study of the Bangbule deposit has proven that there is still a crust‐derived magmatic source region in the western segment of the central Lhasa terrane. Therefore, there is still great potential for Pb‐Zn mineralization and Pb‐Zn exploration. [ABSTRACT FROM AUTHOR]

The Qulong porphyry copper deposit in Tibet is located in the Tethis–Himalaya metallogenic domain, one of the three major porphyry metallogenic domains in the world. At present, the mining area is mainly used for surface mining. The depth revealed by the drilling project is less than 2 km. The potential for deep resources is unknown. Based on an analysis of the geochemical characteristics of the primary halos around the No. 16 prospecting line, deep extension is discussed in this paper. Studies show that the metallogenic elements are Cu and Mo; the near-ore halo elements are Co, Au, Ag, and W; the supra-ore halo elements are Pb, Zn, Mn, and As; and the sub-ore halo elements are Sn and Bi. According to Gregorian's zoning index and the barycenter method, the primary halo zoning of the No. 16 exploration line from shallow to deep is Mn–P–Pb–Ni–Zn–V–As–Hg–Co–Au–Cu–W–Ag–Mo–Sb–Sr–Cd–Sn–Ti–Bi. This sequence has a distinct "reverse" zoning feature, indicating that there may be a blind ore body deep in the mine. The geochemical parameter evaluation index based on the element content contrast coefficient suggests that there may be a hidden ore body in the deep. The relative hydrothermal mineralization in the center position of the section may be located deep below the north side of borehole ZK1601-1 in the middle of the section. The ore body erosion parameter model shows that the bottom of the drilling engineering control is the middle tail of the ore body, and there is a certain amount of extension in the deep part. The ideal superimposed model of the primary halo reflects the ore body trend of the 16th line section. The ore body is inclined to the north as a whole; the ore fluid flows from the deep to the southern side of the north side, and the deep part of the northern side of the ore body has a downward trend. [ABSTRACT FROM AUTHOR]

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Several large-scale porphyry copper deposits (PCDs) with high economic value have been excavated in the Duolong ore district, Tibet, China. However, the high altitudes and harsh conditions in this area make traditional exploration difficult. Hydrothermal alteration minerals related to PCDs with diagnostic spectral absorption features in the visible–near-infrared–shortwave-infrared ranges can be effectively identified by remote sensing imagery. Mainly based on hyperspectral imagery supplemented by multispectral imagery and geochemical element data, the Duolong ore district was selected to conduct data-driven PCD prospectivity modelling. A total of 11 known deposits and 17 evidential layers of multisource geoscience information related to Cu mineralization constitute the input datasets of the predictive models. A deep learning convolutional neural network (CNN) model was applied to mineral prospectivity mapping, and its applicability was tested by comparison to conventional machine learning models, such as support vector machine and random forest. CNN achieves the greatest classification performance with an accuracy of 0.956. This is the first trial in Duolong to conduct mineral prospectivity mapping combined with remote imagery and geochemistry based on deep learning methods. Four metallogenic prospective sites were delineated and verified through field reconnaissance, indicating that the application of deep learning-based methods in PCD prospecting proposed in this paper is feasible by utilizing geoscience big data such as remote sensing datasets and geochemical elements. [ABSTRACT FROM AUTHOR]

The Naruo porphyry copper deposit containing more than 2 Mt of copper is located in the Duolong ore district in the west of the Bangongco–Nujiang belt in central Tibet. New zircon U‐Pb, biotite 40Ar/39Ar, zircon (U‐Th)/He ages, published age data together with thermal modeling were presented in this paper to investigate the thermal history of Naruo deposit. Thermal modeling reveals a prolonged magmatic‐hydrothermal evolution firstly cooling from ∼700°C to ∼350°C at 120 Ma, then cooling to 230°C at 106 Ma and maintaining at 200°C from 106 to 90 Ma which is attributed to multiple magmatic events and thermal effect of strike‐slip fault. Affected by thrust nappe structure, the sample was consistent with 120°C from 70 to 63 Ma. The Naruo deposit started to experience exhumation at a rate of ∼0.07 km/Myr since 60 Ma which is related to India‐Asia collision. The prolonged magmatic‐hydrothermal evolution process might have important influence on the Naruo deposit. The ore‐related intrusions preserved in the foot walls of strike‐slip fault and thrust nappe structure are the objects of future exploration in the Duolong ore district. [ABSTRACT FROM AUTHOR]

The chemical compositions of zircons have been used as magma fertility indicators for porphyry copper mineralization potential. Here, we trained and tested two machine learning (ML) models: support vector machines and random forest to classify the metallogenic fertility (fertile vs. unfertile) based on igneous zircon chemistry. Both models achieved good classification accuracy (~ 93%) against the testing dataset, suggesting the feasibility and effectiveness of using the ML methods to discriminate whether zircons are from fertile or unfertile magmas. The feature importance analysis of the RF classifiers identified that the most important parameters of fertile magma are Eu, Ce, and Dy, further validating previous studies of the genesis of porphyry copper deposit-related magma. As a case study, we predicted the metallogenic fertility of the detrital zircons in the eastern Gangdese belt in southern Tibet by applying the ML models trained by igneous zircon labeled data. Our ML models suggest that the magmas that formed after 50 Ma, especially from 30 to 10 Ma, have higher fertile percentages. Taking this together with the local singularity analysis of detrital zircon U–Pb ages, we suggest that magmatic flare-ups with high FP and singularity index values are more favorable for porphyry copper formation. Our ML models and defined FP may help reveal temporal variation of the favorability for porphyry copper formation. [ABSTRACT FROM AUTHOR]

Demingding is a promising porphyry Mo-dominated deposit recently discovered in the eastern Gangdese metallogenic belt in Tibet, China. We present zircon U-Pb-Lu-Hf isotopic studies, as well as geochemical data of the late monzogranites and the prior rhyolites from the Demingding porphyry deposit to uncover their origin and geodynamic mechanism. Zircon U–Pb dating yielded precise crystallization ages of 17.3 ± 0.6 Ma (MSWD = 2.5) and 186.5 ± 3.0 Ma (MSWD = 2.0) for monzogranite and rhyolite, respectively. The monzogranite is characterized by high-K calc-alkaline, adakitic affinities, and positive zircon εHf(t) values (+0.9∼+5.6, avg.+3.1) with TDM2 (0.73–1.04 Ga), while the rhyolite has εHf(t) values of (+2.1∼+7.3, avg.+5.2) and TDM2 of (0.76–1.09 Ga) similar to the monzogranite. Our results suggest that the Demingding porphyry Mo (Cu) deposit is related to magma generated from the Neo-Tethyan oceanic subduction. The subsequent monzogranite porphyry was likely formed by the remelting of previously subduction-modified arc lithosphere, triggered by continental collision crustal thickening in Miocene. The lower positive εHf(t) values of monzogranites suggest minor inputs from the Mo-rich ancient crust, suggesting that Mo favors the silicate melt. Such magmatic events and special metallogenesis typify intracontinental processes and porphyry copper deposits, which are normally confined to oceanic subduction and Cu-dominated style, thereby making the continental setting and Mo-dominated style of Demingding exceptional and possibly unique. [ABSTRACT FROM AUTHOR]

[Display omitted] • The Dongga Au deposit can be classified as subepithermal deposit. • Fluid mixing between magmatic water and meteoric water triggers gold precipitation. • The Dongga and No.2 deposits constitute a porphyry system, reflecting a continuous fluid evolution. The Dongga Au deposit (9.55 t Au; average grade = 6.9 g/t [up to 61.6 g/t]) is located in the Xiongcun giant porphyry Cu–Au district of the Gangdese porphyry Cu belt, Tibet. Its mineralization age, ore-forming processes, and relationship to adjacent porphyry mineralization remain unclear. To address this, we conducted a geological, pyrite Re–Os dating, He–Ar–H–O–S–Pb isotopic, and fluid inclusion study of the Dongga deposit. Pyrite samples from ore-bearing chlorite–sulfide veins yielded a weighted-mean Re–Os age of 178.4 ± 2.6 Ma (MSWD=0.01), implying the deposit formed during the Early Jurassic. Fluid inclusion analyses yielded homogenization temperatures of 237–360 °C for quartz–sulfide veins and 125–201 °C for late quartz veins, with corresponding salinities of 2.7–43.8 and 0.9–9.9 wt% NaCl eq , respectively. Fluid inclusion analyses of pyrite samples yielded 3He/4He and 40Ar/36Ar values of 0.50–1.08 Ra and 325.1–559.4, respectively, and δD and δ18O fluid values of –86.2 ‰ to –72.1 ‰ and –5.6 ‰ to 3.9 ‰, respectively. The He–Ar–H–O isotopic data suggest the mineralizing fluids were derived mainly from a crustal source with a small mantle contribution, and also contained a mixture of magmatic and meteoric waters. The S (δ34S = –1.57 ‰ to –0.55 ‰) and Pb (206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb are 18.17–18.41 ‰, 15.55–15.63 ‰ and 38.15–38.37 ‰, respectively) isotopic compositions of pyrite suggest the ore-forming metals were derived from a magma source in the mantle containing minor amounts of subducted sediment. Based on the geology, and isotopic and fluid inclusion data, we infer that mixing between magmatic and meteoric waters was the main trigger of Au precipitation. In addition, based on the geochronological, spatial, and genetic relationships with the adjacent No.2 deposit in the Xiongcun ore district, we propose that the Dongga Au deposit is a sub-epithermal deposit, which represents the transition between porphyry and epithermal deposits. The two deposits constitute a porphyry system and record the continuous evolution of hydrothermal fluids transported outwards in a porphyry system. [ABSTRACT FROM AUTHOR]

[Display omitted] • The monzogranite porphyry at Wubaduolai was derived from juvenile Tibetan lower crust, with contributions from Indian plateand metasomatized mantle. • The magma that formed monzogranite porphyry at Wubaduolai is oxidized and hydrous. • The monzogranite porphyry at Wubaduolai has lower potential for copper mineralization than rocks from Zhunuo and Beimulang deposits. The Wubaduolai deposit is a newly discovered porphyry copper deposit in the Zhunuo-Beimulang ore-concentrated area of the Gangdese belt. The monzogranite porphyry is the causative intrusion in the deposit with a zircon U-Pb age of ∼16 Ma. Monzogranites have high Sr (332–673 ppm) and Sr/Y ratios (35–69), typical of adakite affinity. They have initial 87Sr/86Sr ratios of 0.7083–0.7093 and ε Nd (t) values between −9.2 and −7.1. The zircon ε Hf (t) values range from −6.45 to −2.09 and zircon δ 18O values have a narrow range of 7.4 to 8.1 ‰ for the porphyry. These geochemical characteristics indicate that the parental magma was derived from juvenile Tibetan lower crust, with contributions from Indian plate-released fluids and metasomatized mantle-derived mafic magmas. The porphyry shows high values of log w(Fe 2 O 3 /FeO) (>0) and V/Sc (mostly > 12) in whole rock and high values of △FMQ (4.13–5.79), 10000 × (δ Eu)/Y(>4), and low Dy/Yb (<0.3) in zircons, suggesting that the magma was oxidized and hydrous. The oxidized and hydrous parental magma is consistent with those evaluated for the Zhunuo and Beimulang deposits. The three-component mixing model result shows that compared with the ore-related porphyries in the Zhunuo and Beimulang deposits, the Wubaduolai intrusion has higher proportion of Indian plate-released fluids and mafic magmas and lower proportion of juvenile Tibetan lower crust. Therefore, we suggest that although the causative intrusions have similar oxygen fugacity and water content, the source has more Indian continental crust and mantle-derived materials and fewer juvenile Tibetan lower crust materials at Wubaduolai, implying that the Wubaduolai monzogranite porphyry has lower potential for mineralization. [ABSTRACT FROM AUTHOR]

To investigate the behavior of Li isotopes during magmatic differentiation and the petrogenesis of Cu-bearing ore deposits, a suite of post-collisional adakitic rocks from Qulong region, southern Tibet, was studied. Their lithologies range from diorite through granodiorite to granite porphyry with the latter containing giant Cu deposits. Detailed evidence of field observation and geochemical signature suggest that these three sets of rocks were most likely formed by various degrees of partial melting and fractional crystallization from the same source. The dioritic enclave, granodiorite and granite porphyry have δ7Li values ranging from 0.2 to 8.2‰, 3.1 to 6.8‰, and 3.9 to 7.4‰, respectively. Most of these samples are overlapping in Li isotope composition, comparable to other granitoids worldwide, indicating insignificant Li isotope fractionation during partial melting and magma differentiation in adakite-like rocks. By contrast, their Li concentrations are mainly controlled by fractional crystallization as suggested from different modal mineralogy. This process does not lead to further enrichment of Cu although they have initial high concentrations (an average of ∼ 104 ppm). In comparison, granite porphyry has extremely high Cu contents (up to 2000 ppm) and their δ7Li values are positively correlated with Cu content, suggesting the involvement of magmatic fluids that most likely exsolved from deep magma chamber. Such fluids not only modified the Li isotopic compositions of granite porphyries, but also extracted metal elements from the highly evolved magma, eventually resulting in the Cu mineralization. Our work here provides new insight into the formation and evolution of the porphyry Cu-bearing deposit. [ABSTRACT FROM AUTHOR]

The Mamupu skarn‐type Cu‐Au polymetallic deposit represents the first discovery of a medium deposit in the southern Yulong porphyry copper belt (YPCB), eastern Tibet. The Cu‐Au mineralization mainly occurs as chalcopyrite in breccia, within the plate‐like carbonate interlayer, being closely related to chloritization (e.g., chlorite, magnetite and epidote) and skarnization (e.g., diopside, tremolite and garnet). The ore‐related quartz syenite porphyry (QSP) and granodiorite porphyry (GP) were emplaced at 40.1 ± 0.2 Ma and 39.9 ± 0.3 Ma, respectively. The QSP of Mamupu is an alkaline‐rich intrusion, relatively enriched in LREE, LILE, depleted in HFSE, with no significant negative Eu and Ce anomalies, slightly high (87Sr/86Sr)i, low ∊Nd(t), uniform (206Pb/204Pb)i and ∊Hf(t) values, which indicates that the porphyry magma may be caused by both the mixing of metasomatized EM II enriched mantle and thickened juvenile lower crust. The QSP in the Mamupu deposit shares a similar genesis of petrology to other ore‐related porphyries within the YPCB. High oxygen fugacity and water content of the magmas are essential for the formation of porphyry and skarn Cu deposits. The QSP has similar high magmatic oxidation states and water content to the Yulong deposit, which indicates that the Mamupu has a high prospecting potential. Differences in the geological characteristics and scale of mineralization between the Mamupu and other YPCB deposits may be due to the different emplacement depths of ore‐related intrusions, as well as differences in the surrounding rocks. [ABSTRACT FROM AUTHOR]

Porphyry Cu-Mo deposits are magmatic-hydrothermal deposits in which sulfide and oxide minerals precipitate from aqueous solutions. However, many questions remain about the composition and evolution of the magmatic-hydrothermal fluids responsible for mineralization. In response to this knowledge gap at the Qulong porphyry Cu-Mo deposit, Tibet, we present a comprehensive major and trace element dataset for biotite (including halogens) from Qulong to elucidate magmatic-hydrothermal fluid compositions and fluid evolution. Based on genesis and occurrence, biotite is divided into primary (igneous), re-equilibrated (igneous modified by hydrothermal fluids), and secondary (hydrothermal) types. All studied biotite grains are Mg-rich, and XMg values (0.59–0.90) increased during fluid evolution, perhaps controlled by high oxygen fugacity (fO2) and sulfur fugacity (fS2) in the magmatic-hydrothermal fluids. The IV(F) and IV(Cl) values and halogen fugacity of biotite indicate that Cl-rich fluids were dominant during early magmatic-hydrothermal evolution, while later fluids were enriched in F. This is consistent with early Cu and late Mo enrichment in the Qulong deposit. We propose a fluid evolution model based on in situ major and trace element data and cross-cutting relationships between the intrusions and the veins. Iron, Ti, Co, Ni, Zn, and Cl contents decreased, while Mg, Si, Al, Sn, Ge, and F contents increased during the evolution of the magmatic-hydrothermal fluid. Importantly, the increase in Fe, Ti, Co, Zn, and Cl and decrease in Mg, Ge, and F contents in hydrothermal biotite as the core of the deposit is approached (extending to ~ 2.5 km depth) may prove to be an important indicator of high-grade mineralized zones. Finally, this study shows that systematic spatial variations in hydrothermal biotite chemistry can potentially be used as a prospecting tool for porphyry deposits worldwide. [ABSTRACT FROM AUTHOR]

Whether there is a relationship between widespread Cenozoic igneous rocks and the activated Ailao Shan–Red River shear zone (ASRR) in western Yunnan, SE Tibet, remains highly controversial. New geochronological, and geochemical data derived from Cenozoic igneous rocks both within and far from the ASRR offers answers. Although these coeval felsic rocks (36.9–33.5 Ma) are enriched in large‐ion lithophile elements relative to high field strength elements, they also display some special geochemical features, such as high Y and Yb values of syenitic porphyries, which contrast with the high Sr and low Y contents of monzoporphyries and granitic porphyries. The syenitic porphyries exhibit geochemical characteristics similar to those of coeval mafic magmas, e.g., high K2O, Y, and Yb contents, indicating that the former were probably generated by fractional crystallization of the latter. However, the high Sr/Y (56.1–109) monzoporphyries and granitic porphyries, combined with their low MgO, and Cr (or Ni) contents, suggest that they were mainly derived from partial melting of a thickened mafic lower crust. Given that these Cenozoic magmatic events exhibiting planar distributions occurred outside of the activation of the ASRR (31–20 Ma), then they were not controlled by the latter. Instead, they were tied to convective removal of a thickened lower lithospheric mantle in western Yunnan during the Paleogene. [ABSTRACT FROM AUTHOR]

The Tiegelongnan porphyry-epithermal deposit (2089 Mt @ 0.53% Cu, 0.08 g/t Au) is host to a large variety of Cu-sulfide minerals, mainly chalcopyrite, bornite, covellite, digenite, enargite, and tennantite. We used LA-ICP-MS to investigate the trace element geochemistry of the Tiegelongnan Cu-sulfides, as well as pyrite, to understand the correlation between sulfides and trace elements, gold in particular, in the porphyry and epithermal systems. Porphyry mineralization consists of stage 1 chalcopyrite-pyrite ± molybdenite, stage 2 chalcopyrite-bornite, and stage 3 covellite. Epithermal sulfides form stage 4 pyrite-alunite, stage 5 digenite-bornite-chalcopyrite, and stage 6 enargite-tennantite ± tetrahedrite. Stage 2 chalcopyrite (S2 Ccp, median = 9.7 ppm Au) is the primary porphyry Au host, and stage 6 tennantite in alunite veins (S6 Tnt-s, median = 98.0 ppm Au) is the major epithermal Au host. These Au-rich sulfides formed under higher oxidation conditions, suggesting that a high oxidation state favors the incorporation of Au in Cu-sulfides. Gold contents in coeval chalcopyrite and bornite are positively correlated to temperature, and Au is enriched in chalcopyrite over bornite at low temperatures (< 350 ℃). Positive correlations between Au and As and Te in covellite and chalcopyrite result from the reaction of As3+ + (Au+/Ag+) + Te2− ↔ 4Cu+ + S2−. Epithermal chalcopyrite and bornite contain more As and Pd than that in porphyry stages, and high contents of As, Sn, Cd, Zn, Sb, Te, Au, and Bi in epithermal enargite and tennantite are likely the result of partitioning of these elements in sulfides at low epithermal temperatures. Epithermal overprinting likely leached Cu from earlier porphyry stage sulfides to precipitate high Cu-grade epithermal mineralization. The Cu-sulfides and related trace elements show a spatial distribution, potentially useful for the exploration of overprinted porphyry-epithermal systems. [ABSTRACT FROM AUTHOR]

The Qulong deposit in Tibet is one of the largest porphyry copper‐molybdenum deposits in China. We used short‐wave infrared (SWIR) spectroscopy to examine the spectral characteristics of the extensively developed chlorite in this deposit. X‐ray diffraction and electron microprobe analyses were used for phase identification and to obtain the chemical composition, ion substitution relationships, and formation environment of the chlorite. SWIR spectral parameters were applied to detect the hydrothermal centers. The results indicate that the wavelength of the absorption feature for Qulong chlorite Fe‐OH (Pos2250) range from 2240 to 2268.4 nm; the chlorite substitution relationships are dominated by Mg‐Fe substitution at the octahedral sites together with AlIV‐Si substitution at the tetrahedral sites; the chlorite formation temperatures range within the medium‐low temperature hydrothermal alteration range from 164 to 281°C, with an average value of 264°C; the wavelength of the chlorite peak position for Fe‐OH (2250 nm) absorption and its chemical composition are positively correlated with AlVI, Fe + AlVI, Fe/(Fe + Mg), Fe, and Fe + AlIV but negatively correlated with Mg and Mg/(Fe + Mg); and the wavelength associated with the chlorite Fe‐OH (2250 nm) absorption feature is positively correlated with the temperature at which the chlorite formed. These correlations indicate that more Fe and AlVI ions and fewer Mg ions at the octahedral sites of chlorite lead to a longer the wavelength of the chlorite Fe‐OH (2250 nm) absorption feature and a higher chlorite formation temperature. The wavelength of the Qulong chlorite Fe‐OH (2250 nm) absorption feature (>2252 nm) can thus serve as an exploration indicator to guide the detection of hydrothermal centers in porphyry copper deposits. The results of the study indicate that the mineralogical and SWIR spectral characteristics of chlorite are significant indicators for locating hydrothermal centers within porphyry deposits. [ABSTRACT FROM AUTHOR]

• Identification of the Suolong Cu-rich porphyry is suggestive of a new mineralization event. • The porphyry was generated from crust-mantle interactions during the roll-back of subducted NTO. • The features of magma promoted the enrichment of Cu, but thinned crust limited the scale of deposit. The Tibetan Plateau hosts the majority of porphyry Cu deposits in China. There are two large metallogenic belts, the Gangdese and Bangong-Nujiang belts, in the Lhasa Terrane, Central Tibet. The Lhasa Terrane experienced multistage magmatic activity from the Mesozoic to Cenozoic, and the subaerial volcanic areas of the western part of the terrane are regarded as favorable targets of porphyry Cu deposits. In this paper, we describe the geology of our newly identified Early Cretaceous Suolong Cu-rich porphyry in the western Lhasa Terrane and present new U–Pb ages, trace element and Hf isotopic compositions of zircon and whole-rock elemental and Sr–Nd isotopic compositions. The Suolong porphyry contains zircon grains with ages ranging from 136 to 135 Ma, ε Hf (t) values ranging from −1.5 ∼ +2.7 and log f O 2 values ranging from −16.27 ∼ −9.92. Geochemically, the porphyry rocks are peraluminous in nature, with whole-rock ε Nd (t) values of −5.7 ∼ −5.4. We infer that the Suolong porphyry originated from a mixture of ∼53 % enriched lithospheric mantle and ∼47 % ancient lower crustal melt, triggered by the roll-back of the northward-subducting Neo-Tethyan Ocean. The conditions of high oxygen fugacity and water content and tectonic transition promoted the formation of the Suolong Cu-rich porphyry, but the condition of a thinned crust may have constrained the mineralization scale of the Cu deposits. This new identification of Early Cretaceous mineralization event provides important clues for identifying new potential exploration targets for porphyry Cu deposits in the western segment of the Lhasa Terrane. [ABSTRACT FROM AUTHOR]

Porphyry deposits supply most of the world's Cu and Mo resources. Most porphyry deposits are developed in magmatic arcs above subduction zones. However, abundant Miocene porphyry Cu-Mo deposits have been found in the post-collision stage in Tibet, more than ∼30 Myr after the Indian-Eurasian continental collision. The magma source and the enrichment process of ore-forming elements for these post-collision porphyry deposits remain controversial. Here, we present Sr-Nd-Mo isotope compositions of a suite of mineralized and barren igneous rocks from the Rongmucuola pluton in the Miocene post-collisional Qulong porphyry Cu-Mo deposit in Tibet to reveal their magma sources and ore-forming processes. Our results indicate that the mineralized and barren igneous rocks in the Qulong deposit were derived from a cogenetic source with similar Sr-Nd isotope compositions (87Sr/86Sr (i) = 0.7049–0.7050 and ε Nd (t) = −0.24 to 0.20). However, the mineralized igneous rocks have large variations in δ98/95Mo values (−0.30‰ to 0.74‰; relative to NIST SRM 3134) and Mo/Ce ratios (0.01 to 4.84) compared to those of the barren igenous rocks (δ98/95Mo = −0.74‰ to −0.02‰; Mo/Ce = 0.01 to 0.04). In combination with the higher LOI values, Mo/Ce and Cs/Ta ratios and Cu concentrations and lower Ce/Pb ratios of the mineralized igneous rocks relative to the barren igneous rocks, we propose the mineralized igneous rocks were affected by ore-forming hydrothermal fluids originated from the exsolution of later co-genetic magmas, which significantly changed the isotopic and elemental compositions of intrusions and resulted in Mo mineralization. The fluid-rock interaction modeling supports this interpretation and successfully reproduce the observed δ98/95Mo and Mo/Ce compositions of mineralized igneous rocks. Our study indicates that the exsolved magmatic-hydrothermal fluids have heavy Mo isotopes, and the fluids with a slightly heavier Mo isotope composition have the greatest potential for mineralization. As the water-rock reaction progresses, leading to the precipitation of Mo-rich minerals, ore-forming fluids with a heavier Mo isotope composition may not have significant mineralization potential. This highlights that Mo isotope system is an effective tool to study the ore-forming processes of porphyry deposits. [ABSTRACT FROM AUTHOR]

Explanation: From Lakange Mo (Cu) deposit to Jiama Cu polymetallic deposit to Bangpu Mo mineralization to Qulong Cu-Mo deposit to Bangpu Cu mineralization, the Cl contents in apatite gradually increase, but the F contents in apatite gradually decrease, and the S content is similar but variation. It indicates that the Mo-dominated porphyry deposit formed from F-S-rich magma, whereas the Cu-dominated porphyry deposit formed from Cl-S-rich magma. [Display omitted] • There are two different magmatic-hydrothermal systems that formed the Bangpu Mo-Cu deposit. • Cu and Mo mineralization contain zircon and apatite with different geochemical features. • Cu mineralization was related to Cl-rich porphyry system, whereas Mo-mineralization was related to F-rich porphyry system. The Bangpu deposit, located in the eastern part of the Gangdese Porphyry Copper Belt, Tibet, is a porphyry Mo-Cu deposit in a continental collisional orogenic belt. Cu and Mo mineralization occurred separately in the Bangpu deposit. Mo (Cu) mineralization occurred mainly in the monzogranite porphyry (MP), while Cu (Mo) mineralization occurred mainly in the diorite porphyry (DP). The cause of such spatial differences in Cu and Mo mineralization in the Bangpu deposit remains unclear. In this study, the mineral chemistry of apatite and zircon was investigated to reveal the differences in the nature of ore-forming magma between Cu (Mo) and Mo (Cu) mineralization in the Bangpu deposit. The chondrite-normalized REE patterns of the apatite grains from the MP were enriched in LREEs with negative Eu anomalies, whereas those from the DP and biotite monzonitic granite (BM) had strong negative Eu anomalies with no obvious differentiation between LREEs and HREEs. The DP, MP, and BM have a low T TiZ range from 657 °C to 917 °C and a high AST range from 687 °C to 1079 °C. The zircon grains from the DP and MP had different Th/U ratios and T TiZ values, indicating that these porphyry samples probably experienced different magma crystallization or crystal fractionation histories. The zircon Ce4+/Ce3+ and Eu/Eu* ratios indicate that the ore-bearing DP and MP have higher oxygen fugacity than the BM. The F, Cl, and S contents in the apatite showed that the DP magmas were Cl- and S- rich, whereas the MP magmas magmas were F- and S- rich. The Bangpu porphyry Mo-Cu deposit results from two superimposed magmatic-hydrothermal systems. Mo was mainly partitioned into the F-rich magmatic-hydrothermal system released from the MP, and Cu was mainly partitioned into the Cl-rich magmatic-hydrothermal system released from the DP. Our results show that zircon and apatite geochemistry can be used to explain the spatial distribution of Cu and Mo mineralization in porphyry Cu-Mo systems. [ABSTRACT FROM AUTHOR]

Crustal growth is commonly associated with porphyry deposit formation whether in continental arcs or collisional orogens. The Miocene high-K calc-alkaline granitoids in the Gangdese belt in southern Tibet, associated with porphyry copper deposits, are derived from the juvenile lower crust with input from lithospheric mantle trachytic magmas, and are characterized by adakitic affinity with high-Sr/Y and La/Yb ratios as well as high Mg# and more evolved isotopic ratios. Researchers have argued, lower crust with metal fertilization was mainly formed by previous subduction-related modification. The issue is that the arc is composed of three stages of magmatism including Jurassic, Cretaceous, and Paleocene--Eocene, with peaks of activity at 200 Ma, 90 Ma, and ca. 50 Ma, respectively. All three stages of arc growth are essentially similar in terms of their whole-rock geochemistry and Sr-Nd-Hf isotopic compositions, making it difficult to distinguish Miocene magma sources. This study is based on ~430 bulk-rock Sr-Nd isotope data and ~270 zircon Lu-Hf isotope data and >800 whole-rock geochemistry analyses in a 900-km-long section of the Gangdese belt. We found large scale variations along the length of the arc where the Nd-Hf isotopic ratios of the Jurassic, Cretaceous, and Paleocene--Eocene arc rocks change differently from east to west. A significant feature is that the spatial distribution of Nd-Hf isotopic values of the Paleocene--Eocene arc magmas and the Miocene granitoids, including metallogenic ones, are "bell-shaped" from east to west, with a peak of εNd(t) and εHf(t) at ~91°E. In contrast, the Jurassic and Cretaceous arc magmas have different isotopic distribution patterns as a function of longitude. The isotopic spatial similarity of the Paleocene--Eocene and Miocene suites suggests that the lower crust source of the metallogenic Miocene magmas is composed dominantly of the Paleocene--Eocene arc rocks. This is further supported by abundant inherited zircons dominated by Paleocene--Eocene ages in the Miocene rocks. Another important discovery from the large data set is that the Miocene magmatic rocks have higher Mg# and more evolved Sr-Nd-Hf isotopic compositions than all preceding magmatic arcs. These characteristics indicate that the involvement of another different source was required to form the Miocene magmatic rocks. Hybridization of the isotopically unevolved primary magmas with isotopically evolved, lithospheric mantle-derived trachytic magmas is consistent with the geochemical, xenolith, and seismic evidence and is essential for the Miocene crustal growth and porphyry deposit formation. We recognize that the crustal growth in the collisional orogen is a two-step process, the first is the subduction stage dominated by typical magmatic arc processes leading to lower crust fertilization, the second is the collisional stage dominated by partial melting of a subduction-modified lower crust and mixing with a lithospheric mantle-derived melt at the source depth. [ABSTRACT FROM AUTHOR]

[Display omitted] • The alteration zone patterns have been identified based on the SWIR data at Demingding. • The relationship between Pos2200 and compositions of white mica has been demonstrated by EPMA and determined the subspecies in the ore and barren zone. • We predicted the center of hydrothermal/mineralization based on the spatial variations of the white mica SWIR scalars. The Demingding Cu–Mo deposit, found in the eastern Gangdese metallogenic belt in China, has a significant exploration potential. Detailed field studies coupled with short-wavelength infrared (SWIR) spectroscopy and electron probe micro analyses (EPMA) identified a total of 15 alteration minerals such as white mica group minerals, chlorite, kandite, and smectite groups. The study also discovered the spatial distribution of alteration zone patterns, including phyllic, propylitic, and intermediate argillic alterations. Furthermore, variations were observed in the Al-OH absorption position (Pos2200) of the white mica group with variable Al-Si-Fe-Mg content. Most of the white micas in the ore zone were muscovitic series, whereas the barren zone contained phengitic series micas. Some micas have undergone a transition to illite due to low-temperature alteration overprinting. The western part of the deposit exhibited lower Pos2200, higher SWIR-IC, and higher Dep2200 values, implying an intense phyllic alteration and higher paleotemperatures. These characteristics suggest that the area is in close proximity to the hydrothermal center and fluid channel. Therefore, it was identified as an exploratory target for buried copper ore bodies. The SWIR spectra of the white mica group can be used for exploration in other similar porphyry deposits. Under acidic conditions, shorter Pos2200 and higher SWIR-IC can be used as indicators for hydrothermal or mineralization centers. [ABSTRACT FROM AUTHOR]

[Display omitted] • Late Triassic Xuejiping porphyries originated from mantle enriched by slab-melts and fluids. • Hongshan–Hongniu porphyry formed in late Cretaceous and the adakitic features were inherited from magmatic source. • Hongshan–Hongniu porphyry originated from the late Triassic juvenile crust, as well as a minor component of crystalline basement. • Lithospheric cycle of ore-forming ingredients caused recurrent 'flare-ups' of PCDs in a region. The porphyry Cu deposits with distinct mineralisation ages frequently occur as recurrent 'flare-ups' in a narrow region; however, the reasons controlling their occurrence are still debated. The eastern Yidun Arc in eastern Tibet produced a cluster of porphyry Cu deposits of the late Triassic and late Cretaceous ages, making it the ideal location for conducting this research. As a result, we use the late Triassic Xuejiping Cu–(Au) and late Cretaceous Hongshan–Hongniu Cu–Mo deposits as research objects, compiling new and published geochronological, elemental, and Sr–Nd–Hf isotopic data from their ore-forming porphyries to shed light on the above issue. The zircon U–Pb ages of the Xuejiping and Hongshan–Hongniu porphyries are 217.8 – 217.9 Ma and 78.7 Ma, respectively, and display adakitic characteristics. The Xuejiping porphyries present enriched Sr–Nd–Hf isotopes (0.70529 – 0.70590, −3.30 – −1.09, 0.40 – 2.20, respectively), low (Gd/Yb) N (2.24 – 3.20) and Nb/Ta (12.8 – 15.9) ratios, relatively high Nb (14.9 – 20.0 ppm) and Zr/Sm (23.4 – 41.5) values, indicating their origin in the partial melting of enriched mantle that is metasomatised by slab-melts and fluids in subduction zone. Furthermore, the Hongshan–Hongniu porphyry is adakitic, like the late Triassic igneous rocks in this area. Its Sr–Nd–Hf isotopes (0.69873 – 0.70996, −10.7 – −6.72, −14.9 – −0.50, respectively) are close to the isotopic evolution line of the late Triassic Xuejiping intrusions and show a trend towards the regional crystalline basement, which signify that the Hongshan–Hongniu porphyry mainly originated from the late Triassic juvenile crust, with some contributions from crystalline basement. One highly fractionated sample (i.e. HZK17-11-76) has extremely evolved Sr–Nd isotopes (0.70996 and −10.7, respectively), indicative of assimilation of sedimentary rocks. The new genetic models of the late Triassic and late Cretaceous porphyries in the Geza Arc show that the westward subduction of the Garzê–Litang oceanic crust in the late Triassic triggered the occurrence of the highly oxidised and Cu–S–H 2 O rich adakitic melts in the middle–lower crust, which evolved to amphibole cumulates and porphyry Cu–(Au) deposits (i.e. Xuejiping) in the upper crust. In the late Cretaceous, the extensional environment triggered the re-melting of late Triassic juvenile cumulates and Mo-rich crystalline basement, resulting in Cu–Mo–S–H 2 O-rich, highly oxidised magma. Through fractional crystallisation and assimilation of Mo-rich sedimentary rocks, the magma eventually transformed into Hongshan–Hongniu porphyry-(skarn) type Cu–Mo deposits. In summary, we conclude that the periodic recycling of the ore-forming ingredients on a lithospheric scale from slab subduction to post-subduction periods controls the recurrent 'flare-ups' of PCDs in this confined area. [ABSTRACT FROM AUTHOR]

[Display omitted] • The Ahadawa deposit is a newly discovered porphyry Cu–Mo system in the North Qaidam. • The Ahadawa formed by more than 25 Ma prolonged magmatic-hydrothermal activity. • The Late Triassic fertile magmas initially had high water and high oxygen fugacity. • Plagioclase-dominated fractionation occurred with magma evolution. Ongoing exploration in the North Qaidam, Northern Qinghai-Tibet Plateau, NW China, has led to the identification of a porphyry Cu-Mo system centered on Ahadawa. In this study, we conducted a detailed geochronological and geochemical study on porphyritic monzogranite from the Ahadawa deposit, which hosts the Cu-Mo mineralization. The weighted mean zircon U-Pb ages for three mineralized porphyritic monzogranite samples from different sites range from 218.8 ± 1.2 Ma (MSWD = 1.5) to 224.7 ± 1.6 Ma (MSWD = 1.8), and finally to 233.1 ± 0.9 Ma (MSWD = 1.4, n = 23). These results, combined with antecrystic grains as old as ∼ 245.7 Ma, collectively indicate more than 25 Ma multi-stage magmatic emplacement activity in the Ahadawa deposit. Corresponding to complex magma episodes, six studied molybdenite samples yielded variable Re-Os model ages ranging from 436.7 ± 6.6 to 232.6 ± 1.2 Ma, with the three youngest dates constraining a weighted mean Re-Os age of 234.0 ± 6.8 Ma. The 234 Ma mineralization age is consistent with the observed Late Triassic magmatism, whereas the Re-Os model ages of 436.7 to 245.7 Ma, if they remain robust through future investigation, may highlight a long-lived hydrothermal activity in the Ahadawa deposit. Whole-rock and zircon compositions indicate that the Late Triassic porphyries occurring at the surface display distinct geochemical features, with the early porphyritic monzogranite of 233.1 Ma characterized by much higher whole-rock Sr/Y, and zircon Eu/Eu* and Ce/Ce* than the younger (218.8 Ma and 224.7 Ma, respectively) porphyritic monzogranite. This suggests that the Late Triassic magmas were initially characterized by high water content and high oxidation state and the differences between the old and two younger groups might be related to plagioclase-dominated fractionation. The finding of the Ahadawa porphyry system highlights the need for ongoing exploration (especially in poorly studied remote areas) and systematically geochronological and geochemical studies to constrain the temporal and spatial evolution of mineralized episodes within a complex, protracted magmatic history. [ABSTRACT FROM AUTHOR]

The Zegulangbei deposit develops a complete porphyry metallogenetic system, whose magmatic emplacement and mineralization was similarly related to an isolated apophysis derived from a uniform shallow magmatic chamber as the Main deposit. Jiama is a complex porphyry metallogenetic system composed of several isolated magmatic-hydrothermal centers. Multi-types of mineralization and alteration coexist among these metallogenetic centers, partially overlapped, developed with complicated and various metallogenic elements. [Display omitted] • Geological features of Zegulangbei deposit were identified in the Jiama ore district. • Precise geochronology redefine the magmatism, alteration and mineralization age. • Main deposit and Zegulangei deposit have originated from the same magma source. • Jiama is a polycentric, complex porphyry mineralization system. Jiama is a typical giant-scale collisional-type porphyry mineralization system of in the Gangdese metallogenic belt, Tibet. The Zegulangbei deposit is located in the northern part of the ore district, which was a recent discovery. In the Zegulangbei deposit, intrusions have developed in multiple stages and led to the formation of complex porphyry intrusions (2# porphyries), of which granodiorite porphyry and Ⅱ-quartz diorite porphyry occurred related to mineralization. Hydrothermal alteration surrounding the 2# porphyries is characterized by potassic, phyllic, and chlorite–sericite alteration, with minor propylitization, argillization and tourmalinization. Furthermore, veinlet-disseminated copper and molybdenum mineralization mainly occurred within the potassic and phyllic alteration zones. Partial copper mineralization developed within the chlorite–sericite alteration zone. The mineralization is comprised of porphyry Cu–Mo, hornfels Cu–Mo and skarn Cu–polymetallic ore bodies. Hydrothermal vein system developed well, including 5-staged veins (M-, A-, B-, C-, and D-type vein). The similar ages of intrusive rocks (15.8–14.5 Ma, U–Pb), biotite and sericite alteration minerals (15.04–15.02 Ma, 40Ar–39Ar), and molybdenite (14.9 Ma, Re–Os) indicate that the intermediate–felsic magmatic rock emplacement triggered the hydrothermal alteration and mineralization in the Zegulangbei deposit. Geochemistry and Sr–Nd–Pb isotopes of the intrusions in Zegulangbei are consistent with those of the intrusions in the Main deposit (1# porphyries) and the Miocene adakites that developed in the eastern Gangdese belt, implying they were generated from the partial melting of the thickened phlogopite-bearing juvenile crust that had been reworked by diapirs of the arc magma during subduction. The evidence presented in this study suggests that Zegulangbei developed a complete porphyry Cu–polymetallic mineralization system, which was related to the same magma chamber in the upper crust that caused the mineralization in the Main deposit. [ABSTRACT FROM AUTHOR]

[Display omitted] • The Indian slab to the eastern of 93 °E constantly subducted with shallow angle beneath Tibetan lithosphere. • Juvenile pre-collisional magmas restored within Tibetan arc root are the key for porphyry mineralization in southeastern Tibet. • Shallow subducted Indian slab triggered reactivation of juvenile arc root material and caused porphyry mineralization. The 1500-km long Gangdese belt in southern Tibet shows uneven distribution of giant to large porphyry deposits over 45 Mt Cu mainly in the middle-east segment between longitude 87–92°E. However, the western (80–86°E) and eastern end (92–96°E) is generally barren. The recent discovery of Demingding, Cuibaizi and Tangbula porphyry deposits in the east of 92°E has attracted great attention on their origin. Recent high-resolution seismic imaging shows the torn Indian lithosphere subducts with diverse angle. In contrast to the middle-east segment with moderate angle Indian plate subduction, the southeastern Tibet is characterized with a shallow dip of subduction (eastern of Comei rift), where Demingding, Cuibaizi and Tangbula deposits are located. To reveal the formation mechanism of these deposits as well as the Indian slab motion pattern beneath them, we compiled reported whole rock major and trace elements, Sr and Nd isotope signature, zircon trace element, U-Pb ages and Hf isotope data of Miocene ore-related adakitic rocks from Demingding and Tangbula to the north, and Oligocene ore-barren adakitic rocks from Linchi to the south. There is a clear negative correlation between zircon U-Pb ages of rocks and their distance to Indus-Yarlung Zangbo suture: Linchi is around 20 km away from the suture, with an average U-Pb age of 27.1 Ma, while Demingding and Tangbula rocks are 50 and 90 km away from the suture, with ages of 20.3 and 19.7 Ma respectively. Granitoids from Linchi have less compatible element Ni and Cr contents of 4.07 and 5.84 ppm on average respectively, while those of Demingding (20.1 and 43.4 ppm) and Tangbula (5.52 and 7.90 ppm) are much higher. Ni and Cr as compatible elements are concentrated in mafic minerals, and are thus proper indicators for mantle imprint indicators. In addition, as shown by Sr-Nd isotopes, Linchi granitoids have features of ancient crust [(87Sr/86Sr) i = 0.7059 to 0.7085, ε Nd (t) = − 6.20 to −2.90], while Demingding and Tangbula granitoids show less radiogenic features [(87Sr/86Sr) i = 0.7059 to 0.7068, ε Nd (t) = − 3.27 to −1.70], which are more similar to coexisting juvenile arc. Demingding and Tangbula granitoids also show signature of high f O 2 and hydrous melt condition, as indicated by calculated f O 2 of ΔFMQ + 2, and amphibole fractionation indicated by decreasing Dy/Yb with SiO 2 , since amphibole favors MREE (Dy) rather than HREE (Yb). Combining above, our work shows that the Indian slab constantly subducted shallowly beneath these deposits, given no mantle-like signature of near-suture Oligocene adakitic rocks. We suggest the cause to the formation of Demingding, Tangbula and Cuibaizi deposits is the reactivation of pre-enriched arc root materials, triggered by constant northward migration of Indian slab. This is supported by similar isotope signature between Miocene Demingding and Tangbula ore-related porphyries and coexisting arc, and absence of coeval pre-collisional porphyry deposits. The essential components for these porphyry deposits, high f O 2 and water content, were also likely contributed from the pre-enriched juvenile arc root. [ABSTRACT FROM AUTHOR]

[Display omitted] • Luerma is the firstly discovered porphyry in western Gangdese. • The metallogenic of Luerma occurred at ca. ∼ 212 Ma, which thus represents the oldest known porphyry deposit in the Gangdese belt. • Five stages of porphyry copper (molybdenum-gold) mineralization has been put forward in Gangdise porphyry copper belt. Due to the difference of lithospheric structure between the eastern and western segment of Gangdese metallogenic belt, it is generally believed that porphyry copper deposits are mainly developed in the east. However, the newly discovered of Luerma porphyry copper deposit in the western segment of Gangdese provides an excellent research object for us to supplement this understanding. The molybdenite re-Os isotope dating of two samples from quartz veinlet ores (ca. 213.1 ± 5.2 Ma and ca. 212.0 ± 3.7 Ma), combined with the LA-ICP-MS zircon U-Pb dating of three ore-bearing quartz monzonite porphyry samples (ca. 212.7 ± 0.9 Ma, 213.1 ± 1.1 Ma, and ca. 211.8 ± 1.8 Ma), indicates a new generation of Late Triassic Luerma copper porphyry-type mineralization events in the western Gangdese magmatic belt. The Luerma porphyry is a strongly peraluminous shoshonite series rock, is rich in silicon total alkalis, potassium and aluminum, has low contents of calcium, magnesium, and iron. It is enriched in light rare earth elements and large ion lithophile elements, relatively depleted in heavy rare earth elements and high field strength elements, and has negative Eu anomalies and no Ce anomalies. The porphyry exhibits relatively low (87Sr/86Sr) i values (0.705617 on average), high ε Nd (t) values (0.63 on average), high ε Hf (t) values (11.98 on average), and young two-stage Hf model ages. The Luerma ore-related porphyries are most likely generated dominantly from partial melting of juvenile crust that formed by metasomatized mantle during the subduction of the NeoTethys Ocean to the Lhasa terrane and underwent crystal fractionation during the process. The deposit is currently the oldest and westernmost porphyry deposit in the Gangdese porphyry copper belt, providing evidence that porphyry copper mineralization in this belt began in at least the Late Triassic. [ABSTRACT FROM AUTHOR]

Geochemical exploration data plays a vital role in mineral prospectivity mapping (MPM) for discovering unknown mineral deposits. In this study, compositional balance analysis (CoBA), unsupervised and supervised learning are collaboratively used to improve the practice of identification of geochemical anomalies related to mineralization in the Qulong-Jiama mining district of Tibet. For CoBA, five balances of geochemical elements were constructed by the sequential binary partition (SBP) technique, facilitating the interpretation of geochemical/geological processes and contrasting with geochemical anomalies generated by unsupervised and supervised learning. The iterative self-organizing data analysis techniques algorithm (ISODATA) and isolation forest (iForest) are used for preprocessing the geochemical data and therefore optimizing the appropriate training sets (e.g., positive and negative training samples) for supervised learning. Different training datasets including locations of known mineralization, randomly selected positive samples from resulting clusters by ISODATA and outliers by iForest are fed to the support vector machine (SVM) and random forests (RF) algorithm. The results of high AUC values indicate that supervised learning can effectively delineate prospective areas both with SVM and RF, however, the excessive large area of high-prospectivity and a bias toward known mineralization makes the outcomes of MPM unpractical. Nevertheless, a hybrid of the CoBA, unsupervised learning and supervised learning could alleviate such situations and provide insights into MPM using the geochemical data. • Detection of geochemical anomalies related to mineralization using a hybrid method • The effects of training datasets on mineral prospectivity mapping • The paper provides new insights into mineral exploration using geochemical data. [ABSTRACT FROM AUTHOR]

The Lhunze region of southeast Tibet uniquely juxtaposes Cenozoic granitic plutons with subvolcanic rocks in the Tethyan Himalayan Sequence. In this study, the potential petrogenetic connection between two-mica granite and subvolcanic rhyolite porphyry from the Lhunze area is investigated using petrology, geochronology, and geochemistry. Monazite Th Pb ages imply the two-mica granite crystallized during the mid-Eocene at c. 43.5–43.1 Ma, consistent with previous zircon U Pb isotope data. Monazite in the porphyry also records Th Pb ages of c. 44.5–42.9 Ma , suggesting contemporaneous emplacement with the two-mica granite. Porphyritic structure, feldspar aggregates and comb alignment demonstrate that the two-mica granite resulted from transient melt flow associated with melt extraction. Some plagioclase phenocrysts from the porphyry have consistent An contents with the two-mica granite, indicating that both the two-mica granite and the porphyry probably originated from a similar melt. However, the porphyry has a higher SiO 2 concentration (72.2–75.9 wt%) than the two-mica granite (69.0–73.0 wt%). In addition, the porphyry is characterized by lower TiO 2 , MgO, CaO, Ba, Sr, and Zr contents as well as Zr/Hf, Sr/Y, Nb/Ta ratios than the two-mica granite. Moreover, strontium and REE contents of monazite in both the two-mica granite and porphyry also imply that crystal fractionation dominated melt evolution. Whole-rock Sr Nd and in situ monazite Nd isotope compositions indicate that the porphyry is slightly more radiogenic than the two-mica granite, implying that the porphyry likely assimilated more ancient country rocks during its evolution. We interpret the two-mica granite and porphyry as comagmatic intrusives linked by fractional crystallization of a cognate magma mush, in which the crystals accumulated to form the two-mica granite, and the complementary high silicic melt segregated to form the porphyry. Plagioclase accumulation is responsible for the generation of the high Sr /Y adakitic geochemical feather within two-mica granite. The scenario of complementary melt extraction and crystal fractionation might also have been an important process in forming the Himalayan leucogranites. Regionally, Neo-Tethyan slab breakoff during the Eocene could have increased mantle heat flow and triggered the generation and extraction of large volumes of silicic melt. • Two-mica granite and subvolcanic rhyolite porphyry have a coeval crystallization age at 44–43 Ma. • Two-mica granite represents cumulate and the porphyry as its complementary highly fractionated melt. • Magma differentiation via melt extraction from crystal mush is an effective mechanism to produce Himalayan leucogranites. [ABSTRACT FROM AUTHOR]

[Display omitted] • The Gaofen-5 satellite hyperspectral data were used for alteration mineral mapping. • Advanced argillic, argillic, phyllic, and propylitic zones were mapped in detail. • High content of Al-rich white mica (alunite + pyrophyllite + kaolinite ± dickite) is an important indication of hydrothermal alteration. Remote sensing technology is an exploration method that can directly map distribution of alteration minerals or zones associated with different types of mineral systems. Hyperspectral remote sensing can identify key pathfinder minerals and compositional variations within minerals. The Duolong porphyry-epithermal ore district, which has proven reserves of approximately 20 million tons of Cu and 420 tons of Au, is part of an emerging world-class metallogenic area in the western part of the Bangong Co-Nujiang metallogenic belt, Tibet, China. The Gaofen-5 hyperspectral (GF-HS) reflectance data were used to map the distribution patterns of hydrothermal alteration and to locate areas potentially containing mineral deposits in the Duolong ore district (DOD). Based on the mixture tuned matched filtering (MTMF) technique and the absorption feature wavelength positions of the minerals, an alteration map was generated using GF-HS data for mineral mapping in the DOD with sparse vegetation. The widely distributed advanced argillic alteration (alunite + pyrophyllite + kaolinite ± dickite), phyllic alteration (high content of Al-rich white mica), propylitic alteration (Mg-rich chlorite), and limited argillic alteration (kaolinite ± dickite ± white mica) were mapped in detail. The distribution patterns of alteration in known deposits were fairly consistent with the mineralogical information obtained in previous studies. In addition, we identified potential mineralization areas with characteristics similar to the Duobuza, Bolong and Naruo porphyry deposits. [ABSTRACT FROM AUTHOR]

[Display omitted] • The Yare complex as well as granite units in the Mayum, Pujue, Nanmuqie, and Qiagong areas in the Gangdese magmatic arc were emplaced in Miocene. • The barren adakitic porphyries in Gangdese magmatic arc were derived from ancient crustal sources with little contributions from mantle-derived material. • The history of continuous and relatively complex magmatism prior to emplacement are important factors that discriminate between fertile and barren magmatism. Numerous Miocene porphyry deposits related to adakites have been identified in the eastern Gangdese magmatic arc (east of 87°E), but few of these type of deposits have been found in the western part (west of 87°E), even contemporaneous adakitic porphyries were exposed in the western part. A little research has been undertaken on barren adakitic porphyries in the Gangdese magmatic arc, and the key controls on the metallogenic differences remains unclear. This study presents new whole–rock geochemical, Sr–Nd isotopic, zircon U–Pb and Hf isotopic data for barren adakitic rocks of the Yare complex as well as barren porphyritic and adakitic units in the Mayum, Pujue, Nanmuqie, and Qiagong areas. These data are compared with data for fertile adakitic porphyries, providing insights into the origin and evolution of barren and fertile adakitic magmatism as well as the conditions associated with the porphyry mineralization. The barren adakitic porphyries were formed at 18.03–13.29 Ma. These intrusions have higher (87Sr/86Sr) i ratios (0.708752–0.709785) and lower Ɛ Nd (t) values (−8.4 to −6.5) and zircon Ɛ Hf (t) values (−13.81 to 3.23) than the fertile adakitic porphyries, suggesting the former were derived from ancient crustal sources with a little contributions from mantle-derived material. The fertile adakitic porphyries were formed as a result of partial melting of juvenile lower crust (such as Cu–Mo deposits) and with mixing of material from middle-upper crust (such as Mo–(Cu)–Pb–Zn deposits). The fertile adakitic porphyries also contain more water than the barren adakitic porphyries. Other important factors that discriminate between fertile and barren adakitic magmatism include the involvement of parental magma chambers as well as a history of continuous and relatively complex magmatism prior to emplacement. [ABSTRACT FROM AUTHOR]

[Display omitted] • The variation of Pos2200 in the Cimabanshuo-Luobuzhen area is mainly controlled by Tschermak substitution in white mica crystals. • The indications of SWIR (Pos2200 < 2203 nm, Dep2200 > 0.2, IC > 2.0) have been established at the Zhu'nuo ore-cluster district for rapidly identifying potential porphyry copper mineralization. • Three H/M centers and a new porphyry metallogenic system in the Cimabanshuo-Luobuzhen area have been identified based on the indications of SWIR. The Zhu'nuo ore-cluster district in the western Gangdese belt, southern Tibet, is characterized by a significant Cu geochemical anomaly, where the Zhu'nuo super-large porphyry Cu deposit (PCD) was discovered by stream sediment geochemical method. However, due to the extended coverage of volcanic rocks of the Linzizong group and the large area of ore-forming element anomalies, it is quite difficult to locate the concealed PCDs only by geochemical method. Therefore, the application of new technical methods is urgently needed to guide the exploration breakthroughs in the Zhu'nuo district. Recently, our studies have shown that the wavelength variation of diagnostic absorption peaks of alteration minerals measured by shortwave infrared (SWIR) spectrometry is closely related to the mineralization temperature in the Zhu'nuo PCD, which can be footprints to trace the hydrothermal and/or mineralization (H/M) centers of porphyry ore systems. Hence, we carried out SWIR studies in the Luobuzhen-Cimabanshuo areas with high Cu geochemical anomaly. In this study, sixteen alteration minerals were identified by SWIR, consisting mainly of white mica, chlorite, epidote, and kaolinite. Among them, the white mica and chlorite were widely distributed in the study area, and the Al-OH wavelength position of white mica (∼2200 nm; Pos2200) and Fe-OH wavelength position of chlorite (∼2250 nm; Pos2250) varied between 2191–2219 nm and 2239–2260 nm, respectively. Moreover, there is an increasing trend of Pos2200 from porphyry center to periphery, whereas Pos2250 shows the opposite tendency. When combined with geochemical anomalies of stream sediments and geological characteristics and SWIR features in the Zhu'nuo PCD in study area, three potential H/M centers, namely Cimabanshuo, South Luobuzhen and Ya'nuri, were determined, which are dominated by short wave anomalies (Pos2200, 2191–2206 nm; Pos2350, 2243–2250 nm). Significantly, we showed that the Dongshibu-Hongshan-Luobuzhen may belong to the same porphyry system by SWIR. And SWIR implies that the true center is located in South Luobuzhen (H/M II), which has great prospecting potential in its depth, rather than the previously recognized Dongshibu Cu prospect delineated by stream sediment data. We found that the Dongshibu Cu prospect does not show any alteration information associated with porphyry mineralization as reflected by SWIR, consistent with the barren Cu results from the late drilling validation. This decoupling may be caused by the long-term migration and weathering of stream sediment samples, during which the obtained geochemical anomaly do not represent their in-situ information. Therefore, caution must be taken when using stream sediment data to delineate prospecting targets. Instead, SWIR is a potentially powerful vectoring tool to aid exploration for porphyry systems, especially in the western regions where the level of prospecting work is extremely low. [ABSTRACT FROM AUTHOR]

[Display omitted] • Multi-stage intrusions from pre- to post-mineralization at Bairong are studied. • They formed at 14.1 to 11.6 Ma and derived from a cogenetic magma chamber in a post-collisional setting. • They are all oxidized and hydrous with comparable magmatic S contents, but have different Cl contents. • Fluid exsolution and buffering effect of magmatic anhydrite possibly result in S-Cl decoupling. • Oxidized and hydrous magma with effective fluid exsolution is the key factor for Bairong Cu-Mo mineralization. Volatiles are considered to play an important role in porphyry Cu mineralization, and high apatite S and Cl contents are often used to distinguish fertile magma systems from barren ones in the subduction zone. However, magmatic volatile evolution and its implications in post-collisional porphyry deposits remain enigmatic. To address this issue, we conducted zircon U-Pb dating and Hf isotope, and zircon and apatite chemical compositions of multi-stage magmatic rocks from the Bairong post-collisional porphyry Cu-Mo deposit in the Gangdese belt, Tibet. The magmatic rocks included pre-mineralized porphyritic monzogranite and biotite monzogranite, syn -mineralized monzogranite porphyry, and post-mineralized dacite porphyry that formed in 14.1–12.7 Ma, ca. 12.1 Ma, and 11.8–11.6 Ma, respectively. All these intrusions have depleted zircon Hf isotope (ε Hf (t) = 1.7–8.0, 3.7–9.0, 3.3–9.7 for pre-, syn-, and post-mineralized intrusions, respectively) together with the research results of contemporaneous magmatic rocks in the adjacent area, suggesting that the multi-stage intrusions at Bairong are derived from a cogenetic magma chamber in post-collisional extension setting. All the intrusions have similar zircon Ce N /Ce N *, Eu N /Eu N * ratios with average ΔFMQ values of 2.1 – 2.6, together with the high apatite Eu N /Eu N * ratios and low Ga concentrations, implying that their magmas are all oxidized. These intrusions have zircons (10,000 × Eu N /Eu N *) /Y all > 1 and Ce/Nd/Y mostly > 0.01, and obtain low average titanium-in-zircon temperatures of 659 to 714 °C, which indicate their magmas are hydrous. Apatite Cl contents decrease, combined with the drop of apatite X Cl /X OH and the surge of X F /X Cl ratios from pre- to syn -mineralized intrusions, possibly indicating that fluid exsolved from magma at the syn -mineralization stage. The apatite SO 3 contents in these different-stage intrusions, however, are almost unchanged. Combined with previous studies, the buffering effect of magmatic anhydrite maintains the stability of magma S content, which together with fluid exsolution leads to the S-Cl decoupling. Consequently, we conclude that the oxidized and hydrous magma with effective fluid exsolution is a critical control on the formation of Bairong porphyry Cu-Mo mineralization. Considering the wide variations of apatite Cl contents and the occurrences of S-Cl decoupling, simple application of high apatite SO 3 and Cl contents to distinguish the ore-forming and barren systems in the post-collisional porphyry system should be cautious. [ABSTRACT FROM AUTHOR]

In-situ analysis of minerals, such as zircon hafnium (Hf) and oxygen (O) isotopes, has been pivotal in investigating magmatic evolution and related ore systems. In order to better constrain the petrogenesis of Cu-porphyries and related ore-forming processes in southern Tibet, we used a combined application of both zircon by Hf-O isotopes and apatite by developing geochemical indicators involving Sr-O isotopes and volatile (chlorine and sulfur) concentrations. Apatite has several advantages over zircon: it carries ore-related volatiles, is present in less-evolved magmas and is sensitive to magmatic processes. Data on major- and trace elements and Sr-O isotopes in gem-like apatite can supplement information from zircon Hf-O isotopes. We have applied these techniques to granitoids from the Jurassic arc in southern Tibet to illustrate their use in tracing volatile evolution and related genesis of porphyry systems. We demonstrate that (1) robust apatite Sr-O isotopes combined with zircon Hf-O isotopes can record recycled oceanic components in the sources of Gangdese Jurassic porphyries; (2) volatile-enriched magmas metasomatised hydrous mantle wedge to form the Jurassic mineralised rocks; (3) the ore-forming magma with higher contents of water, Cl and S, favoured the transfer of metals and volatiles to the upper crust and to form the Jurassic porphyry Cu-Au deposits. [ABSTRACT FROM AUTHOR]