1. A hierarchically structured self-cleaning energy-free polymer film for daytime radiative cooling.
- Author
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Huang, Meng-Chen, Xue, Chao-Hua, Huang, Jianying, Liu, Bing-Ying, Guo, Xiao-Jing, Bai, Zhong-Xue, Wei, Ren-Xuan, Wang, Hui-Di, Du, Mi-Mi, Jia, Shun-Tian, Chen, Zhong, and Lai, Yuekun
- Subjects
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POLYMER films , *COOLING , *AIR conditioning , *ELECTRIC power consumption , *REFLECTANCE - Abstract
[Display omitted] • A hierarchically structured superhydrophobic radiative cooling film was fabricated. • The film integrates solar reflectance, infrared emittance and superhydrophobicity. • The film exhibits an average sub-ambient temperature drop of 12.3 °C under sunlight. • The superhydrophobicity makes the film maintain long-lasting cooling performance. • The film is promising for energy-free cooling materials towards applications. Radiative cooling without using electricity represents an ideal green solution for air-conditioning. Despite exciting progress made so far, most of the radiative cooling materials are vulnerable to outdoor contamination, which leads to decreased performance. Herein, we fabricate a hierarchically structured PVDF/PDMS porous film which integrates strong sunlight reflectance (97%), high thermal-infrared emittance (96%) and robust superhydrophobicity (160.2°). The synergy of the effective solar reflection and thermal-infrared emission enables the film to yield a sub-ambient temperature drop of 12.3 °C under strong sunlight. More importantly, the superhydrophobicity keeps the film away from contamination by self-cleaning, maintaining well the radiative cooling performance for a long-term outdoor use. Additionally, the as-obtained film shows excellent chemical durability after exposure to different pH solutions and UV light irradiation. This work provides a new strategy to integrate self-cleaning with radiative cooling, showing great potential to advance energy-free cooling materials toward real-world applications. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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