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Summary: Doping Mn element into host material is an efficient approach to enhance the specific capacitance and cycling stability of supercapacitor. In this aspect, we fabricate Co‐Mn LDHs (CMLs) hollow polyhedron generated from ZIF‐67 via a template sacrifice method. Controllable doping of Mn element with gradient contents on the effect of electrochemical performance are investigated in detail. Moreover, in order to assemble a hybrid supercapacitor with superior energy and power output, a negative electrode based on MXene/rGO/V10O24 is synthesized considering the integration of EDLC and pseudocapacitance. As expected, the asymmetric supercapacitor of CMLs‐0.53//MXene/rGO/V10O24 delivers high energy density of 44.4 Wh kg−1, maximum power density of 12 750 W kg−1 and superior cycling life (91.6% capacitance retention after cycling 10 000 cycles). The special idea on the construction of CMLs with hollow structure can offer new insight to resolve the complicated steps during preparation procedure. The results also indicated that the device based on CMLs‐0.53 and MXene/rGO/V10O24 is a good candidate in the utilization of energy storage and conversion system in the future. [ABSTRACT FROM AUTHOR]

As a recently emerging group of 2D materials, MXene has attracted extensive attention in the energy storage field in recent years owing to their outstanding features. However, the notorious issues of inevitable oxidation stability and surface‐to‐surface self‐restacking for MXene significantly prevent its further wide‐ranging application. Herein, the 3D macroporous oxidation‐resistant Ti3C2Tx MXene/graphene/carbon nanotube (MRC) hybrid hydrogels are prepared by a simple gelation method assisted by l‐cysteine as crosslinker and l‐ascorbic acid (VC) as reductant. Benefitting from the effectively alleviated restacking, excellent electrical conductivity, and the 3D inter‐crosslinked macroporous architecture, as a supercapacitor electrode, the obtained MRC aerogel exhibits a superior specific capacitance of 349 F g−1, unparalleled rate capability (52.0% at 3000 mV s−1) and amazing cyclic stability (retention of 97.1% after 100 000 cycles). Moreover, the 3D MRC‐30 aerogel exhibits an impressive oxidation‐resistant performance with just a 9.3% increase in electrical resistance after storing in ambient condition for 60 days, effectively alleviating the oxidation problem of MXene. This work demonstrates a new method for construction of 3D oxidation‐resistant MXene hydrogel, shedding new light on the promising applications of MXene materials, especially in high humidity and oxygen environment. [ABSTRACT FROM AUTHOR]

• α-MnSe Nanosheets are prepared via a facile hydrothermal method. • The effect of reaction time on electrochemical performance is investigated. • The α-MnSe electrode delivers a high capacity of 88.3 mAh g−1 at 1 A g−1. • The asymmetric supercapacitor exhibits a high energy density of 39.3 Wh kg−1. Transition metal selenides are regarded as emerging materials for energy storage devices because of their good electrical conductivity and electrochemical activity. Here, a binder-free ultrathin α-MnSe nanosheets electrode is prepared and the supercapacitor performance is comprehensively explored. Due to the increased active sites, enlarged contact area for electrolyte, as well as shorten ions diffusion pathway, the prepared electrode delivers high capacity of 88.3 mAh g−1 at 1 A g−1, good rate capability, and long-term durability (91% remain after 5000 cycles). Moreover, the asymmetric supercapacitor, fabricated by α-MnSe anode and active carbon cathode, displays a high energy density of 39.3 Wh kg−1 at a power density of 0.92 kW kg−1 and satisfying cycle performance. This study demonstrates that the binder-free α-MnSe electrode holds great promise for supercapacitor. [ABSTRACT FROM AUTHOR]