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The Moon's mare volcanism predominantly occurs within the Procellarum KREEP Terrane (PKT), which is widely thought to be associated with KREEP components within the lunar interior. The Chang'e-5 (CE-5) mission sampled a young (2 Ga) mare basalt Em4/P58 unit of northern Oceanus Procellarum. The geochemistry of the CE-5 mare basalt enables assessment of mantle source compositions which are essential to understand the thermo-chemical mechanism for prolonged volcanism during secular cooling of the Moon. Geochemical compositions of the CE-5 bulk soil, breccias, and basalt clasts from various depths within the drill core consistently display high concentrations of incompatible trace elements (ITE: ∼ 0.3 × high-K KREEP; ∼ 5 μg/g Th) with KREEP-like inter-element ratios, for example for La/Sm, Nb/Ta, and Zr/Y. Exotic impact ejecta, extensive magma differentiation (<70 % fractional crystallization) and significant assimilation of KREEP materials during magma transit and eruption cannot account for the ITE contents and ratios or radiogenic isotope compositions (e.g., εNd initial of + 8 to + 9 and εHf initial of + 40 to + 46) of the CE-5 basalts; instead, partial melting of their mantle source played a dominant role. The Chang'e-5 basalt is a chemically evolved low-Ti mare basalt (Mg# of ∼ 34) with enriched KREEP-like ITE compositions but high long-term time-integrated Sm/Nd and Lu/Hf ratios, which represent a hitherto unsampled type of mare basalt. It formed by melting of an augite-rich mantle source (late-stage magma ocean cumulates containing > 30–60 % augite, and little or no ilmenite), with a small amount of late-stage interstitial melt that resembles KREEP (∼1–1.5 modal %, equivalent to 0.2–0.3 μg/g Th in the mantle source). The voluminous mare basalts making up the Em4/P58 unit (>1500 km3) provide compelling evidence for large-scale, ITE enriched young mare magmatism within Oceanus Procellarum. In combination with remote sensing data and with the unique Th-rich Apollo 12 basalt fragment 12032,366–18 (impact ejecta likely from Oceanus Procellarum), this implies that significant portions of the FeO- and Th-rich mare regions of the western PKT may also have formed in a similar way. [ABSTRACT FROM AUTHOR]

[Display omitted] • Juvenile crust in Singhbhum Craton formed at ∼3.51, ∼3.45, 3.38–3.25, 3.15–3.05 and ∼2.80–2.75 Ga. • Reworking of older crust in the craton occurred at ∼3.46, ∼3.3, ∼3.1 and ∼2.8 Ga. • Maximum crustal thickness was attained at ∼3.3 Ga followed by a possible reduction over ∼3.1–2.8 Ga. • Paleo-Meso–Archean continental growth occurred through episodic intraplate juvenile magmatism and resultant crustal reworking. The composition of continental crust and its temporal variation, the mechanism of crust-mantle interaction, and the degree of mantle depletion during the early Archean have been widely debated. To address these issues related to the Singhbhum Craton, we present whole-rock sediment geochemistry, detrital zircon U-Pb date, trace element and Hf isotope data from four Archean clastic sedimentary successions. The rocks have high whole-rock K 2 O/Na 2 O, relatively high La and Th compared to Ni and Sc, distinct negative Eu anomaly and flat HREE patterns, and high detrital zircon U/Yb ratios. These features suggest attainment of early crustal stability with the sediments derived from a strongly weathered basement dominated by granitoids formed through shallow intracrustal melting. Detrital zircon U-Pb and Hf isotope data indicate episodic crust formation at ∼3.51, ∼3.46, 3.38–3.25, 3.15–3.05 and ∼2.80–2.75 Ga. Each major crust formation event is marked by addition of depleted mantle-derived juvenile crust and its quick reworking. Besides, episodic tapping of older crust, as indicated by a wide range (both positive and negative) of zircon εHf t values, are evident at ∼ 3.46, ∼3.3, ∼3.1 and ∼2.8 Ga. Pressure-sensitive zircon trace element ratios suggest that the crust attained the maximum thickness at ∼3.3 Ga followed by a possible reduction in thickness over ∼3.1–2.8 Ga. In the absence of strong evidence of subduction, the rock association and their temporal distribution (coeval granitoid and mafic-ultramafic magmatism) suggest that the Paleoarchean-Mesoarchean crustal growth in the Singhbhum Craton was a result of episodic, depleted mantle-derived, intraplate magmatic injection and attendant crustal reworking. [ABSTRACT FROM AUTHOR]

The processes responsible for the origin and evolution of Early Archean continental crust are not properly understood. Questions regarding the pattern of crustal growth (episodic vs. continuous) and the role of crust-mantle interaction in the temporal change of crustal composition and thickness are still being widely debated. In order to address the above issues, we present whole-rock geochemistry and detrital zircon U-Pb-Hf isotopes, and trace-element data from Mesoarchean clastic rocks of two selected greenstone belts of western Dharwar Craton. The mineralogically mature character of the sampled sandstones along with their high K 2 O/Na 2 O, Rb/Sr and CIA values, relatively enriched concentrations of La and Th over Cr and Sc, variably negative Eu-anomaly, and high U/Yb values of detrital zircons are indicative of their derivation from strongly weathered stable continental provenance dominated by low-HREE TTGs and K-rich granites of shallow crustal origin. Detrital zircon U-Pb ages indicate the maximum age of deposition for these sandstones is ∼3.1 Ga. The detrital zircon U-Pb and Lu-Hf data suggest two major crust formation events at 3.54–3.33 Ga and 3.27–3.12, mainly via juvenile crustal addition and subsequent rapid reworking. Besides, ∼3.6 Ga detrital zircons with negative εHft values suggest that the antiquity of the western Dharwar Craton can be traced back at least up to 3.8 Ga. Reworking of the older continental crust occurred during ∼ 3.25 Ga and ∼ 3.15–3.07 Ga, the last one represented by emplacement of K-rich granites. Zircon trace element ratios indicate a maximum increase in crustal thickness at ∼3.2 Ga followed by a crustal thinning at around ∼3.15 Ga. The detrital record in combination with geological setting suggests an episodic crustal growth and reworking in the western Dharwar Craton during Paleoarchean to early Mesoarchean period which was possibly related to intraplate processes. • Juvenile crust in Western Dharwar Craton formed at 3.54–3.33 Ga. • The juvenile crust reworked during 3.27–3.12 Ga. • Reworking of older crust occurred at ∼3.25 Ga, ∼3.15–3.07 Ga and ∼ 3.02 Ga. • Maximum crustal thickness attained at ∼3.2 Ga followed by thinning up to ∼3.1 Ga. • Link between crustal thickening and partial convective overturn is suggested. [ABSTRACT FROM AUTHOR]