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Creation of new alloys through in-situ alloying in additive manufacturing is being actively explored to improve the properties and performance of manufactured parts. Multiphysics models are often used to investigate the underlying physics controlling AM processes using high-fidelity simulations of individual powder particle melting within the meltpool. In this paper, we present a novel multiphysics-multiphase model for simulating multicomponent powder beds during the AM process. A convection–diffusion formulation for component mass fraction, in conjunction with the Navier–Stokes equations and enthalpy form of the energy equation, enable us to predict the phase evolution in multicomponent beds and the dispersion of solute metals in the melt pool during the process. A non-equilibrium phase diagram (NEPD) model that incorporates the associated phase diagram is introduced to obtain the mass fraction in both solid and liquid phases as well as local temperature and liquid fraction by efficiently solving a set of nonlinear equations locally at each computational cell. This work introduces a numerical method for multicomponent Al-Zr binary material system for light-weight aluminum alloys, specifically demonstrating its efficacy and accuracy for eutectic solidification of this multicomponent. [ABSTRACT FROM AUTHOR]