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We report the discovery of nine new hot molecular cores in the Deep South (DS) region of Sagittarius B2 using Atacama Large Millimeter/submillimeter Array Band 6 observations. We measure the rotational temperature of CH _3 OH and derive the physical conditions present within these cores and the hot core Sgr B2(S). The cores show heterogeneous temperature structure, with peak temperatures between 252 and 662 K. We find that the cores span a range of masses (203–4842 M _⊙ ) and radii (3587–9436 au). CH _3 OH abundances consistently increase with temperature across the sample. Our measurements show the DS hot cores are structurally similar to Galactic disk hot cores, with radii and temperature gradients that are comparable to sources in the disk. They also show shallower density gradients than disk hot cores, which may arise from the Central Molecular Zone’s higher density threshold for star formation. The hot cores have properties which are consistent with those of Sgr B2(N), with three associated with Class II CH _3 OH masers and one associated with an ultra-compact H ii region. Our sample nearly doubles the high-mass star-forming gas mass near Sgr B2(S) and suggests the region may be a younger, comparably massive counterpart to Sgr B2(N) and (M). The relationship between peak CH _3 OH abundance and rotational temperature traced by our sample and a selection of comparable hot cores is qualitatively consistent with predictions from chemical modeling. However, we observe constant peak abundances at higher temperatures ( T ≳ 250 K), which may indicate mechanisms for methanol survival that are not yet accounted for in models.

We report first laboratory rest frequencies for rotational transitions of protonated methylamine, CH3NH3+, measured in a cryogenic 22-pole ion trap machine and employing an action spectroscopy scheme. For this prolate symmetric top molecule thirteen transitions between 80 and 240 GHz were detected in the ground vibrational state, covering JK = 2K − 1K up to JK = 6K − 5K with K = 0, 1, 2. Some transitions exhibit noticeable structure that is attributed to internal rotation splitting. As the CN radical and several of its hydrogenated and protonated forms up to methylamine, CH3NH2, are well known entities in the laboratory and in space, protonated methylamine, CH3NH3+, is a promising candidate for future radio astronomical detection.

We report the first extragalactic detection of the higher-order millimeter hydrogen recombination lines (Δ n > 2). The γ -, ϵ -, and η -transitions have been detected toward the millimeter continuum source N 105–1 A in the star-forming region N 105 in the Large Magellanic Cloud with the Atacama Large Millimeter/submillimeter Array. We use the H40 α line, the brightest of the detected recombination lines (H40 α , H36 β , H50 β , H41 γ , H57 γ , H49 ϵ , H53 η , and H54 η ), to determine the electron temperature and study ionized gas kinematics in the region, and the 3 mm free–free continuum emission to determine the physical parameters: the size, emission measure, and electron density. We compare the physical properties of N 105–1 A to a large sample of Galactic compact and ultracompact (UC) H ii regions and conclude that N 105–1 A is similar to the most luminous ( L > 10 ^5 L _⊙ ) UC H ii regions in the Galaxy. N 105–1 A is ionized by an O5.5 V star; it is deeply embedded in its natal molecular clump, and likely associated with a (proto)cluster. We incorporate high-resolution molecular line data including CS, SO, SO _2 , and CH _3 OH (∼0.12 pc), and HCO ^+ and CO (∼0.087 pc) to explore the molecular environment of N 105–1 A. Based on the CO data, we find evidence for a cloud–cloud collision that likely triggered star formation in the region. We find no clear outflow signatures, but the presence of filaments and streamers indicates ongoing accretion onto the clump hosting the UC H ii region. Sulfur chemistry in N 105–1 A is consistent with the accretion shock model predictions.

Context. The G31.41+0.31 Unbiased ALMA sPectral Observational Survey (GUAPOS) project targets the hot molecular core (HMC) G31.41+0.31 (G31) to reveal the complex chemistry of one of the most chemically rich high-mass star-forming regions outside the Galactic center (GC). Aims. In the third paper of the project we present a study of nine O-bearing (CH3OH, 13CH3OH, CH318OH , CH3CHO, CH3OCH3, CH3COCH3, C2H5OH, aGg′-(CH2OH)2, and gGg′-(CH2OH)2) and six N-bearing (CH3CN,13CH3CN, CH313CN, C2H3CN, C2H5CN, and C2H513CN) complex organic molecules toward G31. The aim of this work is to characterize the abundances in G31 and to compare them with the values estimated in other sources. Moreover, we searched for a possible chemical segregation between O-bearing and N-bearing species in G31, which hosts four compact sources as seen with higher angular resolution data. In the discussion we also include the three isomers of C2H4O2 and the O- and N-bearing molecular species NH2CHO, CH3NCO, CH3C(O)CH2, and CH3NHCHO, which were analyzed in previous GUAPOS papers. Methods. Observations were carried out with the interferometer ALMA and cover the entire Band 3 from 84 to 116 GHz (~32 GHz bandwidth) with an angular resolution of 1.2″ × 1.2″ (~4400 au × 4400 au) and a spectral resolution of ~0.488 MHz (~1.3–1.7 km s−1). The transitions of the 14 molecular species were analyzed with the tool SLIM of MADCUBA to determine the physical parameters of the emitting gas. Moreover, we analyzed the morphology of the emission of the molecular species. Results. The values of abundances with respect to H2 in G31 range from 10−6 to 10−10 for the different species. We compared the abundances with respect to methanol of O-bearing, N-bearing, and O- and N-bearing COMs in G31 with 27 other sources, including other hot molecular cores inside and outside the GC, hot corinos, shocked regions, envelopes around young stellar objects, and quiescent molecular clouds, and with chemical models. Conclusions. From the comparison with other sources there is not a unique template for the abundances in hot molecular cores, pointing toward the importance of the thermal history for the chemistry of the various sources. The abundances derived from the chemical models are in good agreement, within a factor of 10, with those of G31. From the analysis of the maps we derived the peak positions of all the molecular species toward G31. Different species peak at slightly different positions, and this, together with the different central velocities of the lines obtained from the spectral fitting, point to chemical differentiation of selected O-bearing species. [ABSTRACT FROM AUTHOR]